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The need for an integrated approach to optimization of unit operations in both the pit and the mill has long been recognized, but the complexity and nature of the overall problem has up to now resisted solution. This paper reports on a modeling methodology which couples symbolic and numeric computing to unify operations in both the pit and mill. The ultimate goal of this work is to optimize all operations that are influenced by blasting. Blasting plays a key role in all facets of operations. Obviously, drilling and blasting costs are determined by blast design, but the down-stream costs that are closely related to blasting results are often treated as separate functions: loading, hauling, cleanup, and crushing and grinding are all heavily influenced. Diggablilty and bucket fill factor are a function of fragmentation, the condition of the floor and uniformity in the shape of the muck pile. Likewise, cycle times and loading delays partially determine haul cycles, while fragmentation distribution and size determines the efficiency of truck loading. Removal and breakage of oversize causes loading delays and increases cleanup costs. The influence of blasting doesn't stop at the crusher. Mill productivity, power consumption, and maintenance are a function of the feed. Even at the SAG mill a reduction of a critical particle size during blasting can increase throughput. Thus, a bottle-neck for production far removed from unit operations in the pit can be alleviated by a modification in blast design. The question is: how do we optimize blasting with respect not only to itself but to al\ related mining and milling operations? For that matter, how do we even model blasting so that we can control the results of a blast?

Jan 1, 1991

By N. S. Dalal, Xianglin Shi

Metal ions, such as chromium (Cr) and vanadium (V) are found as trace impurities in mineral dust. Since metal ion mediated free radical generation has been implicated in many disease processes, we carried out a detailed investigation of the metabolism of these metal ions by biological redox systems and the possible oxygenated radical generation therefrom. We found that highly reactive Cr(5+) species are generated in the reduction of Cr(6+) by NADPH-dependent glutathione reductase, lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase. The reduced metal ion species react with hydrogen peroxide, to generate hydroxyl (•OH) radicals in a continuous cycle. The enzymatic catalysis processes also involves the reduction of molecular oxygen to the superoxide [(0-1 2)] radical. Thus only a trace amount of metal ions chemisorbed on mineral dusts, such as quartz, can catalyze the generation of the highly toxic oxygenated radical species from cellular hydrogen peroxide, suggesting a new biochemical mechanism for mineral dust induced chronic lung injury.

Jan 1, 1991

By Q. Xu

Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied with sodium dodecylsulfate as the anionic surfactant and octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactant was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in wettability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant molecules at the interface.

Jan 1, 1991

Increase the productivity of domestic mining operations by improving the performance of rock drilling systems. Approach Investigate the use of chemical solutions at zero surface charge concentrations as drilling fluid additives to enhance penetration rates and extend bit life. Background Bureau researchers have investigated the use of chemical additives to enhance drilling performance and have found that the most efficient drilling occurred when the drilling fluid was able to maintain a zero surface charge (ZSC) on the rock surface. Laboratory drilling studies using 5/8-inch diameter diamond-impregnated coring bits on rock types such as quartzite, granite, taconite, and marble. Cationic compounds were used as the surface charge neutralizing additives during these tests. The drilling studies demonstrated enhanced drilling performance, however, only at the singular additive concentration that produced the ZSC condition. Bureau researchers made a breakthrough when they found that polyethylene oxide, although a nonionic polymer, was able to maintain the ZSC condition over a wide range of concentrations. Success using polyethylene oxide as the drilling fluid additive during subsequent laboratory tests prompted testing under field conditions.

Jan 1, 1991

By G. H. Khoe

Neutralisation of acid uranium mill tailings with lime or other alkaline materials is usually practised to reduce the dissolved concentration of heavy metals and radio nuclides. Computer modelling of this process was carried out using the geochemical equilibrium code MINTEQA2. Computed dissolved metal and sulfate concentrations were compared with laboratory-based experimental data. It was found necessary to include the modelling of adsorption of trace metals (such as uranium and lead) by the precipitated ferric hydroxide in order to obtain acceptable concentrations in the neutralised liquors. There were limitations of the modelling exercise due to important aspects which were not addressed or properly accounted for such as chemical reaction kinetics and the effect of high ionic strength. These are discussed in the paper.

Jan 1, 1991

By Luis R. Bittencourt

Research efforts have been made to characterize a refractory Brazilian bauxite ore composed basically of gibbsite, kaolinite and quartz. Detailed polished-section microprobe analysis of the unbroken ore has been used to describe the liberation characteristics and the association between mineral phases. The linear grade distributions for selected particle size fractions were determined by means? of a particular implementation of King's Random Fracture Model that uses the exponential model for the distribution of linear intercepts through both dispersed (kaolinite) and continuous (gibbsite) phases. The corresponding volumetric grade distributions were then determined by means of a constrained optimization technique for the solution of the transformation equation. Batch flotation experiments were carried out to determine the kinetics for particles of different sizes and the results correlated with the liberation spectrum for each size class.

Jan 1, 1991

Dynamic permeability is a significant hydrologic condition associated with in-situ leaching at the Cyprus Casa Grande operations. Several factors contribute to changes in the permeability conditions. They are: 1) hydraulically induced fracture development, 2) geochemical changes during leaching in the rock matrix, and 3) changes in the relative degree of saturation of the deposit. Dynamic permeability conditions were evaluated using available pressure and flow rates from the 58 injection and recovery wells obtained over one year period. A finite element, 2-D hydrologic model called INVERT which is designed to estimate aquifer parameters under transient and steady state flow conditions was used for the investigation. The permeability conditions during 7 different steady state intervals throughout the one year time frame were determined. The results confirm that big changes in permeability occur as a function of time as well as a function of injection pressure condition.

Jan 1, 1991

By R. L. Grayson

Compliance standards for respirable dust, which are reduced because of high quartz concentrations, have become an industry-wide problem. Research on the physical and chemical character of quartz-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may he coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quartz particles of a mine dust are "pure," then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should he lowered. If, however, the quartz is locked inside another material matrix, or coated, a reduced compliance standard may not he appropriate.

Jan 1, 1991

By William A. Apel

Several different strains of bacteria have been shown capable of reducing hexavalent chromium, Cr(VI), to Cr(III), a less toxic, .. more readily recoverable form of Cr. This paper examined the Cr(VI) reduction efficacies of 3 different Cr(VI) reducing bacteria: Pseudomonas f1uorescens LB300., Pseudomonas aeruginosa PAOI, and Pseudomonas aeruginosa PAOI (pCROI) It was demonstrated that all three bacterial stratns reduced Cr(VI) primarily during their exponential growth phases while using glucose as their carbon and energy source. Significant differences in the three organisms' Cr(Vl) reduction capabilities depending on initial Cr(VI) concentrations were also demonstrated. P. aeruginosa PAOI showed superior Cr(VI) reducing capabilities over the. entire range of Cr(VI) concentrations tested while the Cr(VI) reduction capabilities of the other two strains were increasingly inhibited as Cr(VI) concentrations increased.

Jan 1, 1991

By Martin L. Smith, Robert L. Hautala

The objective of blast optimization can be approached either in a qualitative sense of designing a blast which will be "trouble free", or quantitatively in the sense of minimizing overall mining costs. Blast design simulators and fragmentation models have become an accepted tool in blasting over the last decade. Numeric simulators are very useful for solving quantitative problems, but are limited in their ability to address more qualitative problems such as post-blast bench condition. Also, current blasting models are limited by the complexity of site-specific blasting and are not functionally suited to mathematical optimization. As a result a great deal of expertise is still needed in optimizing a blast. The following describes the application of an expert system approach to integrating both a symbolic model of the expertise of the blasting engineer for attaining a trouble free blast, and a numeric optimization model relating fragmentation to unit operations from drilling to grinding. Research into this application of a coupled modeling approach to blast design is being carried out to develop a modeling methodology which will provide a suboptimal design for qualitative design goals as well as minimizing blast related costs.

Jan 1, 1991

By R. G. Reddy

To better understand the behavior of bacterial-mineral interfacial reactions, a thermodynamic model based on the- studies of bacteria adhesion on mineral surfaces has been evaluated. The bacteria adhesion to the mineral surface would be increased by l ' d1;1creasing the change in Gibbs free energy of adhesion and it would be reduced if the change in Gibbs free energy of adhesion of the system is increased. From the combination -of Young's equation and equation of state, the change in Gibbs free energy of adhesion -for bacterium-mineral system- was calculated. Influence of liquid surface tension, mineral surface tension on the change in Gibbs free energy of adhesion and consequently bacteria behavior on mineral systems- has been discussed.

Jan 1, 1991

By W. R. Sharp

The ability to target, delineate, excavate, and produce local resources is essential to the establishment of man's long-term presence in space. Many procedures and equipment utilized to mine resources here on Earth may be directly applicable on the lunar surface, while others may need extensive redefinition and development. This paper compares, for a lunar base, the alternative of burrowing into and below the lunar surface with that of surface mining. A conceptual underground mechanical excavator is presented.

Jan 1, 1991

By W. A. Crosby

All mine operators using explosives want to maximize explosive performance while minimizing blasting costs. Use of bulk explosive products such as AN/FO, heavy AN/FO, slurries and emulsions has greatly improved blasting efficiency over the years. Many operators have improved energy output from these products by adding aluminum. A major problem facing them is the fluctuation in aluminum price. The question therefore becomes, when is it economically advantageous to use aluminum in bulk products? This paper answers this question by first reviewing the energy output from the main types of aluminized and non aluminized bulk mixed explosives and then by showing the relationship between the different products on a cost and energy basis. The paper finally presents examples of charts and tables which will aid mine operators to conveniently select the most economically correct bulk explosive, including the level of aluminum addition.

Jan 1, 1991

By D. M. Hausen

A refractory siliceous low-grade silver ore (265 g/t Ag) from a prospect in Sonora, Mexico was investigated mineralogically and metallurgically to evaluate extraction of the silver by conventional methods. Approximately half of the silver was recoverable, occurring as coarsely crystalline acanthite (70-300 Am) that was liberated in material crushed to minus 10 mesh. The remaining silver is refractory and occurs mostly as finely locked (-2 to 0.2 Am) acanthite in cherty quartz, and as minor amounts of finely disseminated stylotypite or freibergite in fluorite. The mineralogic data have thus served to explain the 50-60% recovery of silver by flotation and cyanidation.

Jan 1, 1991

By Bogidar V. Mihaylov

Bacterial oxidation of a low-grade sulfide gold ore was investigated in order to enhance leaching of gold. The experiments were carried out in columns using mixed cultures of Thiobacillus ferrooxidansisolated from the ore. Fractions with different screen analyses were oxidized in two regimes - one pass of the solution and circulating, solution. Constant temperature and flow-rate of the percolating solution were maintained during the experiments. A correlation between the concentrations of copper and iron in the solution leaving the columns and pH and Eh values was observed. The effect of bacterial activity was proved by means of thiourea and cyanide leaching of the oxidized ore.

Jan 1, 1991

By Denise A. Herzog

The U.S. Bureau of Mines conducted a study of cyanide leach technology used in Alaska's mineral industry from 1987 through 1990. Literature and cost data were obtained for mines in the contiguous United States, Canada, and Alaska that use cyanide to recover gold and silver. The data was compiled in an effort to evaluate the economics and conditions associated with cyanide use in Alaska. This report discusses heap leaching methodology and evaluates a "typical" heap leach operation in Nevada and compares the results of the Nevada operation to an analogous hypothetical mine in Interior Alaska. Five daily tonnage rates were analyzed for both the Nevada and the Alaska operations to evaluate the spectrum of economic possibilities. The discounted cash flow rate of return (DCFROR) for each production rate was then evaluated in terms of recoverable metal value (RMV). The Nevada RMV for each production rate was then compared with its Alaskan counterpart, and the results averaged. The Alaskan production costs are an average of 1.71 times greater than costs associated with mining in Nevada at a 0% DCFROR. At 15% DCFROR, costs in Alaska are 2.01 times greater than those in Nevada. Costs are higher in Alaska because of the shorter leaching season, increased labor and transportation costs, and heavier precipitation and vegetation.

Jan 1, 1991

By A. Bhattacherjee

Industries in general and the mining industry in particular have become more safe than ever before. However, there is a need to increase the search for the causes of mining work-related injuries and to contribute to their reduction through job design, work procedures, and worker training. Mine accident and hazard control has to be practiced in a manner which is consistent with the overall objectives of the mine management, among which are the optimum allocation and effective utilization of the resources. The purposes of this paper are to (i) review the role risk analysis in safety management with references from mining and other industries; (ii) discuss the risk measures appropriate for injury analysis; (iii) present a set of analytical tools to injury experience data in under-ground coal mines; (i v) apply these tools on case study example; (v) discuss the results of the case study; and (vi) amplify the application limitations and the future research needs.

Jan 1, 1991

By K. Englehardt

J BERESFORD introduced the subject of the paper which is the use of polymeric slurries to support the sides of diaphragm wall and bored pile excavations during construction. In the opinion of the authors the use of a suitable polymeric fluid offers financial and technical advantages compared with traditional bentonite based slurries. Under quiescent conditions a support slurry must have the following properties. - sufficient viscosity to support the sides of the excavation, to prevent infiltration into soils and to hold loose soil particles in suspension. - when agitated it should thin quickly to assist pumping transfer and cleaning and allow free passage of the grab or drill. - viscosity should be low enough during concreting to facilitate placement but high enough to prevent contamination of the concrete.

Jan 1, 1991

By J. Howarth

Two electrochemical processing methodologies have been used to electrogenerate bromine-laden solutions for gold-leaching purposes. In the first process, a laboratory-scale cell in which the anode and cathode compartments were separated by a cation-exchange membrane was employed. The bromine produced by electrolysis of a 4% bromide solution was used to leach gold from a low-grade ore. The pregnant leach solution was then returned to the cell to recommence the cycle. High current efficiencies (90-93%) were maintained over six cycles. In the second process, an undivided hypochlorite generating cell (Chloropac"') was used to generate bromine from a simulated leach solution. Electrolyses were performed on a pilot-scale (100-150 gallons) with solutions containing different levels of bromide ion. The current efficiencies were also high (80-90%) and unaffected by the bromide concentration (over the range 2.5-5%) provided the electrolysis was run to low conversion « 15%). The Chloropac module was capable of delivering 0.6 kg bromine per hour at a power cost of $0.09 per kg. Using these figures, a detailed economic assessment for a 1000 metric tonnes (MT) per day gold ore processing plant was made. Electrolytic regeneration of bromine in a gold leach/recovery circuit dramatically improves the process economics over cyanidation.

Jan 1, 1991

By J. E. Hamak

This publication contains analyses and related source data for 144 natural gas samples from 19 States. Of the total samples, 139 were collected during calendar year 1990. The remainder were collected earlier, but releases granting permission to publish were not received until 1990. All samples were obtained and analyzed as part of the U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free-market economies. This survey has been conducted since 1917. The analyses were made by mass spectrometer and chromatograph.

Jan 1, 1991