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By Jae-Chun Lee, Sadia Ilyas

"The present study was carried out to develop an economically feasible and environmentally friendly technique to extract metals such as Al, Fe, Cu, Zn and Ni from electronic scrap by employing Penicillium chrysogenum strain KBS3. Studies were carried out in various leaching modes, including one-step leaching with combined growth and leaching phases (Mode 1), two-step leaching with alternative growth and leaching phases (Mode 2), spent medium leaching with separated growth and leaching phases (Mode 3), leaching with fresh growth medium without fungal culture (Mode 4), leaching with deionized water (Mode 5) and leaching with commercial organic acids (Mode 6). The main lixiviants produced in leaching Mode 1 were citric, tartaric, oxalic and gluconic acids in concentrations of 12, 2.5, 1.8 and 152 mM, whereas in leaching Mode 2, the concentrations were 15, 0.5, 1.0 and 1,162 mM, respectively. In leaching Mode 3, 63 mM citric acid, 23 mM tartaric acid and 29 mM oxalic acid was observed. At 5% pulp density, both leaching Modes 1 and 2 showed similar metal extraction yields from the electronic scrap at 35º C. Approximately 96% Al, 98% Zn, 48% Cu, 25% Fe, 66% Pb and 73% Ni were extracted in leaching Mode 1 in 14 days. In leaching Mode 3, 85% Al, 81% Zn, 97% Cu, 22% Fe, 50% Pb and 63% Ni were extracted in 14 days. The extraction yield of Cu was much lower in leaching Modes 1 and 2 (48- 50%) than in leaching Mode 3 (97%), as well as in leaching Mode 6 (98%) with organic acids, including citric, tartaric, oxalic and gluconic acids.IntroductionTechnical innovations in electrical and electronic equipment with new functionalities and designs stimulate consumer purchasing and lead a rapid increase in the production of waste materials. Terazono et al. (2006) have reviewed the data on electronic waste generation in different parts of the world. Studies by Bertram et al. (2002) have also affirmed that waste electrical and electronic components are the fastest growing waste category, which emphasizes the need for efficient recycling strategies. The recycling of electronic waste is an important subject, not only from the perspective of waste treatment, but also from the perspective of the recovery of valuable materials. However, the recycling of electronic scrap is still limited, due to the heterogeneity of the materials present in the products (Veit et al., 2005).Bioleaching-based processes offer a number of advantages over conventional pyro or hydrometallurgical methods (Lee et al. 2007; Lee and Pandey, 2012). These advantages include simple, inexpensive (in some cases) and ecofriendly approaches and the generation of less active leach residue relative to other metallurgical processes. Although biohydrometallurgical processes have been successfully applied to the leaching of metals from ores (Olson et al., 2003; Rawlings, 2002), data pertaining to the application of these processes for the extraction of electronic scrap are still scarce. Recently, a few studies have been undertaken for the extraction of metals from electronic scrap/ printed circuit boards (Brandl et al., 2001; Faramarzi et al., 2004; Ilyas et al., 2007; Ilyas et al., 2010). These studies were conducted with mesophilic chemolithotrophic bacteria (Acidithiobacillus ferooxidans and Acidithiobacillus thiooxidans), cyanogenic bacteria (Chromobacterium violaceum) or moderate thermophilic bacteria (Sulfobacillus thermosulfidooxidans). However, compared to bacterial leaching, fungal leaching has several advantages, including (i) the ability to grow at a higher pH, thus making it more suitable for the bioleaching of alkaline solid waste; (ii) a generally faster leaching process with a shorter lag phase and (iii) the chelation of excreted metabolites (e.g., organic acids) with metal ions, thus reducing toxicity to the biomass (Burgstaller and Schinner, 1993; Aung and Ting, 2005)."

Jan 1, 2015

By Tassos Grammatikopoulos, Vladimiros Papangelakis, Douglass Duffy, Cheryl Washer, Srinath Garg

Flotation operations in Sudbury, Ontario, seeking to separate pentlandite and chalcopyrite from mixed sulphide deposits, produce pyrrhotite tailings that have been disposed of in tailings ponds for over 50 years. These reactive tailings are viewed as waste, despite containing ~0.8 wt% Ni, and represent an environmental liability because of their acid mine drainage (AMD) potential. Given the large quantities of pyrrhotite currently stored in Sudbury, and declining ore grades elsewhere, these tailings have shifted from being viewed as a waste to a potential resource. Recent advances in the bioleaching of low-grade sulphide ores have raised the prospect of bioleaching as a potential low-cost processing option. However optimization of this proposed process requires a thorough understanding of the mineralogy of the pyrrhotite tailings that would be leached. The work presented here addresses the characterization of two distinct Sudbury pyrrhotite tailings, namely from the Vale and Glencore operations, using electron microprobe, XRD and QEMSCAN analysis. Particular focus is given to how the mineralogy may affect bioleaching as a processing option, through the deportment of nickel and the various phases present

Jan 1, 2015

By Y. I. Yang, Y. -B. Tang, D. -J. Ma

Chlorine-containing minerals are commonly present in coal. Associated minerals such as pyrite can undergo exothermic reactions. Consequently, it is of great significance to study the effect of inorganic chloride on the spontaneous combustion of coal. In this study, the effects of five inorganic chlorides (sodium chloride, magnesium chloride, potassium chloride, calcium chloride, and zinc chloride) on the spontaneous oxidation of coal were investigated. Analysis of the gaseous products of coal oxidization at low temperatures (323K to 453K) showed that the presence of inorganic chlorine in coal markedly decreases O2 consumption and the generation of CO and CO2. Samples of raw coal and chlorine-loaded coal were oxidized for 36 hours under the same experimental conditions. Infrared diffuse reflectance spectroscopy results showed that inorganic chloride can inhibit the oxidative decomposition of some functional structure components (methyl, methylene, methine, and hydroxy) in the coal. The influence of inorganic chloride on the oxidation characteristics of the functional groups in coal during spontaneous combustion was investigated using benzyl alcohol and 1-phenylpropanol as model compounds, which were tested under the same experimental conditions as the coal samples. The oxygen consumption of model compounds with and without the addition of inorganic chloride further suggested that inorganic chloride may hinder the oxygenolysis of these structures during low-temperature oxidation. This phenomenon can be attributed to the radical reaction from the perspective of radical chemistry. It can therefore be concluded that inorganic chlorides play an inhibitory role in the spontaneous combustion of coal.

Jan 1, 2015

By C. C. Li

Traditionally, strong and stiff devices, such as fully encapsulated rebar bolts and concrete lining and arches, are preferred for underground rock support. The attention is paid to the strength of the devices in such support designs. It has been observed in engineering practice that support systems composed of stiff devices are often subjected to premature failure in high stress rock conditions. In the past decade, yield support devices have been employed to improve the performance of rock support systems. A rock support system usually consists of both internal and external devices that are installed within the rock mass and on the free surface of the rock, respectively. Great efforts have been made to make support devices yieldable in the past years, but the efforts are focused on different aspects in the tunneling and mining branches. In the tunneling branch, the focus has been put on the development of external yield devices, such as Lining Stress Controller (LSC), Honeycomb element and compressible concrete, which are embedded in shotcrete liners, while in the mining industry the efforts has been on the development of yield rockbolts, such as the cone bolt and the D-Bolt. The internal and external support devices are not compatible in their deformation capacities in the current rock support systems even though yield devices have been employed. All the devices in a support system should be deformable and compatible in deformation capacity. With such a support system, premature failure of individual support devices could be avoided and the service life of the support system is prolonged. It is a trend at present to take into account the energy absorption capacity, instead of simply the strength, of support devices in rock support design.

Jan 1, 2015

By Ali S. Fayad

"In June 2014, Orange County Flood Control District (OCFCD) completed construction improvements of the East Garden Grove-Wintersburg Channel for a price of $42 million. Instead of the pre-existing traditional trapezoidal levee, the channel was improved with a vertical compact levee. Dubbed Soil-Mix-Sandwich (SMS), this geo-structural and environmental solution for coastal channel improvements, underlain by liquefiable soil strata, was both a design and construction innovation. It employed Deep Soil Cement Mixing (DSCM) within the confines of a hydraulically-pressed (Giken Method) sheet pile duo. SMS was unique because it incorporated both subterranean and supra-dredge-line soil mixing within a very narrow workspace. Its DSCM pattern aimed at optimum densification of the workspace and was confirmed during the construction process. It availed the DSCM sub-contractor (Hayward Baker Inc.) the opportunity to demonstrate the fitness of their huge wet-mixing machinery within a very confined access-area and introduced approximately 70,000 cubic yards of DSCM within a limited 15 foot workspace width that stretched for a mile. The sheet pile duo created a construction-enclosure that became a stay-in-place load resisting system. PROJECT CHRONOLOGY AND LOCATIONAn Orange County Flood Control District (OCFCD) project-report was commissioned to study the East Garden Grove Wintersburg channel (OCFCD facility # C05). The report examined the hydraulic conveyance of the C05 channel and was concluded in 1994 by Williamson & Schmidt. The project-report did not encompass extensive geologic studies; but it provided several alternatives for channel improvement. It recommended a single row of sheet piles as the preferred alternative for the downstream reach.The most downstream reach of the C05 channel is located in an environmentally sensitive area, in City of Huntington Beach, California, USA. Its site includes seismic chasms that surface within the C05-footprint (the Newport- Inglewood tectonic fault). Extensive deposits of liquefiable soil exist beneath the channel. Furthermore, tidal-influence prevails against the channel levee. Implementation of a successful design for channel improvement emerged after several traditional concepts were deemed unacceptable by geotechnical consultants. OC Public Works (on behalf of OCFCD) was in need of a design and construction technique that mitigated many associated risks. From these circumstances, Soil-Mix-Sandwich was born and was referred to in the rest of this discussion as SMS. OC Public Works required the SMS design concept to undergo verification by independent geotechnical consultants. SMS chronology from conception to construction can be summarized as follows:"

Jan 1, 2015

By C. Grisanti, E. Prina Howald

The major of Swiss territory is occupied by mountains. Natural events as floods, debris flows, landslides, rockfalls, and avalanches regularly threaten the safety of people and properties. On the one hand, extreme weather events cause great damages, on the other hand, the enhancement of territory’s exploitation increases the risk. The Swiss Government makes many efforts to deal with the prevention of natural hazards, especially through measures of land management. As stated by federal law, Swiss cantons are obliged to establish hazard maps and to take the risk into account in the land management. Hazard maps are based on the hazard matrix, whose abscissa and ordinate are probability and intensity of the event on site. This project focuses on rockfalls. It consists of three main parts: the creation of a database to collect data on site, the creation of a catalog with all type of measures, and the development of a methodology for the analysis of the effectiveness of protective measures. The creation of the database allows us to collect information: about the site, about protective structures implemented on it, and about failures. With many multiple choice fields and few free text fields, it can collect data in a homogeneous way, without redundancy. The catalog has to be a tool that gives a basis to make decisions. It collects information about all types of protective measures implemented on Canton Vaud’s territory or available on the Swiss market. Free text fields allow for data storage of specifics, to give a complete view of structure’s characteristics and potentials. Methodology consists of four steps. The core of the procedure is the structure’s evaluation following a score system; it allows for calculation of reduction factors that have to be applied to intensity and probability parameters of the structure. Then it is necessary to convert the reduced structure’s intensity value into a residual site’s intensity value. Although the first step enables us to choose suitable measure for a specific site, it is not necessary to perform it. Second step allows us to evaluate structures under scenario 0, where structures are in best conditions. Third step allows us to evaluate structures under six scenarios of possible failings. Fourth step allows us to convert structure’s reduced intensity into event’s residual intensity and to establish the new point on hazard matrix. While the procedure has already been defined, details of score system and conversion have to be developed during the second phase of the project.

Jan 1, 2015

By Nan Zhou, Jixiong Zhang, Qiang Zhang

"Mining activities under hard roof could easily induce rock burst. Based on the geological conditions of widespread hard roof in China, this paper discusses the type, mechanism of occurrence and prevention of rock burst caused by hard roof from energy evolution point of view. It analyzed the interaction between the solid backfilled body and roof under different backfilling ratios. And by establishing and applying the mechanical model, the deformation of hard roof and energy evolution of the panel under different backfilling ratios were determined, revealing the control effect of solid backfilling on disaster-causing energy. As a result, an innovative method using the solid backfilling method was proposed as a solution to the hard-roof-induced rock burst hazards. Moreover, mine trial was conducted in Panel 6304-1 of Jisan Mine. The result shows that the stress concentration factor of the front abutment stress was only 1.44; the coal dusts in drill holes didn’t exceed the limits and microseism of large energy didn’t occur during mining mining, indicating that solid backfilling mining could be applied as an effective method for preventing rock burst caused by hard roof.INTRODUCTIONSHard roof refers to the thick strata above the coal seam or thin immediate roof. It is strong with poor joint development. After mining, instead of immediate caving, it will overhang for a large area in the gob, resulting in high stress in front of the face and difficulty in gas dispersion. As a result, the face spalls, the roof exposes and the gas accumulates in the gob. With the continuing advance of the face and increase in area of overhang, the stress in the hard roof will eventually exceed its ultimate strength and cause a large area of caving, followed by quick release of energy concentrated in the roof and coal seam, which may cause rock bursts and other dynamic disasters in the mine as well as serious equipment damage and casualties. Therefore, the hard roof becomes one of the main factors causing rock bursts at the face.Hard roofs in China varies in conditions. It ranges from dozens of meters to hundreds of meters in thickness. However, coal reserve under hard roofs accounts for about 1/3 of the total reserve; moreover, nearly 40% of the fully-mechanized coal mining panels are those with hard roofs and more than 50% of the mining areas are associated with problems of hard roofs. Aiming at this problem, researchers at home and abroad have proposed many solutions, e.g. coal pillar support, strength weakening and forced caving, to prevent rock bursts caused by hard roof. These solutions have been employed in some cases with good results. However, due to the variability in geological conditions of mining and hard roofs, the application of the above solutions is limited."

Jan 1, 2015

By M. S. Celik, H. Du, J. D. Miller, F. Cheng, O. Ozdemir

"In this paper, recent progress with respect to the flotation chemistry of soluble salt minerals is reviewed, and some of the more relevant issues including the hydration states of ions, the interfacial phenomena of salt surfaces and the flotation behavior of selected soluble salts are discussed. Due to the high solubility, the flotation of most soluble salts has to be carried out in their saturated brines. Anecdotal evidence has suggested that the hydration states of the ions have significant influence on the physicochemical properties of the solutions, the surface charge and wetting characteristics of the minerals, the collector adsorption states and, further, the flotation behavior of the soluble salts. In this regard, reviewing past research findings, efforts are made to establish a correlation between the ion hydration states with the flotation behavior of the soluble salts. Further, advances in understanding the significance of colloid adsorption involved in the soluble salt flotation process are addressed, and future research efforts to understand the soluble salt flotation chemistry are suggested.IntroductionSoluble salt minerals are essential raw materials for the production of a variety of commodities, fertilizers, potassium hydroxide, soda ash, magnesium compounds and other chemicals. These soluble mineral resources can be processed using flotation technology and, currently, more than 80% percent of the world’s potash is produced by the selective flotation of KCl crystals (sylvite) from other salt crystals, predominately NaCl (halite) and other more complex salts (Searls, 1990). Despite the successful application of flotation technology in the potash industry, the mechanisms for collector adsorption on soluble salts have not yet been fully understood and, therefore, have been of considerable interest to flotation researchers for many decades."

Jan 1, 2015

By Roberto A. Lopez, Eric Lindquist, Jon Bussiere, Dean Iwasa

"The new 11-story U.S. Federal Courthouse building in downtown Los Angeles demanded a cost effective foundation system capable of attaining a strict total settlement criterion of 0.5 inches (12 mm) under high applied loads. A design-build ground improvement system consisting of 3 ft (0.9 m) and 7 ft (2.1 m) diameter deep soil mix (DSM) columns embedded into the relatively soft Fernando Formation bedrock was selected for the project. The DSM columns support applied stresses of up to 8,800 psf from four large concrete core elements that transfer concentrated building loads to a 3 to 6 ft (0.9 to 1.8 m) thick reinforced concrete mat. The soil mixing ground improvement solution provided flexibility by allowing installation of the DSM columns around existing belled caissons left in place from prior structures, and by allowing repositioning of some of the DSM columns to avoid other existing obstructions in the fill. DSM spoils were used to construct a 2 ft (0.6 m) thick load transfer platform on top of the DSM columns. Quality control measures included utilizing equipment outfitted with automated data acquisition systems, performing three full scale load tests, performing daily wet-mix sampling and compression testing, performing full-depth coring and unconfined compression testing on core samples, and using a borehole acoustic televiewer to evaluate the uniformity of the DSM columns where core recovery was problematic. The results of subsurface investigation and the load tests were used to develop 3-dimensional finite differences models for evaluating stress distribution and deformation of the foundation system.INTRODUCTIONThe new U.S. Federal Courthouse building is currently under construction in downtown Los Angeles, California. The new courthouse will be 11 stories tall with one partial below-grade B1 basement level. The building will have four structural core elements that extend from the main building foundation at the B1 level to the top of the structure. The majority of the building loads will be transferred through the structural core elements to a new 3 to 6 ft (0.9 to 1.8 m) thick reinforced concrete mat beneath the central portion of the structure. The foundation pressures beneath each of the core element locations will be approximately 6,200 to 8,800 psf (300 to 420 kPa) with lower foundation pressures at locations farther away from the central core area."

Jan 1, 2015

By S. S. Yuan, Q. Z. Zhu, J. F. Shao

"This paper aims at enriching a homogenization-based anisotropic damage model for hard rocks under complex loading. A new damage criterion is proposed to capture material strain softening. Within the framework of irreversible thermodynamics, we are particularly concerned with two strongly coupled dissipative mechanisms: frictional sliding and damage by microcracking, which usually take place at cracks within cohesive geomaterials under compression. Focusing on the representative elementary volume containing multiple crack families, the free enthalpy of the matrix-cracks system is obtained. Importantly, a back-stress term is involved in the local stress applied to microcracks. This back stress plays the hardening/softening role in the friction criterion which is formulated at local scale. Strain hardening owns to the accumulation of frictional shearing and dilatancy while strain softening is caused by crack growth. The multiscale damage model is used to simulate laboratory tests on the Westerly granite under true triaxial compressions. INTRODUCTIONWhen subjected to compressive loads, hard rocks present nonlinear mechanical behaviors and induced material anisotropies. In that process, two main dissipative mechanisms have been largely identified: damage by crack growth and frictional sliding along closed crack faces, which are usually strongly coupled to each other on crack scale. Theoretical investigations have shown that the damagefriction coupling analyses allow explaining a large number of experimental phenomena involved in brittle or quasi-brittle materials. Concerning constitutive modeling, the standard Eshelby’s solution-based homogenization procedure for heterogeneous materials was recently applied successfully to describing the mechanical and poromechanical behaviors of cracked frictional solids."

Jan 1, 2015

By C. Musingwini, M. Mohutsiwa

"SynopsisCapital cost estimates are important in decisions on whether a project will be approved, mothballed, or abandoned. In South Africa, junior coal miners do not have extensive databases of historical projects from which to estimate capital costs. The purpose of this paper is to establish formulae that can be used for estimating capital costs of developing coal mines in a coal-producing country, using South Africa as a case study. The costs are estimated to an error of magnitude level of -30% to +50%, which is suitable for a concept study level, using a parametric estimation technique. The study uses data from completed coal mining projects from selected coal-producing countries. Three formulae are developed and presented for estimating capital costs of underground bord and pillar, surface shovel and truck, and dragline operations.IntroductionCapital cost estimates play a critical role in deciding whether projects will proceed, be delayed, or abandoned. It is therefore important that capital cost estimates are carried out accurately as determined by the estimation guidelines based on the level of estimation conducted (Shafiee and Topal, 2012). The lack of literature on estimation of capital costs in many coal mining countries is adversely affecting junior coal miners, since they do not have an extensive database of historical projects on which to base estimations. In South Africa, the difficulty in estimating capital costs is attributable to lack of publicly available data on completed South African mining projects (Hall, 2013)."

Jan 1, 2015

By S. Huang, K. Xia

"During crushing, rock particle is subjected to complicated loading and the particle shape influences the fragmentation outcome. Thus, a highly controlled laboratory test is desired to establish the relation between the loading and the fragmentation parameters for better understanding the rock crushing mechanism. In this work, a split Hopkinson pressure bar system in combination with high speed cameras is utilized to carry out a dynamic ball compression test, in which the spherical rock sample is adopted to avoid the shape effect. Using the elasticity theory, the history of the axial symmetric tensile stress perpendicular to the diametrical direction along the loading axis is determined, from which the loading rate and the dynamic indirect tensile strength are calculated. With the aid of the moment-trap technique, the total energy absorbed by samples is accurately determined from the one-dimensional wave analysis. Furthermore by considering the kinetic energy of the sample fragments using the high speed camera snapshots, the surface energy is determined for each sample. The relations between the loading rate and the fragmentation parameters, i.e., the number of fragments and the surface energy are established. The application of this method to a granitic rock shows that it is flexible and can be applied to the crushing study of generic brittle solids. INTRODUCTIONCrushers are widely used to break rocks to extract specific minerals in the mining industry, and to obtain rock fragments with desired size distribution in construction industry. During crushing, the breakage of particles can be in either the single-layer mode or the multi-layer mode. In the single-layer mode, the particle breakage can be assumed to be isolated, in which the interaction between particles can be ignored. It is thus suggested by many researchers that highly controlled single particle test should be performed to establish the relation between the input mechanical energy and size reduction for better understanding the crushing mechanism (Yashima et al., 1987; Tavares, 2007; Pitchumani et al., 2004)."

Jan 1, 2015

By K. V. Raj, T. Bhowmick

"Control of fugitive dust in high latitude open-pit mines is challenging due to unique atmospheric phenomenon resulting in complicated flow regimes, and atmospheric inversion due to lack of adequate solar insolation during prolonged winter seasons. In this study, two idealized (One conical and one trapezoidal) three-dimensional open-pit mine geometries are simulated for differing seasonal conditions using the CRADLE-CFD package. The airflow is modeled using Standard Kappa-Epsilon Turbulence Model solved by RANS equations. The concept of particle tracking is used to predict the flow pattern of dust particles. For various climatic conditions, and two different pit geometries, fugitive dust particles varying in size (PM0.1 to PM10) and concentration are generated at various locations of a mine and dispersed by the airflow pattern inside the open-pit mine. The amount and location of dust particles inside the pit is reported at various time intervals. The development of atmospheric inversion during the winter season significantly affected the amount of dust retention inside the open-pit domain. While during the summer, airborne dust particles were transported outside the open-pit domain in a short time. INTRODUCTIONComputational fluid dynamics (CFD) modeling of open-pit mines is challenging. In a recent paper, Bhowmick et. al. [1] presented different constraints and challenges in developing a 3-Dimensional CFD model. In order to obtain realistic results from a simulation, however, appropriate values of various inputs are required. Simulation results of a 3D non-hydrostatic model by Shi et al. [2] showed that both the mechanical and thermal forcing are important mechanisms, controlling the development of the atmosphere inside an open-pit. Alvarez et al [3] used a CFD model for predicting dust dispersions in a medium sized limestone quarry, and presented several iso-surfaces of varying dust concentrations using ANSYS CFX. A similar study by Torno et al [4] introduced a more sophisticated parameterization of the dust sources. Flores et al. [5] used an OpenFOAM CFD simulation package to simulate and predict pollutant dispersion in an idealized and an actual open-pit mine in Chile with an intense insolation condition. The model was simulated for three different conditions: (i) air advection (10 m/s) driven mechanical turbulence; (ii) surface heat flux (240 W/m2) driven thermal buoyancy; and (iii) both air advection and surface heat flux driven conditions. The results of the simulations showed that the buoyant currents contribute to the removal of a large percentage of the dust particles. The buoyant currents modify the purely mechanical-turbulence induced flow pattern and reduce the particle residence time, commonly observed in a purely mechanical turbulent flow (non-buoyant case)"

Jan 1, 2015

By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015

By Jochen Petersen, Thandazile Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques. The anodic dissolution process has been established to be a seven-electron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions. The number of electrons transferred in the carbonate and sulphate salts suggests that the sulphur is oxidised to a thiosulphate intermediate and the copper and iron released as Cu+ and Fe2+. The Cu+ and Fe2+ is subsequently oxidised in solution in non-Faradaic reactions. The deportment of Fe2+ and S2O32- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, however observations made on the mineral surface after leaching do not support the formation of elemental sulphur. Scanning electron microscopy and energy-dispersive spectroscopy analysis of the mineral surface suggest presence of an iron–sulphur surface layer completely free of copper under the ammonia–ammonium sulphate conditions, an iron-rich surface layer under ammonia–ammonium perchlorate solutions and absence of surface layer build up under ammonia–ammonium carbonate solutions. INTRODUCTION Hydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different approaches to hydrometallurgical treatment of chalcopyrite can be carried out. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base-metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilisation of copper(I) and copper (II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation 1 (Beckstead & Miller, 1977a):"

Jan 1, 2015

By V. G. Papangelakis, G. A. Moldoveanu

The use of anhydrite (AH) seed, control of acidity levels and ageing were assessed as means to promote the conversion of freshly produced metastable gypsum generated in-situ to the less soluble anhydrite phase and force deposition of calcium sulphate on seed as opposed to on equipment as scale, while achieving lower terminal aqueous calcium concentration as well. It was found that moderate sulphuric acid levels (0.25M) and ageing in the presence of AH seed accelerated the gypsum-AH conversion, achieving 100% transformation of the metastable gypsum generated in situ to the more stable, less soluble AH in 6-7 days, while lower/nil acidity did not promote more than 30% AH conversion for 10 days, even in the presence of AH seed. These findings indicate that anhydrite seeding, ageing and incomplete neutralization are beneficial for scale control as well as achieving lower calcium levels, thus rendering the resulting solution more amenable for recycling.

Jan 1, 2015

By L. A. Nazarova, M. Vandamme, L. A. Nazarov, R. I. Rodin

"The paper describes a new method of interpreting the “canister test” data for the quantitative estimation of gas-kinetic parameters of coal bed based on the developed model of gas emission from coal sample placed in a sealed container. The model accounts for grain-size composition of the sample, initial gas content S, as well as coefficients of diffusion D and mass transfer ?. The inverse coefficient problem is formulated to find S, D and ??from the data of pressure measurements in the sealed container. It is shown that the inverse problem is uniquely solvable if the pressure is dropped during the experiment. The method has been tested using the data from an underground coal mine in the Kuznetsk Basin.Based on the poroelastic model of a coal bed and Khristianovich’s concept about origination and evolution of the filtration zone F in the neighborhood of a degassing borehole the authors considered the corresponding direct problem on rock mass geomechanical state. It was offered interpretation method for data on pressure measurements in a plugged degassing borehole allows evaluation of the diffusion coefficient, the horizontal component of natural stress field and parameters of F. The related inverse problem of the mixed type is formulated, and the cost function is constructed. The analysis using synthetic input data has shown that the cost function has a number of local minimums arranged on the same straight line, one of the minimums being the inverse problem solution. INTRODUCTIONPre-mine degassing is an integral part of coal mining. It allows mitigation of induced accidents in mines (coal and gas outbursts, rock bursts) (Guide, 1990; Malyshev & Airuni, 1999; Seidle, 2011) and also furnishes an alternative and ecology-friendly energy source—methane (Rice, 1997; Nambo, 2001). Choosing an optimized pattern of degassing boreholes, as well as estimating degassing time and amount of gas recovered requires data on gas-kinetics indices of coal beds out of which the key parameter is a gas content S. According to the latest guidelines for coal mines in Russia (Ruban et al, 2012), mining is allowed if S in a coal bed section is under 7 kg/m3."

Jan 1, 2015

By Daiki Takano, Naoki Takahashi, Hidenori Takahashi, Ikuo Towhata, Yoshiyuki Morikawa

"The method in this study, in which cement-treated piles are installed into the ground to decrease the amount of liquefied lateral flow, has been studied. The authors are also investigating the most effective arrangement of piles to optimize cost-effectiveness. In their investigation, they propose shifting the position of the piles to prevent lateral flow in various directions. The present study conducted centrifuge model tests to clarify the improvement effect of piles against the lateral flow of liquefied soil and the effect of the pile arrangement. Then, numerical fluid analyses were conducted to consider the improvement mechanism. As a result, the model tests and numerical analyses showed that the pile improvement dramatically reduced the lateral displacement and that the average total flow velocity decreased in the irregular case.INTRODUCTIONLiquefied ground subjected to seismic motion loses its stiffness and strength, and lateral flow often occurs in sloping areas and backfill areas behind collapsed quay walls. In the Hyogoken–Nanbu Earthquake in 1995, the reclaimed island that was surrounded by collapsed quay walls expanded toward the sea and the amount of displacement reached a few metres (Hamada et al., 1996). Two countermeasures can be considered to guard against lateral flow: preventing liquefaction and reducing lateral displacement. The former method is ideal; however it is costly and time-consuming. Based on these considerations, the authors (Takahashi et al., 2013; Morikawa et al., 2014) are currently studying a method in which cement-treated piles are installed into the ground (see Fig. 1) to decrease the amount of liquefied lateral flow. The countermeasure cost using this method is relatively low because of the low replacement ratio. The authors are also investigating the most effective arrangement of piles to optimize cost-effectiveness. It has been proposed that the position of the piles should be shifted so that lateral flow can be prevented in various directions, as described in Fig. 2."

Jan 1, 2015

By N. Saeidi

"For a mine section comprising 100 different stoping activities, there are ~10158 different possible stoping sequences to explore in the mine schedule optimization search and this figure is indicative of the challenge posed in maximising profitability through mine schedule optimization. Any viable excavation timetable must satisfy all conditions that will constrain feasible sequences. In general, consideration of additional constraint will tend to reduce profitability. Geomechanical constraints on mine schedules, introduced with the aim of avoiding excavation instabilities, can be established for underground mine schedule optimization processes but, currently, this is done only rather crudely; precedence relations between excavation activities (stoping or development) are encoded to produce particular stope sequence patterns (e.g. ‘chevron’ or pyramidal sequences).The work reported aimed to investigate automated processes for formulation of such geomechanical constraints. The timetable optimization approach to the problem precipitated a fresh look at time dependent, and excavation sequence dependent, deformation. Abundant evidence emerged that supported the notion that any methodology developed that failed to account for such time and sequence dependencies was itself bound to failure. Yet, it was also recognised that any deviation at all from an assumption of linear elasticity for geomechanical numerical modeling, adopted to inform geomechanical constraint formulation, would rapidly lead to impractical levels of computational effort.Thus the approach presented here represents a compromise: the elastic stress fields induced by individual mining activities are computed for each activity, independently considered within a computational domain identical to that of all other activities. These are stored in a database. Instability risk for a specific sequence of mine activities can be assessed through superimposition of stress fields drawn from the pre-computed database. Time stamps allocated to events corresponding to the excavation processes permit the conversion of the sequence of elastic stress fields into a time table of stress fields. For specific locations within the computational domain, the aggregate effect of the sequence of mine activities leads to stress-time histories having a castellated appearance, a result of the near instantaneous response of an elastic medium to the excavation perturbations. Time dependent deformation responses are crudely allowed for through the re-profiling these castellated histories through graphical construction of curved responses, where the curve gradients are related to a viscous parameter. Such curves form the basis for a geomechanical constraint formulation to be adopted for mine schedule optimization."

Jan 1, 2015

By Baisheng Nie, Longlong Yang, Tao Yang, Wenjie Jia

"Gas adsorption in coal is an exothermic and physical process. Temperature might change during the dynamical process. In order to get the temperature variation of gas adsorption process, the experiment system which can test the temperature variation and analyze the thermal effect was established. Gas adsorption experiments under different conditions were done by using the test system. The results show that temperature increases during the adsorption process. It is an exothermic reaction process. Also, the temperature variation and the variation gradient increase with the increasing of equilibrium pressure. The temperature variation value is smaller if the experiment temperature is higher. The paper will provide basic experimental data for explaining gas adsorption mechanism better.INTRODUCTIONChina is the largest coal producer in the world while it also has the most serious coal mine disasters. According to the statistics, there are nearly a thousand coal mines in China including more than 110 the key state-owned mines risking to happen coal and gas outburst. Hundreds of coal and gas outburst occur each year which often causes serious casualties and economic losses (State Administration of Work Safety, 2007). With the continuing exploitation of the coal resources, the depth of the Chinese coal mines increases about 100 meters every year which causes the situation of gas accident becoming more and more serious (Xie et al., 2006).At present, the real mechanism of gas adsorption, desorption and the diffusion process in coal and the influence factor of it are not so clear. And because of the limit of prediction method and the technological level caused gas accident prevention theory and technology not so valid."

Jan 1, 2015