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By M R. Davidson, M P. Schwarz

A model for column bioleaching is investigated to identify and understand aspects of bacteria in bioleaching applications, which have implications in heap bioleaching operations. The model is used to simulate scenarios that would otherwise be time consuming to perform experimentally. This study uses a model of bacterial transport and attachment/detachment to ore particles, with a bioleaching model for the depletion of a copper-sulfide, also accounting for liquid and gas flow and gas/liquid oxygen mass transfer. The model includes aspects such as oxygen and ferrous ion consumption, coupled with leaching of a copper-sulfide via the shrinking core model. The model is used to investigate how the rate of leaching is affected by the bacterial concentration in the columns, by the bacterial regeneration of the leaching oxidant ferric ions. The model is also used to assess the impact of oxygen limitation and inoculation method on the copper leaching. Some comparison of the model with experimental data will be shown.

Jan 1, 2004

By S. H. Seyedein

A mathematical model was developed to study fluid flow and solidification in a single-roll casting system. Fluid flow coupled with energy equations were solved numerically using a finite volume method. A body-fitted coordinate transformation technique was adopted to handle the irregularly shaped domain. In order to couple the continuity and momentum equations, a SIMPLEC algorithm was used. A fixed-grid enthalpy method was considered to model the solidification in the system. The turbulence effect on flow field was modeled using a low-Re k-e model The model developed in this work was further run under various conditions to optimize the operating parameters of the process.

Jan 1, 2004

By D. Lunt

Telfer bulk concentrates typically contain 8% chalcopyrite, 8% chalcocite, 45% pyrite and 80-120 g/t gold. Although very high copper and gold recoveries can be obtained by subjecting the concentrate to a "conventional" high temperature pressure oxidation step followed by copper recovery by solvent extraction and electrowinning, and cyanidation of the leach residue for gold recovery, the cost of lime required for neutralisation and power for oxygen generation was such that the process was uneconomic in terms of operating costs. The challenge therefore was to develop an alternative flowsheet that maximised copper and gold recovery in which the reagent costs were commercially attractive. An additional objective was to reduce the capital cost so that the overall NPV and IRR values would enhance the economic viability of the total project. Following a series of batch and locked cycle testwork programs, supported by Metsim modelling, it was established that the same high levels of overall copper and gold recoveries can be obtained by use of a novel two-stage split leaching circuit in which the chalcocite component is leached in a low temperature (90-110°C) circuit with the chalcopyrite component treated in a high temperature (220-250°C) circuit. This split circuit has a number of advantages, including minimising the required capacity of the high temperature autoclave, as well as reducing the overall lime consumption and simplifying the total process water balance. The paper outlines the basis for the development of the flowsheet and discusses the integration of the leaching stages into the overall circuit.

Jan 1, 2004

By Robin M. Forbes. Jones, Suhas V. Patankar, Ramesh S. Minisandram, Jr. Carter, Kanchan M. Kelkar

"The nucleated casting process currently under development has the potential for production of Ni-base superalloy preforms that possess superior microstructure to product made by conventional casting processes, primarily for gas turbine applications. In this process, electroslag remelted (ESR) clean (i.e., free of ceramic inclusions) molten metal is conveyed via a watercooled copper Cold-walled Induction Guide (CIG) to a gas atomizer. The spray of clean metal droplets is then directly cast into a water-cooled crucible for ingot production. The microstructure of the resulting ingot preform evolves within the length scale of the individual droplets and is a function of the thermal state of the incoming metal droplets. This, in turn, depends on particle size, flight time and heat exchange with the gas phase.In the present study, computational models is developed for the analysis of the flow and heat transfer in the gas-metal spray system under axisymmetric and steady-state conditions. The gasphase flow is analyzed using an Eulerian framework and turbulent mixing within the gas phase is modeled using the two-equation k-e model. The dynamics of the metal particles is analyzed using a Lagrangian framework that involves calculation of the trajectories of the metal droplets. A two-way coupling is considered whereby the transport and heat transfer in the gas and the metal phases influence each other.The analysis is developed at two levels. The spray model performs a detailed calculation of the spray dynamics in the vicinity of the spray and is intended for predicting the temperature and mass flux distributions of the metal spray depositing into the mold. The chamber model enables prediction of gas flow and motion of metal particles in the entire spray chamber."

Jan 1, 2004

By J. A. Kromhout, J. Trouw, A. A. Kamperman, M. Kick

Mould powders play an important role in the stability of the continuous casting process. The main functions of mould powders are to provide sufficient lubrication and to control the horizontal heat transfer. Because process control of thin slab casting is more stringent, it is generally assumed that mould powder properties become more critical as well. In 2000, the Direct Sheet Plant at Corus IJmuiden (DSP) was commissioned, incorporating a thin slab caster designed for casting speeds up to 6 m/min. During commissioning, several operational problems with mould powders were encountered i.e. insufficient liquid pool depth and the formation of rims/lumps. To investigate the operational mould powder problems, some of the mould powders were characterized using physical and mineralogical methods. The results were linked to operational experiences. It was concluded that for thin slab casting, a stable slag formation is obtained with a proper choice of free carbon and an even distribution of the carbon particles within the granules. The physical properties of mould powders are not as critical as expected when the additional mineralogical requirements are taken into account. Keywords: mould powder, characterization methods, thin slab casting.

Jan 1, 2004

By Larry M. Southwick

Considerable process and equipment development and analysis were conducted during design of Freeport Sulfur's laterite nickel facilities in the late 1950's. These covered ore concentration at Moa Bay, Cuba, and concentrate refining at Port Nickel, Louisiana. Both facilities utilized acid pressure leaching and product refining steps that were similar to those later used elsewhere in the laterite processing industry. Unfortunately, developments in Cuba removed the Moa Bay facilities from Freeport control. This deprived the project of a start-up that would have allowed thorough resolution of difficulties and a quicker attainment of production capacity. This meant lost opportunity to positively prove and complete the technology when optimum resources and staff were available. This paper reviews the original rationale of how design was developed via laboratory, bench scale and pilot studies by Freeport Sulfur. Some later operating problems will also be discussed. This case is unusual, but the lessons learned may be instructive in the application of difficult and complicated technologies, as well as the need to understand and retain access to the original development and design activities Keywords: Moa Bay, Freeport Sulfur, Port Nickel, acid pressure leaching, pilot plant, pachuca, Chemical Construction, pressure letdown, cobalt, titanium

Jan 1, 2004

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By A. Liem, R. L. Johnson, C. Sturgess, E. Kuzub

New challenges in mineral processing arise as high-grade ores become less available and the mining industry is forced to exploit lower grade ores. One of the challenges in beneficiating lower grade ores is the liberation of mineral particles while maintaining control over material management. Lower grade ores need fine grinding to free valuable minerals, but finely divided particles can cause severe problems, such as dustiness and flowability, in subsequent stages of material management. There are at least two approaches that can be taken to resolve this dilemma, both of which relate to particle size enlargement. First, the application of a dust suppressant can be used to control that aspect of material management. The optimal choice of dust suppressant agent depends on effectiveness and cost, both of which can be strongly influenced by the selection of application method. Second, agglomeration combining small particles into larger units-can reduce dust and improve the flow characteristics of the material at the same time. There are several mechanisms that can be employed to agglomerate mineral materials. Although agglomeration adds a new processing step, it is often cost effective. This paper describes these two approaches and their respective challenges, as they relate to a mined ore. We report on modified or newly developed procedures for characterizing mineral ores with respect to material management. On the same material, we use agglomeration processing to capture fines within larger particles and show how dustiness and other aspects of material handling are affected. We conclude by discussing their specific application in accordance with the mineral properties and processing needs.

Jan 1, 2004

By M. G. Irish, E. E. Vidal, M. J. Jahraus, P. R. Taylor

An experimental system has been designed to monitor on-line variations of leaching parameters in a closed circuit of cyanide leaching solutions and gold bearing ores. Experiments performed to deter-mine variations in some important leaching parameters of the solution: pH, dissolved oxygen, free cyanide, oxidation/reduction potential, gold content, temperature, pressure and solution chemistry. By comparing results obtained when the leaching solution is allowed to become acid or kept basic, it was possible to infer the chemical reactions that occurred between the solution and the ores.

Jan 1, 2004

By László I. Kiss, Verena Mackowiak, Alexandre Perron, Dominic Toulouse, Alicia Liedtke, Sándor Poncsák

"Bubbles play a very important role in different metallurgical applications like for example in electrowinning. During heterogeneous nucleation, the maximal size of the bubbles growing at the nucleation sites as well as the nucleation frequency is determined by the so-called detachment condition. Detachment occurs when the external forces acting on the bubble exceed the retaining forces along the solid-gas-liquid triple interface line. The phenomenon depends strongly on the shape and orientation of the solid surface and on the nature and strength of the external buoyancy and drag forces. In the present study the detachment conditions of bubbles from downward facing horizontal and inclined plates were studied experimentally under the effect of gravitational and hydrodynamic forces. The results show the deformation of the bubbles under the effect of the external forces and the detachment conditions as function of the bubble volume.IntroductionIn heterogeneous nucleation bubbles are generated at the so-called nucleation sites along the solid-liquid interfaces. They continue to grow there and after they reached a certain size they detach from the solid surface and leave the nucleation site. This scenario is well known both in boiling and electrolysis. During the growth period a stable equilibrium exists between the forces that retain the bubble at the nucleation site and the forces that try to remove it. This equilibrium evolves with the increasing volume of the bubble to the point when the detachment forces overcome the retaining forces.The life of a single bubble generated by heterogeneous nucleation can be divided into two periods separated by the detachment - or in other words by the departure - of the bubble: first the growth at the nucleation site and then the movement away. The knowledge of the detachment conditions makes possible the determination of the maximal volume of the bubble at the nucleation site that, in tum, makes possible the determination of the nucleation frequency. This is why so many researches have been directed toward the clarification of the details of the bubble detachment in the past decades. The equilibrium between the attaching and separating forces depend on the presence of body, surface and flow induced forces in the liquid, on the geometry and orientation of solid surface, on the properties of the solid-liquidgas system etc."

Jan 1, 2004

By T. Kuhn

The Logatchev hydrothermal field is situated on the east inner flank of the rift valley of the MAR at 14°45?N and is hosted by serpentinized peridotites and minor gabbronorites while basalts are subordinate. Hydrothermal precipitates recovered from the Logatchev field during a recent R/V Meteor cruise include massive chalcopyrite chimneys, massive pyrite crusts, silicified breccias, abundant secondary Cu-sulfides, red jaspers, abundant Fe-Mn-oxyhydroxides as well as atacamite and Mn-oxides (Kuhn et al., 2004). Previous results of hydrothermal fluid studies in the Logatchev field are somewhat at odds with theoretical models of ultramafic-seawater reaction. Butterfield et al. (2003) suggested that the Fe component of orthopyroxene plays the more important role compared to olivine in ultramafic-hosted hydrothermal systems. This consideration is supported by the recovery of large amounts of Opx-rich gabbronorites and orthopyroxenites in the Logatchev field (Kuhn et al., 2004). A possible tool to constrain the contribution of the different rock types (ultramafics, mafics, MORB) to a seafloor hydrothermal system is the systematic analysis of 187/188Os ratios of the host rocks as educts and the sulfides as products. For instance, abyssal peridotites mainly display low 187/188Os ratios (<0.127); in contrast MORB and gabbronorites have radiogenic ratios of >0.13 (Snow and Reisberg, 1995), orthopyroxenite has ratios of about 0.174 (Büchl et al., 2002) and seawater has an ever higher 187/188Os of about 1 (Sharma et al., 1997). Therefore, massive sulfides predominantly leached from ultramafic rocks should have Os isotopic ratios plotting on a mixing line between the ultramafic rocks and seawater (in a 187/188Os vs. 1/Os diagram), whereas those derived from MORB, gabbronorites and/or orthopyroxenites will be plotting on different mixing lines.

Jan 1, 2004

By J M. Santini, I C. A Streimann

Arsenic is a naturally occurring element in the environment and is toxic to biological systems. Arsenic can exist in the environment in the following redox states, arsenite (+3), arsenate (+5), arsine (-3) and elemental (0) (Oremland and Stolz, 2003). Arsenic is released into the environment by natural and anthropogenic activities such as rock weathering and ore mining, respectively. Such activities result in the release of the soluble inorganic arsenic oxyanions, arsenite and arsenate. The redox state of arsenic in the environment is influenced by a number of factors including, redox potential, pH and microorganisms (Irgolic et al, 1977; Genc-Fuhrman, Tjell and McConchie, 2004). Recently, the ability of microorganisms to influence the cycling of arsenic in the environment has attracted much attention. Microorganisms that can oxidise arsenite and reduce arsenate have been isolated and the mechanisms of arsenic metabolism are currently being investigated. The differences between arsenic resistance and arsenic metabolism are being revealed. The role of microorganisms in the release of arsenic into the environment is of particular importance with arsenic contamination of waters causing the death of millions of people worldwide, due to the consumption of contaminated water (Vasken Aposhian et al, 2003; Islam et al, 2004).

Jan 1, 2004

By Houyuan Liu

A new process was developed to recover nickel and cobalt by leaching laterite ore at atmospheric pressure and.95"-105" C. The nickel-containing goethite in limonite was first leached with sulphuric acid to liberate over 90% of nickel, cobalt and iron. The dissolved iron was then precipitated as Ni-free goethite by the additioil of saprolite. The acid released during iron precipitation as goethite was simultaneously used as lixiviant to leach saprolite to recover more nickel. With this process the limonite and saprolite were essentially converted into goethite-, gypsum- and silica- containing tailings. Twenty bench scale tests and two campaigns of pilot plant operation were carried out at BHP Billiton&apos;s Newcastle Technology Centre (NTC) from January to August 2002. The overall nickel and cobalt extractions were 81 to 90% and 91 to 100% respectively. The average plant availability was 99%. The advantages of this process over existing processes include high plant availability, high consistency, robustness and simplicity of the operation.

Jan 1, 2004

By Roberto Parreiras Tavares, Frederico da Costa Fernandes, Guilherme Antonio Defendi, Vangleik Ferreira da Cruz, Júlio César de Sousa Pena

"Near-net-shape casting is an important area of research in the iron and steel industry today. Among the near-net-shape casting processes, the single-belt caster seems to be the most promising, since it is the only one that can achieve levels of productivity similar to those obtained with conventional continuous casting machines. One of the most important aspects in the single-belt casting is the feeding system used to deliver liquid metal over the belt. This system determines the velocity distribution and the levels of turbulence of the liquid metal and affects the quality of the strips. In the present work, a metal delivery system having a simple geometry was proposed. Using the CFD code CFX 5.6, a mathematical model to simulate three-dimensional turbulent fluid flow and heat transfer in that system has been developed. This model was used to analyze different configurations of the metal delivery system and the free surface shape of the fluid was also determined. A physical model of the feeding system was built and used to validate the predictions of the mathematical model. The fluid flow calculations have been validated by dye injection experiments and laser doppler anemometry. Measurements of the free surface levels have also been performed. These experiments provided supporting evidence for the predictions of the mathematical model.IntroductionTo maintain its competitiveness in the present market, the metallurgical sector, particularly the steelmaking companies, are developing new techniques of production. Some of these new processes are focussed on the strip casting technologies. Among these technologies, the SingleBelt process is considered the most interesting option, reducing the number of rolling steps and, consequently, the final cost of the product, especially the part associated to the energy consumption (fuel and/or electric energy). This process can also reach levels of productivity that can not be matched by other strip casting methods(1). One of the most important aspects concerning these new processes is related to the liquid metal delivery system. This system can have a significant effect on the final quality of the strips, since it determines the velocity distribution and the levels of turbulence of the liquid metal."

Jan 1, 2004

By D. Satish Kumar, D. Mazumdar

"95% bulk mixing times in three different size water model ladles of a 140 T cylindrical shaped , dual plug ( located diametrically opposite at mid bath radius position) stirred, industrial ladle were determined experimentally with and without an upper buoyant phase. Based on dimensional analysis and a regression of the experimental data and, it was shown that in the inertial and gravitational force dominated flow regimes, 95% bulk mixing times for a slag-less situation can be described via:[equation]Parallel to this, a large number of experiments were also carried out in one of the water models (D=0.30m) to quantify the influence of an upper buoyant phase on mixing. These indicated that mixing time, operating variables and thermo-physical properties of the upper phase liquid can be correlated via a dimensionless relationship of the type:[equation]in which, Q is the ambient gas flow rate, L is the depth of liquid , (AL) is the slag layer thickness and 6 and t are respectively the surface tension and viscosity of the upper phase fluid The dimensional analysis, regression of experimental data as well as the adequacy of the proposed correlations are discussed in the text."

Jan 1, 2004

By Debbie Marshall

Nickel and cobalt in lateritic ores can be extracted by either a hydrometallurgical or a pyrometallurgical route. The high-iron limonitic fraction of a deposit is best processed&apos; hydrometallurgically while the magnesium-rich transitional and saprolitic fractions are more suited for pyrometallurgical processing. During hydrometallurgical processing, it may be attractive, for economic reasons, to blend the limonitic component with transitional and saprolitic ores, which contain higher nickel levels. However, blending increases the concentration of magnesium in the feed, leading to increased acid demands. The decision on how much ore to process then becomes an economic one. Ore samples with different magnesium contents were prepared for the leach test program by blending limonitic and transitional ores. The ore samples were slurried in seawater and tested in the Falconbridge Hydrometallurgical Pilot Plant. As expected, acid consumption increased with increasing magnesium content of the ore. For target extractions of 95% nickel and 92% cobalt, the required residual free acid concentration increased from 30 g/L at 1.7% magnesium to 50 g/L at 2.7% magnesium. When the magnesium content was raised to 3.8% and 4.6% in subsequent pilot plant testing, the final free acid requirements did not increase beyond what was observed at 2.7% magnesium. Thus, the cut-off ore composition to maximize nickel units and minimize acid requirements is between 1.7- 2.7% magnesium. Keywords: high pressure acid leaching, laterites, magnesium

Jan 1, 2004

By S E. Wallah, D Hardjito, B V. Ran

The manufacture of Ordinary Portland Cement (OPC) is not only energy-intensive but also releases a significant volume of carbon dioxide (CO2) to the atmosphere. In addition, OPC in concrete often causes premature deterioration that affects the durability of concrete structures. This paper explores an alternative to OPC concrete called geopolymer concrete.The present research utilises low calcium (class F) fly ash as the source material to produce geopolymer concrete. Several factors that affect the mix design process such as mix proportion, curing time, and curing temperature have been studied. In addition, the long-term properties such as drying shrinkage, creep, and exposure to sulfate attack are also being investigated.The test data presented in this paper reveal that geopolymer concrete possesses high compressive strength, undergoes very little drying shrinkage and moderately low creep, and shows excellent resistance to sulfate attack. The result is extremely promising and demonstrates the sustainability of geopolymer concrete as a construction material for a sustainable future.

Jan 1, 2004

By W. Pietsch

For a number of reasons, solids entering and leaving facilities for the treatment of minerals are becoming increasingly finer. Such materials pose problems throughout processing. Solids featuring small particle sizes tend to dusting, result in losses and segregation, exhibit various storage, transportation, and metering problems, and fine particulate effluents can not be easily captured, used and/or recycled. Sustainable mineral processing must minimize the exploitation of natural resources and avoid the need for disposal of wastes. The first requires the use of lower quality raw materials and upgrading, which typically results in the production of fine grained concentrates, and the latter encourages the recycling of wastes and byproducts or efforts to investigate them as sources for secondary raw materials or other beneficial applications. To overcome the difficulties associated with fine particulate solids, size enlargement by agglomeration is necessary. The resulting products have free flow characteristics, do no longer dust or segregate, and are sized and shaped as required for optimum processing. In addition, agglomerated materials may be engineered to feature desirable structure, composition, and a number of related, improved properties. Such engineering may be applied for the modification of fine run-of-mine and up-graded minerals as well as the production of secondary raw materials from by-products or wastes. By the interdisciplinary application of size enlargement by agglomeration waste-free processing of minerals becomes feasible.

Jan 1, 2004

By M D. Urbani

HiTec Energy Ltd has been conducting research since 1996 into novel process routes for the treatment of low-grade and waste manganese sources for the production of high value and high quality electrolytic manganese dioxide (EMD) for the alkaline battery market. HiTecÆs approach is to treat previously unsaleable manganese deposits and mine site tailings using a novel sulfur dioxide leach route, followed by purification and electrowinning to generate the sought-after EMD product by an environmentally superior processing route to those presently practiced throughout the world today.HiTec Energy Ltd expects to be in commercial production with its Stage 1 facility in Kalgoorlie in the last quarter of 2004 for the production of 12 500 tpa EMD. With this production facility being adjacent to a laterite nickel producer with available waste manganese units, the opportunity arose for HiTec to combine its existing technologies with processes (that will be discussed in this paper) to turn two waste by-products into products that are used for high-tech purposes.HiTec Energy Ltd and the Parker Centre have had a collaborative research relationship for a number of years in areas involving EMD and battery related technologies. Meanwhile the solvent extraction (SX) group of the Parker Centre (CSIRO Minerals) has developed SX processes to separate manganese from nickel and cobalt. A project was initiated by HiTec Energy to recover manganese from waste laterite leach solutions using SX technology. Batch tests were conducted to select a suitable organic system for the extraction of manganese in terms of selectivity and extraction and stripping kinetics.A total of eight organic systems were tested by determining pH isotherms of metals using a laterite nickel process waste stream. Two organic systems, the Versatic 10 and Versatic 10/synergist systems, were chosen for further test work with Shellsol D70 chosen as the diluent for both systems.The Versatic 10/synergist system would be advantageous over the pure Versatic 10 system because fewer SX stages are required, resulting in a smaller organic inventory and lower capital costs. The risk of gypsum formation is also significantly lower with the synergistic system.

Jan 1, 2004