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By Jeffrey W. Fergus, Shiqiang Hui

"Aluminum is an important alloying addition to the zinc used in the hot-dip galvanization of sheet steel to control the properties and appearance of the resulting coating. Optimization of the galvanization process requires control of the alloy concentration which can be improved through the use of chemical sensors. Aluminum sensors based on molten electrolytes are commercially available but are not widely used because of their high cost. One approach to reducing the cost is to use a solid electrolyte which can simplify the sensor design and thus reduce the cost of fabrication. In this paper, the development of an aluminum sensor based on a solid fluoride electrolyte, specifically magnesium fluoride, will be described.IntroductionThe concentration of the zinc bath used in hot-dip galvanization affects the galvanization process as well as the properties of the resulting coating. Thus, accurate in situ measurement of the alloy composition can be used to improve process control. This paper describes a solid-electrolyte-based aluminum sensor for monitoring the bath composition during hot-dip galvanization."

Jan 1, 1997

Considerable attention has been given to the restoration of low-level radioactive (<1000 pCl/g) sites contaminated during the early years of the atomic energy program. Current clean-up activities which involve the relocation of contaminated soils to licensed disposal sites have been shown to be very costly due to the large volumes of soils which must be excavated, transported and stored. Recent characterization studies conducted at Virginia Tech suggest that the volume of soil requiring disposal can be greatly reduced using mineral processing techniques such as classification, density separation and froth flotation. This article discusses the application of these technologies for soil remediation and describes a conceptual flowsheet for treating soil samples from two contaminated sites.

Jan 1, 1997

By Michael J. Mankosa

Carpco has recently evaluated the use of various mineral processing techniques for secondary materials recovery. These applications include recycled foundry sands, plastics and secondary metals. This paper describes different recycling applications and the associated separation solutions. Results from extensive laboratory-and pilot-scale test work in each area are discussed. Industrial installations resulting from this test work will be presented. A detailed description of an industrial installation patented by Carpco for the recovery of plastic and metallics from current waste by-products is presented.

Jan 1, 1997

By A. Feather

The Minataur? Process (Mintek Alternative Technology for Au Refining) is a novel route for the production of high-purity gold using solvent extraction. Following the successful demonstration of the process on a pilot-plant scale, a full-scale 24 t/a production plant has been commissioned at Harmony Gold Mine in Virginia, Free State. The commercial implementation of this process represents not only a significant advance in gold-refining technology, but may be instrumental in initiating important changes in the legislation regulating the marketing of gold in South Africa. Gold of either 99.99% or 99.999% purity can be produced from intermediate process products having a wide range of gold contents. The process comprises oxidative leaching of the solid feed, followed by selective solvent extraction of the gold from the leach liquor to reject impurities, and precipitation of high-purity gold powder. This paper outlines the process, presents selected results of two pilot-plant trials in which 5 kg/d of high-purity gold was produced from silver-refining anode slime and gold-electrowinning cathode sludge, and provides some details of the cost benefits.

Jan 1, 1997

By H. Wu, V. Izaxon

Intensive ventilation is required during the excavation of a mine opening and the subsequent exploitation of the mineral resources. The exchange of heat between the ventilation air and the rock mass has a major influence on the thermal regime of a mine, especially in the initial segment of the airway. In frozen ground, heat flow into the rock mass from the ventilation air can result in the eventual thawing of the permafrost, which can result in roof-rock instability. This paper presents a mathematical analysis of the dispersion process of ventilation-induced heat by thermosyphons placed on the surface of the mine. The principal uses of thermosyphons in the Arctic are to reduce the ground temperature to prevent potentially unstable permafrost from thawing and to increase the bearing strength of the material. The mathematical model of the physical problem, generally known as "the Stephan problem," takes into account the varying thermo-physical properties of air and the frozen and thawed rock mass, the thermal properties of the freeing fluid in the thermosyphons and the phase change of water. Finite-difference techniques were employed to determine the temperature isotherms around the thermosyphons. It was found that two rows of thermosyphons on a 10- x 10-m grid provide an acceptable design spacing for reducing the ground temperature around the mine airway.

Jan 1, 1997

By John Wallace

"Monitoring compound semiconductor crystal growth using multifrequency eddy currents for sensing illustrates some of the extreme problems of measurement and interpretation that are not often seen in metallic systems. Using sensor arrays and scanning sensors have produced a qualitative and quantitative understanding of some of the high temperature electrical conductivity mechanisms in several compound systems. A detailed review of the CdTe/CdZnTe data is presented showing some of the complexity in the data as opposed to what is found in elemental semiconductors.HistoryThe most common goal in the use of eddy current measurement in crystal growth is to deter-mine the curvature of the liquid solid interface during growth to test if the heat transfer estimates of the thermal design were adequate for single crystal growth[l]. This aim could be met but represented only a small fraction of the data that was produced observing a growth cycle. A secondary consideration was what could be discovered in the recorded data about the growth and subsequent heat treatment as the boule cooled. This is usually a more difficult task because a crystal growth process is not a controlled experiment so much as a process that continually sees modification. Using a sensor arrays or a scanning loop has produced a qualitative and quantitative basis for understanding some of the high temperature electrical conductivity mechanisms. The implication of the these measurements of electrical conductivity variations are important in that they reflect the complex defect states that will occur on cooling and heat treatment following crystal growth. In contrast to the complex behavior of the conductivity of these compound semiconductors in the solid and liquid state we have the very well characterized system silicon to compare. Initially the interest on using eddy currents to monitor compound semiconductors came from G. Westphal at the Texas; Instruments Company in 1987 to monitor aspects of growth and compounding of GaAs. This was followed by work on solution growth of HgCdTe with D. Witter. The initial interest in the use of eddy cur-rents for monitoring CdTe crystal growth came from Prof. Wilcox at Clarkson University in the practical interest to determine and control the crystal interface curvature during vertical brigdeman growth. The first actual work was done by one of his former students. G. Neuge-bauer at the II-VI Corporation which was carried on by G. Rosen at Clarkson and R. Shetty at II-VI Corporation and with A. Socha at Johnson-Matthey Electronics. The work on CdTe extends over four years and yielded sufficient data to allow one to evaluate the utility of the information produced as compared to what could be obtained from monitoring an elemental semiconductor such as silicon."

Jan 1, 1997

By R. Lanza, M. Hytros, N. Saka, I. Jureidini, J. H. Chun, D. Kim

"A novel method for delineating the solidification front in metal casting has been developed using the attenuation phenomenon of electromagnetic radiation (y-rays or x-rays) and computed tomography (CT). The densities of the liquid and solid phases that exist during metal casting may differ anywhere from 4 to 12 % depending on the metal. As in the medical imaging field, CT provides an excellent means of mapping this density variation in a solidifying casting into two-or three-dimensional images.In an effort to develop an industrial-scale sensor, laboratory-scale experiments have been conducted using a cobalt-60 (Co60) radioisotope and a sodium-iodide (Nal) scintillation detector. The CT image reconstruction was performed on a crucible containing pure tin in a two-phase state. Although the spatial resolution and data acquisition speed were not optimum, the CT images clearly differentiate the liquid and solid phases of the tin in the crucible. To maximize resolution and minimize data acquisition time, a linear accelerator (linac)-based CT sensor is being developed and tested for application in the continuous casting of steel and aluminum alloys.IntroductionIn all casting processes, the quality of a finished product and its production rate depend upon the shape and movement of the solidification front. From a quality perspective, it is well documented that solidification kinetics (heat and mass transfer, fluid flow, microstructure evolution) greatly influence the final properties of castings [l,2,3]. Product shortcomings, such as surface defects, cracks, macro-and microsegregation, and inclusions are directly controlled by the solidification process. By understanding the role the solidification front plays in the casting process, product quality may be dramatically increased through the reduction of defects."

Jan 1, 1997

By Christopher Mark

Horizontal stresses are caused by global plate tectonic forces. During 1995 alone, they were largely responsible for closing two U.S. longwall mines. This paper presents six case histories from Pennsylvania, West Virginia, Kentucky, and Alabama. In each case history, a mine encountered roof falls or difficult ground conditions in the headgate, caused by horizontal stress concentrations. The problems are detailed, and the control measures adopted are described. In most cases, nearby longwall panels without stress concentrations were trouble-free. The paper also discusses detailed measurements made at two adjacent Pennsylvania longwalls. One headgate was oriented to avoid a horizontal stress concentration, and the other was not. Eliminating the stress concentration dramatically reduced roof support loads and roof deformation. The paper concludes that proper panel orientation and sequence is the key to maintaining headgate ground control. The optimum orientation is not parallel with the maximum horizontal stress, as previously thought, but rather 20° in the stress shadow of the gob. Other stress control techniques, including artificial support, are briefly discussed.

Jan 1, 1997

By B. M. Loftus

An investigation into the use of impinging stream (jet) reactors for the leaching of a free milling ore produced an increase in gold recovery by 10% while decreasing leaching time by up to 90%.Tests on refractory ores demonstrate no apparent improvement in recovery. However, leaching kinetics are dramatically increased when these ores are subjected to jet reaction prior to agitation.

Jan 1, 1997

By K. Biswas

For the pillars, which have been standing long after mining, the stability depends much on the weathering action in the presence of mine moisture. From the field observations, it has been found that this weathering action becomes critical in terms of pillar stability if the coal seam contains partings or binders in it. The weathering action degrades both the partings and coal in terms of their load bearing capacity as the mine moisture penetrates into them. This paper investigates the effect of weathering action on coal and partings in the laboratory. In the field, the strength profile in the coal and the partings and the effect of time (in terms of the pillar age) on them have been studied by using borehole penetrometer. In this paper, an attempt has also been made to establish formulae for time dependent strength of coal and partings.

Jan 1, 1997

By D. W. Rierson

Svedala has a ported kiln process, designed specifically for the direct reduction of pelletized or natural lump iron ores. The process is called ACCAR. This ported kiln technology has been coupled with Svedala&apos;s GRATE-KILN System, for iron ore pelletizing, into the GRATE-CAR System for the reduction of fine grained ore concentrates through the steps of agglomeration, induration and reduction in a single production line. Additional applications of the GRATE-CAR System include: the recovery, agglomeration and reduction of steelmill waste oxide fines and the use of minus 6mm size natural lump ores to produce a highly metallized pellet agglomerate. Svedala conducts tests to confirm certain operating parameters through process simulations of the GRATE-CAR process. These tests are conducted at Svedala&apos;s Process Research and Test Center, Oak Creek, Wisconsin. Svedala also assesses issues of process variables, heat transfer, equipment sizing, retention time and endothermic demand associated with iron ore reduction using natural gas or coal as the reductant. The purpose of this paper is to present the GRATE-CAR processing concepts, the commercial production line and the testing procedures associated with investigating potential raw materials.

Jan 1, 1997

By Philip Thompson

"Carefully planned laboratory test programs provide valuable data regarding the amenability of low grade gold ores to heap leaching. The most common laboratory test is the column leach test. The overwhelming problem associated with this type of test is the limit on the test column height. Most laboratories use a three (3) meter (10 foot) high column as a standard test due to building ceiling limitations, sample size limitations, etc. This paper presents a case study in which an ore sample was tested in a 1.5 meter, a three meter, and a six meter high column to determine the effect of column height on the test results. Other important factors such as sample preparation protocol, preliminary bottle roll testing to determine appropriate crush size, column diameter requirements, and leach solution analyses, are also discussed.IntroductionColumn leach testing has been used for years by many laboratories to determine the amenability of low grade precious metals bearing ores to heap leaching. However, the test work can be compromised by poor planning, misinterpretation of results, and extrapolation of data beyond the reasonable boundaries of the experiment. Preliminary test work should be performed prior to column testing. This preliminary work provides valuable information regarding the response of the ore to cyanidation and aids in the design of the column tests.The sample should be screened into various size fractions prior to testing. The fractions are assayed to determine the gold content of each size fraction and of the overall sample. The most valuable preliminary test is the bottle roll cyanidation test which is usually performed on five kilograms of coarse sample in a large rolling bottle which can accept material up to 50 millimeters top size. The residue from this test is screened at different sizes to determine the distribution of unleached gold in the residue. Comparison of the gold distribution in the leach residue with the distribution of gold in the feed at the same size intervals provides an indication of the appropriate crush size for the sample. The overall gold extraction from the sample at the crush size tested is also determined from these data. Lime and cyanide requirements can also be estimated from this test. The viscosity of the bottle roll pulp and the size distribution of the feed and leach residue can also suggest whether agglomeration of the ore will be required prior to column testing. Ores which contain significant amounts of clays (greater than 5 percent) will generally require agglomeration to prevent plugging of the test column."

Jan 1, 1997

By D. Hong

The leaching behavior of rhenium in ammonium iodide solutions with iodine as oxidant has been studied. Experiments were carried out in an autoclave. The effect of stirring speed, temperature, pH of the solution, iodine and iodide concentrations on the dissolution of rhenium was investigated. It was found that high temperature and high pH of the solutions were essential for the efficient leaching of rhenium. The dissolution rate was found to be dependent upon the concentration of iodine and iodide. It was concluded that the dissolution of rhenium under the conditions studied was controlled by mass transfer of iodine with an apparent activation energy of 15.77 kJ/mole.

Jan 1, 1997

By Andreas Nolte

This paper includes a comprehensive report about the metallurgical utilisation of reusable products from electronic scrap recycling, car shredding industry, used glasses an various waste products, such as slimes and flue dusts, generated in a secondary copper smelter. Depending on the copper content, the type of copper compounds and the characteristics of accompanying substances, the materials are treated by smelting in furnaces, operating under reducing or oxidizing conditions. HKs pyro- and hydrometallurgical processes, blast furnaces, converters anode furnaces, tin lead alloy plant and tankhouse will be outlined. The reusable products are categorized according to the origin of the materials and then presented in the form of quantity and quality balances. Processing methods, process able quantities and quality requirements of inputs are described. The utilization degree of the most important metals (copper, tin, lead and zinc) is described with graphics. The report is rounded by information on operating licence according to the environmental regulations of the Federal Republic of Germany and data concerning supply and contracts

Jan 1, 1997

By I. Ohnaka

Although many works have been reported on the semisolid casting, the mold filling behavior of semi-solid alloys has not been so well understood. This paper compares the physical and numerical simulation results on the mold filling behavior. Physical simulation was performed by using solid-water mixture. The numerical simulation was made under the assumption of one phase flow with an effective viscosity. It was found that the solid particles stabilize the flow greatly if the kaction solid exceeds about 0.4, because viscosity increases greatly. The overall flow behavior can be estimated by the numerical simulation. Interesting flow behavior was also found which can not be observed in the case of one phase flow and which is difficult to simulate by the one phase flow assumption.

Jan 1, 1997

By Patrick R. Taylor

A novel method for Chemical Vapor Infiltration (CVI) using plasma technology is proposed, Plasma Enhanced CVI (PE-CVI). Due to the low rates at which CVI is currently performed, the use of plasma as a source of heat may be considered to be a faster and less expensive production method. Precursors fed in the hot region of the plasma gas are completely vaporized and forced by the same flow through a porous preform where it condenses as a new material. In this research, silica and methane where used as precursors to form SiC/on a / graphite felt (preform). To enhance the infiltration process, vacuum was used to increase the flow through the preform. Characterization of infiltrated graphite was perfontied using Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). A uniform distribution of Sic was observed along the felt with only twenty minutes of infiltration process, yielding a 178% increment in weight.

Jan 1, 1997

By R. G. Reddy

The oxidation kinetics of A13Ti intermetallics have been studied at the temperature range of 850°C to 100O0C in pure dry oxygen. The oxygen diffusion rates were investigated using TGA method. Parabolic rate constants were calculated. The oxidation scales were analyzed using SEM, EDS and X-ray diffraction. A continuous A120, scales with a little TiO2(rutile) were formed on the intermetallic surface. The A13Ti intermetallic exhibited excellent oxidation resistance among the Ti-Al base intermetallics.

Jan 1, 1997

By H. Soto, J. Jara, F. Nava

A method has been developed to recover cyanide and copper from solutions containing copper complexes and thiocyanate. Copper is precipitated as copper thiocyanate or as copper cyanide depending on pH and the concentrations of thiocyanate and cyanide in the effluent. The copper precipitate assays over 50% copper and presents good dewatering characteristics. After settling it can be separated from the effluent by filtration. The solution containing the bulk of the cyanide is then oxidized with ozone to transform the remaining thiocyanate into cyanide. This results in a regenerated solution rich in free cyanide that can be recycled to the cyanidation process. Careful control of the pH of the solution is required. First, pH of the effluent is lowered to optimize the precipitation and oxidation stages, then the pH is restored to an alkaline value to regenerate the cyanide solution. Recoveries of over 96% copper and cyanide were obtained in laboratory tests using industrial solutions. With this procedure, cyanocidic gold/copper ores could be treated economically by heap leaching, since the cyanide consumed by the copper impurities could be regenerated at very low cost (most of the cost of cyanide regeneration would be compensated by the copper credits). In order to achieve this, a bleed of the barren solution could be treated by the proposed method, and then recycled to the leaching step. The volume of solution to be treated should be large enough to keep a cyanide/copper molar ratio higher than 3:1. This would assure that copper does not cause undue interferences in the leaching or the carbon adsorption stages. If the thiocyanate content is low, the oxidation stage can be avoided, and the solution can be recycled to the leaching stage directly after the solid-liquid separation stage.

Jan 1, 1997

By Alan Rice

Abstract-The mechanism by which stratiform ore deposits of PGE (platinum-group elements) are laid down in ultramafic igneous complexes is not completely clear. Early studies by the author and coworkers on numerical analyses of the convective cooling of low-Rayleigh-number magma chambers examined the effect of suspended crystal load on fluid density, and raised the possibility that the growth of the suspended crystal load during cooling could split a magma chamber into several convecting layers. The lower layers would have a higher content of refractory phases than the upper layers, which would consist of more evolved melt. This paper considers numerical modelling, as well as theoretical and experimental work in other fields dealing with suspended loads in fluids. The calculations, which are based on the physics of convecting magmas, yield quantitative relationships consistent with the observation that economically interesting stratiform PGE deposits are restricted to large magma bodies, and also yield estimation of the depth in a magma chamber at which certain grades of mineralization may occur.

Jan 1, 1997

By D. C. Yang

A packed column jig has been developed for sharp separation of fine particles--150 down to 1 micron--having different densities. The packed jig is a column filled with corrugated packing. A slurry of mixed particles is fed into the middle of the column. Water enters near the bottom of the column as both a steady state and a pulsating flow. The pulsating water sets up a jigging action that interacts with the packing causing the dense particles to sink and exit the bottom of the jig and the lighter particles to rise and exit the top of the packed jig. The result is a sharp, environmentally friendly, gravity separation machine with low operating costs. Grades and recoveries of iron ore exceed that of known devices. Grades as high as 95 percent purity with concomitantly high recoveries are common for iron ore concentration. Low silica, sulfur and phosphate are common. This paper is the first to unveil the packed column jig technology in detail and presents its physical model with performance data. The purification of iron ores and coal is the paper&apos;s focus.

Jan 1, 1997