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By David B. George

Kennecott Utah Copper adopted Outokumpu Flash Smelting and Kennecott-Outokumpu Flash Converting in 1995, a process based on granulating high grade copper matte. While nickel mattes and very small quantities of copper matte had been commercially granulated for years, no large scale copper matte granulation system had been built. This paper summarizes the history and benefits of copper matte granulation, the Kennecott design basis, the successful operation for over 10 years and potential problems inherent in some matte granulation approaches.

Jan 1, 2006

By Khaled Morsy

In the past two decades, high horizontal stress has been attributed to many ground control failures. Most believe that entries parallel to the high horizontal stress is most stable and least stable when perpendicular to it. Entry stability decreases when the angle between entry and horizontal stress increases. The concept of 2-D stress shadow has been proposed for selection of proper panel orientation, often with mixed results. In this paper 3-D finite element modeling was used to analyze the stress distribution at the headgate of a longwall panel subject to high horizontal stress at various angles. It was found that the directions of induced principal stresses at the longwall face and headgate are independent of the panel orientation. The induced principal stresses concentrate or relief at headgate based on the panel orientation with respect to the directions of the induced principal stresses. Accordingly, only 3-D modeling can fully account for the effects of high horizontal stress on panel orientation. The paper illustrates in details the changes in orientation and magnitude of all three principal stresses around the longwall face and T-junction area as panel orientation changes.

Jan 1, 2006

By Sergio N. Monteiro

Polymeric matrix composites with dispersed hard particles are being as wear resistant tools in industrial polishing operations. In the present work, the microstructure of epoxy composites with different amounts of embedded diamond particles, up to 30 wt.%, was investigated for the effect on fracture characteristics. It was found that the introduction of diamond particles promoted an increase the porosity of the epoxy matrix. Moreover, the particle morphology associated with a non-uniform distribution within the matrix was responsible for the nucleation of cracks that caused rupture of the composites.

Jan 1, 2006

By Susan Jacob

The heat of fusion of silver was measured using high temperature differential scanning calorimetry (HTDSC). Heating rate, sample mass, calibration standard and cover gas flow rate were varied to determine their impact on instrument accuracy and reproducibility. Good reproducibility was achieved in most of the runs. Accuracy was not satisfactory in most of the runs, though three runs gave results within 1.7%, 3.3% and 3.5% of the literature value, within the acceptable limits. A larger mass and higher heating rate tend to generate more accurate results.

Jan 1, 2006

In this study, the method of chemical co-precipitation?reduction?diffusion was developed for the preparation of magnetic SmCo5 alloy. In the chemical co-precipitation process, the effects of solution pH, the reactant concentration, the dispersant on the process were investigated. The optimum conditions of the process were determined, and the SmCo5 alloy oxide precursor particles with fine crystalline structure, narrow size distribution was obtained. Then, by reduction-diffusion treatment of the precursor particles, the SmCo5 alloy with high quality was produced. It is anticipated that the co-precipitation-reduction-diffusion is a novel method available for SmCo5 alloy production.

Jan 1, 2006

By S R. Grano

The selection of the proper frother, specifically for a given ore, is essential in flotation. Traditionally, strong and stable froths are required in the scavengers, where metal recovery needs to be maximised, while selectivity must be achieved in the roughers and cleaners, where grade of concentrates is the main issue. The physical properties of a froth are determined both by frother type, by process water composition and by the amount and nature of the suspended particles. The evaluation of different frothers, in terms of metallurgical performance, is complicated at plant scale, since it may lead to periods of malfunctioning of the process and unacceptable decreases in recovery. On the other hand, evaluation based on frother chemistry only, is often unsatisfactory, because the frothing response is strongly ore dependent. A procedure, and proper tools, was developed at the Wark in order to perform the screening of candidate frothers at batch scale on real pulp samples. The main parameters related to froth stability (half-life time, froth height) are measured after introducing the pulp samples into a foaming column, where different conditions in terms of frother addition, agitation and aeration can be maintained. The approach has been applied to the selection of frothers for the flotation of an Australian sulfide ore. Procedure and results are discussed.

Jan 1, 2006

By K J. Davey, J T. Woodcock

Australian steelmakers produce up to 30 000 t/yr of electric arc furnace (EAF) dust. Current disposal techniques include sending EAF dust to landfill, stockpiling, and paying zinc smelters or registered waste removalists/processors to take the dust. Many of the complex overseas pyrometallurgical and hydrometallurgical treatment routes cited in the literature are not considered economic. Governmental, environmental and social pressures on producers to consider more sustainable disposal options are mounting, and there is now a strong push to consider recovering potentially valuable or recyclable components, such as zinc and iron units, from EAF dust. As well, there remain strong economic drivers for producers to find lower cost disposal solutions. Characterisation studies undertaken at CSIRO Minerals have revealed important physical differences in the nature of the zinc- and iron-bearing phases contained in domestic EAF dusts. These differences have been exploited using simple and cheap mineral processing techniques such as water washing, wet cycloning and wet magnetic separation. This has allowed a significant upgrade in the zinc content of EAF dust to be achieved, together with a reduction in the levels of key smelter penalty elements, such as chlorides and fluorides. The zinc-rich portion of the dust is now a more attractive smelter feed while the iron-rich part of the dust could potentially be briquetted or pelletised with a reductant and recycled to recover iron, and thus close the loop on dust processing. The basis of the separations tested together with laboratory results from several Australian dust samples are presented and discussed in this paper.

Jan 1, 2006

By P. Wanjara, M. Xiao, M. Jahazi, C. Poon

Using a robotic 4kW Nd:YAG-laser system, Inconel 718 (1 mm sheet) was welded with and without filler wire to investigate the effect of processing parameters, including power input and welding speed, on the weld geometry, microstructure and mechanical properties. By means of both nondestructive testing and microscopic examination, the weld quality was studied to determine the nature of the welding defects (porosity, cracking and bead shape) over the processing range of 3-3.5 kW for the power input and 4.5-6 m-min-1 for the welding speed. Application of the design of experiment methodology permitted the examination of the relationship between the process parameters and mechanical properties, from which the optimized laser welding conditions could be determined for joining Inconel 718. In particular, the research results indicate that Nd:YAG-laser welding technology can achieve defects free, mechanically sound welds with narrow fusion and heat effected zones.

Jan 1, 2006

By I. M. Masters

Iron removal and control in processes employing pressure leaching technologies developed at Dynatec Corporation are reviewed. Discussions are focused on recent developments in the processing of nickel-copper matte and copper concentrates, and on the Ambatovy laterite project in Madagascar. Iron control and its implications on flowsheet design in the pressure acid leaching (PAL) treatment of laterite ores and in the oxidative pressure leaching of mixed nickel-cobalt sulphide intermediates are also discussed.

Jan 1, 2006

By Anat Deepatana

Bioleaching of nickel laterite ores is the extraction technology based on the use of heterotrophic micro-organisms and their organic acid products to dissolve metals from oxide minerals. This study examined the chemical leaching kinetics of limonite and nontronite ores with metabolites including citric, lactic and malic acids. The leaching process was found to follow the chemically controlled model. The leaching kinetics was found to be significantly influenced by the acid strength or dissociation of acids in solution. Although increasing the acid strength increased the rates of leaching, this trend was not indefinite. An optimal acid concentration that defined the fastest leaching rates was identified for each acid. The amenabilities of the minerals hosting the nickel and cobalt in limonite and nontronite to organic acid leaching were also established.

Jan 1, 2006

By S. Shrestha

Magnesium-based alloys are of growing interest for many industrial applications due to their favourable strength-to-weight ratio and excellent castability. Mass reduction has advantages in many industrial sectors for example, in automotive, a reduction in mass improves fuel economy and can lead to more efficient mechanical systems by reducing the weight of moving parts like wheels, gears, pistons. However, the relatively poor corrosion and wear resistance limits the use of magnesium and its alloys in many potential applications. The patented Keronite® plasma electrolytic oxidation (PEO) process enables manufacturers to overcome such problems and, in its latest generation equipment has been developed to industrial realisation for high volume production. This paper presents microstructural characteristics and corrosion performance of two most widely used high pressure die-cast magnesium alloys AZ91D and AM6OB with a duplex corrosion protection coating system that comprised a thin Keronite pre-treatment followed by a subsequent automotive grade final powder coat.

Jan 1, 2006

By Xiaowen Liu

The DSC/TG, IR and XRD analysis were used to characterize the heating phase transformation of illite, which came from Ouhai deposit, China. It was discovered that the dehydration and de-hydroxylation of illite carried out stage by stage during heating. The adsorptive water and layer-inter water were dehydrated from room temperature to 500°C; and dehydroxylated in the range 500°C~800°C. In these stages of process, illite?s layer structure kept almost unchanged. After 800°Cillite began to change into disorder structure. At about 1100°C, the layer structure of illite had been destroyed, and amorphous SiO2 and mullite crystallite appeared. At about 1200°C the structure of illite completely destroyed and mullite crystal phase had become perfect..

Jan 1, 2006

By Brijes Mishra

This paper presents a correlation of acoustic emission (A.E.) with physical and mechanical properties of different types of rock and coal specimens which were tested under aegis of a consultancy project from a Columbian Mining Company. In this study, three types of rocks which are sandstone (Arneisca), siltstone (Arciolita) and claystone (Limolita) and two different types of coal were tested. The tests were carried out under constant loading rates according to ASTM Standards for determining Young?s Modulus and Poisson?s Ratio. In both cases a MTS electro-hydraulic loading system was used. Mode of failure in each material was characterized by the acoustic emission and the results were substantiated by the deformation characteristics of the materials during failure.

Jan 1, 2006

By A. Bowles

The process of accumulative roll bonding (ARB) has been applied to wrought magnesium alloy AZ31. Accumulative roll bonding results in severe plastic deformation of sheet material. In AZ31, this process leads to the refinement of the microstructure by dynamic recrystallization. The refinement of the microstructure results in an improvement in mechanical properties with potential for producing materials for superplastic forming. In this work AZ31 was bonded with up to 64 layers and the potential of roll cladding with aluminium was also investigated. The development of microstructure and the mechanical properties are reported here.

Jan 1, 2006

By Sergio Neves Monteiro

In the present work, a ceramic foam elaborated with illitic clays was characterized. Properties related to density and compression strength were determined in samples fired at 1300oC, a temperature that permits the clay structure to generate and retain gases that will produce the foamy structure. The microstructure of the ceramic foam was studied by X-ray diffraction, scanning electron microscopy and mercury porosimetry. The results showed that the ceramic foam presents a bulk density of 0.38 g/cm3. The microstructure is formed by large open pores, quartz particles and vitreous phase.

Jan 1, 2006

By M. Huang

A conductivity-based sensor for on-line measurement of free acid was recently built. This sensor is suitable for high ionic strength solutions and its corrosion-free operation is based on induction currents. It has been tested against literature data and measurements made using a previous developed contact-type conductivity cell, with an average difference within 1%. The electrical conductivities of H2SO4?H2O, H2SO4?MgSO4?H2O and NaCl?Laterite-H2Osolutions at temperatures up to 250 °C were discussed. It was found that the solution conductivity depends on various factors, such as the electrolyte concentrations, the type of electrolytes, temperature and the amount of dispersions. A semi-empirical model was developed to account for all the factors discussed. This model was further tested on actual process solutions from the hydrometallurgy of nickel where sulphuric acid solutions containing a variety of metal sulphates and solids. The average difference between the estimated acid concentration from this model and the one from titration was generally less than 5%, which is excellent for industrial applications.

Jan 1, 2006

A molten metal granulator was designed and fabricated at the U.S. Dept. of Energy, Albany Research Center, for granulation of precious metal-bearing alloys and slags. The system was designed to safely granulate a metal alloy at a temperature of up to 1,600°C at a rate of roughly 50 kg of alloy per minute. The primary water jet was supplied by a 18.6-kW, 600 liter per minute pump which provided approximately 600 kg of water per minute through the primary jet. Two 3.7-kW, 150 liter per minute auxiliary pumps provided additional wash water to wet the granulation trough through 4 secondary jets, which were placed at either side of the primary jet. The water supply was closed-loop, including a 37,850-liter supply tank and 22,710-liter recovery tank. Magnetic separators and particulate filters were included for collection of the finest fraction of the granulation product, which cleaned the water sufficiently for continuous recycle.

Jan 1, 2006

By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006

By F. H. Samuel, A. M. Samuel, H. R. Ammar

Casting imperfections, such as porosity, in cast aluminum components greatly influence their fatigue properties. The effect of porosity on the fatigue life of 319-F and A356-T6 aluminum alloys was studied, where the porosity characteristics on the fracture surfaces of fatigue-tested samples were examined using SEM and image analysis. The results show that porosity has the most detrimental effect on the fatigue life: 92 % of all tested samples fractured due to porosity acting as the main crack initiation site. In the absence of casting imperfections, other microstructural aspects such as slip bands can be responsible ( 4 % ). The porosity was investigated in terms of the pore size at the sample fracture surface and its location i.e. near the edge or close to the interior. It was found that porosity located far from the sample surface (edge) has less influence on the fatigue crack initiation, and the fatigue life decreases as the size of the pore located at the sample surface increases. Aluminium

Jan 1, 2006

By K. P. Nishad

The origin of many casting defects can be traced at the mold filling stage. Entrapped air/gas pockets and oxide film formation are notable examples. In the present work, the mold-filling process is simulated using a mathematical model, built on a multi-physics based commercial package PHYSICA. The simulation code has the capability to solve multi-phase problems. The numerical model addresses a complicated dynamics of filling operation including free surface flow and subsequent flow behavior and is based on conservation of mass and momentum. The Free surface is modeled using the scalar equation method (SEM). The model is validated with benchmark experimental results from the literature. The role of turbulence and the pouring rate on variables affecting sites prone to oxide film formation are investigated using a simple but novel technique. Key findings of the work are presented.

Jan 1, 2006