Search Documents

By Donald I. Bleiwas

The U.S. Bureau of Mines has evaluated the potential availability of nickel from 36 deposits or districts in 16 market-economy countries (MECs), analyzing more than 95 percent of production in those countries. This study indicates the quantity of nickel available on the basis of net production costs and total costs with a 0-pct and a 10-pct discounted cash flow rate of return (DCFROR). Costs of production are expressed in dollars per pound of recovered nickel. The study also indicates sensitivities of the cost of production to energy, labor, and other factors. The studied deposits and properties contain approximately 33 Mmt of recoverable nickel. About 26 Mmt of nickel is potentially recoverable from laterite deposits, of which 4.5 Mmt can be produced at $2.50/lb or less with a 0-pct DCFROR. Approximately 7 Mmt of nickel is potentially recoverable from sulfide deposits, of which about 6.3 Mint could be produced at $2.50/lb or less at a 0-pct DCFROR. The price of nickel averaged above $6.00/lb in 1988. Sensitivity studies performed for both laterite and sulfide deposits indicate that the total cost of producing nickel from laterites is most sensitive to increases in energy costs and that the total cost of producing nickel from sulfide deposits is most sensitive to increases in labor costs; sulfides are also affected by changes in revenues from byproducts.

Jan 1, 1991

By T. Sakaguehi

Some attempts were made to recover and remove of uranium that may be present in refining effluents, mine waste Water, and other waste sources by using microbial biomass. To establish which microorganisms accumulate the most uranium, 135 species of microorganisms (42 bacteria, 26 yeasts, 34 fungi and 33 actinomycetes) were screened. Of these 135 species of microorganisms tested, extremely high uranium absorbing ability was found in Pseudomonas stuzeri, Neurospora sitophila, Streptomyces albus and Streptomvces viridochromogenes. In addition to the research on uranium uptake, thorium recovery by using microorganisms was investigated. High abilities were found in Streptomyces levoris and Bacillus subtilis. The selective accumulation of heavy metal ions by various microorganisms has also been examined. Uranyl, mercury and lead ions were readily accumulated by almost all of the species of microorganisms tested. Actinomycetes and fungi differ from many bacteria and most yeasts in their selective accumulation of uranium, and mercury. The basic features of uranium uptake by Streptomyces viridochromogenes, a microorganisms with high uranium-uptake ability, were investigated systematically. Synthesizing these results, we suggested that the accumulation of uranium into these microbial cells is not directly mediated by any metabolic process:, but almost completely dependent upon physicochemical adsorption on the cell components. In addition to this fundamental research, uranium recovery was investigated in immobilized Streptomyces viridochromogenes. These immobilized cells adsorbed, uranium readily and selectively. The immobilized cells recovered uranium almost quantitatively and almost all uranium adsorbed was desorbed with 0.1 N Na2CO3, These results showed that microbial cells are more stable after Immobilization and can be used repeatedly for the process of uranium adsorption-desorption. These results suggested that these microbial cells can be used for the recovery and removal of nuclear fuel elements, such as uranium and thorium, from refining effluents and mine waste water.

Jan 1, 1991

The epithermal Au-Ag deposits of the Hauraki Goldfield have formed in the convergent plate margin setting of the Coromandel Volcanic Zone (CVZ). The deposits form as siliceous lodes in the upper parts of geothermal systems associated with andesitic and rhyolitic volcanism. Two types of low sulphidation epithermal mineralisation are recognised in these volcanic terranes. Vein deposits within the rhyolitic terrane in the east and south of the CVZ (Whitianga Province) are typified by Chalcedonic Silica-Adularia-Illite type mineralisation. The veins are hosted by both rhyolite-dacite volcanic rocks and the underlying andesitic basement. The mineralisation formed by episodic violent decompressional boiling of deeply circulating meteoric water, with some magmatic fluid contribution; this boiling was associated with hydraulic fracturing and hydrothermal eruptions in geothermal systems where the piezometric surface of the deep geothermal reservoir lay near-surface. Such episodic boiling provides chalcedonic veining, banding and brecciation textures, adularia stability, bladed calcite, and extreme loss of H2S gas from the fluid to cause major gold deposition.   Crystalline Quartz-Illite-(Adularia-Kaolinite) type mineralisation is widespread in the andesitic terrane forming the northern and western portions of the CVZ (Kuaotunu Province). There is a spatial association with weak mineralisation of the high sulphidation (Vuggy Silica-Alunite-Kaolinite-Illite) epithermal type and porphyry eu-Au type. Crystalline Quartz mineralisation is probably formed by the mixing of shallow acidic groundwaters with the ascending deep geothermal fluid in geothermal systems beneath andesitic stratovolcanoes. The piezometric surface to the deep geothermal reservoir in these systems is likely to lie at considerable depth, with acidic gases rising from the geothermal reservoir condensing within the overlying vadose zone. The cooling effect, oxidation and pH decrease accompanying mixing apparently overcomes the dilution effect, and results in quartz deposition, illite (and locally kaolinite) alteration, and precipitation of gold. A high level of base-metal sulphide precipitation also enhances gold deposition. Violent boiling of the mixing fluids may occur at local structural dilation sites, producing high grade "bonanza" gold mineralisation.

Jan 1, 1991

By R. G. Reddy

Viscosities of Feo-SiO2 slags were calculated using the previously developed structural based model. An expression was derived using hole theory and the atomic pair model to relate the NO0 and temperature to the viscosity. The deduced equation n=4.9x10-9 T1/2 NO0 exp (E/RT) poise was successfully applied to predict the viscosity of FeO-SiO2 slags in the composition range of 0.1 < XSiO2 < 1 for several temperatures. The calculated data agrees well with the experimental viscosity data.

Jan 1, 1991

By E. G. Noble

Microbial leaching is being investigated as a method for recovering the metal values from a domestic low-grade manganese wad ore. Early work showed that heterotrophic microorganisms present in the ore solubilized manganese when cultured in a glucose-mineral salts medium. More recent shake-flask tests using molasses as the sole nutrient source extracted 97 pct of the manganese from minus 300- µm ore in 4 weeks. Column bioleaching with the molasses medium solubilized 99 pct of the manganese from minus 6.3-mm ore in 50 weeks. The results of flask, column, and lab-scale heap bioleaching studies are presented.

Jan 1, 1991

By D. G. Willard

The U.S. Department of Interior, Bureau of Mines has evaluated the potential resource and annual availability of cobalt from 27 deposits or districts in 11 market-economy countries. More than 95 pct of primary cobalt production from market-economy countries, mainly byproduct output from copper and nickel operations, was analyzed. Approximately 1,200,000 mt of cobalt is potentially recoverable at the demonstrated resource level. Very large additional resources exist, especially in laterite deposits, but are at the inferred level. The producing operations evaluated in this study are expected to produce about 19,000 mt of cobalt in 1989, significantly less than the available capacity of about 31,000 mt. More than 14,000 mt per year of cobalt is produced from copper-cobalt deposits in Zaire and Zambia, of which 11,000 mt can be produced at a copper price of $O.60jlb or less with a O-pct discounted cash-flow rate of return (DCFROR). Approximately 4,400 mt of cobalt is produced annually from nickel-cobalt deposits in six countries, of which about 1,800 mt (in Canada and Brazil) could be produced at a nickel price of $1.50jlb or less at a D-pct DCFROR. Approximately 200 mt per year of cobalt is produced from a cobalt mine in Morocco. Most of the evaluated nonproducing operations and prospects that could potentially produce cobalt as a principal product or byproduct would require a total cost (including a 15 pct-DCFROR) significantly exceeding January, 1989 market prices of the principal commodities. Principal-commodity dependence, transportation routes, cobalt toxicity, and other issues that could affect the availability of cobalt are addressed herein.

Jan 1, 1991

By Cen Guoji

The foundation of bored pouring concrete pile have been adopted in the bridge engineering of China since early in the sixties. They demonstrated tremendous technical advantage and achieved notable economic benefit. With improvement of bridge technique including construction technique work equipment, design theory, examination in quality and applicable range etc, the pile diameter became bigger and the foundation changed from shallow to deep-water. This paper examples Jiujiang Bridge of Guangdong in China, which is single-tower cable-staged bridge, total length of 1675m, and expouds adopted successfully the foundation of variable section large bored pile (upper part d=3m, central part d=2. 4m and lower part d=2m) on the conditions of complicated technique that the load is tremendous (it require specially to resist 12000 kN ship impact) and the piles have free length 30m. The paper will be to describle design project and construction practice of pile foundation with variable section, and to compare schemes of equal section pile and pile in sinking-well.

Jan 1, 1991

By Hang Goo Kim

A computer simulation has been carried out to predict the distribution behavior of minor elements such as Pb. Zn, Bi, Sb and As in recently proposed copper smelting and converting processes with submerged oxygen injection in which tonnage oxygen is used with a shielding gas. In this study the technique of stepwise equilibrium modeling was employed and some of the thermodynamic data were updated or reassessed. The volatilization and slagging of undesirable elements were investigated in copper smelting (steady-state) system, copper matte converting (batch) system, and the combined (smelting + converting) system at extremly high oxygen-enrichment levels. The predicted minor-element behavior under high oxygen- enrichment was compared with that in the Noranda process (normally 42% oxygen-enrichment in smelting and 24% in converting) and the reverberatory process using air. The effects of various operating parameters such as temperature, the final matte grade in smelting, the initial matte grade in converting and the O/Fe ratio in slag on the behavior of minor elements are discussed.

Jan 1, 1991

By Leahy G. J, Moxon N. T, Nicol S. K

Experimental work is described in which extremely dilute aurocyanide liquors are treated with novel surface-active complexing agents to produce a hydrophobic aurocyanide species. Subsequent aeration of these liquors causes accumulation of such species at the air-water interface and the aurocyanide complex is transferred to a froth concentrate. A detailed performance assessment of this process is made and this knowledge used in the design of a pilot plant facility. Early results indicate the feasibility of the selective recovery of aurocyanide ions from reclaimed residue dam water (approximately 0.2ppm Au) with upgrade ratios of the order 180:1. A further study was made applying ion flotation to the recovery of gold from a carbon-in-pulp (CIL) feed liquor (approximately 1.0ppm Au). The probable economics of this process compared to conventional CIL processing is also described. Successful development of countercurrent ion flotation for concentrating solids-free gold solutions may offer a lower cost alternative to existing gold ore processing technologies, or in more secondary applications such as concentrating dilute gold solutions or heap leach runoff. The technology may also have more generalised applications to other heavy metal process- Ing.

Jan 1, 1991

By D. L. Yopps

Platinum-group metal (PGM) flotation .. concentrate from the Stillwater Complex, MT, was subjected to biooxidation using Thiobacillus ferrooxidans in an effort to break down the sulfide minerals and liberate the ? associated PGM&apos;s for subsequent chemical leaching. Bacterial treatment oxidized up to 94 pct of the sulfide present, destroyed the PGM-bearing pentlandite [ (Ni,Fe),9Ss) mineralization, and dissolved most of the nickel in the concentrate. Results showed that increased sulfide oxidation during the biological stage led to improved PGH recovery in the subsequent. chemical leaching stage. cyanidation at 80° c proved to be the best chemical leachant tested. It removed 7.6 pct of the palladium, 94 pct of the rhodium, 97 pct of the gold, but only 34 pct of the platinum from the biooxidized concentrate.

Jan 1, 1991

Bolivia, due to its turbulent past with a history of constant military coups, has given an image of complete instability to the foreign investor. The effects of this have been several fold, the major one resulting in a complete lack of exploration in modern terms since their revolution in 1952. What was overlooked by the foreign investor was the fact that revolution produced Agrarian Reform which is the foundation of the stability which Bolivia enjoys today. Another factor that is overlooked is the fact that its past history is one of vast mining fortunes having being made. Their political problems resulted in economic chaos in 1985 with an annual inflation rate of 26,000 percent. This resulted in the collapse of the government but the democratic process continued. Then came the so-called"South American Miracle" in 1986 when the government of Dr. Paz Estenssoro enacted an extremely harsh austerity program which consisted of the abolition of wage and price controls, the abolition of monopolies, the right to hire and fire, the weekly auctions of dollars and the free convertibility of currency which yielded a stable government with 8 percent inflation. This was followed by massive personnel reductions in the various mines and other industries.

Jan 1, 1991

By John Pilling

The concept of microstructure, its evolution through materials processing and its effect on the properties of the material is, perhaps, the foundation upon which the science of materials is built. PHAUST, a computer aided learning program, attempts to provide instruction in establishing the relationships between phase diagrams, thermal processing and microstructure. Using phase diagrams derived from a database or created by the user, the evolution of microstructure during processing is quantified using the lever rule and/or the Scheil equation and tracked through a doubly linked list (a form of binary tree). Microstructures, in the form of full colour cartoons are then drawn using the quantitative and logical information contained within the linked list using bitmapped templates and logigal operators such as NOT. AND, OR and XOR, giving the student a view of the structure as it would be seen under the optical microscope. The software provides complete diagnostics of student answers, locates errors and misconceptions as well as providing tutoring towards the correct solution method and answer.

Jan 1, 1991

By R. G. Reddy

Viscosities of alkaline metal oxide-silicate melts were estimated using our previously developed mathematical model. The structural based model considers depolymerization effects and related breakdown of the silicate network structure, on the addition of metal oxides to the melt. The developed expression: n =4.9x10 9 NO 0 T ½ exp(E/RT) poise was used to calculate the viscosities of various binary silicate systems such as, CaO-SiO,, MgO-SiO, and MnO-SiO,, as a function of temperature and composition. Excellent agreement was obtained between the calculated and experimentally determined viscosities.

Jan 1, 1991

By Robert F. Chaiken

Burnout Control is a process developed by the U.S. Bureau of Mines for accelerating the burning of wasted coal fires in situ, while at the same time controlling the heat and fumes produced. The Albright fIre project is a fIrst fIeld trial of Burnout Control as applied to a coal waste bank. An exhaust ventilation system was designed and constructed and then operated over a 1-year period at the site of an existing abandoned mine land fire near the town of Albright, WV. While predicted exhaust gas temperatures of 900° C and thermal power levels of 5 MW were achieved at 20-to 3O-in H20 vacuum levels, problems were encountered with engineering designs, equipment breakdown, and fuel-rich combustion that curtailed the time period of satisfactory operation. Effective afterburning of the exhaust gases (as they were drawn from the bank) corrected the problems associated with combustion stoichiometry and led to high thermal outputs. It is believed that with (1) improvements in engineering design and construction, (2) better control of the afterburning process, and (3) the use of conventional stack gas air-pollution controls, Burnout Control can be applied successfully to a coal waste bank fire.

Jan 1, 1991

By E. G. Noble

The potential for using heterotrophic microorganisms to solubilize manganese from low-grade domestic ores is being assessed at the Reno Research. center, U.S. Bureau of Mines. More than 90 pct of the manganese has been extracted from a variety of oxide ores in shake-flask tests using molasses as a source of .. nutrients for the microorganisms. It has also been demonstrated that high recoveries of manganese can be obtained from a domestic wad ore using column bioleaching. &apos;l&apos;he isolation and identification of organisms responsible for manganese extraction is discussed, as are the mechanisms responsible for manganese solubilization.

Jan 1, 1991

By D. P. Gold

Major sources and reserves of Cb/Nb, Ta, REE, Y, Sc, Zr, Hf, Cu, apatite and vermiculite may be concentrated in primary and secondary minerals associated with different stages and depths of emplacement in carbonatite complexes and kindred alkalic intrusive rocks. Exploration targets include: apatite and pyrochlore (Nb) in the plutonic and hypabyssal core and ring-dikes: bastnaesite (REE), strontianite, barite and fluorite in hydrothermal veins and cone-sheets (subvolcanic setting): thortveitite (Sc,Y) and vermiculite in metasomatized aureoles (fenites): high grade eluvial deposits of apatite and pyrochlore, and secondary REE, Nb, Ti. and V-minerals in supergene and weathered zones.

Jan 1, 1991

By L. Betteridge, A. Marks

"An OK 300 cu. ft. Skim - Air cell was installed at the HBM&S concentrator in Flin Flon in 1987. Since that time, 3 additional OK Skim - Air cells have been installed in HBM&S concentrators. The cell treats a coarse 70% solids slurry with a residence time of 2.5 minutes. The product from the cell (a unit cell type application) is a final grade copper concentrate with high precious metal values. Since its installation, the cell has improved gold recovery by 10 - 15%. Process variables such as circulating load, pH, froth depth, feed size, and reagent additions all have an effect on the operation of the cell. Maintenance on the cell has been minimal. Initial operating problems involving level control have been significantly reduced and operations are now relatively trouble free. Although very successful at Flin Flon, site specific operating circumstances will determine the suitability of this cell. INTRODUCTIONHudson Bay Mining and Smelting operates four concentrators in Northern Manitoba. Three treat copper-zinc ores, the fourth mills a copper-nickel ore. The Flin Flan concentrator operates two circuits in parallel which treat copper and zinc ores from the Trout Lake and Callinan mines. Both circuits in the Flin Flan mill have Skim-Air cells integrated into the grinding circuits.The Trout Lake cell was installed first and had a payback period of a few months. Required modifications to the cell were made to enhance its performance. These included changing the discharge valve size, tuning the level controller, and installing an insert into the rubber valve sleeve to increase its wear life. The payback period on the Callinan cell was significantly reduced because these modifications were completed prior to its installation.The cells produce a final grade copper concentrate and since their installation gold and silver recoveries to the final copper concentrate have increased significantly. Operating parameters such as coarseness of cell feed dictate the metal recoveries and froth depth determines the selectivity of the cell and therefore the grade of the concentrate.The Skim-Air cell can be suitable in applications where a final product is generated. However, when a bulk concentrate, which requires further separation, is produced, the coarseness of the product may not make it amenable to conventional flotation.The Flin Flan mills Skim-Air cells have worked exceptionally well with little maintenance required."

Jan 1, 1991

By Jinrong Zhang

Fresh cyanide solution was treated by near UV light with the assistance of photocatalysts. Cyanide was oxidized mainly to cyanate. Photochemical behavior of the anatase and rutile forms of TiO2 was compared. It is found that anatase has a much higher activity than that of rutile. Bubbling of oxygen in the reactor showed no appreciable increase in cyanide oxidation, implying that the reaction is surface controlling. A very interesting finding in this study is that a natural mineral, ilmenite, can replace chemical titanium dioxide as the photocatalyst. Ilmenite without any treatment did not catalyze the oxidation of cyanide. But, after being roasted at high temperature with oxygen, the oxidation was enhanced dramatically. The mechanisms of photooxidation of cyanide and the roasting of ilmenite are proposed.

Jan 1, 1991

By Joseph Matoney, B. K. Parekh

INTRODUCTION The term "dewatering" refers to removal of water from coal. Water associated with coal can be categorized as "free or surface" and "inherent or chemically bound" moisture.&apos; The free moisture is found on the surface of coal, in capillaries and small spaces between two or more particles. The inherent or chemically bound water is found in the interior of the coal and as part of coal structure. A significant amount of free moisture can be removed by mechanical dewatering techniques. However, inherent moisture can only be removed by applying energy intensive techniques, e.g., direct or indirect heating. Moisture in the coal offsets some of the benefits of coal cleaning. Extra water in clean coal adds to extra cost in transportation, heat lost during vaporization, and plugging of chutes. From a utility perspective, a 1 % increase in moisture can offset a 4.5% decrease in ash.2 Mechanical dewatering can be classified into two major process categories according to the principles involved, namely, 1. Sedimentation-liquid is constrained and particles move freely. 2. Filtration-particles are constrained by a medium and the liquid flows through. Each of the process categories is composed of various separation techniques shown in Fig. Equipment currently being used by the mechanical dewatering of coal of varying size ranges and final moisture content is illustrated in Fig. 8-2. This figure indicates that sizes larger than 13/, in. (37.5 mm) present no particular dewatering problem. Shaker screens of the very crudest types and designs are capable of producing these sizes at low surface moistures. High-speed vibrators are used for the intermediate sizes and can be used for smaller sizes down to 0.02 in. (0.5 mm) if high moistures (15% surface moisture or greater) can be tolerated in the product. Usually, however, the vibrator is not used below 3/, to 3/, in. (9.5 to 6.3 mm) because of the moisture associated with these fine sizes. At this level, centrifugal force is usually employed to aid dewatering. Centrifuges of various types and designs are used practically

Jan 1, 1991

A strategy is presented for a relatively. "low-tech" means for decontamination of streams . containing .low concentrations of toxic metals. Metal ion solutions were . circulate through fluidized beds of activated carbon which support bio-films ?of bacteria .that naturally excrete exopolysaccharides. The attached &apos;biomass is shown to significantly enhance nickel, cadmium and silver extraction from dilute solutions (5- l00mg/l). By heat treating (at 300º C) the metal/biomass/carbon particles, bio-sorbed silver was subsequently fixed to the carbon surface. This approach to metal decontamination may therefore also provide a route for dispersing and fixing catalytic metal particles over an activated carbon surface.

Jan 1, 1991