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By R Lastra, J. A. Finch

An artificial standard material has been developed and used to examine the robustness of some of the procedures for correcting stereological bias. Different mineral liberation distributions were constructed from the standard material. The particles were mounted, sectioned and the sectioning data measured with an electron microscope interfaced to an image analyser. Four correction procedures were used and the corrected and true liberation distributions compared. It was found that the large-sections correction provided a simple, uncorrupted correction. Hill's fast approximation performed well except in cases of narrow liberation distributions; the sectioning data appeared to support the assumption that the locked section and locked particle distributions are identical. Barbery's correction performed well in most cases, having difficulty only with the very irregular liberation distribution. The PARGEN correction was able to provide a good estimate of the true amount of free material, but had difficulty in predicting the locked particle distribution

Jun 21, 1905

By M. D. Gibbs, T. N. Smith, B. Verbaan

When heated in the absence of oxygen, pyrite from refractory gold concentrates decomposes endothermically to pyrrhotite, releasing sulphur. The decomposition starts at the particle surface and progresses inwards, leaving an adhering layer of porous pyrrhotite. Use of the conventional shrinking-core model implicitly assumes a negligible partial pressure of sulphur in the bed, but this pressure is in fact at least equal to the equilibrium vapour pressure of sulphur over pyrite, constituting the principal control of the rate of decomposition. Further experiments showed a decrease in reaction rate as the conversion increased. Both phenomena are attributed to the persistence of non-isothermal conditions in the fluidised bed during pyrolysis, caused by the endothermic nature of the reaction and the relatively slow rates of heat transfer to particles and vapour removal from the bed. Equipment must be developed to maximise these two parameters

Jun 19, 1905

1994 estimates for Porgera are probable and proven reserves of 58 200 000 t of ore grading 5 g/t Au. Gold mineralisation is related to an intrusive complex emplaced at shallow levels in poorly consolidated sedimentary rocks. The complex is located in a zone of fold-and-thrust deformation, whose formation may have been initiated shortly before emplacement and continues locally today. Abundant primary magnetite in the complex gives an intense, 5 km wide aeromagnetic anomaly. The deposit formed during two main stages of mineralisation, the first related to early magmatic-hydrothermal activity and the second representing later epithermal overprinting centred on the Roamane fault. Hydrothermal alteration followed closely on emplacement indicating a close genetic relationship between magmatism and mineralisation. Both stages of hydrothermal activity post-date and overprint early propylitic alteration. Several factors have acted in unison or sequentially to concentrate metals at the deposit, including an extensional or trans-tensional tectonic setting within an arc or collisional environment, the exsolution of a magmatic hydrothermal fluid prior to sulphur saturation in the melt, the development of the hydrothermal system into one favourable for transporting gold, the action of late-stage faulting in focusing epithermal fluid flow, and the role of dissolved gases in promoting fluid phase separation and high-grade ore deposition

Jun 19, 1905

By T. M. Williams, P. M. Green

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The sediment geochemistry of streams draining Southern Uplands and Lake District turbidites was compared with lithogeochemical data for the source greywackes, using stratigraphically defined catchments. Several systematic trends in element abundance variation between source and stream sediment can probably be applied more widely to interpretation of drainage geochemistry. Pb and Zr increase markedly from source rock to sediment, by adsorption on clay and zircon grain concentration. Variation of feldspar-related elements Rb, Sr, K and Ba appears to be controlled by source grain size and compositional maturity. Ni shows surprisingly little change and Fe and Co are only slightly raised. Cr is particularly useful, with variations superimposed in anomalously high regional levels. Abrupt changes in Cr distribution in stream sediment coincide with stratigraphical boundaries, allowing drainage data to be used as a surrogate for whole-rock values

Jun 19, 1905

By M. J. Beus, B. Stewart, S. Iverson

Ore-pass hazards are a significant safety problem in US underground metal mines. From 1975 to 1995, nearly 75% of injuries during pulling or freeing of ore-pass chutes were related to falls of broken rock or the use of hand tools. Risk assessment methods are being used to identify the most probable causes of ore-pass failures and analyse the factors that result in malfunctioning or safety reduction. Static and dynamic loads are being measured in the laboratory and by field testing, with data from test ore passes compared with mine data to characterise true system behaviour. Computer modelling using closed-form solutions, finite element analysis and a newly developed particle flow code are being use to predict loads from ore and waste flow and impact. Preliminary results indicate that dynamic impacts may be much less than expected, as a result of damping factors, normal and shear stiffness and mass frictional characteristics

Jun 19, 1905

By A. D. Mukherjee, H. N. Bhattacharya

Middle Proterozoic sulphide ore mineralisation occurs in isolated blocks of the NE-SW trending Delhi fold belt composed of Delhi Supergroup rocks. The Ajari-Basantgarh-Pipela belt forms part of the longest, widest and westernmost tectonic unit of the Delhi fold belt and consists of amphibolites, metapelites, quartzites and carbonates. The metapelite lenses and associated amphibolites host pyritic copper mineralisation. Mineralisation takes the form of sheet-like bodies consisting of ore lenses of various sizes interlayered with host or associated rocks. Massive, banded and disseminated varieties of ore are found. Pyrite is dominant with subordinate chalcopyrite and sphalerite. Pyrrhotite, galena, cubanite, mackinawite, marcasite and freibergite constitute the minor minerals. The characteristic features of the ores suggest a possible correlation with Besshi-type deposits, and the closely associated amphibolites are interpreted as low-K tholeiites of a fore-arc setting

Jun 19, 1905

By W. Petruk, M. J. Matos

An aplite ore from Guarda in northern Portugal, containing albite, microcline and quartz and muscovite gangue was studied to identify conditions for extracting the feldspar minerals. The large amounts of quantitative mineralogical data needed to evaluate grinding behaviour were provided by automated image analysis. The images were acquired on polished surfaces by measuring back-scattered electron signals produced with a microprobe. Minerals were identified from X-ray spectra and discriminated by grey level and element-characteristic X-rays. The quantities and size distributions of the minerals were determined by measuring thin sections of unbroken ore to predict the grind required to liberate the feldspars. The ore was then ground to -1.7 mm, polished sections were prepared from sieved fractions and the quantities of mineral species and apparent total liberation were determined by analysis. The predicted and measured liberations were compared and the grinding behaviour of the ore interpreted. In an appended correction, the correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

By G. G. Roy, R Shekhar

Pachuca tanks are extensively used for the cyanide leaching of gold and the carbonate leaching of uranium, processes in which oxygen mass transfer plays a very important role. Experiments were carried out to clarify the effect of design and operating parameters on oxygen mass transfer. Parameters such as the ratio of tank height to tank diameter, the ratio of draught-tube diameter to tank diameter and the tank design were found not to influence oxygen mass transfer. Results also showed that equal superficial gas velocities may be used as a criterion for scaling up oxygen mass transfer in both full-centre-column and free-air-lift Pachuca tanks with clear water. A volume-averaged, volumetric gas-liquid mass-transfer coefficient (k'av) was used to characterise oxygen mass transfer in full-centre-column tanks. The axial dispersion model was used to determine k'av. The resulting model used only tank geometry and air flow rate as inputs for the prediction of k'av in industrial-scale tanks. Predictions from the model show clearly that "local" mass-transfer coefficients, measured at one or two locations, may not adequately represent gas-liquid mass transfer in industrial tanks. It is therefore necessary to obtain an estimate of k'av

Jun 18, 1905

The first part describes a model (the C model) based on the motion of the grinding charge. The charge is treated as a continuum, which allows analytical solutions to the equations that are developed. The C model is equally applicable to ball-, semi-autogenous and autogenous mills and contains a description of the power draw of both the cylindrical section and the cone-ends. Differences between the power draw of grate- and overflow-discharge mills are described from consideration of the different shapes and compositions of their charges. A large database of industrial mill data is used to demonstrate the accuracy of the model. Part 2 describes a simpler, empirical model (the E model) whose performance is based on that of the C model. The same database was used to assess the predictive capabilities of the E model. The model was shown to be only slightly less accurate than the C model despite its much simpler structure

Jun 18, 1905

By G. E. Christidis, P. W. Scott

The deposits were formed from low-temperature alteration of pyroclastic rocks. Properties investigated include their cation exchange capacity, swelling capacity, pH, rheological properties, the green and dry compressive strengths, shatter index, wet tensile strength, compactability and permeability. It was found that deposits with abundant opal-CT have poor physical properties. The rheological and swelling properties were found to be influenced by the bentonite grade (smectite content) and the degree of disaggregation of the smectite quasi-crystals. The only deposits of high grade which had good foundry properties were those with no opal-CT. Hydrothermal alteration was detrimental to the physical and chemical properties of bentonites in that it decreased the smectite content and the pH and changed the smectite layer charge and the lattice dimensions

Jun 18, 1905

By L Casari

A study of samples from three sectors of the mine, which was worked from Roman times to 1991, revealed different textures, mineral associations and distributions of trace elements in the sulphides. In the last decade before closure, grades of sphalerite concentrate were in the range 51.67-53.30% Zn and 2.21-2.86% Pb and of galena concentrate 69.43-71.62% Pb and 4.70-8.36% Zn, while the estimated by-product germanium content of sphalerite concentrates sold was 300-400 g/t. Passing the different run-of-mine materials through the same concentrator flowsheet produced middlings and tailings during the preconcentration processing. Separate and alternative treatment of run-of-mine products would have yielded improved recoveries of sphalerite and galena and better values of by-product germanium and cadmium

Jun 18, 1905

By Seong-Taek Yun, Chil-Sup So, Seung-Jun Youm

The greisen-bordered quartz veins are spatially, temporally and genetically associated with a late Cretaceous granite intruding an early Palaeozoic, limestone-rich formation. Paragenetic data indicate three stages of hydrothermal mineralisation, the first typically in or within 500 m of the granite stock and showing vertical zoning between deeper Mo and higher W, the other two more abundant in the upper and outer parts of the mineralised area. Fluid inclusion and stable isotope data indicate that hydrothermal veins formed over a temperature range of 120-395 degrees C from low-salinity fluids. Early wolframite and molybdenite deposition in stage I occurred at temperatures of 300-395 degrees C from magma-derived, low-salinity, CO2-rich fluid, mainly as a result of fluid boiling and associated CO2 effervescence. Progressively larger volumes of local meteoric water entering the system led to the successive deposition of scheelite in stage I vugs, stage II base-metal sulphides and stage III fluorite-carbonates. Remobilisation of W and its later deposition of scheelite in the outer and shallower portions of the system occurred at 215-275 degrees C and stage II and III mineralisation from lower-temperature fluids that became progressively lighter in stable isotopes. It is concluded that the influx of meteoric water increased with distance from the cooling pluton

Jun 18, 1905

By D. K. Bose, R. H. Rakhasia, V. D. Shah, J. C. Sehra

A series of experiments was conducted to determine the effects of roasting temperature, soaking period and quantity of soda ash added. At a laboratory scale, under optimum conditions of roasting at 873 K for 2 700 s with soda ash 10 wt% in excess of stoichiometric, molybdenum recovery was 99%. The investigations indicate the technical feasibility of producing high-purity MoO3 by combining the roasting process with carbon adsorption/desorption. The process uses low-cost chemicals, can be scaled up readily and is free of the SO2 pollution generated by conventional roasting, as the sulphur content of the concentrate is converted to sodium sulphate

Jun 18, 1905

A study of the thermodynamic properties of magnesium chloride ammines was carried out with the ultimate objective that the thermal decomposition of the hexammine MgCl2.6NH3 may prove successful on a commercial scale for the manufacture of anhydrous magnesium chloride, which is required for the efficient electrolytic production of magnesium. The experimental data are presented in the form of an equilibrium diagram that aids the understanding of the conditions associated with the thermal decomposition of ammines

Jun 13, 1905

By O. E. Polter, W. J. N. Fernando

Smelter-grade alumina is usually produced by the calcination of gibbsite. The ideal energy requirements for the calcination of gibbsite have been analysed and compared with the actual energy consumption of some industrial calcination processes. The consumption of most of these is considerably in excess of the ideal. Methods suggested for calcining dry gibbsite feeds which claim energy savings of 10-14% consume 26-34% more than the ideal energy requirement for dry feeds. This study indicates that it should be possible to recover appreciably more energy, giving further improvements in fuel efficiency, both in existing gibbsite calcination processes and in methods that have been proposed for the stagewise calcination of dry gibbsite

Jun 13, 1905

By G. E. Pearse

Reports, discussions, a written contribution and two written replies are presented from 11 sessions on: Safety and compressed air; Ground movements; Geotechnical; Channel Tunnel (2 sessions); Machines; Case histories; Transport tunnels; Case studies; Site investigation; and Undersea tunnels

Jun 13, 1905

By E. H. W. Hornbrook, P. W. B. Friske

Paper presented at the 28th International Geological Congress, Washington DC, July 1989 (International geochemical mapping sessions). The objective of the programme is to establish and maintain a nationally consistent geochemical drainage database. Towards this end systematic surveys have been conducted since 1973. To date more than 200 surveys have been completed to the required standards, representing 180 000 sites and covering about 2 100 000 km2 throughout Canada

Jun 13, 1905

By G. G. Lambert

The paper traces the pattern of spontaneous combustion in the workings of what was originally Hemsworth Colliery, but since July 1967 is now part of South Kirby Colliery. Examination is made of the Barnsley Seam sections and the part played by the top section of the seam as it comes in close proximity to the main seam. In this area of the colliery nine mechanised faces were set away between the years 1953 and 1968, every one "fired" at the pillar edge and six "fired" at the face line when production had ceased. The paper deals with the different preventative measures used, from sandbag walls, cement injections, spraying with polyurethane, until finally using Mandoseal as a sealant. Since the latter method was first used, the last three faces worked in this particular area were all salvaged completely, without any sign of a heating developing.

May 23, 1905

By E. A. C. Chamberlain

New techniques for the continuous sampling and analysis of mine air are expected to replace traditional methods used for the early detection of spontaneous combustion. It has been established that the rate of evolution of carbon monoxide is the earliest indicator of incipient spontaneous combustion. Two methods of continuous monitoring of this gas are available and are now in use in the UK collieries. The first is the UNOR infra-red gas analyser, which is flameproof and may be used underground; the second is a system of tube bundles, which permits air to be drawn from any critical point in a colliery and analysed on the surface. Each system has its advantages and disadvantages but both provide the colliery manager with far more information on the condition of his pit than could previously be obtained by spot sampling and laboratory analysis. This paper describes the two systems presently in use and assesses likely future developments.

May 23, 1905

By M. Riddell

This paper describes the incipient heatings that occurred below ground in the High Main and Main seams at the mine between the years 1963 and 1966. The possible causes, effects and activities associated with such heatings are discussed in an attempt to establish the precautions necessary to minimize such occurrences. The assessment of as many "norms" as possible is made to enable the earliest detection and level of activity to be determined.

May 23, 1905