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By Víctor Vázquez, Guillermo Tiburcio, Martin Encinas, Jesús L. Valenzuela, Erick Montaño, Alejandro Valenzuela, José Parga

Merrill-Crowe is the primary process used for the concentration and purification of silver in a cyanide solution. The Langmuir Adsorption model for silver recovery in a cyanide solution was used for the study. The maximum adsorption capacity was 6.19 mmol/g for silver. This model properly adjusts the experimental results of the adsorption equilibrium with high correlation coefficients, which also favors the formation of a single layer of molecules adsorbed for the silver in the electrocoagulation- generated species. The thermodynamic parameters ΔG, ΔH, and ΔS were estimated, and it was found that the adsorption process is exothermic and spontaneous. For the kinetic study, the Lagergren second-order equation was used to study the adsorption speed. To characterize the solids coming from the electrocoagulation, X-ray diffraction (XRD), and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX) were used; the results of this study suggest that silver is present in aluminite, hydroniumjarosite, and alunogen.

Oct 30, 2021

By A. Halim, J. Gustafsson, A. van Wageningen, J. Johansson, · J. Lööw, K. Kocsis

A major part of the European Union’s (EU) project Sustainable Intelligent Mining System (SIMS) is investigating the development of diesel-free/carbon–neutral underground mines in order to ensure sustainable underground mining in the future. Replacing diesel machines with electric vehicles in underground hard rock mines has been widely acknowledged by the mining industry worldwide as a critical step to improve working conditions by reducing diesel exhaust–related contaminants, to reduce mine ventilation electrical power cost by reducing mine airflow quantity, and to reduce mine greenhouse gas emissions. All of these are major requirements to achieve sustainable future underground mining practices. A field trial of Epiroc’s 2nd generation of Battery Electric Vehicles (BEVs) at Agnico Eagle Finland’s Kittilä mine was conducted during 2019–2020. Vehicles tested were MT42 mine truck, ST14 Load-Haul-Dump (LHD), and Boomer E2 jumbo drill rig. This paper outlines the improvement of the working conditions observed in the field trial, and the opinions of the mine personnel at Kittilä mine on using BEVs instead of diesel machines. Measurements of atmospheric contaminants and air temperatures taken during the field trial clearly demonstrated a significant improvement of working conditions when BEVs were operating as opposed to diesel machines. This field observation was supported by the opinion of the majority of the Kittilä mine workers. However, some remaining concerns must be addressed before BEVs can replace diesel machines.

Oct 25, 2021

By Dejan Petrović, Pavle Stojković, Jelena Ivaz, Saša Stojadinović

In spite of the fact that flyrock phenomenon represents the real threat for personnel and machinery, it still remains insufficiently investigated. There are efforts, in the mining community, to explain the causes of flyrock, but the models capable to accurately predict flyrock occurrence and define the flyrock distance still do not exist. This article is an attempt to establish such a predictive model. The model utilized the adaptive nature of artificial neural networks and combined it with the accuracy of numerical modeling of physical phenomena. Necessary data were collected by high-speed camera recordings of actual blasts at three different surface mines and processed for further use for artificial network training. The result was a neuro-numerical couple which was capable to predict flyrock occurrence, estimate the launch velocity of flyrock fragments, and calculate the maximum distance of flyrock fragments. The safe distance was then calculated by multiplying the flyrock distance with a factor of safety. The article explains the procedure for data acquisition and processing, artificial network construction, training, and validation. It also explains the principles of flyrock distance calculation and, finally, provides a definition of factor of safety and safe distance. The results showed that the prediction was satisfactorily accurate and reliable.

Oct 22, 2021

By Qingwen Shi, Gang Xu, Shuwen Wang, Brijes Mishra

Pressure relief borehole is one of the most effective methods to treat coal burst in deep-buried coal seams. However, due to the large amount of randomly distributed fractures in the coal body and the varying stress environments in underground coal mines, there is no practical method to assess relief boreholes by far, which brings problems for borehole design and construction. This study focuses on the assessment of relief boreholes in a single driving entry wherein the impact of mining panels on relief boreholes is eliminated. A practical method, focusing on field monitoring of borehole deformation with a new device, is developed to evaluate the single driving entry’s relief boreholes. This method is applied to a Chinese coal mine. The application results showed that the convergence process of the boreholes showed a three-phase characteristic. Phase one involves the fastest deformation, reaching up to 8% in the first 3 to 4 days. Phase two lasts longer and converges more, reaching up to 30% in 4 months. Phase three stays balanced until the excavating face moves. The three-phase characteristic indicates that a large diameter of the borehole ensures relief efficiency because the borehole provides adequate space for deformation throughout its life span. In addition, it is verified that long boreholes and slow footage improve relief efficiency by providing adequate time for the boreholes to work. The application proposes that boreholes in the test coal mine need to be drilled larger and longer for optimization.

Oct 19, 2021

By Ana E. Bohé, Georgina De Micco, Juan P. Gaviría, FEDERICO J. POMIRO, Gastón G. Fouga

Chlorination and carbochlorination processes have industrial applications in metallurgical activity for extraction and purification of uncommon metals such as rare earth elements (REE). This study reviews the chlorination and carbochlorination reactions of light REE (LREE) oxides with chlorine considering the thermodynamic, stoichiometric, and kinetic aspects of the reactions. Lanthanides between lanthanum to gadolinium were considered as LREE, in agreement with previous literature, and the results were detailed in this review. LREE were analyzed taking into account their oxidation states and were divided into three groups accordingly. The results presented show that, although the LREE are chemically similar, their behaviors during the reactions with Cl2 and Cl2–C, and the different LREE-O–Cl compounds formed, have particularities. It was observed that gadolinium, in both thermodynamic calculations and experimental results, presents some differences, and it can be considered intermediate between light and heavy REE; i.e., reactions between LREE2O3 and Cl2(g) begin at approximately 250 °C, except for Gd2O3 that begins at 327 °C. The present work will contribute to a better understanding of the chemistry of LREE oxides and Cl2 under different conditions and the products obtained in the LREE–O––Cl2(g) and LREE–O–C–Cl2(g) systems.

Oct 15, 2021

By Huiqin Yao, Dongmei Liu

The study investigated the potential use of low activity circulating fluidized bed combustion (CFBC) ash and phosphate tailings for the production of a filling material based on the cement. The phosphate tailings were used as aggregate and consolidated by cement and CFBC ash. The results showed that the bleeding rate and fluidity of all mixtures decreased with the increasing the amount of CFBC ash. The fluidity of filling slurry is highly related to the experimental factors such as the content of sulfur solid ash, B/A ratio, and mass concentration. The replacement of CFBC ash ranging from 20 to 40% led to a significant decrease in setting time and an obvious increase in compressive strength, but the above effect was obviously weakened when reducing the mass concentration and B/A ratio. The hydrated calcium silicate gel and ettringite generated from the hydration of cement and CFBC ash were the main sources of strength for the filling materials. When the recommended proportion was 1/6 binder/phosphorus tailings ratio, 76% solid content, and 40% CFBC ash replacement, the filling material still met demands on working and mechanical properties; at the same time, the utilization of CFBC ash and phosphorus tailings was maximized.

Oct 11, 2021

By D. Sethuram, P. G. Koppad, S. Iyengar, R. Shobha

TiB2 and CeO2 particle-reinforced Al6061 hybrid composites were manufactured using stir casting and hot rolling techniques. The base alloy and composites were hot-rolled at 500ºC and a 50% reduction was achieved through 12 passes. The effect of varying TiB2 and CeO2 particle additions on the microstructure and mechanical properties of the Al6061 matrix was studied. Scanning electron microscopy showed uniform dispersion of both the reinforcements, with good interfacial bonding. Microhardness and tensile properties like yield and tensile strength were found to be higher for hybrid composite with 2.5% TiB2 and 2.5% CeO2 compared to Al6061 alloy and other hybrid composites. The increased tensile strength is attributed to good dispersion and interfacial bonding between the particles and Al6061 matrix. Fracture analysis using a scanning electron microscope revealed ductile fracture for the Al6061 alloy and mixed characteristics of ductile-brittle fracture for hybrid composites

Oct 1, 2021

By Siavash Mahvelati, Alireza Kordjazi, Joseph Thomas Coe

Deep foundations are often constructed as end bearing members with a significant amount of their capacity derived from bedrock. Sites with highly variable bedrock conditions therefore present a unique challenge when attempting to estimate the design elevation of deep foundations. Typical subsurface characterization techniques such as drilling, standard penetration testing (SPT), and cone-penetration testing (CPT) may fail to adequately establish top-of-rock elevation in geologic settings prone to karst and/or significant amounts of residuum, saprolite, and deformed bedrock. Seismic surface wave geophysical methods have been increasingly used to map bedrock topography in such settings. However, the current standard of practice for these methods introduces resolution limitations in spatially variable subsurface conditions due to averaging effects from the analytical framework used to process the acquired data. This study explores the use of a tomographic approach with full waveform inversion (FWI) to map top-of-rock elevations at a numerically simulated site representative of highly variable bedrock topography. Comparisons are made with seismic refraction (SR) and a dispersion-based multichannel analysis of surface waves (MASW) approach as more commonly used in geophysical subsurface investigations. The results highlight that FWI provides a superior estimate of top-of-rock topography than SR and MASW at a cost of a significant increase in the required computational resources and time.

Oct 1, 2021

By R. C. Nkhoma, K. A. Annan, S. Ngomane

The effects of welding current, electrode force, and welding time in a resistance spot weld were studied to investigate the effectiveness of welded joints between a thin EN10130: DC04 material and a thicker 817M40 part, through analysis of the microstructural and mechanical properties. All welded specimens were subjected to tensile testing at room temperature (25°C) and sub-zero temperature (–46°C) to test the strength of the welded joints. No full button failure was observed at either room temperature or sub-zero temperature after optimization of the weldng parameters. The fusion zone was observed to consist mainly of martensitic phase, due to rapid quenching, while the HAZ was composed of clusters of martensite in a ferrite and bainite matrix. The base 817M40 metal remained fully ferritic after welding. The hardness was found to increase with increasing welding current. An increase in nugget size, indicating good fusion of the weld, was observed with an increase in the welding current.

Oct 1, 2021

By MATT RENAUD, Mustafa Kumral

As high-quality mineral deposits are thoroughly exploited, mines of the future will have to move towards more remote and lower quality projects. With these projects comes an increased business risk to the operator. Even now, mining companies often turn to foreign countries for new deposits to produce, introducing the concept of country risk into their portfolio. Furthermore, feasibility studies often fail to accurately quantify the risks associated with various projects, and as such, this study proposes a technique of risk quantification which can both aid mining companies to evaluate the viability of investment and assist in risk disclosure to public investors for the mining industry of the future. This paper aims to quantify the effects of country risk on the valuation of potential mining projects, using a combination of modular and risk-weighting techniques to evaluate the country risk premium (CRP) required to obtain capital for operation of risky foreign mining projects. The techniques proposed in this paper are demonstrated using fictional examples and then evaluated for accuracy against a recently developed debt-funded precious metal project in a country in the Americas.

Sep 30, 2021

By Jogeshwara Sahu, Sapan Kumar Kandi, SANDEEP KUMAR JENA, Sachida Nanda Sahu, Sarada Prasad Das

The present article reports the recovery of potassium from mica scrap using carbide lime waste and NaCl. The acid leaching of mica [4 M H2SO4 at 90 °C] can recover a maximum of 25% potassium. However, in the chlorination roasting (with CLW and NaCl) water leaching process, it was possible to recover potassium to the tune of 94% [900 °C, 50 min roasting; mica:CLW:NaCl 1:0.75:1]. The formation of water-soluble phase like sylvite (KCl) and water-insoluble phases like anorthite ( CaAl2Si2O8) and nepheline ( NaAlSiO4) confirms the complete breakdown of the mica crystal structure. The extraction mechanism proceeds with the formation of a transition state followed by the release of potassium as KCl. The characterisation studies using ICP-OES, XRD, FTIR and FESEM support the proposed extraction mechanism. The salt produced by the evaporation of roast-leached liquor confirms the presence of sylvite and halite only, which can be separated to get the fertiliser grade KCl.

Sep 29, 2021

By S. Rukhaiyar, M. Ramulu, G. Pradeep, P. K. Singh, P. B. Choudhury

The drill and blast method is the most prominent rock excavation method used in mining and civil engineering projects. The ground vibration is the most undesirable effect of the blasting and needs to be controlled. The blasts are designed so that ground vibration at nearby structures must remain under the prescribed limit. Various empirical blast vibration attenuation models have been presented to estimate the ground vibration for designing purposes. These models assume ground vibration as a function of distance and maximum charge per delay. United States Bureau of Mines (USBM) model is most commonly used for the blast design. However, the uncertainty associated with these models is seldom characterized, thus diminishing its reliability. The probabilistic Bayesian approach associated with the Monte Carlo method can easily quantify uncertainties associated with the model and its parameters. Thirty-three blast vibration observation data from a granite quarry in Kerala, India, is used to estimate the probability distribution of model parameters. Markov Chain Monte Carlo (MCMC) approach is used for sampling 12,000 samples for obtaining the posterior distribution of parameters. The uncertainty associated with model parameters is quantified from the posterior distribution, and this is further used to estimate the credible and prediction limits of the model. The point estimate of the most optimum value of the parameter is estimated using maximum-aposteriori or MAP estimate. The model parameters are also obtained using the commonly used least-square error method, which is a maximum likelihood estimation or MLE approach. It has been observed that the accuracy of the model obtained using both MAP and MLE approach is almost equal. However, the MAP estimate as per Bayesian probabilistic analysis has the added advantage that it can estimate the uncertainty of parameters as well as the model, which is not possible using the MLE approach.

Sep 27, 2021

By JESSICA W. A. AZURE, Samuel Frimpong, AZUPURI G. A. KABA, FORSYTH A. KADINGDI, PROSPER E. A. AYAWAH

This study developed machine learning (ML) models for predicting rock formation reactive forces experienced by a hydraulic shovel bucket during excavation. To do this, rock formation in the form of muckpile was modeled as granular ball elements in three-dimensional particle flow code (PFC) using linear bonding logic. A typical field-size hydraulic shovel bucket modelled in AutoCAD was used to excavate the rock formation and the three-dimensional shovel bucket resistive forces required to cut through the rock formation were measured and recorded. The experiments involved different muckpile height, bulk densities, repose angles, and average fragment size. Six ML algorithms, artificial neural network (ANN), K-nearest neighbor (KNN), linear, random forest (RF), regression tree (RT), and support vector machine (SVM), were evaluated on their ability to predict the shovel bucket resistive forces. The input variables used for the prediction of the resistive forces were the muckpile bulk density, angle of repose, height, and fragment size. The results showed that the ML techniques are useful and reliable methods of predicting rock formation resistive forces based on the rock formation properties. This research is a preliminary step towards developing reliable models for accurate prediction of excavation forces/torques which could potentially enhance hydraulic shovel process automation.

Sep 27, 2021

By Xiaobo Zhang, Panshi Xie, Xiaobo Wu, Ding Lang, Jiandong Yu, Yongping Wu, Kun Feng

In a fully mechanized top coal caving mining process, the mechanical properties of the top coal deteriorate constantly, and the stability of the support is determined by the boundary position of the top coal entering the limit equilibrium state. Top coal flaking occurs more easily along the advancing direction owing to an increase in the distance of the boundary from the wall. Moreover, the strength of the coal seam is an important factor that determines the boundary position. The equation of the top coal limit equilibrium zone boundary, used in fully mechanized top coal caving mining, was determined based on the limit equilibrium theory, continuum damage mechanics, and the Hoek–Brown rock empirical strength criterion. Using the RFPA3D and UDEC numerical analysis methods, the effect of top coal strength on the mechanical behavior during the mining process was determined; and the space–time relationship between the top coal deformation failure, damage evolution, and boundary of the limit equilibrium zone was established. The results revealed that when the coal mass entered the limit equilibrium zone, accelerated crack development, accelerated damage, and axial unloading occurred. Moreover, an increase in the coal seam strength caused the boundary of the top coal limit equilibrium zone to be closer to the wall. By comparing the numerical results with the theoretical results, the overall trend was found to be consistent, allowing the verification of the rationality and reliability of the determination equation of the boundary position of the limit equilibrium zone.

Sep 21, 2021

By Yinan Zhang, Y. Luo

Most of the reported coal spontaneous combustion events occur in surface and underground mines where low rank coals (i.e., subbituminous and lower for this particular studies) are extracted indicating their high propensities for spontaneous combustion. Low rank coals have high moisture content (15 to 45%) and are capable of absorbing more moisture in dried condition. However, it is hard to induce the initial stage of self-heating process for the low rank coal using the current laboratory R70 testing method — a method widely used in the coal industry. Like a sponge, dry low rank coals can absorb water vapor in the air while the heat contained in the moist air is transferred to coal and served as the required activation energy to initiate the coal self-heating process. In order to prove this theorem and quantify the effects, the R70 adiabatic oxidation testing method has been improved to introduce a controlled moist flow into the coal reaction vessel. Tests using the new method and its setup on low rank coals showed that the initial self-heating process of coal sample can be greatly accelerated by the added water vapor — impossible with the regular R70 method. Once the self-heating is sustained, the removal of air moisture can further accelerate the process.

Sep 17, 2021

By Qingqing Huang, Aaron Noble

The Mineral & Metallurgical Processing Division (MPD) of the Society for Mining, Metallurgy & Exploration held the first MPD Student Video Contest during the spring of 2021. The event showcased the work of 18 graduate and undergraduate students from several U.S. and international institutions. The contest began in January when students submitted a onepage abstract for judging. Over the next several months, they developed a three-minute video that further explained their research findings. Both the abstract and video were evaluated by a panel of judges, and the top-placing participant was recognized at an MPD virtual event held on June 10.

Sep 13, 2021

By Vijaya Bhushan Rao, Jason Redgers

A mixed-use development comprising of multistoried residential towers, retail and associated infrastructure covering an area of 500,000 m2 is under construction in Dubai. The subsoil conditions consist of calcareous sands with high carbonate and shell content with hard and competent strata encountered at varying depths. To achieve the design requirements of soil stiffness, friction angle, limit differential and total settlements and mitigate the liquefaction due to a seismic event then ground improvement were deemed necessary. In order to provide the most time and cost efficient solution numerous techniques were applied to meet the requirements for all depths such as Vibrocompaction, VC (depth >8m), Dynamic Compaction, DC (depth < 8m)] and Rapid Impact Compaction, RIC (depth <4m). The specified ground improvement requirements were translated into a target Cone Penetration Test, CPT line that served as the defacto performance requirements for the project. Suitable correction factors were applied to the CPT results to account for the high carbonate content following the works of Al-Homoud and Wehr 2006, Belotti and Jamiolkowski , 1991 and Vesic, 1965. Furthermore, the alpha factor, α, used to obtain stiffness from CPT results was applied following A.C. Meigh 1987 and Massarsch & Fellenius, 2005 where high over consolidation ratios (OCR) could be demonstrated.

Sep 8, 2021

By Christian Hoyme, Jochen Maurer, Hans Regler

Up to today, it has been very difficult to obtain qualitative and quantitative information about the status and production process of a construction site. It is becoming more and more important to be able to analyze this process so as to notice bottlenecks and interruptions on the site early on. The high costs of each shift in special foundation industry mean that making the wrong decision and/or interruptions can put the financial result at risk. Previously, keeping reliable data meant manual process documentation. This was done either by an additional staff member (incurring high additional costs for training, education, etc.) or by the equipment operators. The latter is critical, because they have to initiate every process step change, leaving no time to log data separately. Studies have shown that there are considerable deviations from the actual process steps. In this paper, a seamless, automated method will be introduced to analyze the construction process. This method recognizes each process step from the equipment data. The main purpose of the data recorded by the piling rig is the need of quality reports and now basis for the presented analysis. Here, a method was successfully transferred from theoretical computer science (compiler construction field) to find application for process recognition. Because the execution of works in special foundation construction can always be defined sequentially and therefore also practiced sequentially, recognition can occur step-by-step. Our method always recognizes the next step, so it does not have to monitor as much data at the same time. Individual trigger points are easier to define. Unlike solutions that are based on a global approach and allocate suitable process steps to data patterns, thereby also creating gaps, the presented method is always seamless. Furthermore, this method can be applied regardless of time or location provided that the necessary machine data is available, which is normally the case with production data logging. This means that construction sites even from the past can also be analyzed and the results used for comparisons. The first results from the analysis of a complete continuous flight augering (CFA piles) installation process of a construction site will be presented.

Sep 8, 2021

By Louay Owaidat, Daniel Jabbour, Allan Frappier, Jose Gomez, Mark Stanley, Tino Maestas

The U.S. Army Corps of Engineers (USACE) is implementing a levee strengthening program along the Sacramento River East Levee (SREL) designed to correct 11 miles of deficient levees as identified by recent hydraulic and geotechnical investigations. The first project, the subject of this paper, completed in 2020 resulted in approximately 3.0 miles of improvements to the California Central Valley Flood Protection system. The project area lies along the east bank of the Sacramento River in Sacramento. The program consists of constructing cutoff walls through existing levee embankments to remediate levee through seepage and under-seepage. Key challenges included designing and constructing measures to remediate a 100-year-old legacy levee system, the presence of both industrial and residential properties immediately adjacent to the landside of the levee creating severe space and access limitations, and performing this work during the 2020 statewide mandate to shelter-in-place due to the COVID-19 pandemic. The project team of contractors, USACE, state and local agencies, and engineering firms partnered to bring this project to successful completion within budget and on schedule expending more than 60,000 man-hours with no lost time accidents. With the issuance of future planned contracts, the program will significantly reduce flood risk to the City of Sacramento.

Sep 8, 2021

By Karsten Beckhaus

Barrier walls in levees and dams are designed and constructed for new structures and for rehabilitation or upgrade of existing structures to control seepage. Construction methods applied are often deep soil mixing with a cementitious slurry or excavating a trench and refilling it with a plastic concrete. This paper explains the technical background of jointless cementitious barrier walls inevitably developing thermal tensile stresses and how these stresses can be controlled. The theoretical background of thermal stresses is explained based on experimental and numerical studies of essential factors. Although a low cracking risk is generally inherent, risk mitigation measures should be taken to thermal cracking and to ensure the permanent function of such walls as a low-permeability and high-deformability barriers.

Sep 8, 2021