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By Tran T, Young D

During the processing of gold, effluents that are discharged into the tailing dams contain free cyanide, metal cyanide complexes of zinc, copper, iron, etc and their oxidised products such as ammonia, cyanate and thiocyanate. A knowledge of how different cyanides behave in the solution is vital to metallurgists working in the area of cyanide waste treatment. Although the free cyanide ion is not stable in aqueous solutions and is expected to degrade in a natural environment by atmospheric oxidation, the metal cyanide complexes, especially of iron, are very stable. The CHEMIX program from the THERMODATA package, developed by the CSIRO Division of Mineral Products, was used to evaluate various copper-cyanide and iron-cyanide systems. The simulation of these systems show how the free cyanide and cyanide complexes behave at different conditions of solution composition and acidity (pH).

Jan 1, 1991

By M. P. Ahola

This U.S. Bureau of Mines report presents an overview of the use of three unique numerical modeling methods to analyze cutter roof problems in underground coal mines. Cutter roof failures are common in coal mines where the immediate roof is comprised of thin laminae exposed to highly biaxial tectonic stress fields. The predominant mechanism for failure is assumed to be excessive shear stress at the entry corners exceeding the shear strength of the rock. Early work in this area utilized the finite-element method and then the boundary-element method to analyze several cutter roof control measures. Various stress control measures were simulated to estimate their respective effects on reducing the high levels of shear stress at the entry corners. More recent studies made use of the discrete-element method. This method was used to take the analyses beyond the elastic continuum limits to simulate the propagation of a shear fracture and subsequent redistribution of stress within the mine roof. A simple roof bolt model was implemented to show the benefits of bolting to increase the resistance to shearing and separation along horizontal bedding planes and maintain roof stability.

Jan 1, 1991

By D. D. Harbuck

Previous studies at the U.S. Bureau of Hines have shown that only 70 to 80% of the germanium in domestic zinc process residues can be extracted during H2S04 leaching. To increase germanium extraction, the Bureau developed and researched the hypothesis that minor amounts of germanium and zinc silicate, both present in zinc calcine, dissolve during the leaching stages of zinc processing, forming soluble germanium and silica gel. This silica gel then selectively adsorbs germanium from solution, rendering the germanium insoluble. Testing showed that as the amount of silica gel formed increased, the amount of insoluble germanium in the zinc residue increased. Several processing alternatives are presented for overcoming this problem.

Jan 1, 1991

By Soumitro Nagpal

Bacterial oxidation of a pyrite-arsenopyrite-gold ore concentrate was carried out in .14-liter continuous-flow stirred-tank reactors (CSTR). Oxygen and carbondioxide consumption rates mineral dissolution rates, and bacterial concentrations were measured at various steady-state residence times and with 6, 11, and 16 wt.% solids in the feed slurry. A sharp optimum in biooxidation rate .was found at a residence time of approximately 40 hours for operation at each of the three pulp-densities. Biooxidation rates increased consistently. with increasing pulp density. Cell washout accompanied by negligible biooxidation rates was found to occur at a residence time of approximately 20 hours. Mineral' oxidation was found to be strongly dependent on bacterial activity. Arsenopyrite was found to be preferentially oxidized? at the higher Pulp densities.

Jan 1, 1991

By S. K. Kawatra

Under normal conditions, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. In order to reduce this pyrite recovery, it is first necessary to determine the primary recovery mechanism, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not the major mechanism for recovery of liberated pyrite, and that the bulk of the recovered pyrite is there either as a result of simple entrainment or by being physically locked with floatable coal particles.

Jan 1, 1991

By Avraamides J, Ritchie I. M

Gold Tellurides are important sources of gold at Kalgoorlie, Western Australia, Cripple Creek, Colorado and Vatukoula, Fiji. Unlike free gold, the tellurides of gold are rather refractory and the usual treatment practice has been to oxidize the tellurides, either chemically or by roasting prior to cyanidation of the liberated free gold. There is a large measure of disagree- ment as to the actual cause of the refractory nature of gold tellurides. In order to investigate the leaching chemistry of gold telluride, a study was undertaken on the thermodynamics and kinetics of its dissolution using electrochemical methods. From this study suitable direct leaching condi- tions are suggested. In acidic chloride solutions gold telluride can be leached using iron(III) as the oxidant. At lower acid concentrations the reaction is controlled by the formation of a passivating film of H2TeO3. In alkaline solutions containing cyanide the rate of gold telluride dissolution increases with increasing pH and strength of oxidant. However, this can result in excessive consumption of cyanide in the presence of stronger oxidants.

Jan 1, 1991

By M. K. Yelloji Roa

Effect of conditioning with Thiobacillus ferrooxidans on the floatability of sphaierite and galena has been determined in this work. The flotation behavior of the conditioned minerals clearly shows that such bacterial conditioning does produce marked modification of their surfaces. The variables affecting the surface modification and thereby the flotation response of the minerals were found to be cell concentration used for bacterial conditioning, the period of biotreatment and the pulp density. Importantly, while the enhancement in flotation obtained due to sulphuric acid treatment was retarded by biotreatment in the case of galena at all cell concentrations due to electrochemical effects, such decrease occurred in the case of sphalerite only at cell concentration sufficiently high for their attachment to the mineral surface. The effect of bacterial conditioning has significant implications to the differential flotation of sphalerite and galena. Mechanisms responsible for the modification of the surface properties of these sulphides due, to bacterial conditioning are discussed.

Jan 1, 1991

By R. P. King

The central idea presented in this paper is straight forward. Some fairly obscure mathematical techniques are presented from the fields of integral geometry and stereology and these techniques are shown to provide workable quantitative relationships from which the liberation spectrum of an ore after comminution can be determined. The experimental data that is required can be obtained very accurately and conveniently by image analysis of polished sections of the original ore. This quantitative mineralogical analysis provides a bridge that can link the worlds of the mineralogist and the mineral process engineer. This paper has been written to introduce this quantitative approach to a wider audience in the hope that the approach will be used more widely and that the basic linear intercept analysis data will be measured for a wider range of mineralogical textures. This could lead to a more comprehensive characterization of typical mineral ores that will be of considerable use in practical mineral processing.

Jan 1, 1991

By W. M. Snoddy

The Montana Tunnels diatreme is a low-grade polymetallic ore body containing economically mineable quantities of gold, silver, lead, and zinc. Widely varying gold grades combined with the general erratic nature of the mineralization create a complex sampling, assaying, and ore control problem. In order to maximize productivity and profitability, a variety of procedures have been used. These include differing sample size, frequency and method. In addition, assay techniques have been adjusted and refined to fit specific requirements, the result of which is an accurate, functional sampling and ore control system.

Jan 1, 1991

By Thomas W. Camm

In this U.S. Bureau of Mines report, mine and mill cost models are presented to make quick estimates of the cost to develop mineral deposits in the desert region of the Southwest United States. Regression analysis was used to generate capital and operating cost equations for each model in the form Y = AXB, where Y is the cost estimated and X is the assumed daily capacity in short tons. A and B are constants determined by the regression analysis. Each is broken down into 11 subcategories to facilitate escalation of costs for inflation and to increase their versatility in economic evaluation work. This report contains 2 open pit models, 6 underground mine models, 11 mill models, and cost equations for access roads, powerlines, and tailings ponds. In addition, adjustment factors for variation in haulage distances are provided for open pit models and variation in mining depths for underground models.

Jan 1, 1991

By Batric Pesic

Dissolution of gold with elemental bromine was studied by using a rotating disc technique. The main parameters studied were: bromine concentration, stirring speed, pH, and temperature. Additionally, effect of copper, iron, and manganese was also examined. A special attention was paid to elucidate the role of cations, primarily Na+, during gold dissolution. It was found that gold dissolution with bromine was characterized with two pH regions. Below pH=7, gold dissolution was independent of pH, and above this value, gold dissolution decreased with pH increase. Gold dissolution rates were proportional with concentration of bromine. Two regions, diffusional and kinetic, were observed with respect to stirring speed. with respect to the role of Na+, and cations in general, they play absolutely no role during gold dissolution with bromine, unless they are in their lower oxidation state and become oxidized by bromine. In that case they have a negative effect because of bromine consumption.

Jan 1, 1991

By G. A. Bala

As part of ongoing research to define mechanisms of microbial enhanced oil recovery (MEOR), this work describes the activity of Bacillus l1chen1formis JF-2 (ATCC 39307) Mosurfactant against crude oils with varying compositions. Surfactant based MEOR improves oil recovery by lowering the oil/brine interfactal tension (IFT) therefore permitting oil to be displaced or solub1lized into the aqueous phase.? MEOR is an Enhanced Oil Recovery (EOR) process which allows for the introduction of chemical and miscible fluids, in the form of microbial metabolic end-products, through the injection of microorganisms into the reservoir or stimulation of indigenous reservoir microbial populations. These microorganisms represent a replenishable in situ source of acid, gas, biopolymer, solvent, or surfactant products which can be. supported and manipulated by the addition of simple and inexpensive nutrients to enhance the recovery of oil. Microbially mediated surfactant production represents one mechanism of MEOR. Bacillus licheniformis JF-2. has been used in a mode 1 MEOR system based on Berea sandstone cores (permeabilly .85 to 400 md) to examine surfactant based MEOR of medium to heavy crude oils (API gravity 38.1° to 17.5°). Enhanced oil recovery was achieved with all oils tested using either cell free culture supernatants or microbial suspensions as injectants with no detrimental effect to the oil. Spatial distribution of cells following mf?crobtal flooding was analyzed with scanning electron microscopy. Data indkate complete distribution of cells with a predominance of organisms located distal to the point of injection. There appears to be no sign:if1cant recovery trend with respect to oil composition.. The biosurfactant produced by Bacillus lichen1form1s JF-2 lowers the interfacial tension of all oils tested equally well.

Jan 1, 1991

By Donald C. Rotherham

The Endako, British Columbia, deposit was initially discovered in 1927 by two local men, Charles H. Foote and Alf Lagdon, who were at that time on a hunting expedition. Four mineral claims were located to cover an area of quartz-molybdenite float that was centered on two small ridges. They subsequently uncovered a 0.5-m (1.6-ft) wide vein on which an inclined shaft was sunk to a depth of 8.3 m (27.2 ft) in 1934. Additionally, a short adit was driven to intersect another vein. Numerous trenches and small pits were also dug. Small test shipments of vein material from this early work were sent to G.S. Eldridge and Co. in Vancouver for metallurgical testing. A concentrate assaying 89.2% MoS, was produced with a recovery reported as 93.3%. The concentrate was essentially free of copper, arsenic, and phosphate. The property was examined by many geologists and engineers during 1934 to 1952, but the only work done was undertaken by the owners in order to maintain their claims in good standing. In 1952, Kennco Explorations (Canada) Ltd. carried out a limited program of bulldozer trenching, sampling, and geological mapping before relin- quishing their option. In 1956, American Standard Mines Ltd. acquired an option on the property, but no assessment work was apparently recorded and the property was allowed to lapse. The key claims were restaked in 1959 by C. Riley and H.T. James of Vancouver. The property was optioned from the new owners by Andrew Robertson in July 1961, and a small amount of trenching was conducted. Robertson, on behalf of his own company, R & P Metals Corp., reoptioned the property in January 1962. The initial results of this work were favorable and justified further exploration. The additional finances required to continue the program resulted in the formation of Endako Mines Ltd. (N.P.L.) on June 21, 1962. Field work by R & P Metals and the first Endako Mines exploration was directed by Bob Couts.

Jan 1, 1991

By Jinrong Zhang

Major components of soil were tested for their ability to attenuate cyanide. Feldspar, kaolinite, plagioclase and bauxite are found to degrade cyanide at an appreciable amount mainly through adsorption. A soil near a mining site in northern Nevada was studied in detail using a tall column. Many species of cyanide were anlyzed to determine the mechanisms of the reactions of cyanide with soil. Volatilization, adsorption, oxidation, precipitation and complexing were quantitatively identified, being 5 to 10, 11.7, 4.2, 7.3 and 4 per cent of the total cyanide added, respectively. It is found that the oxidation of cyanide to cyanate is due to the catalytic effect of nickel and copper leached from the soil. Precipitation of metal-cyanide complexes occurred at low pH values.

Jan 1, 1991

By F. F. Peng

A unique collector dispersion techniques was developed and used to improve the flotation rate and recovery of coarser and ultrafine coal-rich particles in the froth flotation processes. In this novel collector dispersion method, the collector such as hydrocarbon-oil is gasified and transported by gas phase (air stream) into the pulp. In addition to the excellent mode of collector dispersion, the collector-encapsulated air bubbles are generated in the pulp. This approach alters the surface properties of air bubbles and provides the fast rate of flotation compared to that of direct liquid collector addition froth flotation. Using gasified kerosene as the collector, the effect of altering surface properties of bubbles on the recovery of larger and finer coal-rich particles of -1.7 mm (-12 mesh) and -600 µ m (-30 mesh) raw coal samples were studied. The Redstone seam coal obtained from Northern Central region of West Virginia was used in this work. The effect of particle size on oil-coated bubble flotation rate and recovery were also evaluated. The conventional froth flotation test with a liquid form of kerosene addition was also conducted for comparison purpose.

Jan 1, 1991

By James K. Gowans

The Red Dog Operation is located in northwestern Alaska at Latitude 68°, 100 miles north of the Arctic Circle and 50 miles inland from the Chukchi Sea. The orebody was acquired by the NANA Regional Corporation, (an Alaska Native Corporation established by the Alaska Native Claims Settlement Act of 1971), in 1980 in their land selection. In 1982 Cominco American and the NANA Corporation signed a development agreement and Cominco Alaska Inc., a wholly owned subsidiary of Cominco American, was formed to manage the Red Dog Project. An extensive exploration program in 1980 -1982 outlined a mineral inventory of 85 million tons, at a grade of 5.2% Pb, 17.1 % Zn, and 2.4 oz/ton Ag, which makes the Red Dog the second largest deposit ever discovered. Broken Hill, in Australia, is the only zinc orebody which was originally larger than Red Dog. The design of the facilities is to process 2.1 million tons of ore annually, which will produce 560,000 tons of zinc concentrate, 100,000 tons of lead concentrate and 50,000 tons of bulk lead/zinc concentrate.

Jan 1, 1991

By M. J. Adam

The U.S. Bureau of Mines has investigated the partitioning of complex minerals to simpler phases using sulfidation reactions for selective extraction of mineral values. This report describes research in which thermal processing of the complex Ti-bearing mineral ilmenite (FeTi03) resulted in partitioning of the valuable Ti metal to the simpler compound rutile (TiO2). Samples of ilmenite were blended with elemental S for thermal treatment at various temperatures under controlled atmospheres in an effort to dissociate the Fe from the ilmenite complex. Product characterization revealed that the Fe was partitioned 'from the ilmenite, forming a rim of pyrrhotite/pyrite (FeS/FeS2) on a rut il e core. The products were agate milled and then subjected to cursory magnetic and flotation techniques in an attempt to physically separate the partitioned phases. Partitioning results and phase concentration data are reported relative to thermal treatment variables and physical separation techniques.

Jan 1, 1991

By Lewis L. Oriard

The purpose of this paper is to provide an overview of close-in blasting effects on various types of structures and building materials, as encountered in this writer's professional practice. Structures range from old, deteriorated historical monuments to new, heavily reinforced buildings. Materials range from clay adobe to concrete and steel. Site locations range from tropical to arctic. Blasting ranges from sculpture blasting inside buildings to "coyote" blasting and large surface blasting operations. Space limitations permit a brief discussion of only 25-30 specific cases, but they have been selected to be typical of conditions found on hundreds of similar cases. The writer was asked to present a discussion of representative cases where relatively high vibration intensities were experienced. Virtually all of these cases were free of damage, but the few damage cases provide valuable insight to the mechanisms involved. Observations of such damage and non-damage cases have served as the basis of this writer's criteria for various structures and materials, as well as the technology to conduct blasting operations within those criteria. A sampling of these experiences is gladly shared with the reader.

Jan 1, 1991

By C. A. Summers

The U.S. Bureau of Mines applied process mineralogy to investigate a lead and zinc deposit located near Story Creek, Colville Mining District, Alaska. Mineralization is hosted by the Kayak Shale in veins, veinlets, and breccia. Sphalerite and galena, with supergene anglesite, occur in symmetrical quartz veins and between breccia clasts. The study sample analyzed 2.11 percent Pb, 5.37 percent Zn, 0.014 percent Cu, and 1.2 oz/ton Ag. Analyses of crushed products showed that 33 percent of the sample weight, and more than 50 percent of the Pb and 65 percent of the Zn, are in the minus 850 um fraction. Liberated grains of sphalerite and galena were found in crushed products finer than 300 um. Beneficiation tests indicate the material is amenable to processing by traditional gravity and flotation techniques.

Jan 1, 1991

By K. G. (Ken) Thomas

"This paper gives an insight into the various processes available to treat gold ores. A brief overview is given of the various types of refractory gold ores. Particular emphasis is given /0 comparing the costs of oxide vs refractory gold ore processes, inclusive of grinding through to dore bar.HistoryThro ugh time gold has been recovered from the earth's crust by various mean s. Five major historical steps can be identified for metallurgical processing as shown in Table I .Gravity concent ration started with, for example, river bed panning and developed to more sophisticated processes such as the Johnson concentrator, belt concentrator and jigs. The South African gold fields were a major developer of gravity concentration processes during the first half of the twentieth century.As coarse free gold became depleted, stamp milling, in conjunction with amalgamat ion , was developed. Basically, rock was crushed under large mechanical hammers an d the gold collected in mercury . The mercury was then evaporated in a retort to leave sponge gold for further fire refining.As deposits became deeper and gold finer, the gold became more difficult to recover ; fine grinding was required to liberate the gold. In the 18905, MacArthur and the Forrest Brothers of Glasgow, Scotland, introduced the cyanide pro cess for dissolution of gold and its subsequent precipitaiton by means of zinc. This process, in vogue until the early 1970s, was commonly referred to as the Merrill-Crowe process for recovering fine gold .Activated charcoal was used as a means of recovering gold from solution in the 1880s, especially in chlorination plants in Australia( l). Two factors probably retarded the development of carbon instead of zinc-based processes during those year s. First , there was no satisfactory procedure for the elution of carbon to allow its recycling and, second, the development of the Merrill-Crewe process for gold recovery by zinc cementation probably discouraged any further work on the use of carbon"

Jan 1, 1991