Search Documents

By P. Bakke

Following extensive R&D efforts, Hydro Magnesium has launched a new alloy series with remarkable combinations of properties. The AE alloy family is based on additions of aluminium and rare earth elements to control mechanical properties, including elevated temperature creep strength. By combining these alloying elements with manganese additions, high purity alloys with outstanding corrosion performance are defined. A basic philosophy behind the developments has been to simultaneously approach all the critical issues related to developing a commercial material. Apart from the obvious requirements for material properties, the critical issues relate to die casting performance, as well as alloy production, recycling and environmental compatibility. Some of the important elements related to alloy production and recycling are addressed in the present paper.

Jan 1, 2006

By D. A. Beattie

Talc is a commonly encountered gangue mineral in metal sulfide flotation. Talc is naturally hydrophobic, resulting in high recoveries if polymeric depressants are not used to specifically reject this MgO containing mineral. We have studied the adsorption of a selection of polymers onto talc using a variety of techniques. Adsorption isotherms have been determined using ex situ depletion techniques and in situ ATR-FTIR spectroscopy has been used to determine adsorption kinetics. Adsorbed layer thicknesses have been determined for the polymers on cleaved talc surfaces using the AFM. The effect of the adsorbed polymer layer on the properties of the talc surface has been quantified through contact angle measurements and single mineral flotation tests. Distinct correlations are observed between the adsorbed layer properties and the flotation performance of the polymers. These observations are discussed with reference to the bubble-particle attachment process and the molecular structure of the polymers.

Jan 1, 2006

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By Pengfu Tan

A thermodynamic model of KIVCET lead smelting process has been developed. The model has the capability to predict the distribution behaviors of Pb, Zn, Fe, S, O, As, and heat balance in KIVCET direct lead smelting furnace. The compositions of lead bullion, matte, slag and gaseous phases, and heat balance are calculated. The effect of the ratio between oxygen and feed on the chemistry of the smelt and heat balance of the coke checker has been simulated and discussed. The thermodynamic model also helps to understand the tapping issue of the lead bullion. In this paper, some applications of this model in the industry have been presented.

Jan 1, 2006

Forty years ago Dr Pierre M Gy, a metallurgist, introduced variography as applied to monitoring a process. Consequently, his followers used the variogram to elaborate meaningful process control charts, especially since 1993. The name æChronostatisticsÆ was suggested several times by Gy as a logical name for this new science. The intent was to draw a parallel between the variogram identifying the variability components affecting a process parameter as a function of time, and the variogram used in geostatistics identifying the variability components of a given mineral content as a function of space. Heterogeneity problems encountered have indeed strong similarities. However, there is a fundamental difference. The variogram used in geostatistics is often stationary within a given type of mineralisation. While investigating a dynamic process through Chronostatistics, there is no such thing as a stationary variogram. Still, the evolving variogram provides essential information about subtle, often overlooked process difficulties. Chronostatistics is especially useful for management to take advantage of existing data that are often a forgotten source of valuable information to pinpoint recurring structural problems. The superiority of Chronostatistics over conventional statistical process control approaches is that it links observations to the inherent heterogeneity of materials under investigation, therefore to the sampling theory. Chronostatistics is like opening a new world to the metallurgist, making the process variability speak in a more comprehensive and in-depth way. Several case studies are presented to demonstrate the potency of this new science. For each of them, observations lead to solutions for continuous process improvement, therefore attractive economic opportunities. The philosophy is this: if a control chart shows a process is out of control, it must also suggest logical and pragmatic directions for solutions. The intent of this presentation is to vastly expand on these valuable, almost forgotten ideas.

Jan 1, 2006

By Andrew Howard

As the mining industry moves further into developing countries in search of new resources, its role in international development is coming under increasing scrutiny. This is a trend that is likely to accelerate, along with the potential for headaches among managers in the industry. Public interest in development and environmental issues is rising as faith in “big business” falls. This has strengthened nongovernmental organizations (NGOs) campaigning for sustainable development. And it has put more pressure on banks, governments and development agencies to curb corporate misdemeanors. Developing world governments are also becoming emboldened to reject previously agreed terms they do not consider equitable. The mining industry has begun to formulate a response to these pressures but must go much further. Societal and environmental issues must move from public relations to core strategic thinking. Abiding by rules or codes is not a relevant response. Instead, genuine support for sustainable development is required. This will involve delegating the responsibility for engaging with local communities to on-the-ground staff and developing a dialogue with local stakeholders rather than conducting an initial assessment and disengaging.

Jan 1, 2006

By Darelle T. Janse van Rensburg

Some of the more recent developments in Paint Technology are solvent free materials. These coatings have mainly been formulated to overcome the negative attributes of solvent-based coatings, i.e. environmental, safety and health risks, potential for solvent entrapment and osmotic blistering, as well as the formation of micro-pores during the curing process. Two solvent free liquid epoxy coatings have been used extensively on power generation plant. However, very little is known regarding their long-term performance under different exposure conditions, as well as whether these coatings actually perform better than their solvent-borne counterparts. In addition, solvent free materials are generally used where outage periods are restricted and coatings need to be applied within a very short period. Though these materials have reportedly much shorter curing times than other conventional solvent-borne coatings, little is known regarding their limits with respect to maximum film thicknesses and being put into service while still being wet/partially uncured. The latter has become common practice at many power stations in the past two years or so. In addition, the application and curing methods of solvent free materials are different to that of solvent-borne materials, and may require equipment and application process changes. This paper covers the application and performance properties of solvent free coatings in comparison to solvent-borne materials primarily intended for immersion service. Numerous coatings were evaluated under immersed static and cyclic hydrostatic pressures. Other tests included short curing / early immersion tests, dry-to-touch and dry-through curing times, adhesion tests, surface tolerance tests, etc. The results show that the solvent free materials have clear benefits with respect to safety, health, environmental and long-term performance, but will be more difficult to apply compared to solvent-borne materials.

Jan 1, 2006

By Jacques J. Eksteen

Any effort to improve the metallurgical control of industrial furnaces employed in the primary extraction of high carbon ferroalloys are bound to fail unless the variability of the melt is not fully accounted for. A number of sampling campaigns were performed on both 3phase AC submerged arc and single phase DC open arc furnaces at different smelter sites in South Africa where High Carbon Ferrochrome is produced. It was found that the heterogeneity between multiple samples during a single taps were much higher that for heterogeneity found within a sample. Moreover, this heterogeneity (as quantified by the relative standard deviation per tap) varied with the operating conditions of the furnace, the element monitored and the type of furnace. A relationship was found between the relative standard deviation of certain elements and the degree of subcooling of the melt.

Jan 1, 2006

By Art Cooper

Granulation systems are common in the metals industry. The process of granulating slags, mattes and metals is more than a century old, and a number of different systems have been developed to accomplish this task. These systems have followed an evolutionary path, and may be characterized by common elements in terms of molten material handling, granulation methods and post-granulation processing. This paper will summarize the more common systems used in the metals industry, with particular reference to non-ferrous applications.

Jan 1, 2006

By Collin L. Stewart

The high cost and limited flexibility of modern longwall systems has resulted in the need for mine engineers and geologists to predict possible adverse mining areas ahead of mining and to then design and implement suitable ground control solutions in a timely and cost effective manner. Therefore, over the last 30 years, geo-technical evaluations for coal mine planning and development have advanced from a minor afterthought to an important part of today?s successful, high capacity, longwall mining operations. The latest iteration in this progression of improved analysis for predicting future mining conditions is a computer-based Stability Mapping System developed by West Virginia University. This system is designed to allow the mining engineer and geologist to effectively combine the mine geologic characteristics, stress influences, and structural features into an integrated stability map for use in mine planning and support design. This paper details the application of the stability mapping system to Bowie Resources, LLC, Bowie No. 3, multiple-seam longwall coal mine. At this mine, the prediction of adverse mining conditions using the stability mapping system allowed management to accurately adjust their support densities and operational procedures, and to successfully mine through difficult conditions safely and successfully.

Jan 1, 2006

By S. Shairp

The first commercial application of the Dynatec two-stage zinc pressure leach process commenced operation at the metallurgical complex of Hudson Bay Mining and Smelting Co., Limited in Flin Flon, Manitoba in 1993. A key feature of the successful leaching operation is the presence of iron in solution, which facilitates oxygen transfer in the autoclaves and enables rapid oxidation of zinc sulphide minerals. At the same time, the solution from which zinc is recovered must be essentially iron free. Precipitation of iron from the solution starts in the autoclaves and is completed in subsequent atmospheric purification steps. Conveniently, these iron precipitation steps also remove nuisance elements such as arsenic and fluoride from the solution, while producing solids with good liquid-solid separation characteristics. This paper provides an overview of the current operations in Flin Flon, with particular reference to the behaviour and deportment of iron throughout the zinc plant.

Jan 1, 2006

By P. R. Brenchley

Main ore pass systems should last the life of a mine, and too often expensive and hazardous remedial measures are required to repair a damaged ore pass in an attempt to extend its life. In order to maximize the life expectancy of all ore passes at Moab Khotsong, ?wearing blocks? and ?softer support? systems, combined with basic rock engineering principles, have been implemented. Failure of an ore pass can have severe financial implications, both indirectly because the ore pass cannot deliver the broken rock either from level to level or directly in the shaft ore pass system to the required level for tramming to take place, and directly due to the cost of the repair work that is required. Several factors need to betaken into consideration so that production interruptions are eliminated or minimized. Investigations of damaged ore passes at Moab Khotsong and surrounding mines revealed some interesting mechanisms of damage, and some innovative methods of reducing or eliminating the damage have been implemented at Moab Khotsong. The system design was based on 30 years, experience in main shaft rock passes. The design was to counteract scaling, hang-ups and dust problems associated with main rock passes, and the objective was to increase the life of rockpasses. These problems, including the initial design aspects to try and eliminate the repair measures, are discussed in detail.

Jan 1, 2006

By Jason N. Scott

CFA piling is a ?blind? construction process that relies heavily on the rig instrumentation to produce sound piles. If the data measured and recorded during construction can be made available to engineers and managers within hours after construction then there are many economic and quality control benefits that can be realised. A state of the art CFA instrumentation and data management process has been developed in the UK. The key components of the instrumentation, GSM data service and the central database are described. Many benefits to the business have been realised and, where possible, these are quantified.

Jan 1, 2006

By O. A. Ojo, O. A. Idowu, N. P. Wikstrom, M. C. Chaturvedi

Transient Liquid Phase Bonding (TLP) of a Nickel base superalloy, Inconel 738, was performed to study the influence of holding time, filler gap size, and temperature on the joint microstructure. Insufficient holding time for complete isothermal solidification of liquated insert caused formation of eutectic-type microconstituents along the joint centerline region. An increase in the eutectic thickness with increase in initial filler gap size was observed in joints prepared at a constant temperature and holding time. In agreement with prediction by conventional TLP diffusion models, an increase in bonding temperature for a constant gap size, resulted in decrease in the time, tf, required to form a eutectic-free joint by complete isothermal solidification. However, a significant deviation from these models was observed in specimens bonded at and above l 175°C. A reduction in isothermal solidification rate with increased temperature was observed in these specimens, such that a eutectic-free joint could not be achieved by holding for a time period that produced complete isothermal solidification at lower temperatures. Considerable enrichment of the liquated insert with base metal alloying elements at higher temperatures is suggested to be an important factor contributing to the observed departure from conventional TLP prediction.

Jan 1, 2006

Asgco’s design of the Arrowhead Ceramic Lagging provides solutions to problems experienced with conveyor belt slippage around the drive pulley and severe wear problems on snub and bend pulleys. Asgco has developed a range of pulley lagging from ceramic, drive rubber and non-drive rubber lagging that is available in abrasion-resistant SBR and MSHA grade rubber for conveyor pulleys from slow belts all the way through to high-speed, high load belts. There is a growing need for a maintenance-free and reliable pulley lagging to ensure conveyor belts run to their highest efficiency.

Jan 1, 2006

A three?stages countercurrent fluidized bed prototipe reactor to neutralize the SO2from smelter gases has been developed. For gases with 8 vol-%SO2, at 800°C and for 4 h mean reaction time of the limestone, the capture of SO2 is 99%, with off gases with 0.07 vol-%. For 2 vol-%SO2, the total capture of SO2 can be obtained at 750°C and 4 h reaction time. The calcine obtained contain a blend of unreacted limestone and calcium sulphatewith minor amounts of residual lime.

Jan 1, 2006

By R. Poulin, M. R. Samis

Real options valuation is an alternative net present value framework that is able to incorporate both management flexibility and dynamic project risks. In this paper, management is considering the development of a satellite low-grade zone while operations in a developed high-grade zone continue. If the lowgrade zone is developed prior to high-grade zone exhaustion, mine capacity must be expanded before additional production from the low-grade zone can be processed. This expansion can be avoided only if low-grade zone development is delayed until the high-grade zone is exhausted. The real option model presented here allows the development and capacity expansion decisions to be reconsidered on a discrete half-year basis. It delineates price regions, for given levels of high-grade zone reserves, in which it is optimal to develop the low-grade zone, defer low-grade zone development and abandon the mine irrevocably.

Jan 1, 2006

By Oliver Zach

To know as much as possible about the condition of the refractory material (lining thickness, slag layer, build ups, ...) in an high temperature furnace is very important due to the safety and economic impacts. The new CONSCAN system offers the possibility to measure the inner surface of an furnace, and based on this results to calculate the thickness of the refractory lining, slag layer, build ups,.... The CONSCAN System provides this results as figures and graphics. This system is also working under hot conditions so it is not necessary to cool down the furnace. Based on these results the process control and the refractory lining concept could be optimized for maximum campaign life of the furnace.

Jan 1, 2006

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale (MD/FE) method has been used to study dislocation generation and plastic deformation during a nanoindentation process which is physically associated with the generation of heat within the specimen and as a consequence with a temperature rise. Two different techniques are applied to study the temperature effect on the nanoindention process. In the first technique, a global Nose-Hoover thermostat is applied to the entire atomistic region to keep temperature constant during simulation (finite temperature approach). In the second method, the thermostat is applied only on a damping region along the MD/FE interface. Both techniques are able to effectively and efficiently absorb high frequency reflected waves from atomistic/continuum interface. The temperature profile of the atomistic region beneath the indenter is reported and discussed at four different initial substrate temperatures for both techniques. The loaddisplacement (load/unload) curves for different temperature-controlling techniques are compared and discussed. The nucleation and propagation of dislocations in the atomistic region are investigated for both techniques. Correlations between the observed features in the load-displacement curves with the motion and pile-up of dislocations are reported as a function of temperature.

Jan 1, 2006

By D. Bouchard, J. Langlais, A. Lemieux, N. Andrade

A concerted effort between Akan International Limited and the National Research Council of Canada (NRC) has been initiated to develop a liquid-based slurrymaking process, dubbed SEED (Swirled Enthalpy Equilibration Device) for semi-solid forming. The technology is presently entering the industrial and commercial stages, and will be used by the first customers at the end of 2006. Semi-solid processing of aluminium alloys offers many advantages in fabricating economically near-net-shape parts of superior quality. The SEED process helps to overcome problems experienced with thixocasting and especially the high cost of feedstock. The SEED process involves two main steps: 1) heat extraction to achieve a desired liquid/solid mixture, and 2) drainage of an excess liquid to produce a self-supporting semi-solid slug that is formed under pressure. The heat transfer plays an important role (enthalpy equilibrium) during the manufacture of the semi-solid slurry and its analysis is briefly described. The semisolid material is obtained using different processing times and initial conditions. The impact on the solid fraction distribution and the morphological evolution of the microstructure is presented. The influence of the SEED processing parameters (slurry preparation) and the resulting mechanical properties for the alloy A356 are also reported.

Jan 1, 2006