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By G. W. Jones, R. E. Kennedy

Most gasolines and naphthas are mixtures of paraffin- series hydrocarbons and comprise such substances as pentane , hexane , heptane , octane , and others up to perhaps dodecane . Many of these hydrocarbons , when mixed with the proper proportions of air and ignited , are highly explosive . It is due to this characteristic that gasoline has become so important as a fuel in internal -combustion engines . Gasoline and naphtha also are used in the industry as solvents and cleaning agents . Because of their explosive properties they are dangerous to use unless the composition is so chosen that the vapor pressure of the mixture is not high enough to produce explosive mixtures with air at the temperature at which they are used . Hydrocarbon mixtures may be made less hazardous by adding some incombustible liquid , such as carbon tetrachloride . Barrier reports the amount of carbon tetrachloride that must be added to different naphthas to render such mixtures free from fire and explosion hazards . He found that the amount of carbon tetrachloride that must be present in the final mixture of naphtha and carbon tetrachloride varied with the density of the naphtha . Of the naphthas tested the amount of carbon tetrachloride necessary to render such mixtures free from fire and explosion hazards ranged from 30 to 70 percent . .. Determination of the fire and explosion hazards of carbon tetrachloridehydrocarbon mixtures would be easy if the boiling points and vapor pressures of the two were the same at any given temperature . The fact that carbon tetrachloride boils at 76° C. while the boiling points of the hydrocarbons found in gasoline and naphtha may range from 37° , the boiling point of pentane ,

Nov 1, 1934

By A. U. Miller

Since coal -mining records have been kept , reports of all mining States show that each year the lives of many workers have been sacrificed in the production of coal , and Illinois has contributed its share , Illinois reports for the 50 years 1882 to 1932 , inclusive , show that 6,673 men were killed -- 6,121 underground , 340 in the shaft , and 212 on the surface . Of the fatalities underground , 3,116 were caused by falls of roof or sides , 1,111 by haulage , 630 by explosives , 577 by gas explosions , 139 by electricity, and 548 by other causes ; 166 of the shaft fatalities were caused by falling down the shaft , 143 by the cage , and 31 by other causes ; 108 of the surface fatalities were caused by railroad cars , 46 by machinery , and 58 by other causes . Most of those engaged in mining are still of the opinion that it is an extremely hazardous occupation and that it is practically impossible to operate without accidents ; however , students of safety in mining now believe that with the proper attention to accident prevention mining may be conducted with little , if any , greater accident rate than that of other supposedly hazardous industries . There is no mystery connected with accidents in mining ; reports show that the majority are due to two main causes , falls of roof and sides and haulage . Mining companies in Illinois , as well as in other States , have proved in the past few years that the hazards of mining , like those of other industries , can be controlled to a large extent and the mines operated with few if any accidents , provided a great enough effort is made by employer and worker . Although the past accident rate of Illinois may compare favorably with that of other mining States it is higher than it should be ; the fact that 6,673 men (an average of 133.46 per year) were killed in and around the mines of the State between 1882- and 1932 indicates that accident prevention should receive more consideration in the future than in the past .

Nov 1, 1934

By D. J. Parker

This report is based on data collected in and about the Liberty mine of the Liberty Fuel Co. by D. J. Parker and W. W. Kessler on December 13 and 14, 1933. An important phase of an examination to determine the general condition of a mine with respect to safety is the collection of dust samples from rock- dusted areas. Definite conclusions, based on intelligent interpretation of the analyses of such samples, can be reached only when the general condition of the mine is known. A similar examination and report were made on this property in January 1930 by D. J. Parker and R. I. C. Manning. Since that time much has been done by the management to improve safety conditions in this mine. The changes made will be noted in the course of this report. The mine is in Spring Canyon at Latuda, Carbon County, Utah, and is served by a branch line of the Denver & Rio Grande Western Railroad about 7 miles long and connecting to the main line near Helper, Utah. The writer desires to express his sincere appreciation for the many courtesies and helpful cooperation extended by Superintendent George Schultz and Mine Foreman F. W. Koelling.

Nov 1, 1934

By F. M. Goodwin, John Campbell, G. W. Jones

"INTRODUCTION The investigation of the general hazards of combustible gases and vapors in manholes owned by the Edison Electric Illuminating Co. and the study of methods for eliminating these hazards, conducted by the Bureau of Mines, the Edison Electric Illuminating Co. of Boston, and the Boston Consolidated Gas Co. since 1929, was continued during 1933.From May and through December 1933 these tests were supplemented by a study of the manholes of the New England Telephone & Telegraph Co. The test crew was under the direct supervision of John Campbell, superintendent of the Special Service Department of the Edison Electric Illuminating Co., and F. M. Goodwin, vice president of the Boston Consol¬idated Gas Co.The procedure of sampling manhole atmospheres and of shipping the samples to Pittsburgh was the same as that used heretofore. In previous reports the relative explosibility of the samples was calculated by adding the percentages of the illuminants, hydrogen, carbon monoxide, methane, and ethane, dividing the total by 6.5, and multiplying by 100. Experience has shown that the factor 6.0 is more nearly correct; therefore, this has been used in calculating the relative explosibility of all the samples listed in appendix A and B of this report. If gasoline vapor is present a smaller factor must be used.ACKNOWLEDGMENTSThe cooperative investigation was arranged through the interest and effort of W. C. Bayliss, president of the Edison Electric Illuminating Co. of Boston; W. C. Beckjord, vice president and general manager of the Boston Consolidated Gas Co., and A. C. Fieldner, chief engineer, Experiment Stations Division, United States Bureau of Mines. Thomas H. Haines, superintendent, Distribution Department of the Edison Electric Illuminating Co., cooperated heartily in furnishing both men and information for the work."

Oct 1, 1934

By G. L. Oldright, Virgil Miller

"INTRODUCTION The first ten papers of the series on smelting in the lead blast furnace described the operation at the custom smelter of the International Smelting Co., Tooele, Utah, and at the plant of the Bunker Hill Smelting Co., Kellogg, Idaho, which handled a very rich lead concentrate. These previous papers may be considered a picture of the traditional lead smelter treating custom ores and of the smelter that will treat the type of product likely to be made in the future - lead concentrates of an increasingly rich grade.The great plant at Trail is of special interest to those smelting lead products containing much zinc and faced with the necessity of transforming all of their byproducts into commodities which may be sold profitably. The plant is equipped to produce electrolytic zinc, lead, copper, silver, bismuth, and cadmium. Part of the sulphur evolved from treating the ores is converted into sulphuric acid. Complete fertilizers for agricultural purposes are also produced.The smelter of lead ores has long considered that zinc is one of the most difficult ingredients that he has to handle. Even with the gretat improvement in flotation practice today, the residues from electrolytic zinc plants leaching zinc concentrates must still be smelted for their lead content. Of the total gangue material not separated from the lead concentrate sent to the smelter, zinc is still one of the most notable in percentage. The most successful way of coordinating the over-all operations of a concentrator, an electrolytic zinc plant, and a smelter provided with a plant for re-treating the blast-furnace slag for its lead and zinc content must be of interest to many treating complex ores.ACKNOWLEDGMENTThe data in this paper were collected in cooperation with the Consolidated Mining & Smelting Co. of Canada, Limited, and its entire technical staff. Detailed acknowledgments of assistance received are given in the papers from which this one is briefed."

Sep 1, 1934

By J. J. Forbes

First - aid training is an essential part of safety programs in the mining industry , but it is only a means to an end ; first -aid training will not eliminate accidents , but unquestionably it is of considerable value in any accident prevention program . Numerous features should be incorporated in any efficient , well - developed safety plan ; in addition to first -aid training safety work , to be reasonably effective , should include the establishment and maintenance of a safety organization , safety competitions between mines or sections of mines , safety- inspection committees , accident - investigation committees , safety meetings of mine officials , safety bulletins and posters , employees ' safety publications , Holmes Safety Chapters (which provide for monthly safety meetings of all employees ) , and numerous other activities looking to safe operation of mine or plant . These features are supplementary to the fundamentals of safety-- adequate and effective supervision and discipline . Years of experience , however , have demonstrated that first - aid training is a good accident -prevention auxiliary and should be made an integral part of every company's safety program . Many safety-organization plans have failed because they have been based upon the assumption that the supervisory force should be given full authority and responsibility for achieving safety and eliminating accidents and that the workers , who are most vitally concerned , are nonessential . First -aid training causes the employees to feel that they have a personal and full participation in the safety program and is now available so readily that no individual or organization has any valid excuse for not having it . Early investigations made with a view to bettering health and safety conditions among the employees in the mineral industries demonstrated the need of prompt care of injured employees because , under the difficulties inherent in the occupation , seemingly unimportant wounds , when not treated promptly, became infected and caused permanent disability and even death . Many seriously injured persons , brought out of mines and plants by fellow workers who were ignorant of the approved methods of giving first aid or of safe means of transportation

Aug 1, 1934

By W. W. Adams

"The ninth yearly National Safety Competition covering the calendar year 1933, conducted by the United States Bureau of Mines, w participated in by 332 mines and quarries situated in 35 States. Enrollment represented as increase of 10 plants over 1932, and one addition was made to the number of States represented.The primary purpose of the United. States Bureau of Mines in conducting the contest is to promote safety in United States mineral industries. This purpose is accomplished directly through the efforts of the competing companies and their employees to win first place in the competition and thereupon receive recognition on a national scale for their achievement the purpose is accomplished indirectly through studies by the United States Bureau of Mines of the facts contained in the accident reports the competing companies furnish to enable the Bureau to compute the accident rates that are the basis for determining the winners of the contest.The statistics which constitute the basis for determining the winning companies and the relative standing of all companies are prepared uniformly without regard to the States in which the companies operate, or to differences in classes of accidents covered by State laws relating to compensation for injuries resulting, from industrial accidents.Bronze trophies, known as 'Sentinels of Safety', which were provided by The Explosives Engineer magazine to be awarded annually by the Bureau of Mines, were presented to five companies in the contest of 1933, each company having established the best accident-prevention record within one of the five classes into which all companies were divided, namely, anthracite-mining companies, bituminous-coal-mining companies, metal-mining companies, operators of nonmetallic-mineral mines other than coal mines, and quarries or opencut mines. The trophies are awarded for 1 year and are then transferred to the winners of the succeeding year's contest.The trophy for bituincus-coal mines was won by a company in Wyoming. A company in Tennessee won the trophy for metal mining. In the nonmetal-mine group the trophy was again won by a company in New York. A quarry in Michigan won the trophy for the quarry-and-opencut-mine group. The trophy for anthracite mines remains in Pennsylvania, as all anthracite mines in the contest are in that State."

Jul 1, 1934

By M. B. Boyer, C. H. Herty, F. A. Hartgen, G. L. Frear

"DEFINITION OF VISCOSITYViscosity has been defined as the resistance experienced by one portion of a liquid moving over another portion, such as one molecular plane moving over an adjacent plane. A measure of viscosity is the force required to keep one plane in motion at Unit velocity, the other plane being considered stationary. Figure 1 illustrates the general idea that the surface friction between two adjacent areas will be greater the larger the molecules. Therefore it may be assumed that viscosity will be increased by molecular association or agglomeration, and likewise dissociation rill decrease viscosity. According to Maxwell (1)6 the unit of viscosity, the poise, is the tangential force per square centimeter of area of either of two horizontal planes 1 centimeter apart, one of which is fixed while the other moves with unit velocity, the space between being filled with viscous liquid of unit viscosity.The need for a satisfactory apparatus and experimental procedure for the determination of viscosity of high-melting materials at temperatures corresponding to those in pig-iron and steel making has been recognized during the past few decades. The condition of the slag during the smelting and refining periods in the iron- and steel-making processes exerts an important influence on the metal product obtained, this slag condition really meaning the state of viscosity or, vice versa, fluidity, which the slag attains under certain conditions."

Jun 1, 1934

By T. L. Joseph

"IntroductionThe efficiency of ore reduction in the blast furnace and fuel requirements depend upon the degree of uniformity with which reducing gases can be distributed through the stock column and upon the permeability of individual pieces of ore and sinter. If the ore is fine, the major problem in reduction is to get the ascending gas stream to the surface of the ore-Hard, dense ores of low permeability, mined in coarse sizes, tend to improve the permeability of the bed, but unless they are crushed to the proper size they reach the hearth unreduced.Surveys by the Bureau of Mines have shown conclusively that the gas distribution in the upper three fourths of the furnace is far from ideal. Furnace lines, top design, and methods of charging are important, but more thorough size preparation of the ore is necessary to eliminate size segregation at the stock line, which inevitably leads to non-uniformities in gas distribution.Because of the quantity of sinter now produced close study of the characteristics which determine its behavior in smelting is warranted. As the use of concentrates increases agglomeration will become more of a necessity. Improvements in the physical character of the ore burden are particularly important to plants using coke of poor physical quality. In addition to aiding reduction, improved physical properties of the ore burden will permit the use of higher blast heats, which is equally important.Reduction Tests on Fine Sizes of SinterPrevious reduction tests on minus 0.742— plus 0.525--inch pieces of commercial sinters revealed large differences in porosity and reducibility. The results have been published in a former report. 3 Although the physical properties of the sinter, particularly porosity, were found to be of major importance in determining the rate of deoxidization, it appeared that certain chemical properties of the sinter appreciably retarded the reduction of sinters high in silica. This was attributed to the presence of fayalite, which has been identified by Schwartz and by Luyken and Kraeber4 as an important constituent of sinter. Although furnace operators and metallurgists have assumed that iron silicate is more difficult to reduce than hematite or magnetite, definite data on the reduction characteristics of this material were not available. Tests were undertaken, therefore, to develop a method for de-termining the amount of iron silicate present in sinters so that its effect upon reduction could be observed."

Jun 1, 1934

By W. H. Coghill, F. D. DeVaney

"Introduction Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with no many ""inflection points"" and ""counterflexures"" that they obscure the issue.Some of the investigators have neglected the very essence of the problem, namely, the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration.Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.Grindability Characteristics When the ores are being studied the information sought is grindability characteristics (grain-size distribution) and the grindability (work required to produce new surface) of a group of ores.When the study is of the machines, several machines are used for a given ore or given types of ores, and the grinding performances of the machines are compared by a grain-size study.Table 1 gives the grindability characteristics and grindability of six substances, one of which is coal. The substances are arranged from left to right in progressing order of tons per horsepower-hour. Curves and graphs are not needed for elucidation. The secret of the ease of interpretation is the order mentioned and the similarity of the sizing analyses. Power records must be complete in grinding studies.The grinding device was a ball, plunger, and mortar called the drop weight.' It may be used to advantage when the amount of material to be tested is too small for the orthodox machines.The upper part of table 1 shows the grindability characteristics by the cumulative-sizing analyses. Note how closely the percentage weights agree for a given sieve size. The lower part shows the grindability in terms defined elsewhere. The present paper should be read in conjunction with that paper."

Jun 1, 1934

By Arthur L. Crawford, R. E. Head, Glen Burgener, F. E. Thackwell

"INTRODUCTION This report embodies the results of a detailed statistical microscopic examination of the ore and the mill products of the Silver King Coalition Mines Co., Park City, Utah.The study was conducted under the joint auspices of the United States Bureau of mines is cooperation with the University of Utah at Salt Lake City, Utah. The work was done in the cooperative Microscopic Service Laboratory, which was equipped by contributions from the following companies: Utah Copper Co., International Smelting & Refining Co., American Smelting & Refining Co., United States Smelting, Refining & Mining Co., Tintic Standard Mining Co., Silver King Coalition Mines Co., and Park Utah Consolidated Mines Co. The salaries and the other costs involved in operation of the laboratory were met by contributions from certain supporting companies. In addition to the regular personnel of the laboratory the Bureau of Mines contributed the part-time services of a microscopist-consultant to direct and assist with the technical work.ACKNOWLEDGEMENTSThe authors acknowledge the courtesies extended by the Silver King Coalition Mines Co., through its general manager, M. J. Dailey, in furnishing the various ores and products on which the study was made, together with general information concerning the problems encountered or recognized in connection with the milling of the Silver King ore."

Jun 1, 1934

By George S. Rice

"The emission of hydrocarbon gases from coal beds and contiguous strata causes many accidents in coal—mine workings, the number of fatalities so caused being second only to those due to falls of roof. Gases tend to increase in amount with depth of coal mining, hence the danger of explosion is increased with depth. The pressure of the gas in virgin—coal areas at a distance from mine workings likewise tends to increase with depth from the surface, probably due to corresponding increase in hydraulic head and possibly, when the gas is held in nonporous formations, to greater ground pressure. The rise in gas pressure with depth under usual conditions is shown in wells drilled from the surface and in some coal fields in drill holes into the face of workings; however, under normal conditions of coal formation gas does not issue into workings under high pressure because the coal and adjacent strata have many bedding and joint planes which allow the gas to escape freely at the face of the workings. The rare occurrence of instantaneous outbursts of gas, with violent effects referred to later, constitute the exception.Variations of volume and pressure of fire-damp or methane found in different coal beds by wells at a distance from mine workings, are analogous to variations in volume and pressure of natural gas found in different gas and oil sands, although in general the pressure tends to increase with the depth. Sometimes, however, in tight sands higher in the formation the pressure of gas therein is abnormally high, and on drilling the well deeper gas in the lower strata may be found at lower pressure."

Jun 1, 1934

By J. E. Tiffany, N. A. Tolch

The Pittsburgh Experiment Station has made a survey of the properties and characteristics of the brands of fuse manufactured in the United States ; 25 samples were procured from 4 manufacturers representing the different brands offered on the market when the investigation was begun . It is believed that the field was completely covered except for special fuse made to order for a particular job .

Jun 1, 1934

By ALICE V. Petar

Like many gem materials, amber has a colorful history which may be traced through the writings of the ancients and the ornamental relics discovered from time to time. Like few gem materials, however, it is distinctly useful in products whose value has no connection with the gem industry. Long prized for its beauty, amber was fashioned into articles of jewelry and ornaments to please the fancy of ancient rulers and to find a place among treasured pos- sessions in their tombs; it has been used by adherents of various creeds for rosaries and other religious symbols; and although still sold for these pur- poses it also lends itself to such commercial purposes as raw material for varnish. Amber is only on the border-line of the mineral kingdom; actually it is of vegetable origin, having been formed as resin from trees of the conifer family that existed during the Tertiary period. It is the hardest of the fos- sil gums. The United States produces no amber, although a few occurrences are known. Most of the world's supply comes from East Prussia, where it is ob- tained from both land and sea. For many years pieces of amber were gathered from the Baltic by fishermen and deep-sea divers; and although about 10 per- cent of the Prussian amber is still recovered from the sea, most of the out- put is mined from open pits on the Samland Peninsula.

Jun 1, 1934

By W. D. Musgrove, B. W. Gandrud, A. C. Richardson

"INTRODUCTION The Cahaba coal field is the second largest coal—producing area in Alabama. This field underlies parts of Shelby, Jefferson, St. Clair, and Bibb Counties and has an area of about 270 square miles. The Cahaba formations contain a number of coal beds, about 8 of which are mined at present. Although the area contains many folds and faults, samples from various mines and beds indicate that, except for the variation in ash content, the coal from this field is very uniform in character and quality. It is a high-volatile bituminous coal used chiefly for steam-raising purposes and domestic fuel. The coal as mined usually contains too high a percentage of impurities to be marketed without some preparation. The majority of the mines have washing plants in which jigs are the favorite type of equipment, although at some mines tables are used for cleaning the slack sizes. The washing characteristics of the coal from the Cahaba field are very uniform and differ from those of the near-by Warrior field, in that the coarser sizes contain a much lower percentage of bony material than the finer sizes. In general, the bone increases with decrease in size. It breaks into thin flakes, making difficult its elimination in the cleaning process, and gives rise to what is known among the washery operators of the Cahaba field as the ""rash problem.""A previous publication 5 referred to rash from the standpoint of jig operation and suggested some means of handling it with jigs. This report presents the results of table tests on two samples of fine coal from the Thompson and Woodstock beds, respectively, of the Cahaba field to determine the influence of rash on table efficiency.This investigation has been made in connection with the study of coal-washing problems now being conducted by the U.S. Bureau of Mines and the University of Alabama, with the cooperation of the different coal operators of Alabama."

May 1, 1934

By Sam S. Taylor, H. M. Smith

"INTRODUCTION In most oil fields, natural gas is the major source of energy causing flow of oil to the well. The amount of gas Produced with the oil generally exceeds actual energy requirements, so that in time the gas reserve of the field becomes seriously depleted and the oil production must be stimulated by some auxiliary means. One of these is to repressure the oil formation with natural gas; or, where a gas supply is not available, often air is used.Although P.ir is a Cheap and convenient repressuring medium, its use sometimes is attended with several disadvantages. First, the return air-gas mixture decreases rapidly in fuel value, often until it can be used no longer as a source of power. At the same time, explosive mixtures may result if recycling is used, causing hazards to life and equipment. Second, some fields experience considerable trouble with the formation of emulsions which become increasingly difficult to treat. Although there is no definite proof that air repressuring always causes these emulsions, many operators are convinced that this is the case. The Petroleum Experiment Station of the United States Bureau of Mines at Bartlesville, Okla., has been interested in problems connected with air-repressuring for a number of years. Some time was spent in studying the so-called ""bad gas""--return,mixture of low fuel value. However, it appeared impossible to attack the problem successfully from this angle, and an approach was made through a laboratory--scale study of direct oxidation of crude oil."

May 1, 1934

By G. R. FITT, S. R. B. Cooke, C. W. Davis, V. H. Gottschalk, C. G. Maier, C. E. Wood, R. S. Dean, S. B. THOMAS, John Gross, E. P. Barrett, T. L. Joseph

Lack of funds has prevented publication of much of the metallurgical work of the Bureau of Mines during the past 2 years . The present progress report covers studies in the direct production of iron and steel . The experimental work was carried out in cooperation with the universities of California , Minnesota , and Missouri . Complete reports will be published when funds are available .

May 1, 1934

By W. A. SLOAN, G. L. Oldright, J. D. Sullivan, E. K. PRYOR, A. F. HALLET, R. S. Dean, S. L. BROWN, F. S. Wartman, A. J. Thompson

Lack of sufficient publication funds has resulted in the accumulation of considerable unpublished experimental work on copper metallurgy by the Bureau staff . The present report gives extended abstracts of this work , as well as a discussion of the best direction for future efforts . The experimental work reported in this series of papers was done in cooperation with the University of Arizona , Tucson , Ariz . The investigations covered in the third , fifth , and seventh papers were done under the direction of G. L. Oldright and the remainder under the direction of V. H. Gottschalk .

May 1, 1934

By Edmund S. Leaver, R. S. Dean, T. L. Joseph

The metallurgy of manganese has developed along the lines of iron metal¬ lurgy. Enough high-grade ore has Been available so that by reduction with carbon it could be turned into an iron-ma.nga.nese alloy and a slag containing some 9 to 15 percent manganese. More siliceous ores have been smelted in the blast furnace to form iron-silicon-manganese alloys called spiegel. When lower-grade ores came in for serious consideration, which lias only been since l°l4, two types of processes received the most consideration — hydrometallurgical processes to produce a concentrate which could be smelted like the higher-grade ore and processes involving concentration of the manga¬ nese from manganiferous iron ores by preferential reduction of the iron (184)1. Special chapters in this bulletin are devoted to the production of ferro¬ manganese from ore, the hydrometallurgy cf manganese, and the Bureau of Mines modification of the preferential reduction process. Other methods of producing manganese alloys from low-grade or refractory ores have been suggested and may find future application. Manganese has a very high affinity for sulphur and is particularly adaptable to concentration by matte smelting. According to Betts (26), manganese silicate may be smelted with pyrite to give manganese sulphide and iron silicate. This method would be applicable to concentration of either the silicate or carbonate ores. The sulphide, once obtained, could be roasted to oxide and reduced in the usual way. Another possibility for the production of manganese from silicate ores involves their reduction by silicon or manganese silicides. Swedish Patent 52290, February 25, 1925. covers the reduction of a slag rich in manganese by silicon-manganese alloy containing more than 10 percent silicon, Joseph H. Brennan (38.) describes the concentration of manganese iron ores by partial reduction with silicon. Beckett (7,4,19) describes the reduction of manganese dioxide with a manganese silicide for the production of standard ferromanganese. Beckett gives as a typical alloy, manganese 64.4, silicon 24.6, and as a typi¬ cal ore, 5S.5O manganese as MnO^. The product of the reaction between these two is 80.11 percent manganese and 1.22 percent silicon.

May 1, 1934

By C. G. Maier

The present trend of chemicometallurgical research toward widespread and inclusive use of thermodynamic methods requires the inclusion of available data of this sort in any comprehensive metallurgical report . Such data for manganese are far from adequate for the full utilization of these methods . Even if our knowledge of these properties is weak , the collection of available figures is nevertheless well worth while , especially if their utilization in an approximate way may show inherent possibilities of application . No less important is the necessity for discovering the vital gaps in the existing information , to serve as a basis for further pertinent study . The utility of the thermodynamic methods of Lewis and Randall ( 234 ) 3 has become increasingly evident to metallurgists . It is true that at present no better approach to the general , fundamental problems of chemical metallurgy is available than close adherence to these methods . The effort is here made to collect and correlate , as far as possible , significant quantitative thermodynamic data on manganese and its metallurgically important compounds . There are considered here only the intrinsic properties of pure materials . The order maintained as far as possible will be as follows :

May 1, 1934