Search Documents

By H. Wotruba, K. Neubert

Dual-energy X-ray transmission (DE-XRT) imaging is known from safety luggage inspections at airports. The use of DE-XRT technology for sorting applications in the primary raw materials industry has been the subject of numerous investigations. Beside other metal ores, X-ray transmission sorting is already used for the preconcentration of tungsten ore, gold ore and coal. The applicability of DE-XRT sorting is limited to ore types where differences in metal concentrations are measurable, based on an interpretation of X-ray images. Metal contents in particles occur in large varieties in terms of concentration, grain sizes, spatial distribution and mineralogy and therefore influence the X-ray absorption. As a result, each ore has to be tested individually for its suitability for DE-XRT sorting. The objective of current research at the Department of Mineral Processing (AMR) at RWTH Aachen University is to assess parameters influencing the detectability of rare earth oxides. Two approaches were followed: (1) Practical test work, based on artificial ore samples of defined compositions and (2) Computer-based simulation of absorption features of identical particle compositions. In total, more than 300 artificial samples of various compositions and metal grades were produced and X-ray images from DE-XRT sorting were analyzed. Results from the DE-XRT sensor were put into correlation with metal grades and particle sizes, to analyze influences and limits on the detectability of rare earth oxides. In addition, a new approach was tested in which the X-ray absorption of particles of various compositions was determined based on a Monte Carlo (MCNP) simulation. During the simulation, similar compositions, as used for the artificial samples, were tested and the X-ray absorption behavior during DE-XRT sorting was determined. A comparison of results from both approaches is used to assess the applicability of the MCNP-simulation for the prediction of the X-ray attenuation behavior during DE-XRT sorting.

Jan 1, 2016

By George Gazetas, Sissy Nikolaou, Fani Gelagoti, Irene Georgiou, Rallis Kourkoulis

"The need to shift geotechnical design from a “factor of safety” to a “performance based” design (PBD) approach has increased rapidly in the past years following examples from structural engineering. PBD supports sustainable engineered systems that target project-specific geotechnical behavior objectives and results in more rational and, in most cases, less conservative solutions. Resiliency, efficiency, risk optimization, and cost-effectiveness are key components of this approach. For design of retaining walls, the concept of mechanically stabilized earth (MSE) systems combines these attributes, while being environmentally friendly and adaptive to variable construction conditions. Natural hazards, such as earthquakes, may drive the design of MSE systems whose reliability depends on their performance under extreme events. In this paper, the authors compare the seismic response of an MSE steel-reinforced vs. concrete-reinforced retaining wall. The MSE system is composed of a grid of longitudinal and transverse ribs which internally enhances the capacity of the soil backfill. Results of fully non-linear twodimensional (2-D) numerical finite element analyses using two commercial programs with emphasis on the interface conditions are presented. The pull-out resistance of the grid used in the numerical simulation was evaluated from actual pull-out experiments. The results demonstrate a superior performance of the MSE system as compared to the concrete one, especially when subjected to strong seismic excitations.INTRODUCTIONThe idea of performance-based geotechnical engineering is not new, and has been evolving as our perception for ‘good’ performance has also evolved (Kramer, 2008). In early practice, the only criterion for achieving good performance was to avoid failure; designers had only to ensure that the available capacity of the geotechnical system is sufficiently higher than the expected demand (i.e. Load and Resistance Factor Methodologies). Yet, even when the key design requirements against collapse are satisfied, the system may still be placed into a condition in which the deformation constraints are not met (Bolton, 2012). To address these issues, geotechnical design has been developing into a predominantly performance-based approach that correlates deformation considerations to the severity of the experienced loading. As such, in earthquake-related problems, the definition of good performance of a geotechnical system is no more unique; for a low intensity earthquake the system should remain serviceable (i.e., the developed deformations should remain low), whilst for the design earthquake the maintenance of lifesafety is the single performance criterion."

Jan 1, 2016

By David Guy, John Stanbury, Gilbert Tallard

"In 2009, storm surge from Hurricane Sandy inundated the Bay Park Sewage Treatment Plant located at El. +4 to +12 (+1.2 to +3.6 m) in East Rockaway, Long Island, NY. With all systems down, raw sewage water mixed in the floodwaters. A recurrence of such an event being unacceptable, and in view of rising future sea levels, a flood protection project was developed by Nassau County with funding coming in large part from the federally funded Sandy Rescue Fund. Designed by Arcadis/Hazen & Sawyer Engineers J.V., the protection took the form of a perimeter barrier capable of withstanding future storm surge. Due to limitations imposed by property lines and existing facilities, a levee design with three different types of cross section was developed to adapt to each location, adding construction complexity. The Long Island subsurface is characterized by beach sand extending to great depth. The clay required for the core and levee cover therefore had to be brought in from out of state. A thin silty clay layer at El. -23 to -25 (-7.0 to -7.6 m) served as an aquitard. The under-seepage was reduced by a hanging cut-off wall designed as a vibrated beam thin wall and filled with a salt water resistant, low permeability, self-hardening slurry.INTRODUCTIONOn October 29, 2009, Hurricane Sandy hit New York City, with a devastating effect on the region. The low lying Bay Park Sewage Treatment Plant (STP) (Fig. 1) serving Nassau County on Long Island was submerged (Fig. 2). All basements and underground mechanical facilities were flooded (Fig. 3) and millions gallons of effluent were released into the waters of the nearby Hewlett Bay which connects via other small waterways to the Atlantic Ocean."

Jan 1, 2016

By John P. Turner, Benjamin J. Turner

"Non-destructive testing and evaluation (NDT/NDE) methods have become standard tools as part of the post-construction quality assurance of drilled shaft foundations. In responding to anomalies, foundation designers, owners, and contractors face a number of choices, including: (i) acceptance of a shaft with known anomalies, (ii) further investigations of integrity (e.g., concrete coring), (iii) repair schemes, and (iv) reject and replace. To assist in selecting the best option, analyses are often performed that involve assessing the structural performance of reinforced concrete shafts that may include defective concrete or voids. Currently, the analytical tools for predicting the flexural strength and stiffness of drilled shafts with defective concrete located in discrete regions of the cross section are limited. This paper presents a robust moment-curvature analysis tool for drilled shafts based on the fiber-element discretization method. The tool allows for consideration of anomalous or defective concrete regions in the shape and location that they are believed to exist in the shaft while considering explicitly the nonlinear material behavior of the intact regions based on expected material properties. A case study is used to illustrate the practical application of the analysis to drilled shaft projects.INTRODUCTIONImperfections such as defective concrete or accidental eccentricity of reinforcing cages are an inherent part of the drilled shaft construction process that will occur occasionally even when construction best-practices are followed. Petek et al. (2002), O’Neill and Sarhan (2004), Poulos (2005), and others have described the effects that construction defects can have on the axial and lateral performance of drilled shafts. Our industry has seen rapid progress in recent years in the development and improvement of tools for detecting drilled shaft anomalies, such as gamma-gamma and crosshole-sonic logging, sonic-echo testing, thermal integrity profiling, and even visual inspection with invasive video cameras. Nonetheless, in most cases the wealth of data from these tests is used by foundation engineers to make a fairly “black or white” decision—should the defects be repaired, or should the shaft be rejected? A third option that is not typically considered is to directly analyze the section, including anomalies, and compare the reduced strength and/or ductility to the actual project demands. This option takes full advantage of the data collected during integrity testing, and may provide a justifiable means for avoiding further construction costs and delays, whether for repair or replacement."

Jan 1, 2016

By Marwa Nabil, Alaa A. Ata

"Recent developments in the analysis of piled rafts has incorporated the load sharing of the raft and the piles to support the superstructure. In the piled-raft system, piles are cast monolithically with the raft and the load is partly transmitted by the raft to the soil directly below it, and partly by the piles to more competent deep soil. While these piles are effective in increasing the bearing capacity and reducing the settlements, they often lead to significant straining actions at the pile head-raft connection which may constitute the weakest link. An attempt to provide a more economical solution, that at the same time overcomes this weak link, is to disconnect the pile heads from the raft and introduce an intermediate cushion of compacted fill. In this case, the piles are considered as reinforcement to the subsoil and will also act as settlement reducers. This paper investigates the load transfers mechanism of the unconnected piled raft with cushion using ABAQUS finite elements Program. The main objective is to provide an in depth analysis of the raft–soil–pile interactions in multi-layered soil under static and seismic loads. The investigated system provides an economical alternative for traditional connected piled raft foundation, where there is no need to reinforce the piles, no need for pile head demolition or expensive waterproofing of the pile head connection. Cost analyses of unconnected versus connected piled raft systems confirmed a cost savings in the construction that may reach from 50 to 70 percent.INTRODUCTIONDesigners around the world have gained more confidence to use the piled-raft as a more realistic system where the raft and the piles share transferring the superstructure loads to shallow and deep soil layers. A further advancement is to use unconnected piled rafts as another practical and economical alternative to the traditional piled rafts. Unconnected piled raft is also synonymous to settlement reducing piles; or simply, soil improvement piles. Liang et al. (2003) has extended the concept of pile-raft-foundation to a new type of foundation called composite piled raft foundation or unconnected piled raft foundation. The foundation is composed of a sand/gravel cushion sandwiched between the raft and piles. The piles group may contain short and long piles. The short piles are constructed of flexible materials such as soil-cement columns or sand-gravel columns, and are used mainly to improve the bearing capacity of shallow soft soil; the long piles, which are made of relatively rigid materials such as concrete, and their main function is to reduce settlements. The cushion plays an important role in mobilizing the bearing capacity of the subsoil and in modifying the load transfer mechanism of the piles. In Shanghai, China, this system of unconnected piled raft has proved to be quite suitable and effective in coastal areas, where deep soft soil deposits exist."

Jan 1, 2016

By Christopher R. Harris

"Considerations are presented for developing and implementing self-hardening slurry mix designs to be utilized in barrier seepage walls. Slag-cement-cement-bentonite (SCCB) slurries are the primary focus, with some comparisons referenced to the more traditional Portland-based cement-bentonite (CB) slurries. Field and laboratory mixing methods are reviewed, including 1) single sack – single mixer method; 2) bentonite slurry mixer – cementitious addition mixer method; 3) bentonite mixer – grout mixer – CB blending mixer method. Major phenomena associated with the dynamics of barrier wall excavation, such as loss of water from the in-trench slurry and consolidation of in-trench slurry are discussed. Other topics touched upon include sand content effects, fluidizers utilized, and chemical contaminants. The role of higher bentonite to water ratio is reviewed, with demonstration of improvement of filtration properties, and an increase of water retention of the final consolidated product.IntroductionSelf-hardening slurry has been utilized to construct barrier seepage walls for many decades. This is essentially a single-step slurry excavation and backfill process whereby the trench-supporting fluid gains strength over a short period during installation and maintains or develops low hydraulic conductivity. The resulting curing slurry becomes the actual barrier wall as the resultant cement-augmented clay slurry now fulfills the dual purpose of both temporary trench stabilization and final cured-in-place product. This eliminates the requirement and expense of subsequent backfill/slurry displacement operations required in traditional barrier wall installations.Self-hardening slurries have been fabricated using a number of various clays, most commonly sodium bentonite, calcium bentonite, attapulgite, and sepiolite. Perhaps due to plentiful high quality sodium bentonite deposits found domestically, the proven excavation stabilization properties imparted from sodium bentonite slurries, sodium bentonites are typically specified for formulating self-hardening slurries in the US. Cementitious materials utilized most commonly are Portland cement and slag (ground blast furnace slag or GBFS). For the purposes of this discussion, self-hardening slurry having a cementitious of Portland will be referred to as CB. Those having cementitious material of GBFS replacing Portland (partially or wholly) will be referred to as SCCB."

Jan 1, 2016

By Andreas Brandner, Karl Schoenherr-Strasse, I. B. Brandner, Dipl. Ing

"A world famous Wintersport resort in the Alpine planned to build a parking garage for more than 600 cars and busses situated between a torrent, a district road and the village.A nearly 200 m long building giving place for 6 parking levels and a maintenance level for busses and trucks is situated alongside a hill causing excavation height between 20 and 25 meters, which had to be secured. Due to restrictions – neighbours did not allow the client to drill anchors for retention – we designed a solution combining micropiles, strand anchors, shotcrete and nails as permanent earth retention not exceeding the space of 7 meters provided by the local street. Soil conditions were as challenging - reaching from backfill to moraine with boulders of more than 20 m³ volume – as the construction period of total 12 months for the whole project, which was opened mid of November 2015.The innovative solution outperformed the client´s project from the technical and commercial aspect and helped the contractor to save time and money.The design process with its difficulties as well as erection process is described in the following paper."

Jan 1, 2016

By Matthew C. Janes, Mark C. Spence

"A former coal gasification site next to Rock Bay in Victoria, BC, Canada required a barrier to permit dewatering and excavation of the bay and surrounding property. The adjacent property owners had stringent requirements at the boundaries of their properties. Isherwood Geostructural Engineers designed a temporary steel sheet pile (SSP) water retention structure and excavation shoring system along the perimeter of the site. The project involved challenging geotechnical conditions in soft clay soils and a multi-faceted construction staging plan involving the diversion of two large storm water outfalls that drained into the bay. Despite a well-conceived design and construction plan, unexpected site conditions and delays led to significant changes in design and construction approach. Employment of the Observational Method and on-the-fly geotechnical investigation were instrumental in maintaining project momentum and schedule. The paper presents the geotechnical and geostructural design details and construction events as they transpired, highlighting the key issues, discussions and lessons learned.INTRODUCTIONFor over 100 years, the Rock Bay Site, in Victoria, British Columbia, Canada, had a legacy of contamination left behind from previous industrial activities. The site was the former location of a coal gasification plant that was in operation from 1862 to 1952. The site was also an infilling location for a nearby tannery and sawmill. The remediation of the Rock Bay Site involved the excavation and replacement of approximately 300,000 tonnes of contaminated soils on Transport Canada’s property. The project commenced in 2004 and has occurred over several phases on multiple properties. In the third and final phase of the project, a temporary steel sheet pile (SSP) excavation shoring system and ocean barrier wall – required to seal off the bay – was employed to enable disposal and replacement of approximately 90,000 tonnes of contaminated soils from the shoreline and base of the bay."

Jan 1, 2016

By cheng Peng-fei, TANG Hai-yan, guo Xiao-chen, LI Jing-she, Liang Yong-cang, Zhao Baojun

The origin and evolution of non-metallic inclusions for Al-killed casing steel during EAF-LFVD- CC process were studied by industrial tracer experiments. The formations of Al2O3 and MgO·Al2O3 micro- and macro-inclusions from ladle slag were analyzed by theoretical calculations. The results show that micro-inclusions were formed during deoxidation and temperature decreasing in the process of casting, most of the macro-inclusions come from entrapped ladle and mold slags. In addition, most of the Al2O3 formed were modified into 12CaO·7Al2O3 and 3CaO·Al2O3 inclusions which are liquid at steelmaking temperature. MnS cannot be fully modified to CaS and it was only wrapped outside the alumina or calcium aluminate in the form of (Ca,Mn)S with the amount of Ca-Si wire fed during the test.

Jan 1, 2016

By Pan Gu, Zhen Zhang, Jiang Diao, Bing Xie, Hongyi Li

Viscosities of FeO-SiO2-V2O3-CaO-P2O5 slags have been measured at the temperature range of 1673 K to 1773 K (1400°C to 1500°C). This investigated system represents the major components of basic vanadium slag that is an important intermediate product of a novel vanadium extracting process, in which removal of phosphorus and extraction of vanadium can be achieved from the vanadium-containing hot metal simultaneously. It was found that higher CaO/SiO2 ratio resulted in lower viscosity in the composition range of interest. Also, the viscosities increase with the increasing P2O5 concentration. The varying viscosities can be attributed to the modification in complexity and polymerization of the slag network. The variation of apparent activation energies are in tune with the viscosity measurements. The results of this work revealed the effect of CaO/SiO2 and P2O5 on the viscous properties of FeO-SiO2- V2O3-CaO-P2O5 slags and therefore provide the theoretical foundation for the control of the coupling de-P and V-extraction process.

Jan 1, 2016

By Shengli Wu, Laixin Wang, Minyin Kou, Xinliang Liu, Weidong Zhuang, Yujue Wang

COREX process has obvious advantages in environment protection but still has some disadvantages, for example, it has a higher sulfur content of hot metal than blast furnace. In this paper, the thermodynamics and dynamics of desulfurization have been investigated to obtain the main operation parameters related to the mass fraction of sulfur in the hot metal. In addition, statistical analyses have been carried out to study the relationship between operating parameters and sulfur content of COREX hot metal based on actual plant data. It has been found that the mass fraction of sulfur in hot metal is significantly influenced by the C content in hot metal, MgO/Al2O3 in slag, the concentration of MgO in slag, the temperature of hot metal and binary basicity (R2).A linear model has been developed and subsequently used for reducing the mass fraction of sulfur in hot metal, improve the quality of hot metal and contribute to low carbon ironmaking.

Jan 1, 2016

By Fangqing Yin, Qingyu Deng, Zhengfeng Qu, Mengjun Hu, Meilong Hu

Titanium bearing blast furnace slag, which contains 20%-30% TiO2, is a valuable secondary titanium resource. Based on the thermodynamics calculation effect of the temperature on the reduction of the slag in vacuum were studied at certain vacuum degrees. The results show that magnesium vapor and silicon monoxide vapor can be obtained at the condition of high temperature and low pressure. The purity of TiC increases with temperature increasing. When the temperature arrives at 1623K TiC can be obtained besides the reductant carbon. XRD result of the powder collected from the furnace cover show that magnesium and silicon in the titanium bearing BF slag leave the slag system during carbothermal reduction in vacuum. From the above it can be concluded that TiC can be obtained from the titanium bearing BF slag and silicon and titanium in the slag can be separated by carbothermal reduction in vacuum and acid leaching.

Jan 1, 2016

By Zhanjun Wang, Yongqi Sun, Mei Zhang, Zuotai Zhang, Min Guo

The role of fluorine on the viscous and crystallization behavior of CaO-SiO2-MgO-Al2O3-FetO-P2O5-(CaF2) slags were explored using the rotating cylinder method, non-isothermal differential scanning calorimeter (DSC), X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. It was found that the viscosity slightly decreased with increasing CaF2 content. It was also found that CaF2 addition can promote the primary phase transformed from MgFe2O4 spinel to Ca3(PO4)F, which was beneficial to the enrichment of phosphorus. Additionally, the structure of the slags explained by X-ray photoelectron spectroscopy (XPS) and magic angular spinning nuclear magnetic resonance (MAS-NMR) were further analyzed, which was well in accordance with the above analysis.

Jan 1, 2016

By Merete Tangstad, Fei Li

This paper studies the quartz and carbon black pellets at elevated temperature with varying temperature and gas atmosphere. High-purity quartz and commercial ultra-pure carbon black was mixed (carbon content wt.15%), and then pelletized into particles of 1-3mm in diameter. The stoichiometric analysis of the pellet during heating is studied in thermogravimetric analysis (TGA) furnace at different temperature in CO and Ar atmosphere. The microstructure, phase changes and element content of sample before/after heating is characterized by X-ray diffraction, scanning electron microscope, X-ray fluorescence and LECO analyzer. The reaction process can be divided into two stages. Higher temperature and argon atmosphere are the positive parameters for SiC formation.

Jan 1, 2016

By Lifeng Zhang, Zineb Benouahmane, Yaqiong Li

Experimental oxidation tests at high temperature (1000-1200 °C) on SiC samples have been respectively performed under wet and dry air atmosphere for different holding times. The thickness of thermally grown oxide was experimentally measured by DEKTAK Stylus Profilometry. The results showed that the oxidation rate was increased with temperature and holding time, corresponding to a passive oxidation regime which led to the formation of SiO2 layer. The sessile drop method was employed in order to measure the contact angles between Si and SiC at high temperature. Contact angle can be varied from 39.6° to 75.6° by controlling the atmosphere. The deoxidation of the oxide layer and infiltration of liquid silicon caused a decrease in the contact angle.

Jan 1, 2016

By Junwei Han, Wenqing Qin, Dawei Wang, Fen Jiao, Wei Liu

The removal of iron impurity from zinc calcine was studied by magnetization roasting and magnetic separation. The effects of roasting temperature, magnetic intensity, ore grinding, and leaching pretreatment on iron grade and recovery were investigated. The results indicated that iron recovery increased with the increase of roasting temperature or magnetic intensity, while iron grade was always less than 22%, depending on the fact that the magnetite were not liberated completely. The good liberation was difficult to be achieved by ore grinding but was easier by acid leaching, since the magnetite grains were very fine. After the leaching pretreatment, the recovery of 76.31% with iron grade of 53.24% was obtained by one roughing and cleaning. The SEM/EDS analysis showed that a part of sphalerite, zinc ferrite and other gangues were mixed into the iron concentrate, while some of fine magnetite was reported to the tailing.

Jan 1, 2016

By Manju Gurung, Birendra Babu Adhikari, Keisuke Ohto, Hidetaka Kawakita, Katsutoshi Inoue, Shafiq Alam

Novel bio-adsorbent gel was prepared by immobilizing functional groups of glycidyltrimethyl ammonium chloride, a kind of quaternary ammonium chloride, onto polymer matrices of persimmon extract for the recovery of precious metals such as palladium(II) and platinum(IV) from chloride media. It was found that this adsorption gel exhibits high selectivity to gold(III), palladium(II) and platinum(IV) over base metals such as copper(II) and iron(III) while crude persimmon extract, the feed material, exhibits high selectivity only for gold(III). From the adsorption isotherms study, the maximum adsorption capacities for gold(III), palladium(II) and platinum(IV) were evaluated as 3.30, 1.67 and 1.00 mol/kg, respectively. Those for palladium(II) and platinum(IV) are higher than those of simple quaternary ammonium chloride type of chemically modified persimmon tannin gel and commercially available anion exchange resin.

Jan 1, 2016

By Z. W. Zhang, Songsong Xu, Jinhui Li, Yun Zou, Yu Zhao

High strength low alloy (HSLA) steels with high strength, high toughness, good corrosion resistance and weldability, can be widely used in shipbuilding, automobile, construction, bridging industry, etc. The microstructure evolution and mechanical properties can be influenced by thermomechanical processing. In this study, themomechanical processing is optimized to control the matrix microstructure and nano-scale precipitates in the matrix simultaneously. It is found that the low-temperature toughness and ductility of the steels are significantly the matrix microstructure during enhancing the strength by introducing the nano-scale precipitates. The effects of alloying elements on the microstructure evolution and nano-scale precipitation are also discussed.

Jan 1, 2016

By Anxiang Wang, Kunhua Wu, Yifu Li, Junjie Xu, Yongnian Dai, Bin Yang, Lingxin Kong

In this study, the saturated vapor pressures of tin (Sn) and antimony (Sb), the separation coefficient and the vapor-liquid phase equilibrium of Sn-Sb alloy were theoretically analyzed, which demonstrate that it is possible to separate Sn and Sb by vacuum distillation. The process parameters of vacuum distillation, including the distillation temperature, distillation time and alloy mass (thickness of raw materials) on the direct yield of Sn and the content of Sn in liquid phase were investigated by using single factor experiments. The preliminary results show that the direct yield and the content of Sn are 98.77 wt.% and 96.01% with the optimized distillation conditions of a distillation temperature of 1473 K, a distillation t ime for 45 min and a Sn-Sb alloy mass of 125 g ( thickness o f 8 mm). The distillation parameters in the study provide effective and convenient conditions on separation of Sn-Sb alloy.

Jan 1, 2016

By Metehan Erdogan, Furkan Özdemir, Ishak Karakaya, Mustafa Elmadaglı

Tungsten is mainly produced by H2 reduction of WO3 which makes its production difficult and costly. A promising method was recently reported for direct electrochemical production of tungsten from CaWO4 (scheelite) which is estimated as the seventy percent of the all tungsten reserves of the world. This paper investigates the application of pulse current in the electrochemical reduction of CaWO4 pellets attached to a current collector. The electrolyte was composed of calcium chloride and sodium chloride salts at eutectic composition (48 pct mol NaCl at 873 K). The reduced samples were cleaned with dilute hydrochloric acid solutions and characterized by X-ray diffraction and scanning electron microscopy. Examination of the results revealed that metallic tungsten was obtained by pulse current reduction.

Jan 1, 2016