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By Peter Claus

In the last years, supported gold catalysts with particle sizes smaller than 10 nm have attracted a lot of attention. While gold bulk metal is rather inert in chemical reactions and, thus, is of low interest for catalysis, highly dispersed gold particles supported on oxides as TiO2 or ZrO2 show surprisingly high activities in some reactions important for the chemical industry. The oxidation of carbon monoxide at low temperatures is mainly used as model reaction to study the unusual properties of gold catalysts [1]. On the other hand, to evaluate the catalytic potential of gold, other chemical reactions which allow to control also the selectivity have to be considered. The selective hydrogenation of ???-unsaturated aldehydes to allylic alcohols is of both commercial relevance (e.g. in fine chemical and pharmaceutical intermediate production) and specific scientific interest [2]. Note that thermodynamics favors hydrogenation of the C=C over the C=O group (stronger negative free reaction enthalpy of 35 kJ/mol), and for kinetic reasons the C=C bond is more reactive than the C=O group. Thus, in the presence of most of the conventional hydrogenation catalysts, based on Pt, Rh or Pd, -unsaturated aldehydes such as acrolein and crotonaldehyde are hydrogenated predominantly to the saturated aldehydes and only to a minor extent to unsaturated alcohols. Therefore, it is desirable to find catalysts which are able to control the intramolecular selectivity by hydrogenation preferentially the C=O group while keeping the olefinic double bond intact (Fig. 1).

Oct 1, 2003

By Donka H. Andreeva

Gold catalysts based on different supports, titania, zirconia, ceria and mesoporous titania and zirconia, nonpromoted and promoted by vanadia in the reaction of complete benzene oxidation have been studied. XRD, HRTEM, TPR, Raman and ESR spectroscopy were applied for the characterization of the catalysts. The influence of gold on the reduction behavior, state and structure of vanadia on the surface was studied, as well as the role of supports nature on the properties and catalytic activity. A strong synergistic effect between gold and vanadia was observed for the all studied catalysts with an exception of the catalysts supported on mesoporous zirconia. In the last case the catalysts containing gold and gold-vanadia exhibit high and equal catalytic activity. The catalysts on ceria show highest and stable catalytic activity in the studied reaction among the all studied catalysts.

Oct 1, 2003

By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2'-bipyridine (bipy) (1), 6-alkyl-2,2'-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2'-bipyridine (bipyR') (3), R' = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

By Jun Shan

The preparation of poly(N-isopropylacrylamide)-monolayer-protected clusters (PNIPAM-MPC) of gold nanoparticles was carried out in a homogeneous phase using three ways, in which three types of PNIPAM ligands were employed. The first type comprised of PNIPAMs with narrow molar mass distributions, synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and thus, bearing a dithiobenzoate at the chain end. These polymers were used directly to passivate the gold nanoparticles upon the Schiffrin reaction in a one-pot synthesis. The second type of ligands was derived from the first one through hydrazinolysis, and they therefore contained a thiol end group. The third type of ligands was PNIPAMs obtained through conventional radical polymerization, post-modified to contain thiol end groups. The PNIPAM-MPCs were characterized by high-resolution transmission electron microscopy, and by dynamic light scattering. The one-pot synthesis utilizing the ligands of the first type turned out to be a simple and facile method, compared with the other two ways, with which the size of the gold nanoparticles can be easily manipulated mainly by adjusting the molar ratios of PNIPAM / HAuCl4. PNIPAM is a more efficient ligand to stabilize the gold nanoparticles in water and in organic solvents than alkanethiols. The surface density of PNIPAM chains ranged from 1.8 to 3.6 chain/nm2, which is much lower than that typical for alkanethiols. The thickness of a PNIPAM monolayer bound to the gold core is somewhat larger than the size of the random coil of corresponding free PNIPAM in aqueous solution, which suggests that the conformation of a PNIPAM chain bound to the gold core is to extended.

Oct 1, 2003

By Oleg G. Tovmachenko

We have studied optical properties of fluorescent nanoparticles. These particles consist of a metal (gold/silver) core, an empty and a dye labelled silica shells. The different dye molecules with moderate quantum yields (about 0.3) has been used. Almost all of types of nanoparticles show fluorescence enhancement. This enhancement is strongly dependent on the degree of the overlap between the surface plasmon band of the metal and the absorption/emission band of the dye molecules. The results are interpreted in terms of competition between local field enhancement and quenching of fluorescence by the metal surface.

Oct 1, 2003

By Masaru Kato

The plated gold being used by the electronics industry can be broadly classified into two categories: soft gold and hard gold. Soft gold is used for circuit metallization and for bonding semiconductor chips, while hard gold is indispensable as the contact material on electrical connectors, electromechanical relays, and printed circuit boards. The traditional baths from which to plate soft gold as well as hard gold contain the cyanide complex, [Au(CN)2]-, as the source of gold, which liberates free cyanide ions during the plating. The free cyanide is not only highly toxic but also attacks photoresists used to delineate circuit patterns and bonding pads. For these reasons, non-cyanide baths are in use to plate soft gold, whereas hard gold can be plated only from cyanide baths at present. In this presentation, the current status of both electrolytic and electroless non-cyanide processes for plating soft gold will be reviewed.

Oct 1, 2003

By Fabio Terzi

In this investigation some preliminary results are reported about the electrochemical oxidation of CO using goldbased encapsulated nanoparticles grafted on conducting substrate. The investigation has been planned in four steps: 1. production of Au(111) substrate and modification with self assembled monolayers; 2. synthesis and embedding of nanoparticles; 3. grafting of encapsulated nanoparticles on electrode substrates; 4. investigation of CO electroxidation on the modified electrode. The systems were characterized by means of various techniques (spectroscopic, microscopic, and electrochemical methods), obtaining information about SAM's structure and morphology, size and composition of nanoparticles and electrochemical behavior of modified electrodes.

Oct 1, 2003

By Hannu J. Häkkinen

Metal clusters exhibit unique size-dependent physical and chemical properties that differ from those of bulk materials or large particles. Here we discuss recent theoretical investigations of the catalytic properties of free and MgO-supported gold clusters. The catalytic activity of gold clusters depends sensitively on the environment, charge state, and chemical composition of the catalyst. Relativistic bonding effects stabilize large planar structures for gas-phase gold clusters, and non-compact ?quasiplanar? structures are present as important isomers also for surface-supported clusters. The hybridization of the atomic 5d and 6s states is significantly enhanced by the relativistic effects, and large spatial variations in the nature of the local electronic structure make the low-coordinated gold atoms preferable adsorption sites for oxygen molecules. The adsorbed oxygen molecules are activated to superoxo- and peroxo-states via charge-transfer from gold, and Eley-Rideal and Langmuir-Hinshelwood reactions with CO proceed via low-barrier formation of intermediates, which do not require O-O dissociation as precursors. This facilitates the low-temperature (below 300 K) activity of gold nanocatalysts in CO oxidation. Other gold nanostructures, such as mono-atomic gold nanowires, may also become important prototype systems in chemical sensing and nanocatalysis; here we show that they are active promoters of hydrogen dissociation.

Oct 1, 2003

By Michele L. Kimble

A fast-flow reactor mass spectrometer has been utilized to investigate the reactions of gas-phase gold cluster anions with CO and oxygen. Addition of CO to Aun - produces species of the form Au(CO)m -, where m = 2-5. However, CO does not bind to Au2 - or Au3 -. With oxygen addition in the cluster source, gold oxide species with both molecular and atomized oxygen are produced. The addition of carbon monoxide to these preoxidized gold cluster anions reveals that select species with 1, 2, and 3 gold atoms participate in the oxidation reaction to produce CO2. Bimolecular rate constants for the reactions between these species and CO are also discussed.

Oct 1, 2003

By Arne Renström

A fleet management system such as Minestar with CAES and Aquila could basically be defined as a tool for production control and distribution of drill and load maps, but should also be considered as continuous improvements and a never ending production study. The objective of production studies is to establish facts to be used for production improvements. In a mine operation there are many issues to improve and they spread from achieving productions plans, drilling precision, improved spotting while loading to equipment utilisation. This gives that there is not one single key value to present; we need to manage information presented on maps, as trends, graphs, tables and pre-calculated data for ?free-use? normally in spread-sheets to be able to turn data into useful information.

May 1, 2003

By J. Nsasi Bakambu

This paper describes an autonomous platform for exploration and navigation within networks of tunnels, as those typically found in underground mines and caves. In the exploration mode, a remotely located supervisor instructs the platform to move through successive sections of the network, gathering range data that is, then, concatenated into 2D/3D survey maps of the environment. In the navigation mode, the supervisor specifies high-level missions on the previously acquired survey maps. A motion planner, then, translates each mission into a set of consecutive navigation actions, separated by natural landmarks. Mission execution consists of detecting landmarks, self-localizing and performing the planned navigation actions.

May 1, 2003

By Karl J. C. Harries

This paper looks briefly at some of the agreements and types of royalties that may be met during exploration activities, but does not go into details relating to them. Agreements can either make or break a deal or relationship. A well drafted, comprehensive and fair agreement can create good relations and trust among the parties and will go a long way towards making a deal work. In the best of all worlds the agreement will be put away and not need to be referred to after it has been signed (but it will be there if needed to sort out potential problems). On the other hand, a poorly drafted agreement or one that is inappropriate to the circumstances or unfair to one of the parties can break a deal and end up with the parties facing each other in that expensive, unproductive and time-consuming occupation ? a lawsuit. Accordingly, it is advisable to involve professional advisers with any agreement. The straightforward one may involve no more that a read through whereas the more complex agreement will require considerable involvement. There is, however, one rule for every explorationist to remember: a professional adviser is only an adviser. His responsibility is to make sure that you have the necessary information to make a reasoned decision but the decision is yours, not the adviser?s. It is your deal, you are going to have to live with it, and it is inappropriate for an adviser to introduce new concepts or amend negotiated ones without your specific instructions. Mineral exploration agreements, although basically option, acquisition and joint participation agreements, come in all the shapes and forms, appropriate to give effect to the endless variety of deals negotiated by the ever-active minds of explorationists. You will note the reference to "joint participation agreements" rather than "joint venture agreements". The latter term was purposely avoided because, with the current activity of explorationists from common law jurisdictions in civil law jurisdictions, it has become necessary for the explorationist to become familiar with corporations and shareholders agreements. As most of you are no doubt aware, under the civil law system a joint venture is normally not recognized as a legal entity and, therefore, joint participation in projects is usually by way of corporations.

May 1, 2003

By Lorant B. Geller

Sixteen miners died tragically at the Paymaster gold mine at Timmins, Ontario in February, 1945, when a badly corroded hoist rope broke. The investigation of the Royal Commission that followed arrived at a number of recommendations (Investigations, 1947) aimed at avoiding future disasters of this kind. One consequence was the development, and legislated use in Canada, several decades ago, of powerful electromagnetic (EM) instruments for the nondestructive testing of mine shaft wire ropes. The authors have been involved for many years in the design, production, and testing of EM instruments (Geller and Udd, 1990 and 1992, Geller and Kitzinger, 1991, Geller et al., 1993). Since the mid-1990s particular attention was paid to the design and operational results obtained from the computer- controlled portable MagnographJ II wire rope tester (Geller et al., 1995 and 1998). In the present article the authors summarize further hardware- and software-related developments of this instrument. Further, an account is given of the results obtained from the most recent design known as the PermaScanJ testing system. This is also a computerized dual-function system. In it, however, the sensor head is designed primarily, if not solely, for permanent installation and for remotely controlled operation. This represents a basic departure from traditional designs, which were intended for ad hoc temporary installations. The remotecontrolled instrument described in this paper has now been in operational use for more than 4 years.

May 1, 2003

By S. D. Tolgyesi

Kidd Creek Background ? Located in Northern Ontario, Canada ? Underground base metal mine ? Operating since 1966 ? Total of 125Mt mined to date (2.43% Cu, 6.60% Zn) ? Current plan at 2.4Mt/Y (6575t/D) Current Practices ? Evaluating stope margins to ensure that value is added ? Scheduling sulphide and Cu stringer ore to limit oxidation in passes ? Scheduling to maintain uniform grades to concentrator ? (SOPs highlight problem stopes on mine plans, and limit blast sizes in those stopes which may contain sulphides prone to oxidation) ? Scheduling high-Pb stopes to avoid spikes to concentrator ? Providing weekly, monthly and long-term forecasts ? Reconciling mine and mill production ? Underground grade and dilution estimates by mine supervision ? Terminate mucking when grade becomes sub-economic ? Laser cavity surveys to provide feedback and improve Designs Cut-off Grades ? Ore value is obtained from copper, zinc and silver ? Ore outlines at 2% copper equivalent used to guide stope planning; sulphide outlines obtained from contacts while copper stringer outlines drawn from block model (kriged) ? Datamine block model and CADD software used to evaluate alternative stope shapes ? Stopes classified as waste, incremental, or full-cost based on margin calculations for each stope ? Incremental ore may be mined if it does not displace fullcost Ore Conclusions ? Grade control remains an important function for optimizing the ore extraction at Kidd ? The scope of the function has changed to a scheduling focus ? A change in grade control practices over time has not led to significant changes in concentrator feed ? The lead and iron sulphide content of the ore display upwards trends and may require more attention in the future ? The key function of field observations has shifted to flagging exceptions and terminate mucking at grade cut-off

May 1, 2003

By Greg Baiden

Telerobotics focused on mining is currently being introduced into production systems around the world. Mining companies in Canada, Sweden, South Africa and Australia have tended to lead the international charge to this form of technology for mining. While this introduction is taking place a few basic questions have yet to be answered. How many machines can a single operator run? How many types of machines can a single operator run? A new Canadian Research Chair in Robotics and Mine Automation has been established at Laurentian University. This chair will investigate these questions and many more through a series of experiments in a newly established telerobotics laboratory that connects Laurentian teleoperation workstations to model mining machines at Cambrian college?s eDome. The laboratory will support many experiments allowing researchers to physically run multiple robot scenarios differing the numbers and types of machines at one/quarter scale. Further experiments are being designed to investigate the potential for managing time delays in telerobotics. This paper describes the laboratory, experiments and some preliminary results.

May 1, 2003

By Stephen P. Quin

One of the most prospective undeveloped greenstone belts in Canada, the Hope Bay greenstone belt extends over 80km in a north-south direction and is between 7 and 20km wide. The belt lies on the arctic coast and comprises mafic meta-volcanic and meta-sedimentary rocks that are bounded by Archean granite intrusives and gneisses. The greenstone package has been deformed during multiple events and is transected by major northsouth trending shear zones that appear to exert a significant control on the localization of mineralization. The Hope Bay belt contains a number of significant gold deposits hosted in a typical Archean greenstone belt and which occur in several geologic settings, including shear-hosted, lode-style and breccia-associated. Combined, the deposits host a measured and indicated resource of 1.6 million oz of gold averaging 15.7 g/t plus an inferred resource of 2.7 million oz of gold averaging 12.3 g/t. All deposits remain open to expansion. Exploration in the period 2000-2002 by Miramar includes more than 110,000m of drilling to more fully define the nature of the known deposits, while regional exploration has focused on identifying and evaluating new targets. In carrying out its programs, Miramar uses a number of techniques to improve its chances of exploration success. Activity in 2003 includes 43,000m of drilling focused on expanding resources in the Madrid area, testing the Boston deposit at depth and continuing the hunt for more discoveries. Meanwhile Miramar is advancing one of the deposits towards a production decision, based on a low capital, high return development scenario.

May 1, 2003

While this paper is directed towards the ?Bellambie? type of rope attachment, the principles can be applied to any brand of rope fitting however, it is a only a broad outline and the specific installation and maintenance procedures can be obtained from the attachment supplier. The types of attachment to be discussed are:- ?Thimble Type rope cappel ?Wedge Type cappel ?WRC Rope Clamp ? (Rope Glands) ??Hoist and Balance Rope Sockets In each case, the assembly and stripping (disassembly) plus the basic maintenance procedures is briefly described. A guide for Risk Assessment is also included but because of his familiarity with the installation, the end-user is in the best position to draft the final version.

May 1, 2003

By David Penswick

Despite anecdotal evidence to the contrary, the mining industry is not in decline. Rather, the world?s largest mining companies are among the most consistently profitable companies in any industry. In many cases, profitable mining companies have been built around a few large scale, long life mines. These criteria for success ? size and long life ? have led to the current preference for deposits that can be exploited using open pit methods. However, developments in the science of block caving have resulted in this mining method achieving costs and productivities that are competitive with the largest open pits, while achieving widespread applicability. One implication of the low costs and widespread applicability of block caving is that some current open pits are possibly too deep.

May 1, 2003

By Jerry Ran

When multiple levels are mined in open stope mining with delayed backfill, mining underneath fill is inevitable to achieve higher rate of recovery if no sill pillars are left for the purpose of fill separation or partial ground support. This is particularly true when the orebody has low reserves per unit vertical distance. Instability of the exposed fill back causes stope dilution, production delay and possible equipment damage and consequently increases the mining cost. Previous studies have concentrated on fill mat stability in cut-and-fill and stability of fill walls in open stope mining. Workers are exposed to the fill back in cut-and-fill and therefore smaller open spans are normally adopted and the fill mat is reinforced. In open stope mining openings with large spans are designed, workers are not exposed to the fill back and its stability has to be maintained by fill of sufficient strength. However, the required fill strength is normally determined by considering different modes of fill wall failure. The fill back stability is usually not analyzed in the fill design process. The lack of analysis on fill back stability for open stope mining is mainly due to difficulties in relating the fill properties to the fill and stope geometry. In this paper a simplified wedge model is adopted to analyze stability of the exposed fill back in open stope mining with consolidated backfill. The proposed method calculates the factor of safety of the fill back against shear failure under known fill and stope geometry and fill strength parameters in order to assess the fill back stability. It can also be used to determine the required fill strength with known fill and stope geometry. The proposed approach is indirectly validated by mining experience and observations at two operating mines. In addition there are many factors affecting the fill quality and stope configurations in an operating mine. These factors have to be considered in the analysis of fill back stability. This situation is highlighted by presenting an actual mining case where the fill back failed due to factors commonly encountered in mining operations.

May 1, 2003

By Andrew Abraham

Continual improvement is the key to success in today?s competitive global arena. You require tools that promote dynamic quality management, deliver cost savings to your bottom line and provide the foundation for process improvement. ISO 9000 and ISO 14001 management systems and OHSAS 18001 are those tools. Since their inception, the benefits of ISO management systems and registration have been touted as the way to achieve better bottom line results. This spurred many companies to embark upon the road to registration with high expectations. The potential benefits of ISO management system implementation and third party registration that are commonly provided by Registrars and consultants are compelling adverts for success. ISO 9001:2000 is promoted as an essential tool for systematic efficient and affective management controls that provide a framework for analyzing errors and improving a company?s internal operational processes. It also allows companies to comply with internal and external customer and regulatory requirements thus continually improving the quality of their products and services and thus enhancing customer satisfaction. This, in turn, leads to greater customer recognition and increased market share. ISO 14001 implementation and registration may assist your company in reducing its litigation risk, raw material and energy consumption, waste disposal costs and possibly non tariff trade barriers. It should also provide continuity of operations, enhanced operational efficiency and consequently a competitive advantage in the market place. Registration of your ISO 14001 management system should also improve your company?s profile and credibility leading to regulatory flexibility and improved community goodwill. All of this will be a catalyst for improved morale and pride by employees and management alike. Likewise, OHSAS 18001, the latest certification specification for Occupational Health and Safety Management Systems supports Occupational Health and Safety legal and regulatory obligations and compliance, manages & controls Occupational Health and Safety risks and improves performance, safety culture and efficiency. OHSAS 18001 is an audit certification, and not a legislative requirement. Suggested benefits of implementation include reduction in accidents, lost time and associated liability and insurance costs and improving reputation and credibility through demonstrated commitment to health and safety. The foregoing increases access to new customers, joint venture partners and financing The skeptics say these are motherhood statements and lack corroborative evidence, i.e., ?Show me the money!?

May 1, 2003