Search Documents

By T C. Westerfield, G, M J. Mankosa

An innovative separator known as the HydroFloat cell has been developed specifically for the upgrading of coarse particles that are difficult to recover using conventional flotation cells. The novel characteristic of this separator is the formation of a hindered teeter-bed of fluidised solids into which small air bubbles are injected. The air bubbles selectively attach to hydrophobic particles and form particle/bubble agglomerates that segregate atop the teeter-bed due to their lower apparent specific gravity. The low-density agglomerates are eventually carried into the product overflow launder by the rising current of teeter water. Hydrophilic particles remain in the teeter-bed and are discharged to underflow as a high solids content tailing. Benefits of this hybrid flotation-density separator include enhanced bubble-particle contacting, increased particle residence time, and very low air demand. Test data indicate that significant improvements in the recovery of coarse particles can be achieved using this innovative technology. This article describes the theoretical basis for the development of the HydroFloat cell and provides an overview of recent pilot-scale tests conducted for the phosphate industry.

Jan 1, 2005

Folklore suggests that oxidation is detrimental to sulfide mineral flotation, and in many instances is the reason given for values reporting in the tailing. However, while a considerable body of work examining galena oxidation is available in the literature there are very few studies that investigate the consequences of galena oxidation on its subsequent flotation in base metal sulfide ores. This work clearly demonstrates that pyrite forms a galvanic couple with galena, due to the large difference in their rest potentials, and results in accelerated oxidation of galena, particularly as the pyrite content of the ore is increased. The most obvious effect of the galvanic oxidation of galena by pyrite is the release into the system of galena oxidation products, providing an ample supply of lead ions available to activate gangue minerals, most notably of which in lead/zinc ores is sphalerite. The inadvertent activation of sphalerite by lead ions inevitably leads to the recovery of liberated sphalerite into the lead concentrate, and as a consequence a reduction in the lead concentrate grade. That is, a loss of selectivity for galena against sphalerite. If galena oxidation is excessive not only is there a considerable loss in lead concentrate grade, but also a marked decreased in lead recovery as the flotation rates of the gangue minerals increase, until they rival that of galena.

Jan 1, 2005

By Monica Prezzi

"Auger cast-in-place (ACIP} piles and drilled displacement piles are being increasingly used as foundation elements for structures, particularly in projects requiring accelerated construction or involving the rehabilitation of foundations of existing, overstressed structures. Auger cast-in-place piles (also referred to as continuous-flight-auger piles) are widely used to construct the foundations of all types of structures. There are many different types of drilled displacement piles, with the installation methods varying according to the equipment used. Depending on the specific rotary piling technology used, responses ranging from those associated with non-displacement to those associated with full-displacement piles are obtained. Conventional pile design methods do not account for how the various construction techniques involved in auger piling change the soil state around the pile during installation and, hence, cannot accurately estimate the pile resistance in a consistent way. Research on this subject, identifying the different variables that must be accounted for in design and linking these variables to installation methods, is lacking. This paper describes the different piling methods available for auger cast-in-place and drilled displacement piles, the equipment used to install them and the quality control processes typically used. It also reviews some of the design methods currently used.IntroductionDeep foundations are extensively used in geotechnical engineering practice. The wide spectrum of piling methods results in a variety of pile types. Each type behaves differently, depending on the installation or construction methods. On one end of the spectrum are non-displacement piles, the classicql examples of which are bored piles or drilled · shafts. These piles are constructed by removing a cylinder of soil from the ground and replacing it with concrete and reinforcement. On the other end are full-displacement piles, such as closed-ended pipe piles or precast reinforced concrete piles, which are typically driven into the ground. Driven piles preload the materials below the toe of the pile and displace the soil surrounding the pile shaft laterally during the installation process. Therefore, displacement piles are, in general, more likely to have a stiffer response than non-displacement piles. This is true particularly in the case of sandy soils where displacement causes densification."

Jan 1, 2005

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By Andrukaitis. E.

The increasing use of electronic equipment by the Canadian Forces has increased the importance of electric power. A power source that is packed with energy and yet light, small and durable is the common request of military users. However, this needs to be achieved while also addressing the requirements of safety, reliability and low temperature performance. The potential use of fuel cells in a military environment has become a possibility in several areas in the 21st century. Some examples of power source requirements and the materials related R&D required to give better, higher energy power systems in the future will be discussed.

Jan 1, 2005

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990's. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By Leslie C. Taylor, Anthony L. Kee

Computational modeling of explosively loaded saturated sand on a suspended plate is an inherently complex problem. In this study a computational method is used to predict the dynamic pressure load/impulse from a buried charge. A fully coupled code modeling the explosive charge, sand and air with a Eulerian mesh and the plate structure with Lagrange elements, such as Gemini-Dyna, is an appropriate computational tool. In water-saturated sand, the loadings are soil and water-transmitted shock and bubble or blast effects depending on the depth and the charge size. The computations provide the capability to determine the total impulse load placed on a horizontal plate on or above the soil due to an explosion in the saturated sand for different burial depths in saturated sand and different plate stand off distances. The following test case will be presented: (a) 4.5 Kg (10 lbs) TNT, 10.16 cm (4 in) depth of burial to top of charge, and 20.32 cm (8 inch) stand off distance (Test 4).

Jan 1, 2005

Strips of AA6111 automotive alloy were cast on a horizontal single belt strip casting simulator, Pure copper and carbon steels substrates plasma sprayed with different coatings for improving the strip surface quality, were used as chill moulds, Experimental studies revealed that a graphite coating provided the greatest benefit in achieving good surface quality. The interfacial heat fluxes during solidification of AA6111 strip were calculated by the IHCP method (Inverse Heat Conduction Problem). Temperature variations and cooling rates within the strips were then calculated through numerical simulations based on the time-dependent heat fluxes obtained by IHCP, The effects of casting parameters, including casting temperature and strip thickness, on interfacial heat fluxes, cooling rates and microstructures, were investigated, Although the maximum interfacial heat fluxes on the chill copper substrate were much higher than the results obtained from the steel substrates, the solidification times of the melts were mainly determined by strip thickness. Very fine equi-axed grains were obtained for both 1.2mm and 2.5mm thick strips thanks to the rapid extraction of heat, and effective grain refinement.

Jan 1, 2005

By W. Basuki, B. Setyotomo, L. Hakim, R. Hendrajaya

Due to high crack sensitivity of slab product of gas and oil line pipe application, its steel making process and alloy composition were evaluated and then improved to overcome its critical solidification process and reduced surface defects. The study was conducted at Slab Steel Plant Krakatau Steel. The purpose was to improve slab surface quality by reducing surface defects so that the slab surface doesn't need to be totally repaired. The method applied was by performing plant trial process, which the secondary process parameters such as alloying method and the casting parameters such as casting powder selection, metallurgical cooling, mould level control, and superheat were continuously monitored and then adjusted to the surface quality of the product. Based on the calculation of Ferrite potential of the steel, the chemical composition was designed to achieve optimum casting parameters in order to avoid high shrinkage during solidification. The results of the study are decreased surface defect quantity, and smooth casting process. The quantity of crack decreased by almost 90%. The slab surface repairing was significantly reduced from 85. % to less than 10%. These new casting parameters and developed alloy composition are then used and standardized for the mass production of the steel.

Jan 1, 2005

By G. T. Lapidus, R. M. Luna-Sánchez

In the present study, a series of cyanidation experiments were performed on a bulk sulfide concentrate which contained silver in four distinct phases, to determine its extraction rate, varying the oxygen concentration. The results showed that three of the four phases were refractory, aguilarite (Ag,iSeS) being the only leachable phase, and that the effect of the oxidant concentration is minimal. Mathematical simulations were performed, adjusting only the Damkohler number to adequately fit the experimental data. This model, and the mechanism implied, was compared with that found for acanthite (Ag2S) in a previous study, and the differences between the two discussed.

Jan 1, 2005

By Paul M. Godlewski, Joseph P. Gildner, David S. McAllister

With construction underway on the 22.5 km (14 mile) Initial Segment of the Link Light Rail transit system in Seattle (including the one-mile EPB-driven running tunnels and mined station at Beacon Hill), the Sound Transit Board on May 20, 2004 voted on selection of a preferred route for an approximately eight-mile extension northwards from the central business district to Northgate, and authorized immediate start of advanced conceptual/preliminary engineering and geotechnical exploration programs scheduled to be completed in Spring 2005. The extension includes approximately914 m (30,000) route-feet of bored running tunnels, a mined station with platform level approximately 60 m (200 ft) below grade, three (possibly four) cut-and-cover stations and a cut-and-cover cross-over structure, as well as an aerial terminal station at Northgate and other line-section below-grade and aerial structures. All tunneling will be in glacial soils.

Jan 1, 2005

By J M. F Clout

Geological, textural and mineralogical classification of iron ores is routinely conducted by mine and exploration geologists on reverse circulation percussion, blasthole cone and bulk samples for grade control, defining ore and waste, determining lump:fines ratio and predicting downstream processing characteristics. Classification is based on physical hardness, colour, streak and other visual characteristics. However, logging is generally restricted to the five to 20 per cent of chips above about 2 mm. This means that most of the sample is too fine to be reliably logged for anything but colour or streak and the textural types must be inferred from other information. A recently developed software package called æRecognitionÆ allows automated identification and classification of iron ore textural types and gangue on a particle basis in polished section down to 0.01 mm using processed digital images. It is not designed to be used as a routine logging tool, but is applicable where higher definition is required at the resource evaluation stage on selected percussion, drill core or bulk samples. æRecognitionÆ processes data obtained after optical image analysis of fine iron ore samples. It contains several parts, like æRecognitionÆ, æCompositionÆ, æLiberation by Total IronÆ, æLiberation by PhasesÆ and æStatisticsÆ, which allow vast and diverse information to be obtained about the iron ore samples being studied. Identification and classification of the textural type of each particle is performed according to the CSIRO-Hamersley Iron Ore Group Classification Scheme. The recognition procedure encompasses a good knowledge of different ore types and a logical knowledge tree, managing fuzzy boundary problems and the potential for a few different ore types in the same particle to be considered. This new technology introduces strict criteria to make the process of identifying particles more objective. Automated recognition standardises the identification procedure and significantly saves time. It enables users without a strong background in mineralogy to perform accurate texture identification. The æRecognitionÆ package has a modern user-friendly interface and Word compatible output. The combination of all the features mentioned makes the package a convenient tool for detailed studies of fine iron ores.

Jan 1, 2005

By Nabil F. Ismael, Mohamed El Deeb

"The behavior of laterally loaded step tapered bored piles in calcareous sand was examined by field tests. Lateral load tests were carried out on straight and step tapered bored piles 5.3 m long embedded 5 m below ground level. All piles were installed by augering. The straight piles were 0.2 m, and 0.3 m in diameter. The step tapered piles have a diameter of 0.3 m along the upper 10%, 20%, and 40% segment, respectively, changing to 0.2 m for the lower section. Two piles were instrumented with strain gages to measure the bending strains. All tests were carried out to failure. The purpose being to examine the ultimate lateral capacity and the deflection at working loads. Test results indicate non linear response and substantial increase in lateral capacity and decrease of deflection for the step tapered piles compared with the 0.2 m diameter straight shaft piles. However, beyond a depth of 40% of the pile length, the strengthening of the pile section by enlargement of its diameter had little effect on the lateral capacity and the deflection of step tapered bored piles.IntroductionFor many structures on pile foundations the ultimate capacity under lateral loads is important and may be the controlling factor in foundation design. Examples include transmission tower foundations and fender piles at sea port facilities. Increasing loads on these structures has resulted in piles of large diameter and depth at a significantly higher cost.In this work, the use of step tapered bored piles with a larger diameter along the upper segment of the piles is examined by field testing and analysis on single piles in calcareous desert sands. Lateral load tests were carried out on straight and step tapered piles 5.3 m long embedded 5 m below ground level. The straight piles were 0.2 m, and 0.3 m in diameter. The step tapered piles had a diameter of 0.3 m along the upper 10%, 20%, and 40% segment, respectively, changing to 0.2 m for the lower section. Two piles were instrumented with strain gages to measure the bending strains. All tests were carried out to failure. The purpose being to examine the ultimate lateral capacity and the deflection at working loads for step tapered bored piles."

Jan 1, 2005

Legislation introduced for Queensland and New South Wales Coal mines provides different levels of prescription regarding specification of mine seals û generally in relation to capacity to withstand overpressure. In Queensland, the Coal Mining Safety and Health Regulation (2001), Section 341 (d) places a further onus on the statutory ventilation officer to æensure all ventilation control devices at the mine are properly constructed and maintainedÆ and that the ventilation officer æmust ensure a ventilation control device mentioned in the regulation à and installed at the mine meets the design criteria statedÆ for the ætype of deviceÆ. Based on the experience of the author, it appears that risk management and life cycle approach to seals has not been adopted to the same extent as for other aspects of operations. Further, because of the number of disciplines and personnel involved that may influence various factors affecting seal integrity, the opportunity for oversight or unclear allocation of responsibility is considerable. While suppliers can provide explosion or design rated seals, this should only be a starting point for application of the product in a coal mine. Application is often considered by mine planning staff (taking into consideration mine environment parameters such as water, control of gas, spontaneous combustion risk, etc) in conjunction with the colliery ventilation officer, and then construction completed by contractors under supervision of operational staff. After construction, seals often are managed by operational personnel with input from the ventilation officer. Input of the geotechnical engineer into pillar design, roadway opening size, ground support specification and most stable seal location is also required. The need for a customised design approach for each seal site is proposed in order to take into account the many and variable factors that may influence a site so that improved seal performance reliability and predictability can be developed. A program of quantitative as well as qualitative monitoring of performance and triggers for rectification or maintenance action is required, and would provide support to the aforementioned proposal. Many mines rely on visual/audible inspection and periodic bag sampling as the primary means of assessment. Other significant factors such as seal material properties, rib degradation, convergence, floor heave, effects of water on both structural integrity of the seal as well as the air tightness of the seal do not generally receive the same level of attention. Based on the above observations, the author has compiled a reference checklist in regard to the above matters, including aspects of and approaches to mine and pillar design, geotechnical modelling and data collection, civil engineering design, site evaluation and practical options available.

Jan 1, 2005

By D E. G Connelly, K Y. Wong

Gold at the Harbour Lights Mine (HLM), WA occurs principally in pyrite (Py) and arsenopyrite (AsPy) minerals rendering it inaccessible to direct cyanidation. Froth flotation produces a concentrate with low mass recovery and with high recoveries of sulfides. After investigating several alternatives, a novel flotation process has been developed to separate the concentrate into pyrite and arsenopyrite rich fractions. The pyrite fraction is finely ground and cyanide leached, while the arsenopyrite is treated off-site. This paper describes the separation process from laboratory bench scale through to commercial operation at the HLM gold plant.

Jan 1, 2005

By J. Lu, D. G. Ivey, H. Henein

Microalloyed steels are widely used in the oil and gas industry. They are a class of high strength, low carbon steels containing small additions of niobium (Nb), titanium (Ti), molybdenum (Mo) and/or vanadium (V). These steels have good strength, toughness and excellent weldability, which are attributed in part to the presence of nano-sized carbides, nitrides and carbonitrides. In the pursuit of developing higher strength microalloyed steels, it is of great interest to quantify the size, distribution, volume fraction and chemical speciation of these precipitates. However, characterization techniques suitable for quantifying fine precipitates are limited. Possible characterization techniques include SEM, TEM and matrix dissolution. A comparison is presented of the various techniques.

Jan 1, 2005

The negative effects of pyrite and pyrrhotite on thiosulfate gold leaching have been investigated. Possible remedies to reduce some problems are discussed. In a gold bearing pure silicate ore, 92% of gold could be extracted within 3 hours using a solution containing 0.2 mol/L ammonium thiosulfate, 0.9 mol/L ammonia, 30 - 300 ppm copper sulfate and 8.6 ppm dissolved oxygen at pH 10.26. The thiosulfate consumption was 7.1 kg/t under these conditions and could be further reduced to 3.5 kg/t by decreasing the dissolved oxygen to 0.3 ppm. Addition of 16% pyrrhotite or pyrite into the silicate slurry led to a decrease in gold extraction by 2% or 9% respectively and an increase of thiosulfate consumption by 11 kg/t or12.8 kg/t respectively in three hours. Several adjustments, such as increasing copper ion and ammonia concentration and reducing the dissolved oxygen level to 0.3 ppm resulted in increased gold extraction and lower thiosulfate consumption despite the presence of these sulfides.

Jan 1, 2005

By B Washington, A Campbell, R Taylor

A sampling and measurement program was undertaken on the reaction shaft of the Olympic Dam copper flash smelting furnace. The object of the work was to provide information to validate a mathematical model of the burner and reaction shaft. Samples and measurements were undertaken through the burner inspection ports and the South East (SE) shaft sampling port about half way down the reaction shaft. Samples were collected to enable the calculation of particle loading of shaft gases, or sizing and chemical analysis of the partly-combusted feed, and the preparation of polished sections. Measurements were made of the temperature and sulfur dioxide content of the atmosphere, as well as plume velocity.To implement the program it was necessary to design and construct the following specialised items of equipment. For use at the burner inspection ports: a cup sampler for obtaining samples below the burners (temperature, solids loading and samples for characterisation).For use at the SE shaft sampling port and also at the settler level: trough sampler (plume definition and samples), isokinetic sampler (used as a velocity probe in this work), temperature probe (temperature traverses across the shaft), and sulfur dioxide probe (SO2 measurements across the shaft).The design of the sampling and measuring equipment is described, and examples are cited of the types of information obtained. The problems arising from working in a hot environment with molten or sticky particles are discussed.

Jan 1, 2005

By A S. Kurilko

For mines located in the cryolitic zone, thermal conditions are an important factor for all kinds of mining works, especially for ventilation of workings. In the present paper, some models of mine air heat transfer considering air distribution in a net of mine workings are developed. A combined solution is suggested for heat transfer and air distribution problems in mine workings and other underground structures located in the cryolitic zone. A software package is also presented for calculating temperature conditions in an underground refrigeration plant and for optimisation of ventilation conditions. This software uses a special 3D mathematical model to describe heat transfer in a freezing chamber between surrounding rock massif and stored product as well as between atmospheric air and the daylight surface of rock massif. A problem requiring strengthening of a backfill material and its thermal interaction with surrounding rocks during underground deposit mining by horizontal layers in conditions of the cryolitic zone is also discussed. The developed program takes into account cement consumption, geometrical dimensions of workings filled and a sequence of deposit mining.

Jan 1, 2005