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By K. Lascelles

ABSTRACT Nickel compounds vary significantly in their toxicological properties, so it is critical that continuing studies to accurately quantify worker exposures consider the processing that accompanies refining nickel-containing materials. The Clydach nickel refinery, which has operated for more than 100 years, was the first nickel-producing facility to show a high risk for lung and nasal-sinus cancers among workers employed since it opened in 1902. Process chemistry and equipment have changed dramatically over Clydach’s history. This paper describes the processing evolution at Clydach with a focus on the propensity for aerosol formation and the forms of nickel in airborne dusts.

Jan 1, 2013

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013

By Monte R. Hieb

Study of moisture-induced swelling strain in Pennsylvanian Period rocks of the Appalachian Plateau in West Virginia shows a 2:1 biaxial horizontal anisotropy which trends NW-SE. Oriented in-situ slabs of coal mine roof rock were collected across West Virginia, dry-sawed to size, air-dried to stability, and then monitored for moisture changes and deformations in the horizontal plane through one wetting cycle and drying cycle. Biaxial swelling strains were exhibited in nearly all rocks tested, with maximum horizontal deformations occurring normally-incident to the strike of regional geologic fold structures. This relationship persists as fold strike varies across the study area. A connection with Alleghanian fold development and/or post-Alleghanian fold relaxation is suggested. Deformations were largest in shales, but occurred in sandstones and siltstones as well. During testing, moisture-induced fractures (MIF) developed parallel to the regional fold structure and ranged in size from hairline cracks to sample-destroying cracks that were orthogonal to the observed biaxial swelling strain direction. Preferential wetting and swelling of clay minerals along NE-trending fractures, related to a fold-parallel fracture fabric of regional extent across West Virginia, is the most likely reason for the observed systematic NW-oriented biaxial swelling strains. The testing methods used in this study are simple and inexpensive and produce robust results that offer insight into a regional, anisotropic mechanical weakness that imparts a dynamic, asymmetrical horizontal stress to moisture-sensitive coal mine roof rocks over time. Because a similar mechanical fabric has been reported in Devonian-age shales, these findings may have implications for shale gas developers in the Appalachian Basin challenged by rapid aperture closure rates along horizontallydrilled induced fracture networks in Devonian rocks like the Marcellus Shale. The paper concludes with an example of how the concept of a preferred swelling strain direction might be applied to improve the effectiveness of roof trusses.

Jan 1, 2013

By C. Fortin

ABSTRACT The subject of gold flotation has been reviewed extensively. Most of these reviews focus on the theories of gold flotation and the physical and chemical effects that may impact the efficacy of the gold flotation process. The current status of gold flotation chemistry as it is being applied in industry has not been widely addressed. This paper reviews current gold flotation practice and research advancements and discusses how these applications tie in with the current understanding of gold flotation chemistry. Survey results from worldwide gold flotation operations are analyzed. Potential future areas of gold flotation research are highlighted.

Jan 1, 2013

By Andy Judge

"In traditional Permanent Magnet Machines, such as electric motors and generators, power is transmitted by magnetic flux passing through an air gap, which has a very low magnetic permeability, limiting performance. However, reducing the air gap through traditional means carries risks in manufacturing, with tight tolerances and associated costs, and reliability, with thermal and dynamic effects requiring adequate clearance. Using a magnetically permeable, high thermal conductivity material has the potential to improve magnetic performance, while at the same time offering performance advantages in heat transfer.Ferrofluids can be used to improve permeability in the rotor I stator gap. However, there are several tradeoffs in this approach. Fluid immersion comes with an increase in fluid friction loss compared to the windage losses of a traditional system. Isolating the rotating components from the ferrofluid can offset this effect. Also, while the magnetic effect can be positive for gap permeability, leakage flux can increase, and saturation can limit gains. These effects must be taken into account for a system optimized for ferrofluid immersion.IntroductionPermanent Magnet Machines (PMM's) convert electrical energy to mechanical energy in motor applications, or, for generator applications, convert mechanical energy to electrical energy through means of passing alternately polarized magnets past electrical coils. Looking at a simplified version of a PMM, where Rx is magnetic reluctance and <l>x is magnetic flux, we have the circuit shown in Figure 1."

Jan 1, 2013

By Roberto Folchi, Hans Wallin, Mara Battocchio

An understanding of explosives science and technology, and the competence to harness it is central to maintaining Explosives capability, national security, and in sustaining a competitive industry. A consequence of eroding this competence is the increased likelihood of explosives accidents. These are often catastrophic as demonstrated by accidents in Nigeria, Russia, Toulouse and Enschede. In addition to the serious loss of life there was the very significant damage to houses, domestic and industrial infrastructure and to the environment at a cost of many millions of Euros.

Jan 1, 2013

By Charles S. Spirakis

The consistent occurrence of organic carbon early in the paragenesis of Mississippi Valley-type sulfide deposits suggests a genetic link between organic carbon and the sulfide ores. Reduction of sulfate in the mineralizing solution by organic carbon at the sites of mineralization is commonly proposed as the precipitation mechanism for these deposits, but inorganic sulfate reduction is too slow to be important to the chemistry of the ore zone, and bacteria, which catalyze sulfate reduction at low temperatures, are not known to survive at the temperatures of mineralization. Sulfate reduction with or without bacteria is not consistent with the sulfur Isotope evidence. Sulfur isotope studies also indicate that the derivation of sulfur from hydrocarbon at the sites of mineralization is unlikely. Organometallic complexing may be involved in the transport of metals, but no plausible mechanism for breaking these complexes at the sites of mineralization has been proposed. Reduction of partly oxidized sulfur species in the mineralizing solution by organic carbon at the sites of mineralization is a possibility which deserves further scrutiny.

Jan 1, 2013

By Patrick G. Hatcher

Studies of sedimentary humic acids by nuclear magnetic resonance (NMR), stable isotopes, and elemental analysis show they are derived by oxidative degradation of complex plant macromolecules that are insoluble in aqueous or organic solvents. The mechanism by which humic acids originate is fundamental to our understanding of the role of organic matter in ore deposition, because these substances can complex and mobilize a number of metal ions. The organic matter associated with uranium ores of the San Juan Basin, New Mexico and Carlin-type disseminated gold deposits of Nevada has certain organic geochemical characteristics that suggest an origin from humic acids.

Jan 1, 2013

By Kimberlee Falkenstein, Volha Kibitkina, Jessica Steeves

A series of experiments were conducted to obtain site specific constants for the vibration produced by a single charge and by more charges detonating in sequence, using short delay intervals. All charges were placed in relatively long boreholes in granite without a free face other than the ground surface. The boreholes were filled with water to provide good coupling with the rock and to provide identical confinement for all the blasts. Vibrations were recorded close to each blast in the vertical direction by uniaxial high frequency geophones and far field using a triaxial geophone.

Jan 1, 2013

The authors provide a discussion of the paper, ?Coal workers? pneumoconiosis prevalence disparity between australia and the united States,? a peer-reviewed paper that appeared in the technical papers section of the July 2012 issue of Mining Engineering magazine. The original authors, G.J. Joy (gjoy@cdc.gov), J.F. Colinet (jcolinet@cdc.gov) and D.D. Landen (dlanden@cdc.gov), respond.

Jan 1, 2013

By Sylwia Zymankowska-Kumon, Rafal Danko, Mariusz Holtzer, Artur Bobrowski, Michal Kubecki

"Moulding sands with furan resin constitute constantly growing part in technologies of producing castings from iron alloys. Due to the presence of harmful substances in resins such as furfuryl alcohol, phenol and formaldehyde, using those mould sands may be hazardous to the natural environment and workers. The general assessment of harmfulness of sands used for molds and cores encompasses 2 basic points: emission of hazardous substances during processes of preparing sands, pouring mold with liquid metals (high temperatures), cooling and shaking-out; possibility of washing out hazardous substances from used sands to the environment, during storage or economic use outside foundries. We present the results of research on the assessment of harmfulness of mould sands with furan resin in the scope of the above points. The research was conducted according to the original method prepared by the authors, which has been used for years in cooperation with various foundries (Poland, abroad).IntroductionSands are used by the foundry industry to create metalcasting moulds, where the individual sand grains are typically bound using bentonite clay and carbonaceous additives or resins. During the casting process, the moulds can be exposed to temperatures as high as 1500°C depending upon the metal being poured. The molten metal causes thermal decomposition of carbonaceous additives or resins, which results in the formation of potentially hazardous organics that are emitted to the atmosphere and condense in the moulding sand [1]. The moulding sands are reclaimed within the foundry, but part of them are eventually discarded in landfills, because it is not longer suitable to make metalcasting molds [2, 3]."

Jan 1, 2013

By Mauritz Kotze, Jason Furtney, Ewan Sellers, Sandy Etchells, Tom Szendrei

The development of a simple model for gas flow and burden movement has driven the need to improve our understanding of burden breakage mechanisms for single hole blasts and the interaction between multiple holes in solid and jointed rock masses. Conventional analytical understandings of the burden breakout using the elastic-tensile fracture model were studied and found to provide a breakout angle that is independent of burden in contradiction to experimental data. By considering rock fracture in terms of Mohr-Coulomb plasticity using analytical expressions from the field of cavity expansion analysis an improved relationship between breakout angle and burden is derived until the point of critical breakout at which the angle of breakout suddenly changes from between 90 degree and 100 degrees to zero. This suggests that the critical burden occurs at about 0.6 times the radial fracture zone calculated from the analytical solutions.

Jan 1, 2013

By Josh Swank

Albert Einstein once said, ?the important thing is not to stop questioning.? In the mining industry, a lack of inquisitiveness may lead to a blissful ignorance but it certainly will not increase efficiencies. While one may claim necessity is the mother of invention, questioning and analyzing how methods and systems can be improved is the catalyst to discovering necessities. Understandably, when working in the middle of Canada?s oil sands, where trucks operate around the clock every day of the year, it is nearly impossible to pull the nose from the grindstone long enough to provide thorough analysis. But, fortunately, some manufacturers/inventors have assisted by examining the process and the ensuing headaches within this application.

Jan 1, 2013

By Xinli Wang, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Byoung-Gon Kim

"The microwave reflection loss (RL) of ferric oxide is studied in the temperature range from 297 to approximately 1400 Kat frequencies of 915 and 2450 MHz. It is shown that the maximum microwave absorption with RL of -38.46 and -35.97 dB can be obtained for ferric oxide having thicknesses of 0.03 and 0.01 m at 915 and 2450 MHz, respectively. The maximum absorption peak with RL below -10 dB is in a 250 K temperature range from 723 to 973 Kat 915 MHz, which shifts to the range between 823 and 1073 K at 2450 MHz. This migration is in good agreement with the variation of the dielectric loss tangent of ferric oxide.IntroductionMicrowave irradiation has distinguishing characteristics such as volumetric and selective heating compared with conventional methods, leading to extremely broad applications in materials heating and processing [1-5].The efficiency of microwave heating was found to be dependent on various factors, such as microwave power [6], frequency [7,8], radiation time [8], applicator geometry [8], sample microwave absorption properties and position as well as dimension [9-11 ], etc. Among these parameters, sample dimension plays an important role but is usually neglected by researchers in microwave processing of materials. In fact, although numerous studies have been directed toward the utilization of microwave energy to assist materials heating and processing, few reports were released on the effect of sample dimension [12,13].This is because all aforementioned factors influencing microwave heating generally exert interactive effects to each other during the heating process, making clarification of the effect of sample dimension difficult. Therefore, it is necessary to propose a parameter or concept for quantifying the effect of absorber dimension on microwave heating, increasing heating efficiency."

Jan 1, 2013

By G. Belzil, F. Robichaud, M. Fullam

ABSTRACT The Goldex mining and milling complex is operated by Agnico-Eagle and is located in the Abitibi greenstone region of northwestern Quebec, Canada. Commercial production started in 2008. Average gold recovery is 93.5% with approximately 68% of gold recovery coming from the gravity circuit. During the first three years of production, three gravity audits were carried out to optimize performance of the gravity circuit. This paper presents results of the audits and the development of a model linking gravity and overall gold recovery, and outlines improvements made to increase gravity performance and reduce operating costs.

Jan 1, 2013

By D J. McLane, J T. Rathbun, B T. Lusk

The dynamics of explosive detonations are understood, however recreating a real-world, full scale scenario is costly. The use of a shock-tunnel allows testing to be done on a smaller scale, with the simulated effect of a large explosion. Analyzing explosive waveforms using this method can greatly reduce cost in testing blast resistant products, such as anti-terrorism devices, mine safety products, and military equipment. The purpose of this paper is to better the understanding of how the waveform characteristics resulting from an explosive detonated within a shock-tunnel differ from those in an open-air arena test. The variables of comparison between an open-air arena test and those conducted within a shock tunnel are peak pressure, impulse, shock wave velocity, and cross sectional shape of the shock front. Understanding how these variables differ, tests utilizing a shock tunnel can be conducted with a higher degree of accuracy and repeatability.

Jan 1, 2013

By O. Babak, J. G. Manchuk

ABSTRACT A significant factor in evaluating bitumen recovery from an oil sands mine is the particle size distribution (PSD). Increased understanding of mined ore quality and improvement in predictions of recovery can be achieved through PSD modeling. This paper addresses PSD modeling using geostatistics. PSDs may be described using many discrete particle sizes, making this a challenge. The approach parameterizes PSDs with a few statistics. A lookup table is used to reconstruct the PSDs based on models of the statistics. The workflow is applied to Total E&P Canada’s Joslyn Lease and yields good results that reproduce input statistics without introducing artifacts.

Jan 1, 2013

By Chao Lian, Hongxu Li, Hao Bai, Wei Wei

"Application of high-emissivity coating on inner walls in industrial furnaces increases the furnace thermal efficiency. The coating with high emissivity strengthens radiation heat transfer in the furnace, however, according to Wien's displacement law and Planck's radiation law, under heating temperature, the wavelengths of the radiation transfer are mostly between 1-5 µm, implying that increasing emissivity of the coating in near infrared band is more effective for higher thermal efficiency. In this paper, a new CuO-ZnO-based coating material sintered at 1600K was developed. The emissivity of the samples were measured and the result shows that, in near-infrared band, the emissivity of the sample reaches 0.98 at 773K with 13at.% of CuO doped in ZnO. In addition, the effects of CuO doping and use temperature on emissivity were also discussed. Furthermore, crystallization behaviors of ZnO-CuO sintering were investigated by DTA,XRD and SEM-EDS etc., which offered information for possible optimal design of the material.1. IntroductionIndustrial furnaces are widely used in various industrial heating. For example, the metal smelting furnace, ore sintering furnace in metallurgical industry; the distillation furnace, cracking furnace in petroleum industry etc,. The research on efficient energy saving technology has important significance. High emissivity coatings are widely used in many high temperature applications to effectively transfer the heat by radiation [ 1]. The theoretical calculation and experimental studies have shown that, coated high emissivity coating in the heating surface is an effective method to enlarge the infrared radiation power [2].At present, the infrared high emissivity coating has been widely used in China, and have been achieved remarkable energy saving effect. According to Wien' s displacement law and Planck' slaw, most energy of the black body at high temperature is radiated in the wavelength range of l-5µm; however it happens that many materials have the low emissivity within this range. Thus, it is important to improve the near-infrared band emissivity of materials [3]."

Jan 1, 2013

By S. Gopalan, J. D. Milshtein, S. N. Basu

Production of syngas is proposed utilizing the W/W03 redox system and employing a solarpowered two-step thermochemical cycle. Three chemical reactions occur in two chambers. Assisted by a solar concentrator, a high temperature reaction reduces W03 powder to metallic tungsten in both chambers. Subsequently, the temperature in one of the chambers is lowered and H2(g) is produced via re-oxidation of the tungsten powder using steam. The temperature in the other chamber is simultaneously lowered to an intermediate temperature and CO(g) is produced via oxidation of the tungsten powder using C02(g)· The gas streams coming out of the two chambers result in the syngas production. A complete thermodynamic analysis of the system is described. The W/W03 redox cycle offers greater gravimetric fuel productivity compared to previously proposed systems, and the entire cycle can be operated below 1273K.

Jan 1, 2013

By Andrew P. Gize

The analytical approaches used to solve a specific problem are dependent upon the information required, coupled with limitations imposed by available facilities, costs, and time. The organic matter associated with ore deposits has the potential to yield information for two problems. Information can be obtained to provide guidelines for prospecting, and, secondly, to solve genetic problems. A major potential of organic matter in providing prospecting guides lies in the high thermal sensitivity of organic matter in sediments which are metamorphosed at grades lower than greenschist facies. The organic matter can then be used to map thermal anomalies potentially associated with mineralization. The analytical approach is to determine the thermal maturity of the total organic matter, or of specific fractions, using techniques which are relatively quick and inexpensive. Consideration of genetic models (for example, reduction, complexing, involvement of oil field brines) generally requires more specific information than the overall thermal maturity of the organic matter, necessitating infor¬mation on molecular composition and structure. The facilities, time, and cost of this information are greater than for mapping thermal anomalies. The analytical techniques discussed include elemental analyses, spectroscopy (infra-red, visible and ultra-violet), Fourier Transform infra-red, nuclear magnetic resonance, extraction, pyrolysis techniques, chromatography and mass spectrometry.

Jan 1, 2013