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By R. T. Jones

"SynopsisScientific progress relies on the publication of ideas and experimental results that can be replicated, tested, and improved over time. The first printed book on metallurgy to have been published in Europe is considered to be De la Pirotechnia, written in Italian by Vannoccio Biringuccio, and published in Venice in 1540. Together with De Re Metallica, written by Georgius Agricola and published in Latin in 1556, this can be considered to mark the start of scientific and technical literature in this field. Scientific publishing of journal papers has been in existence for 350 years, since the world's oldest and longest-running scientific journal, the Philosophical Transactions of the Royal Society, was first published in London in 1665.The nature of scientific societies has changed significantly since the early days when regular meetings were held to discuss science and conduct experiments, and the reading of scientific papers took place, and publication of papers was undertaken to record the proceedings of meetings, often including rather robust debate. In today’s world, there is a plethora of publications, and it is close to impossible for anyone to keep up with the vast flow of information. International conferences with hundreds of presentations have taken the place of the local meetings that used to discuss a single paper or experiment. In this frenetic environment, it is essential that researchers are able to trust the material they read.The system of peer review is used to maintain standards and to improve the quality of papers. This vital system is, however, significantly flawed. There is little incentive for reviewers to invest sufficient time in picking up all errors in publications, and any ineptitude on their part is usually protected by anonymity. It has reached the point where some reviewers have mistakenly permitted the publication of hoax papers deliberately presented with a complicated scientific facade. In light of such astounding inadequacies, perhaps a more open review process would be an improvement. Electronic publishing allows errata to be linked to the original papers.There is an increasing trend towards open access for papers in scientific journals and conference proceedings, which helps to reach as wide an audience as possible. This also supports the statement in the Universal Declaration of Human Rights, which says ‘everyone has the right freely to … share in scientific advancement and its benefits’."

Jan 1, 2015

By T. Bartnitzki, N. Fietz

"INTRODUCTION For a long time now automation has been state of the art in production engineering and chemical engineering. The advantages of automation are, for instance, higher reliabilities of production processes, higher product qualities as well as capacities and improved safety conditions for the personnel. In contrast, many operations in mining are still conducted manually by machine operators instead of autonomous control units. One example for this is the excavation of underground hard coal which is still executed with aid of human perception. The Institute for Mining and Metallurgical Machinery (IMR) has been working on possibilities for sensor-based automation of mining machinery for many years now. Thereto the focus is set on the implementation of common material analysis techniques into ruggedized conditions as a basis for automation. Laser-induced breakdown spectroscopy (LIBS) for instance is an atom emission technique which enables the determination of the elemental composition of a sample. After introducing LIBS this paper will give an overview on dust formation during the cutting process. With the illustration of a few examples the challenges in determining dust concentrations specifically such of cutting processes are explained in further detail. The final chapter will outlay the possibilities and challenges in utilizing cutting-induced dust for the automation of shearer loaders. LASER-INDUCED BREAKDOWN SPECTROSCOPY LIBS Fundamentals LIBS (laser-induced breakdown spectroscopy) is a contact-free method for analyzing materials in any state of aggregate. It pertains the atom emission techniques and is based on the generation of plasma, inducing avalanche ionization on the surface of a solid material or any spot in a gas or aqueous solution. With sufficient background information on the expected elements and an additional calibration, this method can determine all present elements not only qualitatively but also quantitatively. However, this method cannot be utilized for determining the molecular composition of materials – if this feature is required a complementary method such as Raman analysis needs to be added. (1, 2)"

Jan 1, 2015

By Ahmad Ghahremaninezhad, Denver H. Cowan

Much of today’s gold is locked within sulphide minerals. These sulphide minerals, including pyrite, need to be subjected to oxidative pre-treatment in order to leach the refractory-gold using traditional methods. Typically autoclaves employing high temperatures between 180?225 ºC, and extremely high pressures between 1,500?3,200 kPa, are used for the oxidative pre-treatment. However, the autoclaves themselves are very expensive, costly to operate and maintain, and produce excess sulphuric acid. This paper studies the atmospheric oxidation of pyrite in ferric sulphate solutions. In general, pyrite oxidation under atmospheric pressure can result in high elemental sulphur production, i.e. less acid generation. Activated carbon has displayed an ability to catalyze the process, achieving reasonable kinetics. The reaction kinetics were investigated by altering acidity of the leaching solution, temperature, catalyst ratio, sparged oxygen and agitation. A combination of X-ray diffraction, scanning electron microscopy, optical microscopy, X-ray fluorescence, inductively coupled plasma mass spectrometry (ICP-MS), and atomic absorption spectroscopy (AAS) were used to monitor the kinetics of the process and elemental sulphur yield. The purpose of this investigation was to determine optimal operating conditions that maximized kinetics of the atmospheric oxidation while maximizing elemental sulphur yield.

Jan 1, 2015

By S. Fahland, P. Vogel

"The Gorleben salt dome has been investigated since 1979 for its suitability as a repository for the disposal of high-level radioactive wastes. The geoscientific surface exploration was followed by underground exploration of the site beginning in 1983: underground excavation work included the sinking of two shafts from 1986 to 1994, the excavation of the infrastructure area and of drifts located in the first exploration area EB1 within the following years. The exploration was interrupted for ten years from 2000 to 2010 as part of a moratorium. After the expiry of the moratorium in March 2010, the geoscientific underground exploration at the Gorleben site was resumed. The investigations were interrupted again in autumn 2012 due to a political decision. The exploration programme included extensive geoscientific investigations: geological exploration, geophysical investigations, mining exploration and mining observation, laboratory tests, in-situ geotechnical measurements, geological modelling and numerical model calculations. To analyse and interpret the results of the in-situ measurements and mining observation geomechanical, thermal and thermo-mechanical model calculations were carried out. One of the main elements of the in-situ geotechnical investigations were high-resolution geothermal measurements performed in boreholes used for geological exploration and geotechnical tests.The geothermal measurements are used to evaluate several geotechnical findings, e. g. drift closure, rock deformation, stress change, and are completed by thermal model calculations to analyse and interpret the results of in-situ measurements and mining observation. The model calculations have been carried out using the special purpose JIFE code. To consider the whole exploration mine with the adjoining host rock as well as the successive excavation of drifts and boreholes in detail a three-dimensional finite-element model was developed. The model calculations are used to analyse the cooling-off of the surrounding rock of the drifts caused by ventilation. The cooling-off of the surrounding rock is an ongoing process affecting the results of further geotechnical measurements in the near field of the drifts. To predict a realistic time and space dependent distribution of the temperature field of the host rock within the exploration area which is influenced by ventilation thermal model calculations are necessary. Comparing the calculated temperature field with the in-situ determined rock mass temperature field within the exploration area EB 1 the results show a sufficient agreement. Furthermore there is very good correspondence, both qualitatively and quantitatively, between the experimental and the calculated findings regarding the temperature profiles including the effects of excavation and ventilation of the drifts."

Jan 1, 2015

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

By Tsuda Wakaki, Naoki Takahashi, Natsuki Okuno, Hidenori Takahashi, Ikuo Towhata, Yoshiyuki Morikawa

"Deep mixing (DM) method has been increasingly employed as a countermeasure against subsoil liquefaction in recent years. Pile-type DM, however, is considered to have little effect as a liquefaction countermeasure, because the shear deformation of unimproved soil around the piles cannot be reduced. However, experimental results, which imply that shear deformation of unimproved soil around DM piles can be reduced, were reported. Furthermore, a new plane-arrangement of DM piles has been proposed to mitigate lateral flow induced by liquefaction. The DM piles in this arrangement confront the lateral flow in any direction, compared with the piles arranged in conventional pattern such as square and triangular arrangements. In this study, a series of dynamic centrifuge model tests was conducted to verify the lateral flow resistance of DM plies in the new arrangement. The results indicate that the DM plies can reduce the lateral flow of liquefied ground when the pile displacement and the pile head rotation are restricted. In addition, lateral load acting on DM pile from liquefied ground, which is required for design strength of the DM pile, was investigated.INTRODUCTIONDeep mixing (DM) method has been increasingly employed as a countermeasure against subsoil liquefaction in recent years. The solidified body formed by the deep mixing method is usually block or lattice shape, composed of solidified columns that overlap each other horizontally. Lattice-type solidification has been shown to be effective as a liquefaction countermeasure despite the presence of unimproved soil inside the lattice wall, because the shear deformation of the interior soil is restrained by the wall (Suzuki et al., 1989). On the other hand, it has been thought that pile-type DM cannot reduce shear deformation of unimproved soil around the piles, because the displacement of the pile is less restricted than that of the lattice wall. DM piles have been reported to have little effect as a liquefaction countermeasure, but to be superior in terms of construction cost and applicability around existing underground structures (Koga et al., 1986). However, there are experimental results implying that DM piles have reduced the shear deformation of unimproved soil and mitigated its liquefaction (Yasuda et al., 2003; Tanaka et al., 2003). Yamamoto et al. (2006) conducted dynamic analyses of ground improved with lattice- and pile-type DM. Their results showed that pile-type DM with an improvement ratio of more than 35% reduces excess pore water pressure generated by earthquakes. Furthermore, the new pile arrangement shown in Fig. 1(a) has been proposed to mitigate lateral flow induced by liquefaction. It was developed and has been verified using dynamic model testing in a 1 g field (Takahashi et al., 2010a; 2010b; 2013; Towhata et al., 2010, Morikawa et al., 2014). The DM piles in this configuration interrupt lateral flow in any direction, unlike those placed in square and triangular arrangements."

Jan 1, 2015

By L. P. Srivastava

Rock bolts have been used since long to enhance the shear strength response of jointed rocks in civil and mining engineering structures. However, the assessment of strength response of a rock mass reinforced with rock bolts remains an unresolved problem till date. In the present article, an attempt has been made to study, through physical model tests, the shear strength enhancement of a blocky mass due to provision of passive rock bolts. Direct shear tests were conducted on large specimens of size 750 mm x 750 mm x 900 mm of rock mass under a normal stress varying from 0 to 2.0 MPa. Concrete was used as a model material to simulate intact rock and, elemental blocks of size 150 mm x 150 mm x 150 mm were used to form the mass specimens. Steel bolts of 6 mm diameter with 2 mm thick grout were used to reinforce the mass. Three different configurations of bolts were adopted. Observations were made on shear stress, horizontal shear displacement, and dilation during the tests. Effect of normal stress and reinforcement on peak shear stress and shear stiffness was studied. It is observed that the rock bolts enhance the shear strength of the mass by preventing sliding along the shearing plane, and by inducing additional normal stress due to tension mobilized in the bolts. The rock mass, therefore, becomes stronger due to the high degree of interlocking produced by the bolts. Shear strength of the mass increases with increasing numbers of bolts. In the case of reinforced mass, the enhancement in shear strength due to provision of bolts decreases with an increase in normal stress. The provision of bolts improves the cohesion of joints substantially. The effect on friction angle is low. The shear strength enhancement depends on the area of the bolts, spacing of the joints, spacing between the bolts and the cohesion of the intact material. A correlation has been established using which the enhancement in shear strength due to the provision of bolts can be assessed.

Jan 1, 2015

By K. Purazrang, P. Musavi Garavi, P. Sh. Naseri, P. Abachi

The fracture behavior of high strength Al7050 alloy was investigated at room and elevated temperatures using small size, V-notched tear (called Kahn specimen) and compact tension, CT, specimens, respectively.To study the elastic-plastic behavior of the alloy, the tensile test was also performed on the sub-sized cylindrical tension test specimen. The microstructure of the alloy was examined using optical- and scanning electron- microscopy. The rupture mechanisms and crack path were also studied by examination of specimens' fracture surfaces using SEM. The microstructure examination revealed equiaxed grains and some elongated grains in rolling direction, with the areas of partial re-crystallized grains where coarse intermetallic particles are mostly found.In general, fracture surfaces were indicative of dimpled ductile type. Considering the fractographs of tensile specimens, the void growth mechanism is also dominant in fracture of these specimens. Nevertheless, in some regions, smooth areas can be observed due to the friction during rupture process. The results of mechanical tests at RT made the evaluation of tear strength to 0.2 % tensile yield strength ratio, as a measure of notch toughness, available. According to elevated temperature, 150°C, test results and plots of log da/dt vs. log KI , the crack propagation behavior over discrete ranges of crack growth rates could be assumed linear and then be obeyed as a power law equation in the form of da/dt = A (KI)n .

Jan 1, 2015

By B. Panton, J. Carvalho, E. T. Brown

"A major consideration in the design of high capacity tiedown anchors for dam, bridge and tower foundations is the tensile resistance of the rock mass to pullout, typically as a result of overturning moments or hydrostatic uplift. Rock mass pullout capacity for installed anchors is developed from the tensile strength and fracture propagation properties of intact rock, the orientation and physical properties of the discontinuities and anchor confinement at depth. The typically assumed, but generally conservative, design approach is to calculate anchor pullout capacity using the dead weight of a uniformly shaped inverted “cone” with an assumed initiation point and breakout angle. In some cases, some tensile or shear strength is considered across the area of the assumed pullout cone, however, these strength estimates are based primarily on based on limited historic testing data, empirical relationships for rock mass strength developed for other applications, and engineering judgement.As an alternative to the current foundation anchor design method, this paper presents a new approach to the rock cone pullout problem using Discrete Fracture Networks (DFN) combined with numerical simulations. The simulations presented in the paper investigate the influence of fractures in a synthetic rock mass on ultimate anchor strength. In addition, the global influence on fracture network statistics on rock mass pullout failure is also discussed and it is contended that some of the aleatory and epistemic uncertainty inherent in the design of rock anchors can be reduced by considering fracture statistics in anchor design."

Jan 1, 2015

By Nikzad Oraee, Parham Khajehpour, Kazam Oraee, Arash Goodarzi

"Rock fall related accidents continue to occur in coal mines, although artificial support mechanisms have been used extensively [1]. Roof stability is primarily determined in many underground mines by a limited number of methods that often resort to subjective criteria. It is argued in this paper that stability conditions of mine roof strata, as a key factor in coal mines, must be determined by a survey which proactively investigates fundamental aspects.Failure of rock around the opening happens as a result of both high rock stress conditions and the presence of structural discontinuities. The properties of such discontinuities affect the engineering behavior of rock masses causing wedges or blocks to fall from the roof or slide out of the walls [2]. A practical rule based approach to assess the risk of a roof fall is proposed in the paper. The method is based on the analysis of structural data and the geometry and stability of wedges in underground coal mines. In this regard, an accident causing a huge collapse in a coal mine leading to four fatalities is illustrated by way of a case study. A comprehensive investigation of the hanging wall has been gathered through a systematic collection of evidence. The investigation results are then analyzed, and an interpretation of the evidence gathered is provided.For this purpose, horizontal and vertical profiles are prepared by geophysical methods to define the falling zone and its boundaries. The collapse is then modeled by the use of sophisticated computer programs in order to identify the causes of the accident and hence recommend corrective actions to prevent or minimize reoccurrence probability of similar accidents. The corrective measures are placed into a rule-based framework for the benefit of the mine operators.INTRODUCTIONRoof rock failure has generally been the most dangerous hazard for underground coal mining in the world. Failure of rock around shallow coal mine openings often results from loosening of blocks of rock on the weakened planes under the influence of gravity. This condition is not typically seen in large deep coal mines. There are a number of differences between large mechanized mines and small mines related to ground control [3]."

Jan 1, 2015

By P. Munjal

"Usage of Supercritical CO2 in place of high pressure freshwater has proven to be a potential breakthrough in the technique of fracturing. Tapping of carbon footprints from feasible sources like industries can be used to manufacture Supercritical CO2 required for fracking. Supercritical CO2, being less viscous than water, creates complex and coherent micro-fractures which can connect many more natural fractures greatly, increasing maximally the fractures’ conductivity leading to an increment in production. The better clean-up property of Supercritical CO2 provides auxiliary benefits of immediate evaluation of fracture zones, usage of an optimized quantity of mesh proppant and elimination of the need of swabbing. Also, Coal has a stronger affinity for CO2 than for CH4. When CO2 is present, CH4 on coal is replaced by CO2. This also ensures rigorous recovery of gas from the coal beds. Use of Supercritical CO2 will obliterate many problems as the CO2 used for fracturing is either sequestered beneath the crust or is recovered at the surface and reused. Therefore, injecting CO2 into coalbeds achieves not only enhanced CBM recovery, but also greenhouse sequestration underground. INTRODUCTION Coalbed Methane At various times in the geologic past, earth had dense forests in low-lying wetland areas. Due to natural processes such as flooding, these forests were buried underneath the soil. As more and more soil deposited over them, these dead plant remains were compressed. As the process continued the plant matter was protected from biodegradation and oxidation, usually by mud or acidic water. Under high pressure and high temperature, dead vegetation was slowly converted to coal. The omnibus process of formation of coal, thus, comprises of conversion of dead plant matter into peat, followed by its conversion to lignite, then sub-bituminous coal, after that bituminous coal, and lastly anthracite. This process of enrichment of coal as it is progressively forced deeper into an ambience with higher temperature and pressure involves biological and geological processes that take place over a long period and is called coalification. During coalification, large amounts of methane-rich gas are generated and stored within the coal on internal surfaces; hence comes coalbed methane. Coalbed methane (CBM), a gas formed as part of the geological processes that are responsible for the generation of coal, is adsorbed into the solid matrix of the coal during its formation process. Coalbed methane is distinct from a typical sandstone or other conventional gas reservoirs, as the methane is adsorbed and not absorbed. The methane is in a near-liquid state, lining the inside of pores within the coal. The open fractures in the coal that result from the liberation of volatile materials (and subsequent contraction due to the liberation) from the coal due to the high temperature and pressure conditions encountered, called cleats, may also contain free gas or can be saturated with water."

Jan 1, 2015

By R. Gerritsen, Erwin de Jong, E. van der Velde, C. te Boekhorst

"In recent years the market for Mixed-In-Place soil mix techniques in the Netherlands has been growing rapidly. Initially the technique was used to create cut-off walls near river dikes and as a vibration free method to create retaining walls for building pits. Studies have been undertaken and projects are executed in order to strengthen the dike itself by the use of Mixed-In-Place techniques. In February 2012 Bauer Funderingstechniek started the construction of the first polder in the Netherlands with their approved Mixed-In-Place cut-off walls. This article explains the background of the use of this cost-effective and durable construction method and discusses how the challenging requirements from the client were fulfilled, both in design and execution. The quality assurance and quality control consisted of preliminary soil and mixture investigations, extensive measurements during construction and leakage detection through geophysical methods. The information is presented in 3 case histories, all subprojects of a large infrastructural project ‘Leeuwarden Vrij-Baan’ in the Netherlands.INTRODUCTIONThe Netherlands have a worldwide reputation in creating their own country by reclaiming land from the sea. Since the 15th century the Dutch have been creating “polders”, areas of reclaimed land below sea level, surrounded by dykes and with a mechanically maintained water level. In the 20th century the use of artificial polders became an interesting construction method for creating underpasses below motorways and canals using watertight geomembranes to create an impermeable layer that separated the polder from its surroundings. These kinds of structures have one big disadvantage, they need a lot of space. The main idea of such a structure is that the upward water pressure under the geomembrane has to be in balance with the remaining soil on top of it. For this reason, the geomembrane has to be placed at a depth significantly deeper than the polder surface, depending on the hydraulic head in the aquifer. Slopes of 1:3 (1 vertical : 3 horizontal) are most commonly used, resulting in very large open excavations and massive earthworks, even for relatively small underpasses. Special measures can be taken to reduce the spatial use with vertical limits, but these measures will increase the building costs (Gerritsen et al. 2014)."

Jan 1, 2015

By M. Pötsch, A. Kluckner, P. Söllner, W. Schubert

"The in situ block size is a key parameter in the geomechanical characterization of rock masses. It describes the fracturing of the rock mass and thus is a measure for the degradation of the rock mass strength. Several classification systems use the in situ block size. For instance, the Geological Strength Index (GSI) requires the “blockiness” and joint surface condition factor as key input parameters. The “blockiness” has recently been related to the in situ block volume (Cai et al., 2004). Due to the limited information about the internals of a rock mass, it is not possible to determine the in situ block size directly. Currently, the in situ block size is determined by calculations using oversimplified models, vague estimations or, due to the lack of relevant information, it is neglected. As remote measurement systems have become available for rock mass characterization, a more comprehensive record of discontinuities can take place. Measurements can be performed on exposed rock outcrops and in particular on tunnel faces and walls, delivering the location, orientation, spacing and persistence of discontinuities at an arbitrary number and locations. An estimation of the in situ block size at the same level of sophistication is still not available. This paper aims at examining the relationship between visible and measureable information at the rock surface, and the in situ block size. Three-dimensional block model simulations were performed using the block model engine of the distinct element code 3DEC. Initial investigations focussed on the minimally required observation area in order to obtain reliable block size distributions. Based on a representative volume element, a reference distribution of the block area at the observation area for a specific discontinuity system was determined. Subsequently, the size of the observation area was decreased stepwise and each new distribution was compared to the reference distribution. For all analyzed systems, it turned out that the mean block area must be smaller than 1% of the observation area to achieve a reliable block size distribution. Further simulations focussed on discontinuity systems with three non-persistent sets. The results were compared to the formula proposed by Cai et al. (2004). A transformation factor T was introduced which replaces the persistence terms in Cai et al.’s proposed formula. The factor describes the correlation between block volumes generated by persistent and corresponding non-persistent discontinuity sets. The simulations included the variation of the discontinuity set spacing, persistence, and orientation. The mean and additionally the 25%-, 50%- and 75%-quantiles of the block size distribution were analyzed. Examining all values for the transformation factor the distribution can be described by a power function with a negative exponent. The function depends on the persistence only. Finally, the results of random simulations were compared to the analytical formula using the transformation factor. The predicted mean and selected quantiles show a good agreement with the simulation results. It gives a comprehensive picture about the block size distribution in discontinuity systems with three non-persistent sets."

Jan 1, 2015

By J. J. Taute, N. B. du Preez

"A well-performing solvent-extraction circuit is a key part of producing good quality copper cathode. To ensure consistent operation, a good understanding of the circuit’s operation and an ability to rapidly troubleshoot key parameters is required. This paper briefly discusses the modeling of solventextraction circuits. The paper then goes on to discuss the determination of key performance parameters from plant data and comparing these with the circuit models to quantify circuit performance. The identification and troubleshooting of circuit issues is presented with a worked example. INTRODUCTIONA well-performing solvent-extraction (SX) circuit is a key part of producing good quality copper cathode. To ensure a consistent, high-quality operation, a good understanding of the circuit performance is required. Evaluating the performance of an SX circuit is an extensive topic. The objective of this paper is to focus on the evaluation that the metallurgist should be performing on a regular basis using flow and concentration data. This paper does not cover important topics, such as crud management, phase continuity, or organic management. Some basic SX modeling concepts are first be presented. The calculation of the parameters is then presented with a brief discussion and recommended ranges (where applicable). A worked example is used to provide a basis for further discussion on the evaluation of the calculated parameters and use of data collected.BASIC SOLVENT-EXTRACTION MODELING CONCEPTSThis section presents the basic modeling concepts used in SX simulation packages currently available. SX reagent suppliers have invested significant time and effort into collecting data on the performance of their reagents under different conditions. Based on these data, suppliers have developed packages which they normally make available to their clients for free. These are typically used for process design and plant optimization studies. For example, BASF developed ISOCALCTM and CYTEC Industries developed MINCHEM® and MEUMTM.Chemistry of Copper Solvent ExtractionLiquid–liquid extraction involves the selective transfer of a substance between two immiscible liquid phases by controlling the relative solubility in each phase. In the case of copper SX, the exchange is typically achieved by an oxime-based chelating mechanism. In particular, mixtures of aldoxime and ketoxime are normally used in conjunction with modifiers. More detail on this extensive topic can be found in Schlesinger et al. (2011)."

Jan 1, 2015

By A. Blackmore, D. Baker, L. Human

"Mechanical mixing equipment is common in a wide variety of mining, metals and process applications, such as hydrometallurgical reactors, solvent extraction, digestors, and tanks for storage of slurry or hydrocarbons. Computational Fluid Dynamics (CFD) has been applied successfully to single-phase mechanical mixing problems for several decades and is established as a reliable design tool. As computational power and CFD codes have improved over the years, there have been significant advances in modelling capabilities including improved models of turbulence, interaction of rotating and stationary components, multiphase flows, and modelling of free surface interfaces, for example. This paper will provide an overview of the application of CFD to mechanical mixing problems. First, it will review the traditional single phase Multiple Reference Frame (MRF) approach and introduce a range of advanced modelling techniques. Three examples of the application of CFD to industrial mixing problems will be given. It will be demonstrated that CFD is an effective tool for reducing technical risk in design, for identifying the root-cause of mixing problems, and testing modifications to existing operations."

Jan 1, 2015

By Gabriel Böde Jimenez Leon, Michael Karmis, Christopher Newman, Zach Agioutantis

"When utilizing high recovery underground mining methods, such as longwall or high-extraction room-and-pillar mining, the movement and deformation of the overburden propagate toward the surface and may affect the integrity of overlying surface streams (Peng et al, 1996). Published studies cite three major mechanisms of subsidence as most likely to impact streams: displacement, slope and strain. While subsidence-induced vertical displacement cause little structural damage to the stream bed, it may create adverse drainage and stream flow issues as the subsidence trough allows for ponding (Dawkins, 2003). Subsidenceinduced changes to the slope, or tilt, of a stream may have adverse effects on water flow. As the stream enters the subsidence trough, the gradient increases providing potential erosion control problems. When exiting the subsidence trough, a reduction of the gradient may inhibit stream flow, causing localized ponding (Peng, 2008). While vertical displacement and tilt both may have detrimental effects to surface streams, the resulting strains have been documented as being the most damaging to surface streams and structures causing distortion, fractures, or failure (Singh, 1992). When stream beds are subjected to high tensile strain, tensile cracks may form at the surface level allowing for the direct loss of stream flow through fissures. When stream beds are located in areas of high compressive strain, rock layers forming the stream bed can fail as the stream bed ruptures, upward, blocking stream flow or having the stream diverted into the fracture zone at the base (Iannacchione, et. al., 2010).Recent investigations on the effects of underground mining on surface bodies of water suggest that to determine the degree of stream impact one must also consider the geologic structure and thicknesses, surface topography, watershed drainage areas, width of river bed and rate of mining. Due to the complex nature and number of parameters affecting surface streams, subsidence modeling tools and software packages should be implemented throughout all stages of subsidence planning, prediction and control. The Surface Deformation Prediction System (SDPS) utilizes the influence function for the calculation of final subsidence deformations with respect to the angle of influence, supercritical subsidence factor as a function of the percent hard rock, edge effect offset distance, and surface topography. Developed more than 25 years ago, SDPS has been continually updated with new analysis and prediction features, providing a reliable and versatile program for subsidence management methodologies. Most recently, the program has been updated to evaluate the effect of varying surface topography in the prediction of horizontal displacements, referred to as ground strain, allowing for the accurate three-dimensional representation of surface deformations in mountainous terrain (Agioutantis and Karmis, 2014). Ground strain has become one of the predominant deformation indices used in the evaluation of potential damage to surface structures (Karmis et al., 1995). Ongoing work with SDPS software seeks to investigate the calculation of ground strain in SDPS and its ability to accurately and realistically predict damage to surface streams due to underground mining operations."

Jan 1, 2015

By L. Trytten, S. Bass, P. Nawrocki, J. Mercer

The Sherritt Fort Site nickel refinery and fertilizer plant has been operating continuously since 1954. The ammonia leach process uses ammonia and sulphuric acid, producing nickel and cobalt and an ammonium sulphate byproduct. One of the features of an ammonium sulphate based process is the aggressive nature of ammonium sulphate to concrete and structural steel. After six decades of operation, portions of the structural steel and concrete at the Sherritt facility have become degraded. Infrastructure replacement programs started in earnest more than a decade ago with pipe racks and electrical infrastructure, and have now progressed into building steel. Replacing and repairing this infrastructure within the tight constraints of an operating plant poses several difficult challenges. This paper will outline the approach taken to accomplish this difficult work, and discuss key learnings from the ongoing program.

Jan 1, 2015

By J. L. Havenga, L. J. van der Walt, J. T. Nel, H. Bissett

"SynopsisNew technologies used to manufacture high-quality components, such as direct laser sintering, require spherical powders of a narrow particle size distribution as this affects the packing density and sintering mechanism. The powder also has to be chemically pure as impurities such as H, O, C, N, and S causes brittleness, influence metal properties such as tensile strength, hardness, and ductility, and also increase surface tension during processing.Two new metal powder processes have been developed over the past few years. Necsa produces zirconium powders via a plasma process for use in the nuclear industry, and the CSIR produces titanium particles for use in the aerospace industry.Spheroidization and densification of these metal powders require remelting of irregular shaped particles at high temperature and solidifying the resulting droplets by rapid quenching. Spherical metal powders can be obtained by various energy-intensive methods such as atomization of molten metal at high temperatures or rotating electrode methods. Rapid heating and cooling, which prevents contamination of the powder by impurities, is, however, difficult when using these methods for highmelting- point metals. For this reason plasma methods should be considered.Thermal plasmas, characterized by their extremely high temperatures (3000–10 000 K) and rapid heating and cooling rates (approx. 106 K/s) under oxidizing, reducing, or inert conditions, are suitable for spheroidization of metal powders with relatively high melting points. Thermal plasmas for this purpose can be produced by direct current (DC) plasma arc torches or radio frequency (RF) inductively coupled discharges. In order to obtain chemically pure spheroidized powder, plasma gases such as N2, H2, O2, and CH4 cannot be considered, while Ar, Ne, and He are suitable. Neon is, however, expensive, while helium ionizes easily and it is therefore difficult to obtain a thermal helium plasma at temperatures higher than 3000 K. Therefore argon should be used as plasma gas. Residence times of particles in the plasma region range from 5–20 ms, but this is usually sufficient as 7–8 ms is required for heating and melting of titanium or zirconium metal particles in the 30 µm size range at 3500 K. In this study the melting and spheriodization of titanium powders was investigated by DC non-transferred arc and RF induction plasma methods. The powders were characterized before and after plasma treatment by optical microscopy and scanning electron microscopy (SEM) to observe if any melting or spheroidization had occurred."

Jan 1, 2015

By S. Bhattacharyya

"Coal bearing rocks are low in strength and have geological discontinuities and moisture sensitivity. Roof and rib falls have been a major cause of fatalities in underground coal mines. Mine engineers design ground control plans for regulatory approvals. A number of tools are available from the National Institute for Occupational Safety and Health to design and assess these plans. Quite often there is not enough geotechnical input information available and databases are used. The Appalachian coalfields have extensive scientific studies to provide reliable regional inputs. Coal mines in the western United States and Canada have different geological and geotechnical conditions, and less available data. Use of inappropriate inputs in the tools like Analysis of Retreat Mining Pillar Stability, Analysis of Longwall Pillar Stability, and Analysis of Roof Bolt Systems may result in unsafe designs or over conservative designs. The tools are convenient but thorough understanding of the inputs, calibration with local test results, and operating experience are important for effective designs. The current paper contains examples of difficulties faced during mine planning using the above tools. INTRODUCTION Sedimentary rocks hosting coal are low in strength. Scientific studies have placed the uniaxial compressive strength (UCS), triaxial strength, tensile strength, and shear strength of sandstone, shale, siltstone, and claystone in lower range of strength among engineering materials (1). Coal bearing rocks are most often weakened by the presence of faults, folds, slickensides, bedding planes, fractures, and other geological discontinuities. The host rocks and coal are often moisture sensitive. The geological discontinuities allow water to enter the strata from surface and underground sources. This combination of low strength, structural weakness, and presence of water results in difficult ground control situations for the coal mines. Roof (2) and rib falls have been a major cause of fatalities in the U.S. coal mines. Modern underground coal mines necessitate wide entries to accommodate large production equipment. The gate roads, section entries, and the mains entries of a highly productive coal mine are as wide as twenty feet (6.1 m). The actual intersection width is nearly thirty feet (9.1 m). Adequate ground control is a key to maintain safe production in such mines. Mine engineers and their consultants routinely submit ground control plans to the regulatory authorities. While working out the necessary roof control system the mine engineers are required to demonstrate the adequacy of the proposed system. There are multiple ways to demonstrate this. Some engineers use traditional load calculation approach of roof bolts (3). Some engineers use numerical methods. Yet a large number of professionals resort to a suite of ground control design software offered by National Institute for Occupational Safety and Health (NIOSH) commonly referred to as “NIOSH Ground Control Toolbar.” These software tools are free and easy to download from NIOSH website. The software included in this package are: Analysis of Longwall Pillar Stability (ALPS), Analysis of Retreat Mining Pillar Stability (ARMPS), Coal Mine Roof Rating (CMRR), Analysis of Roof Bolt Systems (ARBS), Analysis of Horizontal Stress Effects in Mining (AHSM), Analysis of Multiple Seam Stability (AMSS), Analysis of Retreat Mining Pillar Stability - Highwall Mining (ARMPS-HWM). These tools are relatively simple to install and use in planning and designing coal mines and prospective coal mines. They accept a number of geotechnical inputs which are collected from either an existing mining operation or from exploratory boreholes. In the absence of necessary input parameters, the programs use default values which are drawn from databases of geotechnical properties built by NIOSH."

Jan 1, 2015

By Moraka N. V., van Rensburg M. Jansen

"SynopsisGoing beyond transformation claims contained in employment equity scorecards and industry compliance reports, this article provides qualitative insight into the initiatives employed and challenges experienced by mining companies in a quest to transform the mining industry. Perceptions expressed during in-depth interviews with 10 senior executives showed that the assumption that mining companies are reluctant to transform is erroneous. Results from this study suggest buy-in and commitment to transformation. This article describes specific initiatives undertaken by mining companies to transform. The most notable initiatives include staff recruitment efforts to appoint historically disadvantaged South Africans (HDSAs), staff development initiatives, as well as community development. The findings furthermore contextualize the challenges experienced by industry participants in their quest to transform. Despite accusations that industry participants are not taking responsibility for the implementation of the transformation agenda, government needs to recognize that they too have a role to play and need to appreciate and assist in the current challenges experienced by the industry.IntroductionWe need a mining sector that works. Mining employs over half a million people. It is the biggest earner of foreign exchange in our country. It also contributes about 20 billion rand directly to tax revenue. Mining also makes a far larger contribution as a buyer of goods and services, and a supplier of inputs to other sectors of our economy and other economies around the globe’ said President Jacob Zuma during the 2014 State of the Nation Address (Zuma, 2014). However, despite apparent commitment from government, enforced compliance with social and labour plans, regulations and Mining Charter targets, the South African mining industry is slow to gain local and international investor trust (Deloitte & Touche, 2013; Mashego, 2013).Industry players acknowledge that their context has changed – creating various challenges (Davis, 2014). In the past few years, such challenges included subdued commodity prices, increased working costs, constrained infrastructure, and high labour costs, coupled with poor levels of productivity, strained labour-management relations, an uncertain regulatory environment, and the inevitable maturation of the industry (Deloitte & Touche, 2013; Davenport, 2014). Mining affected communities also became more cognisant of their rights, and politicians more vocal in their expectations from their relationships with the mining giants (Davis, 2014). One of the main issues that contributed to the difficult operating conditions was claims from organized labour and Minister Shabangu that this industry is too slow to transform. Specific claims were made in terms of employment equity, fair salaries and wages for mineworkers, housing and living conditions, health and safety issues, and general working conditions (Limpitlaw et al., 2005; Miningmx, 2013; Shabangu, 2010). These claims were followed by what Gill Marcus, Reserve Bank Governor, explained as ‘unprotected strike action [that] has escalated into an uncontrolled, violent and unlawful landscape, led by a mob mentality in the absence of formal and recognised leaders’ (Mavuso,2013)."

Jan 1, 2015