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By E. Gutierrez-Miravete

A computational method for the simulation of mold filling processes is described. The method is based on the representation of the flowing or deforming medium as a collection of mutually interacting parcels of material. Instantaneous positions of individual material parcels are calculated by numerical integration of the dynamic equations, subject to appropriate initial and boundary conditions. So far, the method has been used to produce qualitative simulations of some flowing and deforming systems encountered in mold filling technology, and our findings are summarized herein. In all cases, individual material particle motions can be followed in detail, allowing critical examination of potentially problematic mold design features.

Jan 1, 1992

By Drummond Earley III

The hydrology of in situ leach mining operations is being studied by the U.S. Bureau of Mines using a variety of techniques, and the Bureau has made significant advances in tracking and modeling the flow of leach solutions in rock formations. However, the influence that leach solution composition has on the hydrology of these systems is poorly understood, and geochemically-controlled changes in the hydrologic characteristic of ore deposits during in situ leach mining of porphyry-hosted, copper oxide ores have not been previously studied. The Cyprus Casa Grande in situ leach mining operation mines fracture-hosted and disseminated copper oxides (predominantly chrysocolla) hosted by granodiorite porphyry using a pattern of underground wells. The injection solution consists of sulfuric acid raffinate from a solvent extraction-electrowinning plant. Chemical analysis of representative injection and recovery solutions reveals that gangue cation concentrations in these solutions are high, and geochemical modeling shows that the solutions are saturated or nearly saturated with respect to gypsum, jarosite, and various amorphous oxides. Precipitation of these solids is evoked by calcium-exchange reactions, rising pH, and perhaps locally rising redox potential, as the leach solution reacts with the ore minerals, host rocks, and the atmosphere. Mass and volume balance calculations show that approximately 25 cm of precipitates are formed per gram of copper recovered at Cyprus Casa Grande. The results of geochemical modeling agree with petrologic examination of pre-and post-leach core samples from the leached horizon. Moreover, hydrochemical modeling and hydrologic field data suggests that chemical precipitation causes significant decreases in porosity and permeability during in situ leach mining of porphyry-hosted, copper oxide ore.

Jan 1, 1992

By Jr. Pitts

Elevation of surface charge density on colloidal particles in the presence of a high potential electrostatic field is demonstrated as a viable technique for preventing the accumulation of solids in solvent extraction circuits. The effect of the technique is manifest by relative turbidity measurements between pregnant leach solution and raffinate, by changes in the character of the sludge accumulations, by alteration of the zeta potential of particulates, and by a general reduction in the mass of solids.

Jan 1, 1992

By John J. Mortvedt

Application of some by-products of the metals industry which contain plant nutrients to agricultural lands could constitute resource recovery instead of costly disposal. Some industrial by-products contain appreciable concentrations of heavy metal contaminants, such as Cd, Cr, Ni, and Pb. After land application, these metals may be absorbed by plants and enter the human food chain or be leached to groundwaters. Plant uptake of these heavy metals varies with plant species:, soil pH, soil texture, and the particular metal. Certain leafy vegetables can absorb significant amounts of heavy metals, while absorbed metals are usually poorly translocated to cereal grains. Allowable heavy metal concentrations in fertilizers now are not regulated, but EPA is considering such regulations. Heavy metal impurities in animal feed supplements are regulated by the states; so some by-products may not be permitted for this use.

Jan 1, 1992

By R. K. Mehta

An accurate, efficient and stable computation of the mill matrix function (eAt) is needed where mill matrix (A) is a real general matrix. Two important modeling cases in comminution where such need arises are: Heterogeneous comminution behavior of multi-component ores and ultra-fine grinding involving simultaneous attrition and fragmentation breakages. This paper presents the application of a novel splitting method in conjunction With similarity transformation technique in the form of "product formula" which is found to work in all cases and uses a most aggravating, yet interesting property of the matrix exponential in a restricted sense. Results are presented showing that this method can yield solution as accurate as those obtained With an analytical technique. The utility of this computational approach is demonstrated by parameter estimation analysis using a distributed component model in the liberation area through computer simulations.

Jan 1, 1992

By Lisa A. McDonald

The environmental compliance process affects all aspects of hardrock-mining operations, from exploration through post-closure. The primary components of the environmental compliance process are requirements under the National Environmental Protection Act of 1969 (NEPA) and the permitting requirements associated with various other federal, state and local laws. This study considers the Greens Creek Mine and the development of two other projects (Alaska-Juneau & Kensington). These mines were used as the foundation for a case study of the impacts of the environmental compliance process on hardrock-mining activity in Southeast Alaska. The case study presents the institutional and legal requirements, followed by a discussion of the impact of this process on the production and timing of the three mines. The results of this preliminary study reveal some interesting findings, some expected and others unexpected, regarding the impact of the permitting process on the exploration, development and (proposed) operation of the three mining projects in the Juneau area. Determining the cost of compliance with these requirements is an important step in evaluating the appropriate course of action to protecting the environment while providing the necessary raw materials needed for society. This preliminary study highlights the initial starting point for such an analysis.

Jan 1, 1992

Heap leaching has become one of the prime technologies used for the recovery of precious metals from low-grade ores over the past ten years. The recovery process involves mining and stacking the ore on engineered leach pads, with or without crushing and/or agglomeration, followed by leaching with a low concentration sodium cyanide solution. The metal-bearing, pregnant solution is then processed by zinc precipitation or activated carbon absorption to extract the precious metals. The leaching process continues until all economic metal values are removed at which time the spent heap leach pads, the leached materials and excess process solutions require decommissioning. The management of these solutions may present a potential challenge for successful and environmentally sound decommissioning due to their composition, volume or continuity of generation from the spent ore even though active leaching has been terminated. The principal objectives of solution management in decommissioning spent heap leach pads are to meet all operative environmental regulations in a cost-effective manner and to leave the pads in a condition where they do not present a long-term liability either to the operator or to the environment. This involves the reduction in volume of the residual process solutions and/or treatment of these solutions to where they meet applicable water quality criteria. In the past, the environmental and economic aspects of decommissioning and solution management have been overlooked or under-estimated during the planning of mining operations. As a result, there is a potential for long-term liabilities and costs to be recognized only at the end of active leaching, a time at which operating revenues and cash-flow are minimal. Therefore, the decommissioning process requires addressing at the mine planning stage and agencies now require that a plan for solution management after the cessation of operations be submitted prior to initiation of mining. This paper discusses aspects of process solution management during decommissioning, both in terms of quantity and quality, and how potential issues may be recognized and planned for in the initial stages of heap leach design.

Jan 1, 1992

By J. B. Griffiths

Clearly there is a tremendous need for assistance in Eastern Europe since most industries must undergo major restructuring. The new governments face many dilemmas, the first task being to establish an order of priorities to deal with the numerous problems at hand. Issues such as the standard of living take low priority compared with market economy and ecological problems. The concept of a Comecon market is now virtually non-existent and trade in roubles ceased from 1991. From this time onwards countries were obliged to trade using free market prices. Governments must also avoid the economic mistakes of countries such as Poland with its high devaluation and lack of economic control and, if possible, contain inflation and unemployment. The privatization of Eastern European enterprises raises considerable difficulties, particularly for large corporations, employing anywhere from 50-100,000 people, which played a major role in the national economy. Whichever method is selected, however, still has to overcome the problem of lack of capital and evaluating the national property. For example, earnings represent only a small percentage of the value of these national industries and thus cannot convert to private ownership without foreign capital investment, either direct or as joint venture capital.

Jan 1, 1992

By G. Upadhya

Considerable success has been achieved recently in modeling microstructural evolution during solidification of castings bthrough the coupling of macroscopic heat transfer with microscopic solidification kinetics models. However, a complete model for simulation of solidification in complex shaped castings involves: (i) the description of fluid flow, during and after mold filling, coupled with (ii) heat transfer to the mold and surroundings by use of a macro model, followed by (iii) a description of subsequent solidification of liquid metal by use of a micro model for solidification of the alloy under consideration. This paper describes the coupling of solidification kinetics model to a 3D, transient, fully coupled fluid flow and heat transfer model. Coupling between the macremicro models is achieved by using the latent heat method. Micro models for the eutectics of gray, white and ductile iron are discussed. This coupled code has been used for predicting the thermal history and microstructural data for shaped castings. Various applications of the model, including prediction of shrinkage defects, grain density contours, and graylwhite transition region in the casting, are presented for a relatively complex casting geometry.

Jan 1, 1992

By Peter Krause

This report provides an overview of the worldwide photographic industry and of the applications of photography. It also covers important technological and market trends, with special emphasis on those factors which may affect the consumption of silver in the future. The text is divided into the following eight sections: 1. Principal manufacturers of silver-based photographic products 2. Major product sectors 3. Structure of the international market for silver-based photographic products 4. Silver-bearing raw materials for the manufacture of photographic products 5. Processing of photographic products: recovery of silver and recycling 6. Methods for estimating the use of silver in photographic products 7. Basic function of silver in photography and alternate image capture and recording systems 8. Brief history of photography Silver- based photographic materials are made for many applications that require different photochemical and physical response characteristics and a wide variety of formats and sizes. All of these products are laminates consisting of a surface-treated support and bonded gelatin layers. Two basic types predominate - films and papers. Films have transparent or translucent plastic supports (mostly cellulose tri-acetate and polyester), while papers have mostly a paper core coated with polyethylene resin layers on both sides (RC type). The front layer contains white titanium dioxide to provide high reflectivity and the back layer a matting agent. However, a few so-called fiber base papers are still supplied. These have a high quality paper base coated with a baryta layer ; i.e. a gelatin layer containing white barium sulfate. The manufacture of photographic film and paper supports requires special procedures and equipment, because of the severe requirements for chemical purity, optical integrity and uniformity (see Table 1 on page 10 for a list of the principal makers of film and paper supports).

Jan 1, 1992

By Thomas M. Harris

To avoid the escalating cost of disposal of metals-containing wastewater and residues, new wastewater treatments will focus on the recovery of the metals. A combination of ion exchange and electrowinning can produce water suitable for discharge and relatively pure metals. The use of a chelating resin can enhance the selectivity of both the removal process and the elution of metals from the resin. A new, simple method of preparing a variety of chelating resins is being developed. The materials produced by this method exhibit interesting, as well as potentially useful, elution behavior. The performance of one test resin is described.

Jan 1, 1992

By M. Barkhudarov

The results are presented of research aimed at validation and development of a general purpose CFD code FLOW-3D. FLOW-3D is a commercial code developed by FLOW SCIENCE, INC. A number of physical modeling experiments involving the filling of cavities of different geometries with coloured water have been performed in order to compare the measurements with the results of computer simulations. Other numerical calculations were also done to be compared with the known analytical solutions.

Jan 1, 1992

By Y. Shu, A. R. Laplante

"A laboratory Knelson Concentrator (LKC), 7.5 cm in diameter, was used to study the performance of a similar unit at plant scale, 76 cm in diameter, This paper reports on sampling and assaying procedures and problems, and discusses the performance of the plant unit.The sampling procedure was based on the extraction of large samples, 5-15 kg, and their complete processing with a LKC, to characterize size-by-size performance. The procedure yielded reliable estimates of overall gold assays, after blatant assaying errors were corrected. The plant centrifugal unit concentrate was sampled in situ, which yielded very erratic grades, with a large overall negative bias. Due to the very heterogeneous nature of the concentrate, which can be linked to flow patterns in the riffles of the unit, it is recommended that for future testwork, the concentrate be recovered separately, blended and then sampled.The plant centrifugal separator, when operated at a feed rate of 25 t/h, yielded total and free gold recoveries of 41 % and 62%, respectively. This is much lower than previously reported data, and suggest that at 25 t/h, the unit is overloaded. However, recovery did not decrease with time over a loading cycle of 2 hours, which suggests that present loading cycles, generally 1 hour, can be significantly increased. INTRODUCTIONThe study of gold gravity circuits is plagued with the statistical problem of determining the behaviour of particles occurring with a very low frequency. This problem becomes particularly acute with increasing particle size. For example, considering the average weight of a gold flake in the 840-1200 µm (20/28 mesh) to be about 5 mg (Banisi et al, 1991), a reasonably high grade feed of 10 git would require, for a relative error (standard deviation) of 10% on grade, 100 particles, that is 0.5 g of gold, or 50 kg of 840-1200 µm material (a Poisson distribution is assumed). Gy's formula, for the same data, yields a weight of 33 kg, with a shape factor of 0.1 and a size distribution factor of 0.5. Both results are comparable; to obtain the suggested weight of material, a stream containing 5% weight in the 840-1200 µm would require 1 tonne samples (of unsized material). The problem rapidly disappears with decreasing particle size. Still with Banisi et al's data, a gold flake in the 300-420 µm range averages 0.5 mg in weight; the same 10% error on grade corresponds to a weight of 5 kg. Gy's formula for the same size distribution and particle shape factors as above predicts a required mass of 1.4 kg. This would correspond to an unsized sample weight of 10 kg with 14% weight in the 300-420 µm, for example."

Jan 1, 1992

By Donald R. Sadoway

The viability of treating certain forms of hazardous waste by direct electrolysis in molten oxides is under investigation. Secondary residue or waste mud produced in the course of chromate chemical production is the focus of attention in this study. The goal is to reduce the water soluble hexavalent chromium either to insoluble trivalent chromium or to chromium metal. Electrolysis tests have been conducted in a high temperature cell containing chromate sludge dissolved in an electrolyte composed of Al2O3, SiO2, CaO, and MgO. Oxygen production on a carbon-free anode has been confirmed.

Jan 1, 1992

By Leo J. Miller

Sulphur deposits occur within the upper Salado and Rustler gypsum beds. The formation of a sulphur ore deposit requires large quantities of oil and /or gas, which must find a permeable pathway into the gypsum beds. The Permian beds weathered for 90 million years in an arid environment prior to the advent of a more humid climate at the beginning of the Cretaceous Period. The first Cretaceous rivers enlarged the sinkholes and caverns of the Karstified Permian terrain and deposited coarse conglomerates and sands into the subsurface gypsum beds. The resulting network of caverns and sinkholes, filled with permeable sediments, permitted the free flow of hydrocarbons through gypsum. All sinkholes and caverns infilled with Cretaceous sediments that have penetrated beds of gypsum are associated with sulphur deposits. The Castile gypsum lies directly upon the oil bearing Bell Canyon formation. Sinkholes and caverns filled with Cretaceous sediments occur in the lower Castile. Biogenic calcite and sulphur are adjacent to these sediments. However, faults assume the major role in generating the initial permeability, allowing hydrocarbons to penetrate the lower Castile gypsum. The largest faults are associated with biogenic calcite and sulphur for a distance of 250 meters up from the bottom of the Castile gypsum. It is apparent that two dynamic geological processes are generating permeability within the gypsum beds: (1) the Cretaceous sands decending with difficulty into gypsum and (2) the faults creating permeability in the lower Castile but losing energy through soft bed deformation in the overlying gypsum. Both of these sulphur ore controls are mappable, but another large sulphur deposit of the magnitude of the Culberson Sulphur Mine has yet to be discovered. It appears that massive sulphur deposits are associated with the largest scale examples of each system, that is (1) high densities of deep sinkholes and separately

Jan 1, 1992

By B. A. Hillman

Silicon is the second most abundant element on earth, exceeded only by oxygen. Silicon dioxide forms a crystalline structure of repeating SiO2 molecules which form characteristically hard, durable crystals. As a result, crystalline silica is Ubiquitous in the crustal rocks, sediments and the mineral products derived from mining. An examination of the history of studies that identify silica as a human and animal carcinogen is presented in the context of the development of a public health policy in California. The implications for the cost of conducting aggregate and other mining operations in the state are discussed.

Jan 1, 1992

By Y. Guan

The dissolution behavior of copper and gold from their pure state and from Au/Cu alloys in cyanide solutions has been investigated using a rotating disc. Oxygen was used as an oxidant. The effect of the composition of the alloys, stirring speed of the disc, concentration of lixiviants and temperature on the overall dissolution kinetics has been studied. Gold/copper alloys of three compositions were used in this study. The atomic percent of gold in these alloys was 75, 50 and 25, respectively. The dissolution behavior of these three alloys was compared with that of pure gold and of copper under the same chemical conditions. In general, the dissolution of copper and gold from alloys is partially controlled by surface chemical reaction and largely by mass transfer.

Jan 1, 1992

By Stephen J. Hales

State-of-the-art Resistance Spot Welding (RSW) equipment has the potential to permit adaptive feedback through recent advances in computerized process control. The initial step toward achieving this goal involves assessment of the effect of specific variables and the interaction between these process inputs on spot weld characteristics. This investigation addresses this issue through the application of Taguchi methodology to understand and refine a RSW schedule developed for joining of two dissimilar aluminum-lithium (AI-Li) alloys of different nominal thickness. The experiment was designed to establish a hierarchy of inputs with respect to each 'other, and to determine the significance of these inputs with respect to experimental noise. Valuable insight was gained regarding the interaction between process variables and the effect of certain equipment-related changes. In spite of a decrease in equipment performance, an improvement in the maximum strength attainable for defect-free spot welds resulted from the application of the statistical experiment.

Jan 1, 1992

By M. Zamalloa

Slag foaming is an important phenomenon in many metallurgical processes. It creates large surface areas for multi-phase reactions to take place. In other applications, it protects electrodes and improves the energy efficiency by reducing radiation from hot surfaces. However, it may also be a source of serious disturbances. To control and optimize the use of slag foams, an extensive knowledge of the factors controlling the foam formation and stability is required. Slag foaming experiments were carried out using synthetic FeO-CaO-Si02 slags at temperatures ranging from 1200 to 1350 "C. A data acquisition system was used to continuously measure the foam height, gas flow rate, bubble frequency and temperature. The experimental results show that the gas injection rate has a strong effect on the behaviour of slag foams. At high flow rates and rapid bubbling, unstable foams with short decay times were created. The addition of P20, favours the foam formation and stability by lowering the surface tension of the slag. The average foam life increases with decreasing basicity (CaO/Si02). It is proposed that this is attributed to the increase of the surface viscosity due to surface adsorption of a thin film of silica, retarding the drainage of the liquid films.

Jan 1, 1992

By P. D. Ferro

The direct oxide reduction (DOR) of plutonium oxide generates significant amounts of contaminated waste. This waste primarily consists of calcium oxide-saturated calcium chloride salt. This investigation explores the possibility of recycling the salt, by the electroreduction of the calcium oxide. Fused salt electrolysis of a simulated salt mix (CaC12 + ~10 wt. pct. CaO) is being carried out to electrowin calcium, and the process is being optimized in terms of the calcium solubility, cell temperature, current density and cell design to maximize the current efficiency. This work identifies the major concerns in the development of a process to electrowin calcium from this simulated salt mix.

Jan 1, 1992