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By Merete Tangstad, Fei Li

This paper studies the quartz and carbon black pellets at elevated temperature with varying temperature and gas atmosphere. High-purity quartz and commercial ultra-pure carbon black was mixed (carbon content wt.15%), and then pelletized into particles of 1-3mm in diameter. The stoichiometric analysis of the pellet during heating is studied in thermogravimetric analysis (TGA) furnace at different temperature in CO and Ar atmosphere. The microstructure, phase changes and element content of sample before/after heating is characterized by X-ray diffraction, scanning electron microscope, X-ray fluorescence and LECO analyzer. The reaction process can be divided into two stages. Higher temperature and argon atmosphere are the positive parameters for SiC formation.

Jan 1, 2016

By Lifeng Zhang, Zineb Benouahmane, Yaqiong Li

Experimental oxidation tests at high temperature (1000-1200 °C) on SiC samples have been respectively performed under wet and dry air atmosphere for different holding times. The thickness of thermally grown oxide was experimentally measured by DEKTAK Stylus Profilometry. The results showed that the oxidation rate was increased with temperature and holding time, corresponding to a passive oxidation regime which led to the formation of SiO2 layer. The sessile drop method was employed in order to measure the contact angles between Si and SiC at high temperature. Contact angle can be varied from 39.6° to 75.6° by controlling the atmosphere. The deoxidation of the oxide layer and infiltration of liquid silicon caused a decrease in the contact angle.

Jan 1, 2016

By Junwei Han, Wenqing Qin, Dawei Wang, Fen Jiao, Wei Liu

The removal of iron impurity from zinc calcine was studied by magnetization roasting and magnetic separation. The effects of roasting temperature, magnetic intensity, ore grinding, and leaching pretreatment on iron grade and recovery were investigated. The results indicated that iron recovery increased with the increase of roasting temperature or magnetic intensity, while iron grade was always less than 22%, depending on the fact that the magnetite were not liberated completely. The good liberation was difficult to be achieved by ore grinding but was easier by acid leaching, since the magnetite grains were very fine. After the leaching pretreatment, the recovery of 76.31% with iron grade of 53.24% was obtained by one roughing and cleaning. The SEM/EDS analysis showed that a part of sphalerite, zinc ferrite and other gangues were mixed into the iron concentrate, while some of fine magnetite was reported to the tailing.

Jan 1, 2016

By Manju Gurung, Birendra Babu Adhikari, Keisuke Ohto, Hidetaka Kawakita, Katsutoshi Inoue, Shafiq Alam

Novel bio-adsorbent gel was prepared by immobilizing functional groups of glycidyltrimethyl ammonium chloride, a kind of quaternary ammonium chloride, onto polymer matrices of persimmon extract for the recovery of precious metals such as palladium(II) and platinum(IV) from chloride media. It was found that this adsorption gel exhibits high selectivity to gold(III), palladium(II) and platinum(IV) over base metals such as copper(II) and iron(III) while crude persimmon extract, the feed material, exhibits high selectivity only for gold(III). From the adsorption isotherms study, the maximum adsorption capacities for gold(III), palladium(II) and platinum(IV) were evaluated as 3.30, 1.67 and 1.00 mol/kg, respectively. Those for palladium(II) and platinum(IV) are higher than those of simple quaternary ammonium chloride type of chemically modified persimmon tannin gel and commercially available anion exchange resin.

Jan 1, 2016

By Z. W. Zhang, Songsong Xu, Jinhui Li, Yun Zou, Yu Zhao

High strength low alloy (HSLA) steels with high strength, high toughness, good corrosion resistance and weldability, can be widely used in shipbuilding, automobile, construction, bridging industry, etc. The microstructure evolution and mechanical properties can be influenced by thermomechanical processing. In this study, themomechanical processing is optimized to control the matrix microstructure and nano-scale precipitates in the matrix simultaneously. It is found that the low-temperature toughness and ductility of the steels are significantly the matrix microstructure during enhancing the strength by introducing the nano-scale precipitates. The effects of alloying elements on the microstructure evolution and nano-scale precipitation are also discussed.

Jan 1, 2016

By Anxiang Wang, Kunhua Wu, Yifu Li, Junjie Xu, Yongnian Dai, Bin Yang, Lingxin Kong

In this study, the saturated vapor pressures of tin (Sn) and antimony (Sb), the separation coefficient and the vapor-liquid phase equilibrium of Sn-Sb alloy were theoretically analyzed, which demonstrate that it is possible to separate Sn and Sb by vacuum distillation. The process parameters of vacuum distillation, including the distillation temperature, distillation time and alloy mass (thickness of raw materials) on the direct yield of Sn and the content of Sn in liquid phase were investigated by using single factor experiments. The preliminary results show that the direct yield and the content of Sn are 98.77 wt.% and 96.01% with the optimized distillation conditions of a distillation temperature of 1473 K, a distillation t ime for 45 min and a Sn-Sb alloy mass of 125 g ( thickness o f 8 mm). The distillation parameters in the study provide effective and convenient conditions on separation of Sn-Sb alloy.

Jan 1, 2016

By Metehan Erdogan, Furkan Özdemir, Ishak Karakaya, Mustafa Elmadaglı

Tungsten is mainly produced by H2 reduction of WO3 which makes its production difficult and costly. A promising method was recently reported for direct electrochemical production of tungsten from CaWO4 (scheelite) which is estimated as the seventy percent of the all tungsten reserves of the world. This paper investigates the application of pulse current in the electrochemical reduction of CaWO4 pellets attached to a current collector. The electrolyte was composed of calcium chloride and sodium chloride salts at eutectic composition (48 pct mol NaCl at 873 K). The reduced samples were cleaned with dilute hydrochloric acid solutions and characterized by X-ray diffraction and scanning electron microscopy. Examination of the results revealed that metallic tungsten was obtained by pulse current reduction.

Jan 1, 2016

By Itavahn Alves da Silva, Jose Dimas de Arruda, Amanda Aparecida Fátima Arruda, da Silva de Souza, Carlos Antonio da Silva, Varadarajan Seshadri, Samuel

The knowledge of the flow field inside a continuous casting mold is essential to improve operational efficiency of the process and also to achieve better inclusion control. Physical modeling, PIV technique and CFD have been employed to assess the velocity distribution in the metal- slag interface region in a slab mold. The analysis of results shows how higher casting velocity and lower immersion depth of submerged nozzle can lead to higher turbulence in the slag-metal interface. The effects of density difference between slag and metal and interfacial tension between the phases have been highlighted.

Jan 1, 2016

By Zhengjie Chen, Wenhui Ma, Jijun Wu, Kuixian Wei

The gasification reactivity of PC (petroleum coke), strengthened by addition of different potassium carbonate proportions using different grinding medium, was investigated by using thermogravimetric analysis (TGA). Results showed that the gasification reactivity of PC not only increased with the increase of catalyst-loaded, but also showed the effective improvement by anhydrous alcohol. The PC was mixed with potassium carbonate [K2CO3] catalyst at 0.5%, 0.8%, 1.0% and 1.5%, and then ground wet with distilled water. The CO2-gasification rate of PC was only 77.35%, 80.55%, 84.07% and 85.88% under the gasification temperature 1100 °C and holding time 120 min, at different K2CO3 respectively. However, when the PC was ground in anhydrous alcohol at the same condition of catalyst-loading, the gasification rate of PC reached 95.43%, 96.63%, 95.50% and 95.61% at the holding time of 108 min, 101 min, 74 min and 35 min, respectively. It was shown by FTIR, SEM and EDX determinations that the anhydrous alcohol used as the grinding medium can further improve the gasification reactivity of PC when compared with the distilled water.

Jan 1, 2016

By Ping Long, Bin Yang, Jian Wu, Xiumin Chen, Wenli Zhang

In this study, the analysis method of trace element in pure indium using glow discharge mass spectrometry (GD-MS) has been established by correcting the analysis result, which was obtained from non-standard quantitative method of GD-MS. The effect of instrument operating parameters, the resolution and isotopes and the pre-sputtering time on the determination results were investigated respectively. The optimized operating parameters of the instrument were obtained as follows: the discharge current was 37.5mA and discharge airflow was 475ml/min. Mass spectral interferences have been eliminated using selected resolution and isotope. The pre-sputtering time was 30 min. 4 trace elements in two pure samples were determined for 6 times. The RSD were less than 20%. The content of trace elements in indium samples was determined by GD-MS and Chemical Analysis Method of Indium which is tested by inductively coupled plasma atomic emission spectrometry, respectively. The results were consistent with each other.

Jan 1, 2016

By Linfeng Zhou, Yuanbo Zhang, Rong Sun, Guanghui Li, Zhiwei Peng

The volatilization behavior of rhenium in the process of oxidative roasting of a molybdenite concentrate with 43.55 wt.% Mo and 321 g/t Re is explored based on identifying the relationship between volatilization of sulfur and rhenium. The results show that rhenium volatizes after sulfur and precise control of operating variables plays an important role in separating rhenium from molybdenite concentrate. When the roasting parameters are optimized as follows: roasting temperature 600 oC, roasting time 2 h, roasting atmosphere air, the volatilization rate of rhenium reaches 89.26%. In the process of solidification roasting, the volatilization rate of rhenium decreased almost to zero when the ratio of slaked lime/molybdenum concentrate was 10% excess to the stoichiometric requirement at 600 oC for 2 h.

Jan 1, 2016

By Cong Wang, Siyang Long, Pengcheng Zhang, Haibin Zuo

This paper introduced the research progress of microwave treatment on coal. The mechanics of microwave treatment mainly include thermal effects and non-thermal effects. Thermal effects, which lead to cracks and changes of pore structure, attribute to the selective heating of microwave. Non-thermal effects involve the removal of oxygen functional groups, improvement of coal rank and decomposition of minerals. Therefore, microwave treatment of coal has a lot of potential applications, mainly including drying, desulfurization, improvement of grindability, enhancement of coal-water slurry property and change the combustion and gasification properties.

Jan 1, 2016

By Qian Xu, Xionggang Lu, Xingli Zou, Zhongfu Zhou, Shuhua Geng, Hongwei Cheng

Herein we report an electrochemical route from oxides (SiO2, TiO2)/sulfide (MoS2)/carbon mixture precursors to Mo-Si-Ti-C composites in molten salt. The electrochemical process was carried out in molten CaCl2 at 800 °C with a potential of 3.1 V, and a graphite-based anode was used in the electroreduction process. The reaction mechanism and the influences of the stoichiometry of the initial mixture precursor on the morphology and phase composition of the final products were investigated. It has been found that Mo5Si3/MoSi2/Mo3Si/Mo, Mo5Si3/MoSi2/Mo2C/SiC, and Mo5Si3/Mo2C/Ti3SiC2/TiC/Mo composites can be electrosynthesized directly from their oxides/sulfide/carbon mixture. The preliminary experimental results suggest that the electroreduction process can be used for the controllable electrolytic production of alloys/carbide-containing composites from oxides/sulfides/carbon precursors.

Jan 1, 2016

By Athena C. Denivo, Pablo V. Lopez, Michael McMaster, Sissy Nikolaou, Alfred H. Brand

"The paper presents the history of development of the United States Tennis Association (USTA) site, focusing on geotechnical, geoseismic, and foundation engineering challenges associated with it. The site is located at the Flushing Meadows Corona Park area of Queens, New York. Now home to the Billie Jean King National Tennis Center (BJKNTC), the site used to be a biologically rich, tidal salt marsh that extended south from Flushing Bay and overlaid an ancient buried valley. In early 20th century, Brooklyn Ash Co. was contracted to fill the marshland with cinders and furnace ashes. F. Scott Fitzgerald describes the “Valley of Ashes” as “a fantastic farm where ashes grow like wheat into ridges and hills and grotesque gardens; where ashes take the forms of houses and chimneys and rising smoke, and finally, with a transcendent effort, of ash-gray men who move dimly and already crumbling through the powdery air.” In 1939 the site was leveled and filled to host the World’s Fair and refilled again for the 1964 World’s Fair.The USTA moved to the site in 1978 and in mid-1990’s constructed the 23,000-seat Arthur Ashe Stadium (AAS). Currently, USTA has a Strategic Vision Plan venue with several interconnected construction projects including buildings, infrastructure upgrades and improvements to site circulation. In addition to a historical walkthrough, the authors will discuss technical challenges of supporting these developments through layers of fill, thick organic silty plastic clays and regional varved soils with bedrock found 300 to 400 feet deep. The subsurface is not only a weak foundation medium, but is susceptible to large amplification of seismic waves propagating from the bedrock during earthquakes. The developments are usually founded on project-specific pile foundations that carry static loads in deeper layers and accommodate lateral demands and performance objectives. Engineering innovations from the most recent development, the roof structure over AAS, will be discussed."

Jan 1, 2016

By Konstantin G. Ashkinadze

The paper considers performance of piles supporting transient pipe anchors in heavy industrial pipelines. Events such as pump trips or opening and closing of large valves produce short-term dynamic pulses in the pipeline with variable spectral characteristics. Their magnitude is large enough to cause major damage to the pipeline and its anchors, which face horizontal impact loads amounting to hundreds of kN. Design of pile foundations supporting these anchors is often governed by limitation of deflection of the support to prevent overstressing pipeline connections and equipment nozzles. The maximum deflection does not always correspond to the largest load because the stiffness of the soil surrounding the piles heavily depends on the rate of loading. Faster actions encounter stiffer soil response while loads of smaller magnitude applied slowly may be more critical for the deflection time history of the anchor. A typical transient action has both high- and low-frequency harmonics, which makes the response complex. Using load rate-dependent p-y curves published in literature, the paper develops methods of analysis of pile foundations for transient anchors. Pile displacement amplitude – input frequency – natural frequency correlations and time histories of pile response are constructed for typical profiles of transient actions, considering nonlinear soil response to large horizontal loads.

Jan 1, 2016

By Armin W. Stuedlein, Jim Zammataro, Bernie Hertlein, Daniel Belardo, Qiang Li, Antonio Marinucci

"An experimental program focusing on four drilled shafts was conducted to determine the effect of high strength steel reinforcement bars on lateral resistance, steel casing on axial and lateral resistance, and steel casing without internal reinforcement on lateral resistance. Thermal Integrity Profiling (TIP) Thermal Wires and crosshole sonic logging (CSL) access tubes were installed in each shaft, and thereafter the corresponding non-destructive testing (NDT) was performed on each shaft to assess the integrity of the shafts and to compare the results from the different NDT methods. The results of the CSL tests using scored PVC tubes are compared against those conducted in 73/56 fully-threaded steel hollow bars, whereby the results indicated that the threaded bars served as a good host for performing the CSL tests. The data from the TIP Thermal Wires is compared against the results from the CSL tests for each of the four shafts, and the similarities and discrepancies between the two methods are discussed. This paper will serve as a reference to those interpreting the measurements and data obtained by performing nondestructive integrity tests on drilled foundations.INTRODUCTIONNon-destructive tests (NDTs) embody a set of critical tools for the evaluation of the integrity of constructed deep foundations, particularly for cast-in-place foundation elements. Construction defects may require the rejection of the foundation element by the owner’s representative, resulting in costly repairs or replacements and delays to the project schedule. The use and appropriate interpretation of the results from the NDTs provide the information required when evaluating the integrity of these constructed elements. A cooperative research program was conducted to assess the effects of various construction variables on the axial and lateral performance of drilled shaft foundations, which provided an opportunity to compare the established Crosshole Sonic Logging (CSL) test method to the newer Thermal Integrity Profiling (TIP) Thermal Wire method. This paper presents an overview of the experimental program performed at the geotechnical test site at Oregon State University (OSU), details of the CSL and TIP installation and testing methods, and the results of the NDTs on the constructed drilled shafts. Because one of the shafts was constructed with fully-threaded longitudinal steel hollow bars, this experimental program also allowed the assessment of the use of the hollow bars as access tubes for the CSL tests. Both the CSL and TIP test methods indicated that the shafts were of good quality and free from defects or anomalies; the data obtained using the TIP method also provided an estimate of the as-constructed shaft diameter and the reinforcement cage alignment, which will prove helpful when back-calculating axial and lateral load transfer during future loading tests."

Jan 1, 2016

By Keith MacKay, John Carter, David Siddle, Fernando Faminia

"The River Green Residential development, is located in the municipality of Richmond, BC adjacent to the Fraser River. Ground conditions at the site consisted of medium to fine grained alluvial sands and a high groundwater elevation. A temporary low permeability retaining wall was required in order to facilitate the construction of an underground parking structure without inducing settlement of adjacent structures, which include the Richmond Olympic Oval; part of the legacy of the Vancouver 2010 Winter Olympics. Golder Associates Ltd. and GeoPacific Consultants Ltd. utilized Cutter Soil Mixing (CSM) technology to enable construction of a continuous combined low permeability cut-off and retaining wall around the perimeter of the property. The 350m long wall was keyed into marine clay at a depth of 28m below ground surface, and contained H-Pile reinforcement installed at regular intervals. The CSM technology provided many benefits for this project, allowing the combined cut-off and retaining wall to be constructed within a very narrow footprint (650mm width). The low noise impact and near vibration free construction of the CSM equipment provided minimal inconvenience to nearby stakeholders during construction. To reduce dewatering volumes during excavation and prevent significant water-table drawdown the Hydraulic Conductivity requirements for the wall were 1 x 10-7 cm/s or less. Project specifications called for a different strength requirement for upper and lower portions of the wall. The top 13 meters of the wall required an Unconfined Compressive Strength (UCS) of 4MPa to act as a retaining and cut-off wall, whereas the bottom 15 meters of the wall required a UCS of only 0.5 MPa to act only as a cut-off wall. Wet-grab and core samples were obtained from the panels to confirm the UCS and Hydraulic Conductivity specifications were met.INTRODUCTIONGolder Construction Inc. and GeoPacific Consultants Ltd. conducted the design and construction of a deep soil mixed cut-off and retaining wall system. The “dry-box” solution was used to surround the excavation of an underground parkade and prevent flows of groundwater into the excavation."

Jan 1, 2016

By I. D. Dayal, Anil Kumar Jain

"Cutoff walls are frequently used to slow down or prevent seepage of water through and/or around dams. Cutoff wall is a type of seepage barrier structure designed to reduce the flow of water underneath temporary or main dam. There are number of techniques for the construction of cutoff walls including concrete, Jet grouting and permeation grouting. NHPC LTD, a premier Govt. of India undertaking has been instrumental in the hydropower development within the country & in nearby countries like Nepal & Bhutan since last four decades. NHPC LTD has completed more than 20 hydro-electric projects with total installed capacity of 6587MW (including capacity addition by JV- NHDC). In all these projects, different types of dams and spillways were constructed in not so benign to extreme challenging geological set up. There has always been challenge associated with the temporary diversion works. The project sites sometimes incur huge river bed excavations in case of concrete gravity dam founded on rock foundation at large depth. The challenges for minimizing the seepage have been well taken care by constructing the dedicated seepage barriers. The construction of cut-off walls have progressed from “conventional continuous trench backfilled with conventional concrete or plastic concrete” to “grout curtain”, to “jet grouting” to the “concrete cut-off wall” , the last being the most sophisticated & credible seepage barrier.The efficiency of the cut-off walls are monitored by the seepage quantity observed (reduction of the seepage flow), uplift pressures or exit gradients after construction of cut-off walls. For construction of the main concrete dam, required space is created by the river bed excavation for placing the dam foundation on sound rock. Sometimes there is deep river bed excavation from 30 to 40 m depth or even more as per the available rock profile. Temporary coffer dams are constructed for diverting the river flow through diversion tunnels / channels etc. In deep river bed excavation; there are high chances of the significant seepage through the coffer dam foundation / river bed material due to high hydraulic gradients. Seepage and piping are the main causes of the failure / damage of the temporary coffer dams. If the seepage quantity is too high, then it becomes difficult to handle it by dewatering in the dam pit. Dam concrete is required to be placed unhindered to have a monolithic construction of dam blocks & to have faster construction in the working season. Cut-off walls increase the seepage path considerably thus reducing the exit gradient and further reduction of the seepage thus helping in maintaining the seepage free area for working."

Jan 1, 2016

By Satyajit Vaidya, Rudolph Frizzi, Quadri Owokoniran

"This paper presents a case history in the design and construction of high-capacity drilled shafts for the iconic New York Wheel presently being constructed along the St. George area waterfront in northern Staten Island, New York. Although the site is located in an area that offers views of the Statue of Liberty, the Manhattan skyline, and New York Harbor, the variable and challenging subsurface conditions at the site and the structural loading requirements for Wheel erection and service conditions presented geotechnical design and construction challenges. The paper focuses on site and subsurface conditions, drilled shaft design and construction details, results of Osterberg-cell and lateral load testing, and load test data analysis and evaluation.PROJECT DESCRIPTIONThe proposed 630-foot (190 m) -tall New York Wheel (the Wheel) is projected to be one of the tallest observation wheels in the world. Upon completion, the Wheel will be capable of carrying over 1,400 passengers in its 36 capsules. The Wheel site is located along New York Harbor offering views of the Statue of Liberty, the Manhattan skyline, and the New York Harbor; see Fig. 1. The Wheel structure is sited along the waterfront, and served by a 3-story terminal located south of the Wheel in the eastern portion of the site and having a footprint area of about 34,250 sq-ft (3,180 sq-m). A 4-story parking Garage, with a footprint of about 112,840 sq-ft (10,480 sqm), is to be constructed south of the Wheel in the central and western portions of the site.SITE AND SUBSURFACE CONDITIONSThe site’s close proximity to the New York Harbor presented geotechnical challenges because the site is located in an area that was once beyond the historic shoreline of Staten Island. The site is an about 350,000-sq-ft (32,500-sq-m) parcel generally bounded by the Richmond County Bank Ballpark to the southeast, the 9-11 Memorial to the east, Bank Street to the north and northeast, and Richmond Terrace and an associated retaining wall to the southwest and south. A 50-ft (15-m) -wide New York City Transit Easement, with an active on-grade service area and tracks, is located in the southern portion of the site. See Fig. 2 for site location and approximate location of the Wheel foundation footprint."

Jan 1, 2016

By Marco D. Boscardin, Kenneth A. Pidgeon, Adriane G. Boscardin

"Hollow bar tiebacks can offer an economical alternative to conventional solid bar and strand tieback systems for use in temporary excavation support construction. However, the limitations associated with the installation of hollow bar tiebacks require special attention during design, construction and load testing to verify conformance with conventional performance and proof testing criteria (PTI, 2014). In particular, providing a reliable free length is complicated by the 10-foot (3-m) -long, segmental, couplingto- coupling nature of the free length sheath in the hollow bar system, and addressing the fully grouted annulus of the bond zone and the free length zone at the end of installation are key concerns. In addition, it is often more convenient to install a greater number of more closely spaced, lower capacity tiebacks with the hollow bar system, compared to conventional tiebacks. This paper examines how these issues were addressed for a project involving a 60-foot (18-m) -deep sheet pile excavation through a highway embankment and a 70-foot-deep sheet pile and soldier pile and lagging excavation through a railroad embankment, both supported by a hybrid system of hollow bar tiebacks and hollow bar soil nails. The project involved approximately 300 tiebacks and 400 soil nails.INTRODUCTIONEngineers Construction, Inc. (ECI), constructed a pair of 32-foot (9.8-m) -wide (clear span), 30-foot (9- m) -high (21 feet (6.4 m) above the stream bed), cast-in-place concrete arch culverts as a design-build project for the Vermont Agency of Transportation (VTrans) in East Ryegate, Vermont. The new culverts replaced an existing 8-foot (2.4-m) -wide by 6-foot (1.8-m) -high cast-in-place concrete culvert under US Route 5 (RTE5), and twin, 2-foot (0.6-m) -wide by 5-foot (1.5-m) -high granite block culverts under the Washington County Railroad (WACR) alignment. The culverts convey Manchester Brook eastward, through the embankments for RTE5 and the WACR, on its way to the Connecticut River. The Connecticut River is located approximately 100 feet (30 m) east of the WACR embankment. The existing structures were undersized and backed up water behind the embankments during high flow events; and often trapped debris that flowed down the brook and became clogged. The existing culverts also had cracks and openings that have resulted in the loss of ground into the culverts and the formation of sinkholes in the sides of the embankments. Moreover, the reason for the large cross-sectional dimensions of the culverts was to make them of sufficient size and openness to encourage the migration of fish up the stream to spawn. The culvert through the RTE5 embankment is 144 feet (44 m) long, and the culvert through the WACR embankment is 128 feet (39 m) long, with a 57-foot (17.4-m) -long by 32–foot (9.8- m) -wide by 17-foot (5.2-m) -deep 10 feet (3 m) deep above the stream bed) open channel section between the two culverts. A plan view of the culvert alignment is presented in Figure 1."

Jan 1, 2016