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By T. R. Ley

"RELIABILITY & SAFETY – TOGETHER. REALLY? I was starkly reminded of the challenges facing by the coal industry while talking with a number of senior mining executives. One said to me: “Safety is the #1 priority in our organization but of course, dollars are very, very important!!!” A coal mine worker at the Bluefield Coal Show claimed: “We know our equipment is bleeding hydraulic fluid all over the place but all that matters is getting the coal out”. We all understand. We want our people to go home safely at the end of the day but the coal industry is bleeding – fluids, dollars and real blood. An issue getting plenty of buzz these days is equipment reliability – in mining too! Achieving an optimal return from the massive investments in equipment is a critical requirement for success within a capital intensive industry like coal mining. You can cut costs by scrimping on maintenance, scavenging used parts and downsizing. Or, you can save money by being smarter with your asset management processes. Can we afford to spend money on both safety and reliability? Is one more important than the other? Many leading edge companies from a variety of industries will tell you that you can’t just cost-cut your way to profitability - or even survival. You need to systematically improve the effectiveness of your business. Do reliability and safety both have a place in improving the performance of the coal industry? According to Ron Moore, of The RM Group, the answer is emphatically YES! Ron says: “If you believe in safety, then you MUST believe in reliability and, more importantly, have the appropriate policies, systems, practices and measures in place. If you want lower costs, you must get your processes right. Simple cost cutting will remove resources from your system without changing the underlying system design, and performance will likely deteriorate.” Figure 1 shows the 5+ year results of a large manufacturing company. When plants are running well (high Asset Utilization), then injuries are less likely. Figure 2 plots data from a number of manufacturing plants. If you want sustainably lower costs get your reliability processes right. But these are manufacturing companies, not coal mining operations! It doesn’t matter. The fundamentals still apply. Mining industry thought leaders tell us that manufacturing is 20-30 years ahead of us and we need to learn from them – and do so quickly. Leading companies, no matter the industry, think in terms of operational excellence. They see this as the meshing of people, process and technology to achieve optimal results. Safety and reliability go hand-in-hand. People and equipment are different – but only to the extent that each requires its own relevant, but related, policies, practices, systems and metrics to achieve effective performance."

Jan 1, 2016

By Paolo M. Brion, Z. Bade Sozer

"The Bypass Tunnel has high head conditions ranging from a minimum of 600 feet (183 m) under the Hudson River to a maximum of 875 feet (267 m) on the west side. The ground cover ranges from 425 feet to 900 feet (130 to 274 m). A two-pass lining is designed for the Bypass Tunnel. The bolted, gasketed precast segments carry the temporary hydrostatic and permanent ground loads. After the tunnel is put into service, the design assumes that the final lining, which varies from reinforced concrete to reinforced concrete with steel interliner, will carry the permanent hydrostatic loads. The design head for the segments is assumed at 775 feet (236 m), and the internal operating pressure head is around 1,200 feet (366 m). This paper discusses the design hydrostatic head and different load conditions considered for the segments, the load sharing between the segments and final lining, and the means employed to control water and hydrostatic pressure. PROJECT BACKGROUND The Rondout-West Branch Tunnel (RWBT), a segment of the Delaware Aqueduct, was built from 1937 to 1944 and provides about 50% of New York City’s total water supply. Monitoring and tunnel operations have shown that the RWBT is leaking up to 35 million gallons per day (MGD) (132.5 million L/day). In particular, two locations have been identified as areas of concern: Roseton and Wawarsing, as shown in Figure 1. The Wawarsing reach of the aqueduct will be repaired with an extensive grouting program when the RWBT is unwatered. However, because of the extensive nature of the leakage in the Roseton area, a Bypass Tunnel will be constructed to divert the flow around this area."

Jan 1, 2016

By M. C. Harris

"Excess Gibbs energy is a thermodynamic parameter which quantifies the difference between the value of the Gibbs energy for a real mixture and that for an ideal mixture. More specifically the partial molar excess Gibbs energy of a species (i) in a mixture is indicated by the change in the overall excess Gibbs energy of the solution as the number of moles of species (i) changes while keeping temperature, pressure and the number of moles of all other species in the solution constant. Generally it is obtained from the activity coefficient which in turn can be obtained for a species in a mixture using a variety of models. The most widely used method is to use UNIFAC. Flotation is probably the most important process in the concentration of minerals and requires the use of reagents such as collectors and frothers. There is abundant experimental data which illustrates that collectors of different alkyl chain lengths will change the contact angle and that frothers of different structures and molecular weights will result in changes in key flotation properties such as froth behavior, surface tension and critical coalescence concentration. In this paper it is shown that there is a strong linear relationship between measured parameters such as froth volume/height, surface tension, critical coalescence concentration and contact angle and the partial molar excess Gibbs energy of the molecules used. Proposals are made to explain these correlations.INTRODUCTIONAs is well known froth flotation is arguably the most widely used process in the separation of minerals. In broad terms the process relies on the use of reagents known as collectors to adsorb onto a mineral surface and thus render the mineral particle hydrophobic. Alkyl thiolates are very commonly used for this purpose. The hydrophobicity is induced as a result of the alkyl group’s molecular structural properties which results in it forming a non-ideal mixture with the process water. Surfactants (or frothers) are typically alcohols and are known to lower the surface tension of the system and also inhibit bubble coalescence and reduce bubble size. Since alcohols are polar they will also form a non-ideal mixture with water. The hydrophobic mineral attaches to the bubble and rises to the froth phase where the valuable mineral is recovered as a concentrate. Frothers have often been characterized using the so-called HLB (hydrophobic-lipophilic balance) number but recently it was shown that the use of activity coefficients (?) or excess Gibbs energy (G ex ), which is calculated using equation (1) is a much more appropriate way to describe the behavior of these reagents in non-ideal mixtures with water (Corin and O’Connor, 2014)."

Jan 1, 2016

By Lin Li, Ahmad Ghahremaninezhad

"In this paper, the electrochemical behavior of ferric and ferrous couple on the pyrite surface was studied by application of the chronoamperometry technique in an acidic solution at room temperatures and atmospheric pressure. The effects of the pyrite origin, ferric and ferrous ions concentration on the electron transfer kinetics of Fe3+/Fe2+ reaction were probed. Tafel behavior of all the test conditions were developed. The results showed that the ferric-ferrous reaction on pyrite electrodes with different origins have a common mechanism, despite different reaction kinetics. The exchange current densities of the redox reaction have the same magnitude of about 10-5 A·cm-2, which is far lower than the value reported for the gold and platinum electrodes, but larger than that of the chalcopyrite electrode. The cathodic transfer coefficients are between 0.4 and 0.5, while the anodic transfer coefficients appear unusual with the lowest value being 0.23. It was also demonstrated that an increase of one order of magnitude of iron concentration has no clear effect on the exchange current density and cathodic transfer coefficients of Fe3+/Fe2+ redox reaction.INTRODUCTIONPyrite, FeS2, is mostly considered as a gangue mineral which frequently coexists with valuable minerals and metals, such as gold, copper and nickel. Its separation from valuable minerals can be a costly process (Chandra & Gerson, 2010). In refractory gold ores, the fine gold particles are locked inside the pyrite structure. Oxidative leaching of pyrite is a hydrometallurgical method to destroy the structure of pyrite and expose the fine gold particles to the cyanide solution in the downstream cyanidation circuit. Pyrite oxidative leaching can be achieved by oxidation of pyrite via oxygen and ferric ion(McKibben & Barnes, 1986). In fact, pyrite oxidation by oxygen and ferric is a significant source of acid mine drainage(AMD), which adversely causes serious environmental problems(V. P. Evangelou, 1995).The pyrite oxidation mechanism is accomplished in three consecutive steps: (i) pyrite is oxidized by oxygen and ferrous ion formation (Eq. 1); (ii) ferrous oxidation by oxygen and ferric ion formation (Eq. 2); (iii) pyrite oxidation by means of ferric ions (Eq. 3). Hence, both oxygen and ferric participate in the pyrite oxidation process (Moses & Herman, 1991):"

Jan 1, 2016

By P. Leeuw, H. Mtegha

"The aim of this paper is to enhance the understanding of the nature of mining input technologies in the South African mining industry. In the context of this research, mining inputs refer to input technology into the activities in mining engineering fields, which include mining-related production activities, rock engineering, mine ventilation, and mine transportation (handling of personnel, material, broken rock, and pumping). Input technologies in supporting fields such as geology, other engineering disciplines, human resource, procurement, finance, as well as downstream fields that include metallurgy, and marketing of minerals, were disregarded.The mining input technologies were divided into 12 nodes, and data from a sample of 150 first-tier mining suppliers was analysed. It was found that, in general, there is a high local content in mining input technologies, particularly as regards technical support services, artefacts, and machine technologies. This points to the presence of mining-induced backward linkages in the South African mining industry. The majority (83%) of companies that provide input technologies into mining are located in Gauteng Province, and relatively few are found in provinces where mining is concentrated such as North-West, Limpopo, Mpumalanga, and Free State. IntroductionSouth Africa is well endowed with minerals, with more than fifty different minerals being mined throughout the country. For this and other reasons, mining is one of the crucial pillars in the South African economy and its importance is well documented (Robinson and von Below, 1990; Creamer, 2010; Department of Mineral Resources, 2015). In 2013, South Africa was the largest global producer of chromium, ferrochrome, platinum group metals (PGMs), and vermiculite and the second largest global producer of antimony, manganese, titanium, and vanadium (Chamber of Mines of South Africa, 2014). In 2013, the mining industry contributed 6.7% to South Africa’s GDP and was the fifth largest sector in the economy, as shown in Figure 1."

Jan 1, 2016

By Houquan Zhang, Yu Wu, Yanlong Chen, Zhenfu Luo, Aihong Lu

"A non-destructive detection scheme for bolt installation quality was designed by adopting the method of non-destructive detection on bolt installation quality. Based on the field measurements, a random non-destructive detection method for determining the characteristic length including anchoring length, free segment length and initial axial load of bolt was discussed, and the characteristics of increasing bolt axial load in the initial stable stage was obtained. The results show that the bolt axial load and deformation of surrounding rocks correlate each other. Compared with the traditional detection technique for bolt installation quality, the non-destructive detection method has obvious advantages such as random, accuracy, and economic. The method provides a reliable basis for bolt support optimization and stability control of surrounding rocks.INTRODUCTIONBolt support in roadway can make the surrounding rocks and bolt form a structure in the early stage of roadway development through the bolt pre-tension, which can maximize the self-bearing capacity of surrounding rocks. Thus it is a form of active support (Kang, 2007). In order to make the bolt play an active supporting role, it needs to ensure the installation quality of bolting. Thus the bolts can supply a high initial anchoring force and control the deformation of surrounding rocks (Shan, 2009; Wei, 2012). Moreover, bolt supporting is a concealed work. Once installation quality problems appear; it will be difficult for effective detection and screening (Xie, 2008).THE PROBLEMS OF BOLT INSTALLATION QUALITY IN COAL MINE AND ITS DETECTIONThe Problems of the In Situ Bolt InstallationDue to the problems in installation environment, machine, and technique, and workers proficiency (Li, 2003), there are many problems exist in bolt installation. If the borehole depth is too long, the anchoring agent will accumulate at the bottom of the bore, which reduces the anchoring length. Furthermore, if the borehole depth is short due to the poor geological condition, the exposed part of the bolt will be too Jong and the pallet cannot cling to the rock face, which prevent the pre-tension from being applied. The pre-tension is very important for bolt installation. If pre-tension is insufficient the rock bolt cannot control the deformation of surrounding rock efficiently and the bolt anchoring force will decrease considerably. The bolt length is another important parameter for anchoring quality, which will affect the control area of bolt supporting. In addition, the cleanness of drill hole has a great influence on the effective anchorage length of bolt. If the drill hole cleaning is not enough, it will directly affect the anchoring agent and the contact area of surrounding rocks, which will decrease the effective anchorage length and initial anchor-force."

Jan 1, 2016

By F Ouchterlony

Soviet precursors to Cunningham’s Kuz-Ram model from 1983 are described. They are rooted in the mean fragment size and Rosin-Rammler (RR) fits to sieving data and rely on approximations. Three versions of Kuz-Ram model are presented and all three are de facto based on the median fragment size x50, even if the term mean is used in the papers. This discrepancy caused Spathis in 2004 to suggest a correction procedure for the Kuz-Ram rock factor A, which was said to explain some of the missing fines in the model. This correction, while applicable to Cunningham’s 1983 paper, does not apply to his 1987 paper in which he presents his own A factor. Common fixes of the Kuz-Ram model’s fines issue are fragmentation models where the fines are mainly generated in a crushed zone around a blast hole. This is contradicted by careful model blasting tests. The lack of a largest block size in the RR function may lead to spurious values of the uniformity coefficient n, e.g. in conjunction with image based fragmentation measurements or crusher modeling. These issues may be solved by using the transformed RR function, which has a largest block size xmax or its replacement by the Swebrec function such as in the KCO model.

Jan 1, 2016

By N. Moemise, M. B. Shongwe, P. A. Olubambi, M. M. Ramakokovhu

"Near-infrared (NIR) spectroscopy sorting technology is incorporated in an automated optical mineral sorter that can discriminate between materials using the differences in characteristics when exposed to near-infrared radiation. During September 2014 to April 2015, a pilot plant that utilized NIR technology to discriminate between kimberlite and waste materials was commissioned to determine the viability of including this technology in the diamond winning process flow sheet at Cullinan Diamond Mine. The plant was used to minimize the waste content in the size fraction -70+35 mm that reports to the crushing section and then to the dense media separation process. This paper describes the initial test work, conducted at Mintek, that led to the decision to conduct a pilot-scale study. The mineralogical characterization of the feed and product streams to establish the sorting criteria and the operational data obtained during the pilot plant campaign are described. The results indicated a good possibility of discriminating between the kimberlite and waste material using NIR technology. However, the consistency of discrimination was not good enough to avoid the risk of potential diamond loss. Furthermore, a lower than expected availability of the machine reduced the throughput capabilities. IntroductionUsing near-infrared spectroscopy (NIRS) technology for ore sorting is a new concept for the mineral processing and mining industry. NIRS has been used for decades in the laboratory for the identification of pure minerals, and has its roots in the recycling, food, and pharmaceutical industries (Salter and Wyatt, 1991; Robben et al., 2009). Ore sorting in itself is not a new concept; it was introduced during the Stone Age with handsorting being the first method to separate valuable materials from gangue (Wills and Napier-Munn, 2006; Sassos, 1985). However, over the years the scale of mining has increased and hand-sorting has become challenging to implement (Joensson, 2014).Sensor-based sorting is an advanced technology that can help overcome problems such as ore dilution experienced in mineral processing operations. The benefits are lower energy and water costs, reduced ore dilution, lower environmental impact, and improved profit margin (Mathew, 1974; Jonsson, 2014; Salter and Wyatt, 2009; Death et al., 2009). In sensor-based sorting, materials are mechanically sorted based on certain physical properties that are detected by a sensor (Dalm, 2013). Research has found that with NIR scanners it is possible to obtain a ‘fingerprint’ of a sample that is directly related to its mineralogical composition. According to Woutruba et al. (2009), molecules absorb NIR radiation by means of electronic and vibrational transitions. Nowadays, there are many sensors available in the market that utilize different material properties; the choice of a sensor is dependent on the mineralogy of the ore."

Jan 1, 2016

By Mike Hall, Tim Kelly, Mohammad Reza Jafari, Ulf Georg Gwildis

"Qatar’s capital Doha is undergoing major infrastructure improvements including a multiphase stormwater management program. Although located in an arid climate, Doha experiences flooding during rainfall events. Dewatering operations and rising groundwater levels add to the management needs. To address those needs, construction of the Musaimeer collection tunnel along Doha’s southern rim is being followed by a marine outfall tunnel connecting a pump station to a dispersion field 10 km offshore. Qatar’s geology is characterized by sabkha deposits, a series of predominantly weak and karstic rock strata that creates challenging conditions for mechanized tunneling, as highlighted by the uncontrolled flooding of a tunnel boring machine (TBM) used on the Doha Metro tunnels. Risk associated with these challenges is magnified for the outfall tunnel by drive length, sub-sea elevation, and a single access point. This paper describes the outfall exploration strategy and design decisions made in light of experience gained during the collection tunnel construction. CONTEXT – STORMWATER MANAGEMENT PROGRAM Qatar has an arid climate with an average annual precipitation of less than 100 mm. Precipitation is mostly confined to the winter months when rare, but occasionally heavy rainfall events easily lead to flooding in Doha’s metropolitan area. Its coastal location and flat topography a few meters above the sea level mean that the depth to the groundwater table is generally shallow. The karstic aquifers in the regional dolomite and limestone series contain groundwater of high salinity, which is not suitable as a potable water source. For supplying Doha’s population of more than 900,000 (2014) with potable water, the Ras Abu Fontas seawater desalination plant is operated about 10 km south of the city. This potable water production capacity is crucial for Doha’s development and – in conjunction with overirrigation and leaking sewage tanks – is also the root cause for rising groundwater tables that have been observed over the past years."

Jan 1, 2016

By Longjiang Li, Song Mao, Zhengyang Qiao, Qin Zhang, Guizhou University, Ling Wang

"After a study on the advantages and disadvantages of flotation column, according to the limitation of ordinary flotation column only is used for a flotation of microgranular minerals, the paper designed a new kind of layered convection coarse particle flotation column.Using a bauxite to test the rationality of the flotation column.The test results show that the new layered convection coarse particle flotation column is feasible.It has certain advantages about coarse particles flotation.INTRODUCTIONFlotation column has many advantages, for example,a simple structure, high efficiency and energy saving, the obvious advantage of fine particles flotation , the index superior and so on. The advantages gradually getting people's recognition. Research of flotation column has been a breakthrough, however, due to it only is used for the flotation of microgranular minerals, and the microgranular mineral particles will lead to a series of problems, and makes the processing cost is increased. Due to increase grinding fineness can save the grinding time and reduce the cost of grinding, also can avoid the disadvantage of fairly granular mineral particles cause a deterioration in the flotation. So it is necessary to research a kind of coarse particle flotation column.After a research on the advantages and disadvantages of flotation column, the authors designed and manufactured a new layered convection coarse particle flotation column, the flotation column both in theory and operation is better than flotation machine.DESIGN OF THE LAYERED CONVECTION COARSE PARTICLE FLOTATION COLUMNAdvantages and Disadvantages of the Traditional Flotation ColumnIn the field of mineral processing, as the increasing proportion of ore that has low grade, fine dissemination size, complex mineral composition characteristics. The limitations of traditional flotation machine is increasing[1],for instance, the high energy consumption, severe wear, inconvenient configuration , large amount of maintenance and so on. Compared with flotation machine, the flotation column with high separation efficiency, low investment and production cost, covers a less area low installation cost, less reagent dosage, more suitable for separation of fine particles and can automatically control, etc[2]. At present, the ore is facing the world energy crisis situation, and becoming increasingly difficult to flotation. So it is important to invent a coarse particle flotation column."

Jan 1, 2016

By Vasiliki Founta, Andrew J. Whittle

"This paper describes the development of a 3D finite element model for predicting ground movements caused by construction of 7.1 m diameter twin bored tunnels for the Crossrail project in London using Earth Pressure Balance (EPB) machines. The model uses the commercial FE code, Plaxis 3D, to represent the face pressure, conical shield, grouting process and activation of precast segmental concrete lining systems through a set of boundary conditions that advance through the soil mass along a prescribed trajectory. Soil behavior is described using the Mohr-Coulomb soil model with input parameters calibrated from laboratory element tests. The analyses focus on the performance of the EPB tunneling machines in greenfield conditions beneath Hyde Park, where the tunneling occurs within deep layers of relatively uniform London Clay. The model predictions are in good agreement with surface and sub-surface vertical settlements measured at a well-instrumented section, but tend to overestimate the measured lateral displacements towards the tunnel. Ongoing studies are focused on the role of soil behavior and the approximations in FE model predictions of tunnel-induced ground deformations. Introduction Since their introduction in the 1970’s, closed-face Earth Pressure Balance (EPB) machines have become widely used for soft ground tunnel construction. The EPB design relies on a screw conveyor system to regulate the pressure of the excavated soil/spoil within the head chamber and hence control stability at the face of the machine. One of the key design issues in the application of EPB machines is to establish how control parameters, including the advance rate, face pressure and grouting processes (used to compensate for the tail void at the rear of the shield and to infill gaps between the precast lining rings and surrounding soil) affect and/or control the far-field ground movements. For closed-face systems, short-term deformations are associated with ground losses at the face, overcutting and ploughing of the shield and poor control of grouting in the tail void; while long-term deformations can occur due to consolidation and creep within the surrounding soil (and are closely connected to the seepage boundary conditions;e.g., Laver & Soga, 2012). The control parameters for advancing the EPB machine can have a significant effect on the magnitude and distribution of the far-field deformations. Therefore, analyses of the ground response to tunneling require accurate modeling of the soil stratigraphy and constitutive behavior as well as the construction process. Finite element (FE) methods have been used to simulate tunnel construction since the early 1980s, but only a few studies involved three-dimensional modelling of mechanized tunneling (e.g., Finno and Clough 1985; Bernat and Cambou 1999; Swoboda and Abu-Krisha 1999; Dias et.al. 2000; Melis et.al. 2002; Kasper and Meschke 2004; Möller 2006). In order to get a better understanding of the effect of the construction process and soil properties on the development of the ground deformations more comprehensive models of tunnel excavation and tunnel support are required in order to capture the 3D nature of mechanized tunneling and the effect of construction parameters such as advance rate, face and grout pressure."

Jan 1, 2016

By Bahjat Khoshaba, Bern Klein, Haixing Yan, Libin Tong, Andrew Bamber

"When a conductive or magnetic particle was put into an electromagnetic field introduced by an electromagnetic sensor, the particle can influence the electromagnetic field which can be used to characterize this particle. The electromagnetic technology based on eddy current theory was explored to investigate its potential in both the separation of minerals and the pre-concentration of a base metal ore. Samples tested in the study included the minerals obtained from Ward’s Science and the low grade copper ore particles obtained from Mount Polley Mine. The effects of mineral type, sensor frequency, particle size, particle position on the sensor surface, and particle lift-off on the magnitude and phase of the electromagnetic spectra were investigated. The electromagnetic spectra of various minerals show that it is possible to separate chalcopyrite or magnetite from tested minerals, simply based on the magnitude of the spectra. The spectra of the ore particles were determined by the mineral in the particles with the strongest signal. The effect of the pre-concentration of the low grade copper ore is determined by the association of chalcopyrite with magnetite. Direct sorting is the mechanism in the separation of mineral particles, while indirect sorting is the mechanism for low grade ores.INTRODUCTIONSensor-based sorting technologies include radiometric, X-ray transmission, X-ray fluorescence, near infrared, photometric, inductive, microwave heating and so on. Sorting not only discards barren rocks away from the concentrator but also recovers metal bearing that would be lose to the waste dump. The benefits of pre-concentration using sensor-based sorting are achieved on reduced energy consumption for comminution and reduced water usage on a volume per weight of metal basis (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). Amongst others, high frequency electromagnetic sensors were developed for ore sorting at MineSense Technologies Ltd. and are subject of this paper. Improving the understanding of ore heterogeneity is the basis for developing a successful semi-bulk or bulk sorting systems by incorporating the sensors in the material handling equipment (MineSense Technologies Ltd., 2016). The present study focuses on the bulk sorting potential and bulk sorting mechanisms of the electromagnetic technology in the pre-concentration of minerals or ores."

Jan 1, 2016

By G. Deschênes

"In 2013, as the prices of precious metals dropped, investors moved their positions to equity markets for higher returns. As a result, the price of gold dropped further to below US$1200 per ounce, prompting additional substantial outflows from gold investments. In response to lagging gold prices, major gold producers initiated large asset write-downs and cost-cutting programmes. In 2015, this trend continues and gold mining stocks are close to lows not seen since the global financial crisis (GFC) of 2008. In the current economic climate many projects have marginal economics, and the number of projects that have competitive development and production costs is declining. A competitive edge is particularly important with the decreasing grades of orebodies, increasing complexity of the mineralogy, and increasingly demanding environmental constraints. In addition, higher cost producers seek to optimize their process t o reduce operating costs.This paper presents some highlights of three case studies on optimization of gold leaching strategies that improved the economics of brownfield projects. Processing of sulphide-bearing ores was optimized by using the synergy between cyanide, lead nitrate, and oxygen. The outcomes were significant reduction of retention times while maintaining or increasing gold extraction and reducing cyanide addition and effluent treatment costs. A stirred tank reactor experimental programme led to direct implementation of reliable leaching strategies from laboratory scale to production. This approach resulted in savings of $2.2 million to $15.2 million on the three brownfield projects discussed in this paper."

Jan 1, 2016

By R. M. LaDouceur, C. A. Young, W. Nicholas

"Salicyl hydroxamic acid (SHA) adsorption on two rare earth oxides, lanthanum and yttrium, was studied. Adsorption at both surfaces occurred in two stages. Initially, the monovalent anionic collector appears to adsorb significantly and instantaneously in stage one and then becomes sluggish in stage two presumably because the initial stage passivated the surface. By comparison, adsorption during the sluggish second stage with lanthanum oxide did not stop but with yttrium oxide essentially stopped. Surface monolayer formation could not be observed in either of the two cases. Both stages appear to be due to multilayer formation of a surface precipitate as proven by Raman Spectroscopy for lanthanum oxide but inferred for yttrium oxide. Unlike the use of octyl hydroxamate as stated in the literature, increasing temperatures do not increase adsorption such that flotation of rare earths with SHA may be performed at room temperature leading to improved recoveries as well as significant energy savings. INTRODUCTION Rare Earth Elements (REEs) are comprised of the 15 lanthanides along with scandium and yttrium. The REEs with lower atomic numbers are relatively more abundant and are categorized as light REEs. On the contrary, the REEs with high atomic numbers are less abundant and referred to as heavy REEs. They are not really “rare” and, in fact, some of them are quite abundant in the Earth’s crust; it’s just that they “rarely” exist in concentrated deposits but rather are found dilute and practically everywhere. REEs share very similar physico-chemical properties but, because many of these properties are unique, they have gained enormous importance in recent times making several critical and strategic pending their use. For example, REEs have found extensive application in phosphor coatings, magnetics, and automobile cracking catalysts. Early technology was not advanced enough to produce commodity level production of the REEs and can be attributed to REE-bearing ores containing many rare earth minerals (REMs), not just one. In this regard, there are numerous REMs but bastnaesite, xenotime and monazite are considered to be the most common. Bastnaesite is a fluorocarbonate whereas the other two are phosphates. The separation of the individual REE-bearing minerals from the ores is not an easy task since they also exhibit very similar properties. Consequently, when flotation is used, it is done to produce bulk REM concentrates. For REM flotation, it is well established that octyl hydroxamate is more selective than fatty acid collectors (Pradip and Fuerstenau, 1983 and 1991). Liu et al. (2006) indicated that hydroxamates are the most common collectors for REMs. Pavez et al. (1996) studied the adsorption of oleic fatty acid and octyl hydroxamate on REM surfaces. Cui et al. (2012) studied the interaction of octyl hydroxamate with various REMs surfaces using various spectroscopic techniques such as XPS, FT-IR and Raman along with electron microscopy and concluded that such techniques offer ample information to establish adsorption mechanisms. Ren et al. (1997) studied napthalenic hydroxamic acid as a unique collector for flotation of REMs from bastnaesite ore and indicated that more selective collectors were needed. From these studies, it is clear that the quest of more selective collectors is essential but understanding how they adsorb at mineral surfaces is prerequisite to improving flotation performance."

Jan 1, 2016

By G. Danha, D. Glasser, D. Hildebrandt, N. Hlabangana

"In this work, we apply a method known as the attainable region (AR) technique in order to optimize the milling and leaching process of a low grade gold ore. No work on the application of the AR optimization technique has been done yet on a joint milling and leaching process. The advantage of the AR approach lies in its ability to simplify the optimization problem, as searching over a defined set for the maximum of an objective function is a fairly standard procedure. The objective function we selected was that of optimizing a linear function of the value of the recovered material minus the cost of both milling and leaching. Using the three variables (milling time, leaching time and recovery), we constructed a 3D plot and used it to obtain all the possible recoveries from the different milling and leaching times. The optimum for our chosen objective was then found by overlaying a contour plot of the objective function on the 3D plot. Our results show that the optimum was obtained at 90 % recovery with a profit value of 600, milling time of 30 minutes and leaching time of 1750 minutes.INTRODUCTIONAfrican countries are facing a general increase in demand for electrical power. In South Africa, the demand is now surpassing the supply from ESKOM, the main electric power provider of the country. This has resulted in load shedding strategies being implemented in many local communities in an attempt by ESKOM to cope with the high demand. A potentially better approach is to propose use of energy efficient technologies in the country’s largest power consuming industry; the mineral processing sector.In mineral processing, milling is the highest consumer of energy. The objective of carrying out milling is not merely to reduce the particle size of the feed material, but also to liberate the constituent minerals that make up an ore. This is done so that valuable minerals can be separated from the gangue, in downstream processes, such as leaching. However, the milling process is generally performed relatively poorly, and at a considerable expense in terms of electrical power utilization. Tomanec and Milovanovic (1994) estimated that milling accounts for more than 50 % of the total power used in the concentration process, but this can rise to as high as 70 % for hard or finely dispersed and inter-grown ores. Apart from being relatively wasteful of energy, the milling process is also inefficient with regard to mineral liberation because of the indiscriminate nature of the grinding force."

Jan 1, 2016

By Janice Zinck, Maziar E. Sauber

"To counter the recent uncertainty in the rare earths market, diversify the supply source, and help meet the future demand in this sector Canada initiated development of several new rare earth deposits. In the past few years, a number of various studies on rare earths plant design have taken place mainly covering process development, process selection, and flowsheet design. The purpose of this paper is to provide an overview of known domestic and potential resources and reserves of rare earths and their status quo with a focus on the metallurgical processes using the information available in the public domain. Plant designs currently under consideration in Canada are reviewed and evaluated. An outline of the areas of opportunity for selective innovation and technology development in the rare earths flowsheet development and the associated risks and rewards is provided.INTRODUCTIONThe rare earth elements (REE) have a very small annual market, but they are categorized as very strategic metals vital to global economic growth due to their indispensability to the development of modern defence system, green technologies and electronic applications. The International Union of Applied and Pure Chemistry (IUPAC) defines the REE as the 15 elements on the lanthanide series on periodic table of elements, plus yttrium and scandium. REE are classified as light rare earth elements (LREE; La to Gd), and heavy rare earth elements (HREE; Tb to Lu). Physical properties and chemical reactivity of yttrium is similar to those of HREE, thus it is categorized as such. Properties of scandium are not similar enough to classify it as either a LREE or HREE (Weng et al., 2015; Sappin & Beaudoin, 2015). However, the mining industry does not always abide to this definitive classification of the split between LREE and HREE. Therefore, in a comparative study of projects, there is a need to pay attention to how the elements are classified."

Jan 1, 2016

"A cationic surfactant, tetradecyl tributyl phosphonium chloride (TTPC), was first used as a collector. Flotation characteristics of muscovite using TTPC have been investigated through flotation tests. And dodecyl trimethyl ammonium chloride (DTAC) was tested for comparison. Their adsorption mechanisms on muscovite surface were clarified using zeta potential measurement, DFT calculation and molecular dynamics (MD). The flotation results indicate that the recovery of muscovite decreases when the pH increases in the presence of surfactants. When a maximum of recovery was reached, the dosage of TTPC was 2×10-5mol/L which was half of that of DTAC. Zeta potential measurements confirm that the TTPC displays a stronger collecting power than DTAC and is a superior collector for the muscovite flotation. DFT calculation and MD simulations show that TTPC interacts with the muscovite mainly through electrostatic attraction and hydrogen-bonding. The conclusions drawn from purely theoretical computations matched remarkably well with the experimental results. Keywords: Quaternary phosphonium salts; Flotation collectors; Flotation INTRODUCTION Muscovite mica is widespread in igneous, sedimentary and metamorphic rocks. It has the general composition KAl2(AlSi3O10)(OH)2. Muscovite mica exhibits perfect cleavage along the (001) plane, which exposes interlayer potassium ions[1-3]. In aqueous suspensions, the potassium ions readily enter into solution, leading to the development of a net negative charge on the (001) plane[4-6]. The surface of the muscovite mica is negatively charged at all pH > 1[7]. Due to the negative charge surface over the whole pH range of 2–12, the muscovite mica would not be expected to respond to anionic collectors in the absence of an activator. Conversely, the mineral is readily recovered using cationic collectors. However, until now, various amines and their derivatives (with N atoms as the center) are still the only available cationic collectors which still had their shortcomings such as weak selectivity, low flotation speed. Since few types of cationic collectors could be used, in some sense, the limitations of collectors are increasing significantly and the cationic flotation is facing more and more challenges. Quaternary phosphonium salts, as novel cationic surfactants, are widely used in antimicrobial, catalysis and surface modification field due to their biological activities, hydrogen bonding capability, stability and superior group electrical property[8-10]. There are a number of processes where quaternary phosphonium salt surfactants have shown better properties than quaternary ammonium salts and amines. Although the adsorption of quaternary phosphonium salt surfactants at the bacterium–liquid interface has been studied thoroughly, the case of adsorption in mineral surface has not been investigated thus far."

Jan 1, 2016

By Dale S. Preece, Ruilin Yang

Shock wave physics is an important part of air-deck behavior since the bulk explosives in the column impart a shock into the air-deck where the air shock then passes through the air-deck at a rapidly attenuating velocity. Through both high-fidelity modeling and shock physics theory it is shown that the resulting pressure in the air-deck is two orders of magnitude less than the detonation pressure of the explosive. The induced air blast reflects from the bottom of the borehole and this reflected pressure, even though doubled, is still approximately two orders of magnitude less than the detonation pressure. Air-shocks will ring back and forth in the air-deck for a few tens of milliseconds while the adjacent explosive column(s) are detonating. Transmission of the initial shock through the air along with reflections is an intensive energy consuming process. Energy balance results in shock heating of the air and a temperature increase. However, the increased temperature of the air is also orders of magnitude less than that of the explosive detonation products immediately behind the detonation front. Replacing high energy explosives with zero energy air-decks in a blasthole will always have a negative impact on the adjacent rock fragmentation and movement.

Jan 1, 2016

By Mike Johnson, Greg Andrews, Niels Verbaan, David Dreisinger

"The Search Minerals Foxtrot project in Labrador represents a significant Canadian resource of rare earth elements rich in the sought after heavy rare earth elements (19.8% HREE/TREE). A preliminary economic assessment of the project indicated that the project is technically feasible and economically attractive. A variety of metallurgical test programs have been undertaken which have led to significant streamlining and simplification of the process flowsheet. The improved flowsheet should allow Search to reach production earlier and will use conventional processing equipment. The results of these test programs are presented and discussed in this paper INTRODUCTIONSearch Minerals Inc. (Search) is exploring and developing a number of deposits for rare earth element (REE) recovery in Labrador, Canada. The Port Hope Simpson District is in the southeast of Labrador and is highly prospective for heavy and light rare earth elements. The Foxtrot deposit sits within the Port Hope Simpson REE District (Figure 1), which is 70 km long by up to 10 km wide. The infrastructure available at Foxtrot is excellent; a deep-water port, air strip, and road and power infrastructure are pre-existing at St. Lewis. The three communities of Port Hope Simpson, St. Lewis and Mary’s Harbour are in close proximity to the site."

Jan 1, 2016

By Charolett Hayes, A. L. Russell, Anthony J. Bednar, Jared Smith, Valentine A. Nzengung, Stephen L. Pilcher

The manufacture of Energetics Materials (EM), including maintenance and demilitarization of munitions causes dangerously high levels of explosives residues to be harbored in building features. The two commonly approved methods of decontaminating energetics contaminated equipment and building features are thermal treatment and steam washing. The current regulatory environment is generally becoming more stringent and unfavorable to thermal and steam decontamination because of their adverse impact on air, soil, and water and their ineffectiveness to completely remove accumulated energetics from foundation cracks, internal and external piping, voids in walls and ventilation systems, and internal cavities of fixed equipment. However, chemical destruction of energetics, especially high explosives, is gaining acceptance as a safer, cost-effective and environmental friendly alternative to thermal and steam decontamination. Organic explosives, including nitramines and nitrate esters are oxidized organic compounds that are susceptible to chemical oxidation and reduction reactions. Under suitable conditions, a chemical reagent consisting of sulfur-based bulk reductants (neutralent) commercialized as MuniRem generates highly reactive free radicals that very rapidly degrade many energetic compounds to innocuous end products while stabilizing metals as the insoluble metal sulfides.

Jan 1, 2016