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By Byung-Su Kim

The recovery of elemental sulfur from sulfur dioxide has important implications for coal- burning power plants and nonferrous metal smelters. The thermodynamic analyses showed calcium sulfide to be suitable for recovering elemental sulfur from sulfur dioxide. At the temperatures of 1023 to 1153 K under the sulfur dioxide partial pressures of 5.0 - 60.1 kPa, elemental sulfur from sulfur dioxide was recovered by its reaction with calcium sulfide. The kinetics of this reaction were measured at the same conditions using a thermogravimetric analysis technique. This reaction scheme would be attractive if the coproduct calcium sulfate can be reduced to regenerate calcium sulfide. This is the topic of another paper. At 1073 K under the sulfur dioxide partial pressure of 25.8 kPa, 48 % of the original calcium sulfide was converted to calcium sulfate in an hour. Under the same conditions, 55 % of the regenerated calcium sulfide were converted to calcium sulfate in an hour even after third regeneration.

Jan 1, 1999

By G. A. Munoz

Gold leaching of an auriferous pyrite ore from the Portovelo deposit in Ecuador indicates that noncyanide leaching systems, such as thiocyanate and thiourea, are not as effective as the traditional cyanide system. For example, whereas approximately 95% of the gold can be leached from the ore with cyanide, only about 50% gold dissolution can be achieved with a thiocyanate leaching system. Electrochemical measurements indicate that gold is not cathodically protected by pyrite in these systems. Based on the results of preliminary diagnostic experiments, it appears that gold dissolution in thiocyanate and thiourea systems is limited by passivation due to the formation of either elemental sulfur or sulfur compounds on the gold surface.

Jan 1, 1999

By R. Schaller, Ch. Karcher, A. Thess

"Electron beam evaporation of liquid metals is an innovative technology increasingly used in industry to produce very thin coatings of high purity. In this process the surface of a metal ingot, placed in a water-cooled copper crucible, is heated by bombarding it with a high-energy electron beam gun. The material melts, forming a free surface and eventually starting to evaporate. The rising vapor cloud condensates as a thin film on a moving substrate. The strong energy input at the free surface gives rise to vigorous thermos capillary and buoyancy driven convective motion within the melt, leading to unwelcome heat losses. This paper aims to show how these losses can be reduced by optimizing the geometry of the crucible and by using external magnetic fields. We present both experimental and numerical results.IntroductionElectron beam evaporation of liquid metals [l] is an innovative PVD-technology which is excellently suited for the industrial production of high-quality coatings. In this vacuum process a high-energy electron beam heats up the surface of a metal ingot. The ingot melts and forms a free surface. A schematic view of the arrangement is shown in Figure 1. When the temperature of the free surface exceeds the actual (pressure-dependent) saturation temperature of the ambient gas, the liquid starts to vaporize. The rising vapor cloud finally condensates on a moving substrate located at some distance above. To guarantee a superior quality of the coating the melt is typically confined in a water-cooled copper crucible. The intensive cooling is necessary to avoid chemical reactions between the melt and the crucible walls, that is, crucible materials and their reaction products are practically excluded from evaporation."

Jan 1, 1999

Column flotation cells continue to gain acceptance in the coal industry for the treatment of high-ash streams containing clay slimes. Unfortunately, some industrial installations have failed to meet expectations due to improper scale-up, incorrect operation and poor ancillary circuit design. To overcome these problems, case studies have been conducted to fully define the capabilities of column cells for coal applications. These data have been used to develop generic engineering guidelines for column circuit design and operation. An economic analysis has also been conducted to illustrate the importance of key capital cost considerations. These analyses indicate that column cells are significantly more expensive than conventional machines, although this difference can be greatly reduced through the installation of very large-diameter columns.

Jan 1, 1999

By Fathi Habashi

The year 1987 marked the centennial of the beginning of modern hydrometallurgy. On October 19, 1887 British Patent No. 14174 entitled Process of Obtaining Gold and Silver from Ores was issued*. The discovery was made by John Steward MacArthur (Fig. 1), a chemist-metallurgist, supported and assisted by Robert and William Forrest, two brothers practicing medicine in Glasgow. The discovery was made in the basement of their clinic. The process, which became known as the cyanidation process in reference to the alkali cyanide reagent used, immediately received industrial success in New Zealand in 1889 and in South Africa in 1890t. It displaced the chlorination method which had been in use. In 1903 MacArthur was awarded the first Medal of the Institution of Mining and Metallurgy in London1131 - The cyanidation process was responsible for the doubling of gold production in the world in the two decades which followed its first application (Fig. 2). To the modern metallurgist, it may be surprising to think of MacArthur coming across an obscure reagent such as an alkali cyanide as a leaching agent for gold ores. It is the purpose of this paper to discuss the background and the factors that led to this invention, the development of the understanding of the process, and the application of modern technology.

Jan 1, 1999

By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By S. Sener

In this investigation, the changes in the grindability of both ulexite and colemanite related with the different structural modifications created by the heat treatment were examined with respect to work index (Wi). The effects of the heat treatment temperature and time on grindability index were also investigated. It was observed that, heat treatment significantly affected on the grindability of ulexite. The work index of original ulexite was found 7.11 kWh/shton and decreased to 3.5 kWh/shton level within 200-480°C for 60 minutes. On the other hand, the work index of original colemanite was found as 6.48 kWh/shton and no appreciable change was observed when heated up to 320°C. Thermally assisted comminution can be used to improve the grindability characteristics of ulexite. Besides, the different behaviour of ulexite and colemanite under heat treatment can be used for their separation. The artificial mixture of ulexite and colemanite could be separated with over 90% recovery by utilizing their different grindability characteristics by thermal treatment, semi-autogeneous grinding and screening.

Jan 1, 1999

By D. A. Salinas G., A. H. Castillejos E.

Pachuca tanks are commonly used in the hydrometallurgical industry to carry out leaching operations. The fluidynamic characteristics of the liquid phase, resulting from the injection of gas into the draft tube, are important to achieve the complete suspension of the mineral particles and has a decisive influence in the mass transfer processes occurring in this reactor. This study investigated the effect of different design and operating characteristics on the liquid velocity field. using a laboratory-scale Pachuca tank. The transparent model was filled with water, and air was injected through the bottom in the absence of mineral particles. The liquid velocities over the whole reactor were measured under several experimental conditions using particle image velocimetry (PIV). This technique allowed to obtain a very detailed picture of the liquid motion even in the draft tube, as long as bubbles were absent from the measured field of view. The experiments have shown that the liquid velocities increase with increasing the draft tube to tank diameters ratio, the distance from the conical bottom to the draft tube entrance, or the gas superficial velocity. On the other hand, an increase in the water level with respect to the draft tube outlet caused a decrease. A mathematical model, which used the no-slip model, to calculate the variation of axial effective density along the two-phase region, was found to predict liquid velocity fields which agree very satisfactory with the experimental results obtained under all the conditions studied.

Jan 1, 1999

By Jr. Langhans, J. S. McPartland

"The presence of zinc in cyanide solutions is generally thought to not have an adverse effect on precious metal recovery or recovery rate by heap leach processing. However, analytical interferences of zinc in solution can cause problems in accurately determining and controlling cyanide concentration in the leach solution, leading to increased cyanide consumption. Analytical methods and the chemistry of cyanide in the presence of zinc are reviewed. The effects of solution pH and zinc concentration on the free cyanide determination were evaluated in detail. Use of the standard silver nitrate titration and a modified titration method for controlling cyanide concentration during heap leaching were investigated experimentally. The practical implications of cyanide heap leaching in the presence of cyanide soluble zinc minerals are discussed.IntroductionThe presence of zinc in precious metal cyanidation circuits is not uncommon. Zinc can be introduced into cyanide leach solutions through dissolution of various zinc minerals1>, or through the use of a Merrill Crowe (zinc precipitation) circuit. Zinc minerals typically occur infrequently and in low concentration in gold ores, but are more abundant in silver ores. Merrill Crowe systems are most commonly employed for recovery of precious metals from solution for relatively high silver ores. It is desirable to control the amount of dissolved zinc in a cyanidation circuit for several reasons. Excessive zinc build-up in cyanide leach solution can, under certain circumstances, inhibit precious metal dissolution and adversely affect solution recovery systems. Additionally, high zinc concentrations can lead to excessive in-process cyanide inventories and potentially, to higher cyanide consumption"

Jan 1, 1999

An important problem in mine operations is the classification of material as waste, low-grade stockpile, and ore. This classification must often be made with blasthole data that are widely spaced and that have sampling errors. Geo-statistical simulation techniques combined with basic economic principles allows a procedure for classification that maximizes expected profit. Geostatistical simulation methods (Gaussian, indicator, or annealing-based) allow the integration of hard and soft data in the creation of alternative, equally-probable, realizations of the mineral grade(s). At each location, for each realization, we calculate the "profit" if the block were to be classified as ore or waste The optimal classification is the one that maximizes expected profit (a Maximum Profit Se-lection (MPS) procedure). We discuss the theoretical justification of the method and implementation details. The use of blasthole data from different types of mineral deposits, that is, different levels of continuity, is considered. We also show the efficacy of the procedure with different levels of sampling error. The increased revenue due to the MPS procedure and improved sampling is shown. We show the geostatistical simulation procedure and the uncertainty in block grades that result from incomplete and imperfect sampling. The optimal classification is presented. Optimal block classifications are transferred to realizable dig-limits by hand-drawing polygonal boundaries. We compare the results of the proposed method to classification based on kriging. Limitations and areas of future work are identified.

Jan 1, 1999

By S. Vivek

An atomic force microscope (AFM) was used to measure the surface forces between silica plate and glass sphere in sodium oleate solutions. Hydrophobic forces were observed when the two surfaces were activated by CaOH+ or MgOH+ ions. The force measurements conducted in the absence of the surfactant showed that the activated silica surfaces do not exhibit the primary hydration forces that have been observed between unactivated surfaces. The activation mechanism was studied by calculating the contributions from electrostatic and chemical interactions to the total free energy change. The results suggest that the adsorption of the hydroxo-complexes is controlled mainly by the lateral interactions between the adsorbed species on the silica surface.

Jan 1, 1999

By R. Moreau, V. Uspenski, K. Messadek, Y. Delannoy

Experiments and numerical simulations have been carried out to investigate the properties of quasi-2D turbulence. A new mercury model experiment has been built and tested in a uniform magnetic field up to 6T, (Ha~ 1000), ensuring a better two-dimensional behaviour than earlier versions (Alboussiere et al., 1997), limited to 0.2T. The quality of the experimental results has been improved in order to get wave number spectra (instead of frequency spectra) and higher signal over noise ratio (due to the higher magnetic fields). In parallel, some two-dimensional "direct" numerical simulations were performed using a commercially available code to solve a 2-D motion equation involving a source term to model the Hartmann layer. This term is derived from the condition of closure of the electric current, which allows to transfer the Hartmann effect into the 2D-core flow without simulating the layer itself (Sommeria & Moreau, 1982). No subgrid scale modelling is needed in such a two-dimensional situation where most of the energy is carried by the large scales.

Jan 1, 1999

By Peter G. Mason

Over the last 15 years numerous Pressure Oxidation and Pressure Leach plants have been installed throughout the world. The technology is no longer regarded with awe and trepidation as plants designed to treat a wide range of feedstocks continue to be successfully brought on line. Important aspects of the design of such plants include feed preparation, slurry pumping, heating and heat recovery, pressure control and let-down, vessel design, safety and provision of associated services.

Jan 1, 1999

By Basem Sh. Hazzan

In the last four decades significant effort has been devoted to designing piles in expansive clay soils. Nevertheless, only a scant effort has been devoted to the elimination of heave forces acting on the upper part of lightly loaded piles. For this purpose, an investigation site was established in Karmiel in Northern Israel. On this site sixteen unloaded cast-in-situ piles, both uncoated and coated, were installed in a moderately expansive clay soil in the end of summer 1996. The piles were executed to different depths ranging between 2m and 7m and were observed over a period of 27 months. Another nine unloaded cast-in-situ bored piles were installed at the end of summer 1998 for carrying out pullout tests. These piles were embedded two meters from the ground surface. Results obtained from observations and from full-scale static pull out tests showed that separating the piles from the surrounding clay in the active zone by a twin walled sleeve eliminated the heave forces significantly. The scope of the work is, determining of the elimination degree of the heave forces due to the provision of the above sleeve.

Jan 1, 1999

By J. O. Costello

Marble is a preferred surfacing material in up-scale buildings. Its use increased in the 1870's with rising national wealth and declined in the 1950's when synthetic materials for these applications were developed. Natural marble is now limited to high-end domestic and commercial structures. Cultured marble is a paste of white marble dust and polyester resin cured in molds yielding fixtures of specific finished dimensions. Dyes incorporated at different stages in the mixing cycle mimic shades and veining of natural marble. This paper discusses the filler requirements for cultured marble production and reviews new techniques to cut and finish natural marble.

Jan 1, 1999

By N. El-Kaddah, V. L. Acoff, M. Arenas

"Control of the weld penetration, weld pool shape and temperature field in arc welding is critical to achieve the desired microstructure and mechanical properties in the resultant welds. This is particularly important in welding gamma titanium aluminides (y-TiAl) where the weld pool is relatively shallow and the temperature gradient in the heat-affected zone is quite steep. This paper investigates theoretically and experimentally the evolution of the shape of the weld pool for stationary gas tungsten arc welds in y-TiAl alloys. A mathematical model has been developed for predicting the electric current flow, the resultant electromagnetic forces in the metal, and the transient development of the temperature and velocity fields in the molten pool generated by a spatially variable heat flux at the arc-striking zone. The governing equations were solved numerically using the control volume technique. Welding experiments were carried out to determine the shape of the weld pool and the extent of the heat affected zone at different welding times for model validation. The numerical predictions were found to be in reasonable agreement with measurements. It is suggested that the model presented in this paper is likely to provide the information needed for predicting the microstructure and mechanical properties of y-TiAl welds. IntroductionIn recent years, there has been considerable interest in the welding of gamma titanium aluminides as a means of manufacturing high-temperature, high-performance components for turbine and automobile engines. These alloys are highly reactive, and must be welded in vacuum or inert gas atmosphere, rendering electron beam, and inert gas tungsten arc welding (GTA) to be the only suitable welding techniques for joining these materials [1-3]. The GTA welding is especially attractive because of its flexibility and relative cost-effectiveness. However, previous studies on the weldability and weld properties of these alloys using this process revealed a decrease in the mechanical properties in the fusion zone [4]. This is generally attributed to the change of the original duplex structure to a dendritic structure amplified by the shallowness of weld spot. Quantifying the effect of arc operating parameters on the geometry and temperature profile of the welding pool prior cooling is the first step for controlling the fusion zone microstructure and mechanical properties."

Jan 1, 1999

This paper has been developed for æThe Race for SpaceÆ conference. It ranges over various aspects, all of which are within the umbrella of marketing. The question is posed because many engineers, tunnelling and other specialisations, frequently demonstrate an unwillingness to embrace marketing. The accurate reply is probably à ænot an engineer!Æ The paper identifies some of the possible explanations for this reply. The vast majority of the themes, ideas and principles are based on more than 25 years actual experience for the author with Engineers, Tunnelling and other disciplines. This experience has been gained with leading consulting engineering practices; some of the worldÆs largest construction contractors together with other organisations employing engineers in the public, private and tertiary sectors in the UK; US; Europe; the Middle East and throughout Australia and New Zealand. Experience has been gained in design offices; head offices and construction job sites in four contrasting continents. The most significant themes developed throughout this paper are as follows:æLetÆs go and do some ærealÆ work and leave the marketing to others!ÆæMarketing is just a æsoftÆ option and neither technically based nor true management!ÆNIMBY-ism (Not In My Back Yard) so leave well alone!Engineers regularly confuse services marketing -v- product marketing à a useful cop out, or a genuine cry for help?Marketing databasesæLetÆs get rid of the term æsellingÆ and replace it with the more acceptable à and less distracting for tunnelling engineers à 'marketingÆDistinction between benefits and features à in The Race for SpaceSales Comprehension Test, Benchmarking TestJack WelshÆs æmost difficult decision for a CEOÆHarvard Business ReviewÆs (HBRÆs) formula for performanceMany engineers are losing the balance in their lives Sustainable development and engineering æQuality work doesnÆt mean quality serviceÆMajor recommendationsRecommended references

Jan 1, 1999

By N. El-Kaddah, A. D. Patel, T. T. Natarajan

The phenomenon of particle migration in a conducting fluid under an applied electromagnetic force field finds its application in selective sorting of minerals and more recently in the removal of inclusion from molten metal. This paper deals with the analysis of the expulsion force and the flow around a spherical particle in crossed uniform electric and magnetic fields in .infinite and in confined medium. Analytical solutions will be presented for the electrk and magnetic fields as well as the induced flow at the limit of zero Hartmann number. The flow around the particle was investigated numerically at low and high values of Hartmann number. It will be shown the magnetic field has almost no effect on the velocity field when Hartmann number is less than 1.0. At higher Hartmann numbers the damping effect of the magnetic field was pronounced in the direction of the applied current. It is concluded that Hartmann number has little effect on the net force on the sphere particle.

Jan 1, 1999

By Leslie F. Ruppert

The US Geological Survey (USGS) is currently conducting a coal resource assessment of the coalbeds and zones that are projected to provide the bulk of the nation’s resources for the next few decades. The Pittsburgh and Upper Freeport coals are the first two beds in the northern and central Appalachian basin region to undergo fully digital coal assessments. The bed-specific assessments are being carried out in partnership with the state geologic surveys of West Virginia, Ohio, Pennsylvania and Maryland. Comprehensive stratigraphic and geochemical databases have been developed for both of the beds. The extent of the bed with mined areas, structure contour, isopach, and overburden thickness maps for the Pittsburgh coal bed have been released as USGS open-file reports.

Jan 1, 1999

By G. Southam

Bacterial populations play an active role in mineral weathering in subsurface and near-surface environments e.g., supergene enrichment of Cu at Morenci, AZ. An in vitro bacterial biofilm model was used to examine the interaction between Sporosarcina ureae and ionic gold (which is toxic) or amino acid-gold complexes in gold mobility. The immobilization of ionic gold was between 80-90% for 1 week but as the available, cellular reactive sites became saturated immobilization decreased to 14% within 2 weeks. In the asparagine-gold system, gold immobilization occurred at a high rate (80-90%) throughout the experiment with limited toxicity towards Sporosarcina ureae.

Jan 1, 1999