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By Felipe Fardin Grillo

The aim of this work was to study the use of slags to desulfurization of cast iron. It was proposed to use alumina instead fluorspar. In addition, marble waste was used instead lime. Simulations applying Thermo-Calc software were performed in order to obtain the theoretical phases thermodynamic data. Then, a comparison between theoretical data and experimental tests were performed. The cast iron was melting in induction furnace at 1550°C. Slags composed mainly for CaO and Al2O3 were used to cast iron desulphurization. It was observed that increasing liquid phase, the desulphurization reaction was favored. Besides, it was found that cast iron desulfurization occurs by top slag mechanism.

Aug 17, 2017

By Paula Aliprandini

Os minérios limoníticos de níquel apresentam na sua composição metais como ferro, níquel e cobalto, sendo o primeiro o elemento majoritário. A presença majoritária de ferro prejudica a separação dos demais metais que possuem interesse comercial. Para remoção do ferro, técnicas hidrometalúrgicas são usadas. A extração por solventes é uma técnica com foco na separação seletiva de metais. Neste trabalho, foi preparada uma solução sintética baseada nas concentrações dos metais presentes na lixiviação de um minério limonítico de níquel. A solução foi colocada em contato com o extratante Cyanex 272. Este extratante é conhecido pela sua seletividade ao ferro em valores de pH próximos a 2,0. As amostras foram analisadas utilizando a técnica de Espectroscopia de Fluorescência de Raios X por Energia Dispersiva (EDX). Após concluídos os ensaios foi encontrado que durante a extração do ferro, o cobalto foi coextraído junto, mesmo em pHs entre 0,5 e 2,0, indicando que a presença do ferro altera o comportamento do cobalto.

Aug 17, 2017

By Márcia Maria da Silva Monteiro Pereira

Tundish is the last reactor where significant metallurgical operations can still be done. Calcium aluminate slags are able to positively contribute to metallurgy considering oxide separation, protection against reoxidation and preclusion of resulphurisation. However, these are poor insulators. When using low melting point slags it is necessary to use another covering material. The deviation from saturation can be used as a measure of absorption capacity. By utilizing computerized construction of ternary and quaternary diagrams it is possible to compare different slags and to find proper slag compositions with reasonable capacity to dissolve inclusions. Objective of the present technical contribution is to evaluate tundish slag capacity to absorb inclusions, considering a particular tundish industrial slag and the changes in its chemical composition during continuous casting of steel. It was observed that slag composition changed during the continuous casting process; this variation is possibly related to interaction between the CaO-Al2O3 liquid slag and the rice hull ash layer which is used above it. Computational thermodynamics was used to determine activity of alumina dissolved in liquid slag; it was observed that the variation in slag composition did not change slag capacity to absorb inclusions, since precipitation of Al2O3 solid phases is not predicted.

Aug 17, 2017

By Tairine Berbert Tavares

A eletro-obtenção constitui em um importante processo na recuperação dos principais metais produzidos através de processos hidrometalúrgicos (i.e. Cu, Ni, Au, Co, Zn), pois permite a obtenção de depósitos catódicos de elevada pureza a partir de soluções aquosas contendo o metal. O presente trabalho investigou a eletro-obtenção de zinco, a fim de avaliar a influência da gelatina, um aditivo orgânico, na eficiência de corrente e na qualidade do metal depositado no catodo de alumínio. A caracterização dos depósitos de zinco através do MEV revelou que, na presença de concentrações crescentes de gelatina até 40mg/L, houve diminuição da quantidade de poros ocasionados por evolução de hidrogênio na superfície do zinco depositado, contudo, em concentrações de 80mg/L, os poros voltaram a aparecer. Além disso, notou-se que diferentes concentrações de gelatina não alteraram a forma dos cristais de zinco, porém provocaram redução do tamanho de suas plaquetas hexagonais, à medida que a concentração de gelatina aumentou, mostrando efeito de refino de grão, em comparação à solução livre da adição de gelatina.

Aug 17, 2017

By Ayumi Yoshioka

Os componentes automotivos em geral devem atender a especificações rigorosas de propriedades mecânicas, requisitos de limpeza inclusionária, entre outros. Enxofre e alumínio são dois elementos adicionados ao banho líquido, que têm papel importante na obtenção destas propriedades, mas que dificultam o processo de produção por lingotamento contínuo por favorecer a formação de partículas sólidas de alto ponto de fusão, que podem prejudicar a limpeza inclusionária e provocar a obstrução das válvulas de lingotamento. O objetivo do presente trabalho é analisar e classificar as inclusões de corridas do aço DIN 38MnSiVS6 em escala industrial e avaliar estes resultados em conjunto com os dados de processo de aciaria e com os resultados de simulação termodinâmica utilizando o software FactSage 6.4. Foi observado que as corridas apresentaram tanto sulfetos de cálcio quanto espinélios, mas as primeiras, associadas a uma fração líquida menor na escória, tiveram uma correlação mais perceptível com a má lingotabilidade.

Aug 17, 2017

By Juliana Mendonça Silva de Jesus

O estudo do comportamento de membranas trocadoras de íons em um sistema específico permite verificar a interação de um eletrólito com suas propriedades. No presente trabalho, foram utilizadas soluções de cobre à base de HEDP, proveniente de um banho galvânico isento de cianeto. A membrana utilizada foi a HDX 200 (aniônica) fornecida pela empresa Hidrodex. Amostras da membrana foram submetidas a um ensaio de envelhecimento durante 13, 26, 60 e 90 dias, imersas em uma solução a 5% v/v do banho de cobre. Após o envelhecimento essas foram preparadas para a realização de análises estruturais por FTIR, MEV e TGA. Os resultados obtidos pelo MEV e FTIR mostram que a membrana possui morfologia heterogênea. Além disso, verificou-se pelos resultados da análise térmica que o complexo presente no banho eletrolítico influi no comportamento térmico da membrana.

Aug 17, 2017

By Ernst Lindemann

The SMS group has developed the ultrasound technology “HD scan” for inspection of the internal quality of as-cast products. This method of sample analysis requires less preparation work and is safer than the current, most common technique of etching and/or sulphur printing. Furthermore, this technology offers a three-dimensional view into the sample of the cast product and thus more representative information for a better quality evaluation. The internal quality evaluation can be performed automatically and objectively by software based on clear statistical methods. A quantitative centerline segregation rating can be assigned to each sample, based on the size and distribution of segregates detected by the unit. Internal crack statistic (length, position, orientation, etc.) and narrow side profile can also be measured. Grain macrostructure can also be visualized which allows for a potential optimization of casting parameters like strand cooling, soft reduction or electromagnetic stirring. The accuracy of the new method was proven by parallel metallographic investigations of more than 100 samples of different steel grades and sample shapes. Automatic defect evaluation and classification was compared against macroetching results. It was found that HD scan identified more defects and the visualization of the macro structure could be performed in more cases than with macro etching. All tests, comparisons, further developments and analyses for various steel producers and steel treatment companies have been conducted at the HD scan unit, located at the SMS group headquarters in Düsseldorf, Germany (Figure 1). Based on the results, SMS group has designed a unit which can be used in industrial scale.

Aug 17, 2017

By Antonio Fabiano de Oliveira

The aim of the present research work is to study the influence of hard chrome covered skin pass cold rolling rolls using 2D/3D surface topography, i.e. roughness characterization. The common stochastic structure Shot Blast Texturing (SBT) does not meet all requirements related to the production line regards to the finished product. The Hard Chrome layer, applied on these SBT rolls, can improve the sheet surface quality and is of fundamental interest mainly for those steel mills that do not have another alternative to new surface structures such as those that may be provided by the EDT, LT, EBT, etc. methods. The function of the generated surfaces, obtained by these different methods is going to influence the tribological properties during the subsequent forming processes. On the other hand, they can increase the product final cost or require large investments to obtain such surfaces. The results here presented are in accordance with other recently published research work, showing that there is a relationship between these parameters, and that further detailed studies are needed.

Aug 17, 2017

By Luke A. Balzan

Access to information is a key component for making improvements to any process. This is particularly true for all aspects of the iron mining and steelmaking process. The ability to make rapid control decisions can significantly influence process outcomes, including ensuring product specification, mining quality, transportation limits, upgrade factors, waste bypass and direct shipping, among many others. While traditional laboratory methods provide feedback for such processes, having access to analysis results in real-time can lead to positive reactive and predictive control decisions to be made rapidly, leading to significant improvements throughout the process. Scantech has been designing, manufacturing and supplying technological products to the minerals industry since 2002 to enable the availability of such realtime information to a mine or plant, with the benefits being enjoyed by a wide range of operators. This paper provides a summary of the available technologies used in the iron ore and steel industries, as well as providing a case study of their use at an Australian site, and a description of the potential benefits of a range of analysis equipment.

Aug 17, 2017

By Eduardo Macedo Junior

O presente trabalho descreve o desenvolvimento de uma nova especificação para a Linha de zincagem numero 3 (LZC#3) da Companhia siderúrgica nacional (CSN), de grande demanda e aceitação, alta produtividade e foco nos requisitos do cliente que tangem qualidade superficial e características metalúrgicas (resistência mecânica) em aços para atendimento do mercado Norte-americano. Este novo produto tem como característica o ciclo de recozimento com velocidade alta para obtenção de microestrutura 100% encruada na saída do equipamento e limites de escoamento e resistência acima de 500 MPa. A combinação dessas características do produto junto com as características do processo tornou a especificação “ASTM-A653MSS80CL1” um grande desafio para garantir qualidade superficial sem comprometer as propriedades mecânicas especificadas assim como a integridade do equipamento. O baixo custo de produção associado a alta produtividade desse produto fazem da especificação “ASTM-A653M-SS80CL1” um produto de extrema importância para a estratégia adotada pela CSN, mantendo dessa maneira sua competitividade no mercado Norte-americano e garantindo capacidade máxima de produção do seu equipamento em tempos de retração do mercado interno.

Aug 17, 2017

By Douglas Glenn Stalheim

Production of structural hot strip coils in yield strengths up to 700 MPa and higher is increasing worldwide. In addition to requiring higher strengths, structural designs require good formability, toughness and weldability. Toughness and formability come from optimization of ductility properties while weldability comes from lower carbon equivalent alloy designs. The key to the production of optimized cost effective hot strip produced structural coils is to create the correct balance of a proper alloy/processing design to create as fine and uniformly distributed cross sectional grain size as possible. In addition to the creation of the fine/uniformly distributed cross sectional grain size, the correct microstructure needs to be created. In the higher yield strength grades, not only does the grain size/distribution play a role but a proper understanding and control of microalloying precipitation kinetics is required. This paper will present various examples of hot strip alloy designs to produce cost effective hot strip structural coil in yield strengths up to 700 MPa with good ductility and weldability. In addition, steelmaking/casting parameters will be discussed to assure successful production. Optimized reheating, rolling and cooling parameters of these alloy designs will be introduced in an accompanying paper.

Aug 17, 2017

By Yasser Ghobara

Phosphorus is a problematic impurity that has challenged steelmakers for decades. Steel producers have developed specific technologies to eliminate phosphorus prior to and during steelmaking. These process technologies reduce phosphorus to various degrees and increase the cost of making steel. The state-of-the art dephosphorization technologies are described and operating costs compared for each of the established technologies. Costs are discussed in terms of price penalties for high P iron ore and selling premiums for low P steel. From this, strategies to control P in a cost effective manner are described.

Aug 17, 2017

By Edelink Efrain Tinoco Falero

Na atualidade a produção e a utilização de DRI estão aumentando nos países desenvolvidos, principalmente devido à redução do preço do gás natural e do sucesso da nova tecnologia de extração de gás de xisto. Os custos operacionais e os problemas ambientais são, efetivamente, os fatores tecnológicos importantes a serem considerados na otimização da produção de DRI. Portanto, o teor de carbono do DRI tornou-se essencial em virtude da capacidade de gerar energia química no banho de aço, complementando assim a eletricidade em FEA, e as contribuições exotérmicas da oxidação de Si e C nos conversores LD. Este trabalho faz parte de um programa completo de cooperação entre a companhia de mineração Samarco e o Grupo de Siderurgia da PUC-Rio, lidando com as equações cinéticas da metalização e carburização simultânea em fornos de redução direta. Para este efeito, o reator foi dividido em três zonas internas: Redução, Transição e zona de resfriamento. Além disso, também foram consideradas três regiões concêntricas: periférica, média e centro. Á partir desses resultados, para um tipo de pelotas RD específico, mistura de gases utilizados nas instalações industriais e similar flui-dinâmica do processo, as equações cinéticas de metalização e carburização foram estabelecidas para cada zona. Um programa computacional METCARB, totalmente baseado nessas equações cinéticas, foi então concebido. Finalmente, uma validação adicional procedeu-se tendo em conta duas corridas operacionais industriais.

Aug 17, 2017

By Cristiano José Scheuer

Experiments were carried out aiming to study the influence of micro-abrasive wear test variables and plasma treatment parameters, on the tribological characteristics of low-temperature plasma carburized AISI 420 steel. The first part of this study was conducted in order to evaluate the influence of abrasive particle size, normal load and counter body rotation speed on carburized sample wear behavior; and the second part was conducted in order to evaluate the treatment temperature and time effect on carburized samples wear behavior. Plasma carburizing treatments were performed at 8 and 12 h, for temperatures ranging from 350 to 500°C; and at constant temperatures of 400°C for times between 12 to 48h, and for 450°C for times of 4 to 16h. Micro-abrasive wear test were performed by mean of a calowear ball-cratering equipment using a polished ball of AISI 52100 steel rotating at 80, 120 and 160 rpm, for sliding distances from 2.6 to 104.2 m. Alumina abrasive particles with sizes of 0.05, 0.3 and 1.0 ?m were employed. The normal loads applied on this study were 0.1, 0.3 and 0.5 N. Carburized sample was characterized by mean of OM, XRD and hardness measurements. Worn crater characteristics were evaluated by confocal laser microscopy. Results showed that the transient wear regime prevails along the outer layer length (composed by Fe3C and ?’C), and the steady-state wear stabilizes in the diffusion layer region (composed by ?’C). It was verified that the wear rate and wear coefficient decreases with treatment temperature in the range of 350–450°C and increase for 500°C. It was also verified that the wear rate and wear coefficient decreases with treatment time in the range of 12–36 h (for 400°C cycle) and 4–12 h (for 450°C cycle), and increase for larger treatment times due the chromium carbide precipitation. It was also found that the wear coefficient increases with the increase of abrasive particle size, and decrease with the increase in counter body rotation speed and normal load. Lastly, the analysis of the worn craters indicates the occurrence of grooving and micro-rolling abrasion wear mechanisms.

Aug 17, 2017

By Ricardo Tadeu Meneses Sodré

O mercado siderúrgico vive nos últimos anos um de seus maiores desafios de toda história. As empresas buscam, a todo instante, formas de redução de custo visando a manutenção da operação dos seus ativos. A gestão eficiente de estoques é parte fundamental para a redução de custos e garantia da segurança das operações da empresa. Para a classificação da criticidade dos sobressalentes não existe um critério claro e bem definido. Outro ponto importante é que sobressalentes realmente importantes podem não estar contemplados no estoque. O trabalho estabelece um modelo para melhorar a gestão de sobressalentes na ArcelorMittal Tubarão incluindo a correta identificação dos sobressalentes críticos, a priorização desses sobressalentes com foco no que deve ser comprado imediatamente e o que podemos postergar, a reclassificação dos sobressalentes de manutenção quanto a sua criticidade e à criação de alternativas para gerenciar e manter nos estoques os sobressalentes realmente críticos e dispor/criar alternativas para os sobressalentes não críticos. Essa nova metodologia foi aplicada como piloto na Linha de Acabamento e Linha de Tesoura da ArcelorMittal Tubarão indicando ganhos expressivos.

Aug 17, 2017

By Glaydson Simões dos Reisr

Micropore organosilicas (MOs) were synthesized using methyl-phenyl-polysiloxane as precursor. The MOs were characterized using several analytical and functional techniques. The materials were assigned as micropores materials, with specific surface area up to 642 m2 g-1 and yield up to 72.55%. The adsorbents have hydrophobic surfaces and were used for removal of diclofenac from aqueous solutions. The adsorption kinetic and isothermal data were well described by the general order and Sips models, respectively. Diclofenac exhibited a better affinity than NM and the mechanism of adsorption suggested that hydrophobic groups play a key role in the adsorption process.

Aug 17, 2017

By Konrad Krimpelstätter

The need for more effective and flexible roll-gap lubrication technologies in hot and cold rolling mills is steadily increasing due to ever-greater requirements placed on the rolling process and the final products. In particular, the rolling of high-strength steels poses enormous demands for both the rolling mill and the coolant/lubricant to be used. The presented paper focuses on two innovative technologies for highly efficient roll-gap lubrication for hot and cold rolling, which were developed utilizing extensive knowledge and expertise about the tribological interactions in the roll-gap. The advanced work-roll lubrication package (A-WRL) for hot rolling and ESP mills is using specially designed mixer-nozzle units to mix the water/oil emulsion very close to the nozzles to minimize the risk for contamination and clogging. The nozzles are quickly exchangeable and are optimized to ensure uniform lubricant distribution, high plateout efficiency and minimum oil consumption. This eco-friendly solution does not require any chemical additives or cleaning agents and significantly reduces electrical energy consumption and work-roll wear. The roll cooling system on mill entry and exit side remains switched-on, which is of vital importance especially for highperformance hot strip mills. Minimum Quantity Lubrication MQL® represents a new generation of roll-gap lubrication technologies for cold rolling, which applies minimum amounts of pure rolling oil finely atomized with pressurized air directly onto the work roll surface. This allows controlling the oil film thickness depending on actual process and product parameters, providing increased lubrication flexibility, significant improvement of strip surface cleanliness through reduction of strip wear. MQL® was successfully installed and tested on two industrial tandem cold rolling mills in Europe. Advanced WRL and MQL® represent Primetals’ latest technologies that feature a robust and reliable system comprising standardized interfaces and flexible communication options. Both packages can easily be integrated into existing or new hot strip mills, ESP lines or cold mills.

Aug 17, 2017

By Patrick Tassot

Increased worldwide highly competition in steel market imposes innovative measure for the steelmaker targeting cost reduction and climate-friendly steelmaking process in order to have the ability to withstand the pressure of the market. At the same time the demand for high purity and highest quality steels continues to grow from year to year, especially in the sector automotive in transportation of oil and gas, in the construction Industry and in the manufacture of heavy plate. As they allow producers to be up to the requirements while allowing expanding their product mix, new secondary metallurgical treatments have become a must additionally to standard equipment elements of steel plants modern. Most of these treatments occurs in the steel ladle increasing the pressure to ensure a reliable and as possible neutral reactor. Intelligent solutions for refractory lining ladles should integrate better adaptation to the operational process parameters and the high reliability/availability at the best cost/performance. This challenge has conducted Refratechnik to develop new concepts to overcome the frontier between shaped and unshaped materials and that’s what will be covered in this paper.

Aug 17, 2017

By Thomas Schanz

Current steel market conditions require small investments only to lower operational cost. SMS Concast has developed new products which optimize continuous casting process cost for long product steel production. This paper describes a selection of three products. All three systems are patented (patent pending for CONDRIVE). CONSAFE, a non-radioactive mould level measurement system for reliable mould level measuring on open stream casting CCM’s; CONSTIR-MWS, an improved control software for electromagnetic stirrers which lowers energy cost by 35%; CONDRIVE, a brand new oscillation drive system which provides the features of a hydraulic oscillator, however with a cost efficient electric drive.

Aug 17, 2017

By Carlos Alexandre Azevedo

Aços microligados ao nióbio possuem grande aplicação na indústria automotiva, muitas vezes como itens de segurança. Estes aços possuem certa tendência à geração de trincas transversais de superfície em placas produzidas via lingotamento contínuo, principalmente se as variáveis de processo durante a solidificação não forem adequadas. Experimentalmente, verificou-se que a ocorrência de trincas estava associada à composição química e às variáveis de processo. Com base nestas observações, avaliações da literatura e simulações com software Thermocalc ®, foram propostas alterações de composição química e ajuste na curva de oscilação, sendo este último considerado fator principal para a obtenção de placas isentas de trincas.

Aug 17, 2017