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By David P. Conover

The U.S. Bureau of Mines (USBM) has developed a computer-assisted Ground Control Management System (GCMS) for near realtime evaluation of underground coal mine ground conditions. The GCMS combines existing mine-monitoring system and sensor technology with automated computer analysis techniques to enhance the acquisition, analysis, and display of geostructural data. The GCMS, which combines mine structure data with other information, such as geologic conditions and mine layout, has provided information on mining-induced stress transfer and pressure buildup associated with several ground control events. The GCMS collects and analyzes shield-leg pressure, ground pressure, and strata movement data to evaluate the structural behavior of an active Western U.S. Iongwall coal mine. Field data are transmitted over a dedicated phone line to the USBM Denver Research Center (DRC) mine monitoring laboratory, 240 km (150 miles) from the mine site. Real-time collection, processing, and analysis of mine structure and shield pressure information has proved to be an effective method for near-face ground conditions while mining progresses. The GCMS provides the mine operator with information to rapidly identify and manage potentially hazardous ground conditions while mining is in progress.

Jan 1, 1994

By O. Ozcan

Oleic acid has been almost invariably used in the flotation of siliceous fluorite ores. The performance of oleic acid, however, deteriorates with carbonaceous fluorite ores. Oleoyl sarcosine developed recently has been found to produce results superior over oleic acid with ores containing high calcite contents. While the mechanism of oleate adsorption is usually considered as chemisorption involving calcium oleate formation on both calcite and fluorite, no mechanism has been so far proposed to explain the adsorption mechanism of oleoyl sarcosine. In this study, the selectivity of oleoyl sarcosine, as inferred from flotation, zeta potential and infrared measurements, is ascribed to the interaction of fluorine ion to the nitrogen via hydrogen bonding.

Jan 1, 1994

Improve the dust-control effectiveness of the Rotoclone1 dry-dust collection systems used on surface coal mine drills.

Jan 1, 1994

By Alexandre Bonan

This paper reports the results of a kinetic study on the oxidation of free cyanide and Cu-cyanide complex ions with HO,. The variables and respective ranges studied were the following: [CN] total =10 - 500 mg/l; pH=10-11; (H2O2/CN) mole ratio = 1- 3; (Cu/CN) mole ratio = 0.10 - 0.25. The results were interpreted by a semi-empirical model that incorporates the useful oxidation reactions and the parallel alkaline decomposition of H2O2

Jan 1, 1994

By D. L. Boreck

With increasing land development, the potential of fatalities from abandoned mine shafts increases. To minimize potential liability, shaft closure should be a critical part of mined land reclamation. The Bureau of Mines is conducting research into using lightweight foam concrete in sealing abandoned coal mine shafts. A demonstration seal consisted of a 3m thick foam concrete plug to provide lateral stability inside the shaft. A high density concrete cap provided load-bearing capacity for a 100-year service life. The USBM has also completed research into changes in foam concrete when it is pumped or dropped from different heights. It is concluded from the research that foam concrete can undergo significant air loss with pumping or dropping. This foretells significant changes in the characteristics of the concrete as well as an increase in the weight and cost of the in-place concrete seal. When using foam concrete to seal abandoned mine shafts, care must be taken to minimize air loss during placement.

Jan 1, 1994

By V. de la Garza

The La Cienega Gold District is located at latitude 25°01'01"N and longitude 106°19'00"W, in the NW part of the State of Durango, Mexico. Ore deposits at The La Cienega District consist of a series of sub-parallel, NE-trending veins which cut andesitic and rhyolitic rocks that belong to both upper and lower tertiary volcanic sequences. The veins are vertical to steeply-depping structures which consist of quartz, generally containing gold-silver and less than ten percent lead, zinc and copper sulfide and sulfosalt minerals. Supergene enrichment is present on the upper parts of known oreshoots. Tertiary volcanic rocks of rhyolitic composition are the main host rocks of the gold-bearing quartz veins in the District. Gold productionc from the La Cienega orebody is scheduled to reach 100,000 ounces per year, becoming the largest gold-producing District in the Sierra Madre Occidental Province.

Jan 1, 1994

By H. EI-shall

In this paper, the results of a fundamental study involving zeta potential and turbidity determinations of solid suspensions are discussed. Illustrations of how these results are utilized to design field applications of solid grade polymers to clarify mine drainage water are presented. Other applications in different industries are also reported. The operational and economical advantages are examined.

Jan 1, 1994

By G. V. R. Landman

In order to obtain a better understanding of the explosion risk at the coal face, anomalies in the ignition sensitivity for different modes of ignition of hybrid mixtures of dust, methane and air were studied. Results indicated that the explosible behaviour of the working environment is highly dependent upon the ignition source and the fuel composition. For example, depending on the ignition source, the same hybrid mixture can be inert or extremely explosible. In conclusion, it is stressed how the explosion risk can be expressed in terms of a safety factor which takes into account the influence of both the fuel and the ignition source.

Jan 1, 1994

By Robert Vidal

The performance of a laboratory-scale cell for the electrolysis of an aqueous chrome alum solution was studied. Electrode potentials, pH, and Eh were recorded. An optimum catholyte pH of about 2.5, consistent with information from the literature was observed. Values exceeding this range resulted in a precipitate formation and are detected by wavering cathode potentials. The role of anodically produced dichromate ions was investigated by chemical analysis. It was found that the steady state concentration of dichromate ions varies inversely with fluid flow from catholyte to anolyte. This concentration was also reduced with the use of precious metal coated titanium anodes.

Jan 1, 1994

By R. Flores V.

The Refugio Project is located in the Andes mountains of northern Chile, in the Maricunga Hineral Belt. The Verde, Pancho and Guanaco Au ore bodies have been recognized and are Early Miocene in age. Mineralization consists of fine-grained disseminated gold hosted by dacitic to dioritic subvolcanic porphyries. Alteration comprises massive to veinlet-controlled silicification overprinted on earlier potassic and propylitic alteration and surrounded by later argillic alteration. Geologic relationships suggest that the Refugio ore bodies occur within an Early Tertiary volcano overlying Paleozoic and Mesozoic basement rocks. Geologic reserves at Refugio are approximately 300 million grams (9.7 million ounces) of gold. The Verde deposit contains 185 million tonnes of mineable and leachable ore with an average grade of 0.90 glt Au and is currently in the pre-construction stage after a positive feasibility study. Proven and probable mining reserves at Verde deposit are 101 million tonnes at an average grade of 1.02 glt gold. Additional potential exists at to other deposits within the Refugio property (Pancho and Guanaco) but no reserves have yet been defined due to the limited drilling to date.

Jan 1, 1994

By Yutaka Yasuda

The particle dispersion phenomena in a turbulent gas jet of the flash smelting process has been investigated. The particle number density in a non- reacting jet was measured experimentally by taking photographs of the particles in flight and counting them using the image analysis. Numerical computations were also performed using a mathematical model for a turbulent particle laden gas jet The experimental particle number density data were then compared with the predicted results of the model. Good agreement was obtained between the experimental and predicted data. The effects of the parameters such as the injector design, particle loading and air flow rate are discussed. Optimization of the concentrate burner design can be achieved with the help of experimental and theoretical simulation as performed in this work.

Jan 1, 1994

By Niels Krebs Ovesen

Close economic cooperation was established among the countries in western Europe during the seventies. As a consequence, among others, a need for harmonized technical specifications for civil engineering works arose. Technical specifications for design and execution of building and civil engineering structures exist in most of the European countries. In some countries such technical specifications are part of the building regulations and in other they are independent codes of practice and standards. The works on the Eurocodes was initiated by the Commission of the European Communities about 1976. The Eurocodes are intended as common unified design codes for different load bearing structures constructed from different materials. They are also intended to cover design of geotechnical structures. They are established with a view to promote the free movement of goods and services within the member states of the European Community - the so called Internal Market - and within the member countries of the European Free Trade Association, EFTA by removing obstacles arising from different rules for calculation and design.

Jan 1, 1994

By D. K. Panda

The behavior of single drops with gas evolution at the interface is of interest because this is one of the important reactions that occur in oxygen steelmaking vessels, where a large amount of iron-carbon drops are dispersed in an oxidizing slag. The carbon dissolved in these drops, reacts with the slag to form CO, which is evolved as a gaseous phase. A room- temperature model was used to study the nature of this type of reaction including the effect of various factors such as viscosity and the presence of surface active impurities. Experiments were done for reacting drops over a wide size range to observe various regimes of behavior. Large single drops were levitated in a counter current flow to produce a sufficiently long residence time to allow the study of the various stages in the reaction. The emphasis of this work was to obtain photographic evidence of a high quality to describe all possible modes of behavior, and so a lot of effort was given to developing and perfecting experimental techniques.

Jan 1, 1994

By W. C. Lacy

It is the responsibility of educators to look ahead and prepare young engineers and scientists to cope with industrial and social problems of the future. We are faced with a review of history as well as prophesy of the future. The mining industry exists in a "bubble" with little interaction or communication with the outside. This isolation must be broken down if the industry is to survive in the U.S. and Canada. The ability to communicate with the general public and public officials is essential. Many changes are occurring that will require readjustments in technology and staffing. Aging population will result in raising retirement and increasing available workforce. This may force shorter working weeks to supply additional jobs. Environmental concerns will likely direct more attention not only to these concerns during mining, but to planning for post-mining land usage. Retraining and up-dating educational programs are required to cope with these changes.

Jan 1, 1994

Provide a low-cost, low-maintenance method for im¬proving mine water quality on abandoned mine land (AML) sites. Approach A model (figure 1) is presented for selecting, designing, and sizing one or several passive mine drainage treatment systems that can be used in remediation of AML. The three principal types of passive mine drainage technologies for the treatment of coal mine drainage are an aerobic system, a compost wetland, and an anoxic limestone drain. The multistep approach presented here provides a simplified method to characterize the type and magnitude of the water quality problem and then to select either a single treatment system or a combination of treatment systems to address the specific site situation. How It Works Step 1. Discharge Characterization. Characterization of the discharge consists of measuring the discharge flow rate and collecting water samples at the point of discharge for chemical analysis. Both the flow rate and chemistry of a discharge can vary seasonally and in response to storm events. It is important to account for this variability by determining flow rates and water chemistry under various conditions. Water should be analyzed for pH, dissolved iron (Fe), alkalinity, and hot acidity (using the H2O2 method).

Jan 1, 1994

By Mukesh K. Agarwala

Alloy composite parts were made from powders by Selective Laser Sintering (SLS). SLS is a rapid prototyping process that uses data from CADICAMICAE systems to guide a laser beam and rapidly form 3-D prototype parts from powders without any part specific tooling. In this study, Bronze-Nickel parts made by SLS were studied for their mechanical properties. To make the parts structurally sound, SLS parts were further processed by conventional isothermal sintering, without loss of shape. The resultant densification and mechanical properties were studied and related to microstructures and P/M densification models. These results were then correlated to the SLS processing parameters.

Jan 1, 1994

By Gregory R. Wessel

Sulfur is a nonmetallic element widely distributed in nature and of great physical and economic importance. It is the 14th most abundant element in the Earth's crust (0.06%) and an important constituent of animal and plant life. Sulfur has been known and used since ancient times for a number of medicinal and industrial uses. At present, most sulfur is used to generate sulfuric acid that is used in a wide variety of industrial processes, particularly the production of fertilizer. Because of this, sulfuric acid (and hence sulfur) consumption is often regarded as a good index of a nation's industrial development. In the past, sulfur was mined from surface occurrences in several geologic environments, and was used in relatively small amounts. With time, the uses of sulfur and sulfuric acid expanded, as has the need for larger quantities of these commodities. Sulfur is now mined from both surface and underground deposits, and is recovered as a byproduct from a number of industrial processes. Despite valiant efforts and years of work by sulfur explorationists and others, many aspects of sulfur mineralization remain controversial. Almost as controversial is the spelling of the word sulfur. The English spelling sulphur commonly is used outside America and in the American sulfur mining industry, but sulfur is the correct American spelling as approved by the American Chemical Society, the American Geological Institute, and many others. Those new to the American sulfur industry often find it puzzling to be reprimanded for using the correct American spelling. Sulfur resources are abundant and widespread, but the extent to which they can be classified as reserves is constrained by pre- vailing prices and extraction technologies. At present, sulfur can be economically mined from very few deposits. The sulfur industry is roughly divisible into two sectors: voluntary (or discretionary) and involuntary (or nondiscretionary). In voluntary production, the mining of sulfur or pyrites is the sole objective, and the recovery of the resource is as complete as economic conditions will allow. During involuntary production, sulfur or sulfuric acid (termed recovered sulfur) are produced as byproducts, and the quantity of the output is dictated by the demand for the primary product. Voluntary sulfur now accounts for only about 35% of the elemental sulfur produced worldwide, and most inves- tigators believe that voluntary sulfur will be less important in the future. Sulfur sources and products are described as follows (after Barker, 1983): Sulfur Sources: Combined sulfur-sulfur that occurs in nature combined with other elements, commonly referring to sulfides and sulfates. Cupriferous pyrites-pyrite containing minor amounts of cop- per sulfides. Hydrogen sulfide-a toxic gas that occurs in petroleum and natural gas. Involuntary sulfur-sulfur produced as a byproduct in response to legislative or process mandates. Native sulfur-naturally occurring elemental sulfur. Nonferrous metal sulfides-opper, lead, zinc, nickel, and molybdenum sulfides that are processed for their metal content. Organic sulfur complex organic sulfur compounds that occur in petroleum, coal, oil shale, and tar sands. Pyrites-iron sulfide minerals that include pyrite, marcasite, and pyrrhotite. Sulfate sulfur-sulfur contained in anhydrite and gypsum. Voluntary sulfur-sulfur produced in response to market demand. Basic Sulfur Products: Acid sludge-contaminated sulfuric acid usually returned to acid plants for reconstitution. Brimstone-synonymous with crude sulfur. Bright sulfur-crude sulfur free of discoloring impurities and bright yellow in color. Broken sulfur-solid crude sulfur crushed to -8 in. Byproduct sulfuric acid-sulfuric acid produced as a byproduct of a metallurgical or industrial process, generally relating to combined sulfur sources. Crude sulfur-commercial nomenclature for elemental sulfur. Dark sulfur-crude sulfur discolored by minor quantities of hydrocarbons, ranging up to 0.3% carbon content. Elemental sulfur-processed sulfur in the elemental form produced from native sulfur or combined sulfur sources, generally with a minimum sulfur content of 99.5%. Formed sulfur-elemental sulfur cast or pressed into particular shapes to enhance handling and to suppress dust generation and moisture retention. Frasch sulfur-elemental sulfur produced from native sulfur sources by the Frasch mining process. Liquid sulfur-synonymous with molten sulfur. Liquid sulfur dioxide-purified sulfur dioxide compressed to the liquid phase. Molten sulfur-crude sulfur in the molten state. Prilled sulfur-solid crude sulfur in the form of pellets produced by cooling molten sulfur in air or water. Recovered sulfur-elemental sulfur produced from combined sulfur sources (including byproduct hydrogen sulfide, but sometimes referring only to sulfur from fossil fuels) by any method. Slated sulfur-solid crude sulfur in the form of slate-like lumps, produced by allowing molten sulfur to solidify on a moving belt. Specialty sulfur-prepared or refined grades of elemental sulfur that include amorphous, colloidal, flowers, precipitated, wettable, flour, and paste sulfur. Sulfur ore-unprocessed ore containing native sulfur.

Jan 1, 1994

By W. Miola

The MSHA prescribed method for the determination of quartz in airborne respirable dust samples from underground coal mines is the P-7 method, a combination of low temperature radio-frequency ashing (LTA) and infrared analysis (lR). There is no prescribed procedure for quartz analysis in bulk samples of coal and host rock. Dispersive Infrared (IR), Fourier-transform Infrared (FTIR), and X-Ray Diffraction (XRD) methods are most commonly used for quartz analysis in powders. Several aspects of the experimental procedures such as the analysis sample preparation from bulk samples, ashing techniques, scanning procedures, peak measurement location, calibration techniques, sample amounts, size consist, and data interpretation affect differently the results from each of the methods. Significant differences in analysis results from X-ray diffraction (XRD) and infrared spectroscopy (IR) on the same samples are reported. All these studies point to the need for reliable quartz analysis methods. In a recent research, a procedure for preparing bulk coal and host rock samples for quantitative quartz analysis was developed. Further the results from X-ray diffractometry and infrared spectroscopy for quartz content on identical samples were compared. Calibrations with pure and mixed standards were used to assess the influence of particle size distribution, matrix, and calibration on analysis results. In this paper, several issues with the measurement of quartz in the samples of coal, host rock, and airborne respirable dust from mines are outlined and quantified.

Jan 1, 1994

By M. J. Friedel

The U.S. Bureau of Mines (USBM) investigated the use of seismic refraction tomography (SRT) for identifying changes in pillar loading at the Foidel Creek coal mine near Steamboat Springs, CO. The inherent three-dimensional problem of directly imaging coal pillar conditions is reduced to a single plane by considering only the load transmitted from the pillar to the adjacent floor rock. Floor strata velocity tomograms (at two pillar locations) illustrate that loading conditions are non-uniform and non-unique. Also, time sequence monitoring, as the longwall face advanced, demonstrated that SRT can be used to image spatial changes in loading conditions. SRT offers the mining engineer a simple and flexible technique for evaluating pillar conditions, and thus, both present and alternative mine designs.

Jan 1, 1994

By F. Sill

The disposal of residual material from processing and combustion of coal, from incineration of domestic refuse and sewage sludges kind to the environment is a prior task for the future. Deutsche Montan Technologie (DMT) has developed a new technique which makes possible to fill-up goaf cavities behind running caving systems in coalmining. In a mixing and pumping station on the surface high concentrated suspensions are produced from the above mentioned materials. The paste is pumped through pipes to the coalfaces and via trailing discharge pipes stretched to the fracture zone in the caved-in goaf. Since three years a special designed plant is working successfully on a coal mine of Ruhrkohie AG.

Jan 1, 1994