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By D. A. Reynolds

Yields of ammonium sulfate obtained in the carbonization of coal frequently vary from plant to plant, because ammonia is an unstable compound at high temperatures and therefore sensitive, to changes in carbonizing conditions. Differences in byproduct yields of ammonium sulfate obtained at different plants generally are accounted for by variations in plant procedure, either in preparing the coal or in its carbonization. However, technicians of one large corporation,- which frequently obtained higher yields of ammonium sulfate in its Alabama plants than ever were attained in its Ohio plants, "could not reconcile the differences in yields with their plant operations. These investigators suspected that the Alabama, coal used in their southern plant yielded more ammonia because its composition differed inherently from that of the Pennsylvania and West Virginia coals fused in their Ohio plants, although this concept could not be proved readily in their large-scale operations. Their view is supported by experimental data obtained A Beau of Mines-American Gas Association (BM-AGA) carbonization tests) -21 of a large number of coals including those carbonized commercially in Alabama and Ohio.

Jan 1, 1949

By John Lamb

"The French Mine (formerly the Oregon) is 4 miles by road south of the Nickel Plate Mine. It lies on the steep eastern slope of the Similkameen River valley at elevation 4,000 feet, between Cahill and Winters Creeks.The property was discovered in .1901 and bought 4 years later by Messrs. French and Deardorf. It was developed in a modest way by the owners and by several companies until 1947, without success. The spectacular showings of bornite and chalcopyrite in the outcrop drew attention to its possibilities for copper rather than gold. Diamond drilling by the owners in 1947 yielded several high-grade gold intersections and created new interest. In 1949 the property was purchased by Kelowna Mines Hedley Limited. Exploration drilling and geological mapping outlined sufficient ore to commence production in 1950. Except for a few months each winter the operation has been continuous, and to the end of 1954 had produced almost 30,000 tons of high grade ore. The ore is crushed at the mine and hauled 8 miles by truck to the Company mill at Hedley, where it is treated together with the ore from Nickel Plate.Regional GeologyThe country rock consists of brown tuff, flows, limestone, and cherty formations belonging to the Nicola group (Rice 1947) of Triassic age. West of and just below the mine is a large mass of granodiorite which is part of the same body that underlies Nickel Plate Mountain. Bedding attitudes in the mine area are locally complicated, but dips are generally less than 45 degrees. To the south and below the mine the beds stand almost vertical, continuing downward with this attitude for 2,000 feet to Winters Creek. The main granodiorite contact is also steep, conforming to the sedimentary formations, whereas northward towards Nickel Plate it dips gently to the northwest, slightly flattter than the thick westerly dipping pile of sediments above it. The interpretation of this structure by Billingsley (1936) is that the French mine lies near the crest of the large northeasterly trending asymmetrical anticline which contains in its gently dipping western limb the Nickel Plate orebodies. The granodiorite body conforming roughly to this shape seems to occupy the core of the anticline. Sill-like prongs of granodiorite extend upward to the east from the main mass, outcropping over wide areas at the head of Winters Creek (Figure 1). There is a possibility that overthrusting from the west, similar to that on Nickel Plate Mountain, occurs not far below the French mine.An interesting feature of the granodiorite-sediment contact is that where it dips gently westward no alteration exists in the sediments, but where it has a steep front pronounced heat effects are indicated by the presence of a thousand-foot-wide zone of reddish garnet skarn."

Jan 1, 1949

By Albert E. Long

During the summer and fall of 1948 the Bureau of Mines, in cooperation with the U. S. Geological Survey, conducted 6xperiments in diamond core drilling in the Phosphoria formation in southeastern Idaho and southwestern Wyoming. Nearly all of the diamond core drilling in the Phosphoria formation has been done by mining companies interested in finding and developing phosphate-bearing beds amenable to stripping. The recovery of sludge; and enough core (usually 30 to 60 percent) to identify certain marker beds produced by current drilling practices meets both the primary requirement of mining companies in determining depth of overburden and their secondary need to determine the phosphate content of relatively thick minable units whose general composition and nature are already fairly well established.

Jan 1, 1949

By H. W. Busch

In the course of examinations by representatives of the Bureau of Mines of several compressed-air systems in which explosions had occurred, samples were obtained of the carbon deposits that are formed normally in various parts of the systems by decomposition of the compressor lubricating oil. Experimentation with these carbon deposits has demonstrated that they contain a "carbon-oxygen complex" similar to that formed on coal and on other carbonaceous materials and generally recognized as being the cause of spontaneous heating of coal. The exothermic properties exhibited by such a complex are considered significant in relation to the possible initiation of combustion reactions that may lead to explosions or formation of carbon monoxide in compressed-air systems. This report discusses the occurrence of explosions and formation of carbon monoxide in the use of compressed air and presents results of experimentation conducted with carbon deposits from air compressors.

Jan 1, 1949

By Hazel Lyman Nickel

Daring to try where others had failed, Herbert and Lou Henry Hoover translated from the Latin the principal (and first) textbook on the mining and metallurgical profession, De Re Metallica, 1556, which had been in use for two centuries and then had lain dormant for 350 years in a language unreadable except by a chosen few. Thus the Hoovers enriched the English tongue with a vitally important contribution to history in the fields of mining, metallurgy, and chemistry. To them it was a joint hobby, because they were actively interested in the beginnings of the mining profession in which they had both been trained. Illuminating the years of toil to perfect this translation shone their ideal of service to humanity, since, in the Preface, they refer to their task as "a labour of love", which had to find the moments for its execution in night hours, weekends, and holidays, extending over a period of about five years. And they add: "If the work serves to strengthen the traditions of one of the most important and least recognized of the world's professions, we shall be amply repaid". While a student at Stanford University, during the years of 1891-95, Herbert Hoover had become familiar with a copy of this Latin mineralogy classic, De Re Metallica, a rare book in the private library of Dr. John C. Branner, at that time head of the department of geology and mining. Another Stanford student in geology was also examining and studying the ponderous volume of twelve 'books'. She was Miss Lou Henry, of Monterey, who graduated in 1898, and the following year became Mrs. Herbert Hoover. Interwoven through the tapestry of their life experiences gleamed the silver thread of their interest in this mediaeval Latin textbook. Just nine years lacer, the Hoovers had commenced their translation, while they were in temporary residence in London after the seething years in China under the shadow of the Boxer rebellion.

Jan 1, 1949

By F. T. Mooney

Introduction The Flin Flon mine of the Hudson Bay Mining and Smelting Company, Limited, is on the interprovincial boundary between Manitoba and Saskatchewan, about four hundred miles north of the Canada-United States boundary. The orebodies are gold, silver, zinc, and copper replacement deposits occurring as irregular lenses of massive sulphides, arranged en echelon, and irregular masses of disseminated copper sulphides in chlorite. The country rocks are of Precambrian age, dominantly lava flows. Development of the Mine The mine is opened by two vertical main shafts- the North Main and South Main shafts- 3,800 feet apart. The North Main shaft has a depth of 2,210 feet and the South Main shaft is completed for stoping operations to the 3,250-foot level (see Figure 1). These shafts are connected by main haulages driven, on the footwall side of the orebodies, at 520-foot intervals down to the 2,210-foot level. No. 3 (subsidiary) shaft is on the footwall side of the orebodies at a point between the North Main and South Main shafts, 2,400 feet south of the former. It has a depth of 3,250 feet and connects with all main haulage levels- with both Main shafts down to the 2,210-foot level and with the South Main shaft on the 2,750-, 3,000-, and 3,250-foot levels. Other openings tO the mine include B North fan raise, the opening due to the recovery of the open pit sill pillar, and several back-fill raises.

Jan 1, 1949

By B. K. Shibler

As a part of the Bureau of Mines' intensive; 'investigation of domestic manganese deposits, ore-dressing studies were conducted on three samples of oxide and silicate manganese ores from various Wyoming properties. The samples wore as follows: 1. A 2-ton sample of ore was obtained by a Bureau engineer during examination of the Caulkins-McGuckin property in the center of Crook County, 10 miles north of Sundance, Wyo. The ore body was described as a vein deposit in rhyolite porphyry. 2. The J. B. C. Mining Co. submitted a 1-ton sample of oxide manganese ore from a property located 44 miles northeast of Rock River in Albany County, Wyoming. 3. A 1-ton sample of oxide-silicate-ore was obtained by a Bureau examining engineer from the Gheen property in the northeast corner of Washakie County, Wyo. The ore body was described as a replacement deposit in a country rock of silicified limestone. As the samples differed widely in physical and chemical characteristics and also in their response to methods of concentration, ore from each property was considered a separate ore-dressing problem.

Jan 1, 1949

By Foster Fraas

That variations in the humidity of the air and in the moisture content of a mixture of broken solids being separated electrostatically cause trouble is not new.' Much of the reputation for unreliability commonly ascribed to the electrostatic separation processes is probably due to this one factor alone. Some operators dry thoroughly before separating; and while this is good in many instances, there are others in which it is not the remedy for trouble. Some mixtures behave best in very dry air and with the mixtures fed to the separator while hot to reduce the adsorbed water content. On the other hand, an overdried mixture on coming to equilibrium with more humid air, has been known to take up moisture selectively on one family of particles, as of coal in the presence of slate and clay, and give sharper electrostatic separation. From these observations it is concluded that there is a permissible moisture content for a particle and also for the atmosphere surrounding it, if in equilibrium, at which the particle will have a conductivity or cntact potential2-4 that is ideal for electrostatic separation. This permissible moisture content varies between a wide range of limits for the different materials that are are and with the kind of electrostatic separating process used. Water can be present as a result of adsorption and condensation from the atmosphere, as an accumulation before or during mining, or as a residue from a previous process step. The water may exist as a liquid film or as an adsorbed layer of vapor. If the water exceeds permissible limits it must be removed. Its state determines the method. Drying by evaporation is necessary for adsorbed water, for part of the liquid-film water (that is, up to several percent of the dry weight), and for free water in the internal structure. Large water contents may be removed by drainage Or filtration. At just what point mechanical removal should cease and drying by evaporation begin depends upon the method of mechanical removal and its cost. Particles can also be separated according to their differences in dielectric constant when suspended in a liquid of intermediate dielectric constant. Recovery of this liquid presents a a problem' Permissible Moisture The adsorbed moisture on the outer surface of minerals can be quickly removed or replaced. Accordingly, in speaking of adsorbed moisture contents, either that of the solid or that of the surrounding air may be considered, the two values being connected by a distribution coefficient which varies with the temperature. However, such a condition does not necessarily exist in processes where an initially dry material is suddenly introduced into an atmosphere having a partial pressure of water vapor or where a moist material is suddenly introduced into a dry atmosphere. Here the resultant differences in the

Jan 1, 1949

By Carlton E. Brown

This report contains information on the relation between and precision or reproducibility of counts (light-and dark-field) of the dust in liquid from simultaneous impinger, midget-impinger, electric-precipitator, and filter-paper samples. The impinger was the main sampler used from about 1922 to 1939 by industrial hygienists in the United States for collecting samples of unhygienic dust from the atmospheric environment of workers. The midget-impinger, a small modification of the preceding impinger described in 1937, has been the sampler used most since about 1939. Electric precipitators5/6/ have been used to a limited extent, mainly by the Bureau of Mines in the laboratory, for obtaining results comparable to impinger results. A filter-paper sampler for obtaining results comparable to impinger results has been described by Brown. All these samplers have a high collecting efficiency for particles larger than 1 micron in diameter revealed by the usual light-field counting procedure. However, their collecting efficiencies are quite variable for the smaller particles revealed by the dark-field counting procedure used in this study. Published information on the relation between the results of these samplers is limited and scattered. Summaries of some of this information are given in this report along with some previously unpublished information.

Jan 1, 1949

By W. R. Hibbard

The term lineage was first introduced by Buergerl to denote dendritic branches, grown from a crystal nucleus during solidification from the liquid, with imper- fections in alignment of the order of 10 : to 10-4 cm. These imperfections are associated with distortions of the dendrites caused by the subsequent solidification of the inter-dendritic filling and are illustrated in Fig I. Buerger etched zinc single crystals made by the Bridgman3 method to develop this dendritic pattern and show lineage microscopically. Since maximum crystal growth in face-centered cubic metals occurs along the [IT] directions,2 lineage would appear in copper as small deviations of dendritic branches from these directions. Elam4 and others5"8 reported etching effects resulting from coring along the cube face traces of various copper alloy crystals. These traces were used by Samans8 to orient single crystals. Williamson9 noted a "lined structure (in alpha brass single crystals) consisting of an ordered arrangement of etch pits" which were probably traces of {IOO} planes but somewhat uncertain because they were never straight (that is, apparently lineage). Greningerl1 described the distortion and multiplicity of Laue spots in back reflection X ray photograms of copper single crystals showing lineage. The present investigation -includes metal-lographic, X ray, and property studies of lineage in large grain and single crystal specimens of copper. Preparation of Specimens specilnens 10 in. long 35 1/2 in. diam of oxygen-free copper (o.F.H.c.) (99.985 pet) were' melted vertically in graphite crucibles under an atmosphere of commercial nitrogen purified through a gas train including sulfuric acid, potassium chloride, magnesium chiorate, hot copper chips and phosphorus pentoxide. After a temperature of 1200°C had been maintained for 1/2 hr, the furnace was turned off and the specimens cooled at a rate of about 150°c an hour' This method of direct solidification was used by Greningerlo to produce single crystals with marked lineage and in this investigation produced a fair yield of single crystal specimens in

Jan 1, 1949

By Y. G. Shiau, J. E. Burke

Several attempts have been made to account for the fact that grains in a fully recrystallized metal will coarsen on annealmg. Two fundamentally different hypotheses have been advanced, with several variations of each. One school considers that the cause of grain growth is the surface energy of the grain boundary. The theory of Jeffriesl that grain size and grain size contrast control growth is an example. The second school considers the primary cause to be a difference in the lattice energy on either side of the grain boundary. The more perfect grains are considered to grow at the expense of their less perfect neighbors, with a decrease in free energy, and a consequent increase in the stability of the system. Burgers2 presents the case for the strain or lattice imperfection theory of grain growth quite completely. The latter theory is attractive, since there is no doubt that differences in lattice energy or lattice perfection can cause grain boundary migration. A recrystallization nucleus grows for this reason as was beautifully demonstrated by van Arkel and Ploos van Amstel.³ Although it is generally stated that grain growth does not precede recrystallization, several workers4-5 have shown that small strains may induce a single crystal in an aggregate to grow, or at least may cause some grain boundary migration. The origin and nature of the imperfections that are considered to be responsible for normal grain growth have never been clearly described, but it is generally agreed that they are a consequence of the difficulty of atomic reorientation in the solid state, and that they do not seriously differ from the type of imperfection that can be introduced by mechanical deformation. An object of the present work was to determine whether the introduction of mechanical deformation would cause grain growth in a specimen which would not otherwise show it under the conditions used. It was also planned to determine the effect of such deformation on the rate of growth in a specimen which would show growth in the unstrained condition. Recently Maddigan and Blank6 have indicated that slightly strained specimens of alpha brass can undergo considerable growth prior to recrystallization if annealed at low temperatures. French7 has reported that at deformations less than 17 pet it is very difficult to detect the beginning of recrystallization in the same material. It was therefore planned to broaden this work to include a complete study of the microscopic behavior of alpha brass under condition~ of temperature, time, grain size and deformation such that recrystallization would not occur or would occur to only a Small extent. Experimental Procedure The brass was prepared by melting cathode copper and commercially pure zinc

Jan 1, 1949

By Lester Guttman

The connection between short-range order and thermodynamic activities in binary solid solutions has been pointed out by Birchenall1 who calculated approximate values of the energy of interaction of Zn and Cu and of the degree of short-range order in alpha-brass at one composition and two temperatures. The purpose of this note is to call attention to a somewhat more accurate theory than that used by Birchenall and to extend the calculations to a wider range of temperatures and compositions as a means of testing its applicability. This is an example of the well-known general method of comparing measured thermodynamic functions of a system with those calculated from a microscopic model by means of statistical mechanics. In this case, mathematical approximations must be used which make difficult any decision about the validity of the model. Birchenall's statistical method resembles closely that calletl by Fowler and Guggenheim2 the "quasi-chemical" method which has been shown to lead in certain cases to results identical with those obtained by the method of Bethe.3 The quasi-chemical method has been extended by Takagi4 to give general formulas for the free energy of binary solid solutions based on several lattices at all compositions and temperatures. Specifically, he treats the four systems typified by: I. ß—brass; 2. a— brass; 3. AuCus; 4. AuCu. When the temperature is so high that no long-range order exists, these formulas reduce to the same form for all lattice types, namely: F - FO = (E - EO) - T(S - S°) = ½N(c — x)(2vAB — vAa - Vbb) + M1/2KTzN[x log x + 2(c - x) log (c - X) + (I - 26 + X) log (1 - 2c + x)] -kT(z - I)N[c log c+(I-c) log (I -c)] Eq 1 Here the symbols have the following meanings: F—Helmholtz free energy E—nergy 5—ntropy k—the gas constant per molecule z—coordination number, (e.g. I2 in a-brass). N—total number of atoms c—atomic fraction of A Vaa, vbb, vab—nergy per bond of the corresponding bonds log means log, throughout The superscript ° denotes the thermodynamic fuliction in the standard state, which has been chosen to be pure A or B with the same crystal structure as the solid solution. The quantity x is the ratio of the number of A-A bonds to the total number and for minimum F satisfies the equilibrium condition Vaa + Vbb — 2Vab _ (c — x)2 kT l0g x(i - 2C + x The free energy may also be written in terms of /La and B, the chemical potentials or partial free energies per alom:

Jan 1, 1949

By L. S. Darken

It has been known for sometime that in an ionic lattice, such as that of Ag,S or FeO, the migration velocity of the anion may differ markedly from that of the cation, the cation being usually the more mobile. It has been shown, for example, that during the formation of silver sulphide tarnish on silver, the tarnish layer grows principally by the motion of silver cations through an essentially stationary silver sulphide lattice. Similarly, the growth of wüstite scale on iron proceeds principally by motion of iron ions, this being accomplished with the aid of vacant iron lattice sites into which the iron may readily move. Likewise investigations of solid solutions of various salts show that there is usually considerable difference in the mobility of the different cations. Measurements of the mobility of various metals in liquid mercury indicate that the various metals move at different rates relative to the mercury. In view of the foregoing it seems reasonable to suppose that when any single phase solution is acted upon by a field, the atoms of different elements respond in different ways; in particular, that the force arising from a particular concentration gradient in a binary alloy would cause the atoms of one component to move with a drift velocity which is in general different from that of the atoms of the other component. The recent experiments of Smigelskas and Kirkendall' support this viewpoint, since they found, in essence, that during diffusion in alpha brass zinc moves appreciably faster than copper. This was evidenced by the relative motion of inert molybdenum wires. Such a phenomenon is incompatible with the place interchange theory of diffdsion proposed by several authors, most recently by Bir-chenall and Mehl.2 This theory has, however, also been questioned3v4 for other reasons, principally because of the high energy required for direct atomic interchange. The rather large difference between self-diffusivity, as determined by tracer technique, and mutual diffusivity, as determined with the aid of another element at low concentration, might also be interpreted as favoring the above idea; however. Birchenall and Mehl have pointed out that there is another possible interpretation of this difference; this is discussed later. A rather interesting and pertinent observation was made by Schwartz, who noticed that tungsten lamp filaments, heated by direct current, commonly fail by necking down in the region at the temperature gradient near the positive end, with a concomitant swelling at the corresponding position near the negative end. He introduces considerable auxiliary evidence to show that this phenomenon is occasioned by the motion of tungsten cations which migrate in the high temperature region from the positive end toward the negative end. The mechanism of this migration is not clearly understood. If, however, this experimental evidence be accepted, we are forced to conclude that alloying elements in the tungsten may migrate by the same or a Similar mechanism, whatever it may be, at a greater Or lesser rate, thus giving rise

Jan 1, 1949

By J. C. Fisher, J. H. Hollomon, David Turnbull

Understanding of the diffusion problem has recently been furthered by the analysis of Birchenall and Meh1.l They pursued the problem of the variation of the diffusion coefficient with composition for non-ideal solid solutions. Their analysis follows the tradition of Wagner,l Jost, Dehlinger, and Darken & who assumed the net flux of diffusing material to be proportional to the gradient of a quantity related to free energy. The basic assumption in Birchenall and Mehl's formulation of the problem is that the net flux of diffusing material is proportional to a thermodynamic activity gradient. To estimate the applicability of the derived relations, they corrected the diffusion coefficients of carbon in austenite by utilizing Smith's6 activity data for carbon, and the diffusion coefficients for zinc in copper with activity data computed from the vapor pressure measurements of Har-greaves.' The corrected coefficients for carbon were virtually independent of carbon concentration. For the diffusion of zinc in copper a moderate variation of diffusion coefficient with concentration remained after the correction. The problem of diffusion can be formulated in another way than that used by Birchenall and Mehl. The method is that of chemical rate theory and has been used by Eyring and his coworkers8,9 as well as by Eyring and Zwolinskilo in a discussion to Birchenall and Mehl's paper. As yet the method has not been applied to substitu-tional solid solutions. On the basis of their assumptions, Eyring and Zwolinski derived a relation between the diffusion coefficient and activity that is identical with that of Dehlinger and Darken but which does not correct for the variation of the diffusion coefficient with concentration as well as does the relation derived by Birchenall and Mehl. It was thought that the theory of diffusion would be more complete if the inconsistency between the two analyses could be rationalized and if diffusion in substitu-tional alloys were analyzed on the basis of the concepts of the chemical rate theory. Chemical Rate Theory According to the theory of absolute reaction ratess the reaction +..... +X, Eq I is viewed as taking place in two steps. First the reactants A1, A², . . . A; combine to form an activated complex M with which they are in equilibrium: A1 + A1+ . . . + A=M. Eq 2 Second the activated complex decomposes to give the products XI, XZ, . . . Xi: M?X, + X²+ . . . +Xi Eq g It has been showns that the number of activated complexes decomposing per unit volume per unit time is given by the expressiont kT -h CM † The transmission coefficient has been taken as unity.

Jan 1, 1949

By Fremont T. Johnson

Credited with production of more than 164,000 flasks Of quicksilver from 1876 to 1944, the Oat Hill mine has ranked third in output in the United States. During World War II, when the demand for mercury was high, this property was selected for diamond drill with the purpose of increasing ore reserves so that production could be maintained or, if necessary, increased. Although the existence of marginal-grade ore (fill material) left in the stapes and possibly of virgin ore of good grade had suspected in certain parts of the Oat Hill mine, no factual information to tonnage, grade, or location was available. In close cooperation with the Federal Geological Survey, the Bureau of Mines studied old records and the few available incomplete maps. Diamond drilling began in November 1943 and was completed in December 1944. Twenty-eight holes aggregating 8,121 feet were drilled, in only parts of the promising areas disclosed by the study of the data available. Detailed data on the work done by the Bureau as well as a brief history of the property and some operating details are described in this report.

Jan 1, 1949

By M. S. Badollet

Introduction The manufacture of some asbestos products involves the use of asbestos in combination with water, cement and granular fillers. This type of production is often called the wet or semi-wet process and requires the use of either pressure or vacuum to eliminate the excess water in the fibrous blend so that the product may develop the proper strength during the curing stage. Asbestos - cement products available today are numerous and are a valuable contribution to the building industry. Their production in quantity depends upon the type of equipment employed, the speed at which it can be operated, and the factors involving the? blending of asbestos, cement, water, and fillers. Assuming that all mechanical troubles at a plant have been eliminated or are under control it is still advisable to study the basic properties of the raw materials used in the asbestos-cement products. The type of cement used is an important factor, but usually the manufacturer of the cement is willing to work with the asbestos development engineer and recommend the proper type to be used for the product. The source of the water should not be overlooked as a general factor involved in the production cycle. Waters containing a high percentage of contamination such as silts, humus, or soluble salts may adversely affect the setting of the cement or cause a slowing down of the production rate in the factory. Asbestos in combination with cement is an ideal material fo1 building products. It is inorganic, will not deteriorate, and can be handled by mechanical equipment with a minimum reduction of fibre length. The many physical properties peculiar to asbestos fibres should be well understood by the manufacturer. They may be briefly enumerated as follows: fibre strength, fibre composition, sliminess, length, harshness, softness, and filterability or porosity. This last named property is important and it is the purpose of this paper to present some basic studies on filtration as applied to production problems.

Jan 1, 1949

By Lester Guttman

The connection between short-range order and thermodynamic activities in binary solid solutions has been pointed out by Birchenall1 who calculated approximate values of the energy of interaction of Zn and Cu and of the degree of short-range order in alpha-brass at one composition and two temperatures. The purpose of this note is to call attention to a somewhat more accurate theory than that used by Birchenall and to extend the calculations to a wider range of temperatures and compositions as a means of testing its applicability. This is an example of the well-known general method of comparing measured thermodynamic functions of a system with those calculated from a microscopic model by means of statistical mechanics. In this case, mathematical approximations must be used which make difficult any decision about the validity of the model. Birchenall's statistical method resembles closely that calletl by Fowler and Guggenheim2 the "quasi-chemical" method which has been shown to lead in certain cases to results identical with those obtained by the method of Bethe.3 The quasi-chemical method has been extended by Takagi4 to give general formulas for the free energy of binary solid solutions based on several lattices at all compositions and temperatures. Specifically, he treats the four systems typified by: I. ß—brass; 2. a— brass; 3. AuCus; 4. AuCu. When the temperature is so high that no long-range order exists, these formulas reduce to the same form for all lattice types, namely: F - FO = (E - EO) - T(S - S°) = ½N(c — x)(2vAB — vAa - Vbb) + M1/2KTzN[x log x + 2(c - x) log (c - X) + (I - 26 + X) log (1 - 2c + x)] -kT(z - I)N[c log c+(I-c) log (I -c)] Eq 1 Here the symbols have the following meanings: F—Helmholtz free energy E—nergy 5—ntropy k—the gas constant per molecule z—coordination number, (e.g. I2 in a-brass). N—total number of atoms c—atomic fraction of A Vaa, vbb, vab—nergy per bond of the corresponding bonds log means log, throughout The superscript ° denotes the thermodynamic fuliction in the standard state, which has been chosen to be pure A or B with the same crystal structure as the solid solution. The quantity x is the ratio of the number of A-A bonds to the total number and for minimum F satisfies the equilibrium condition Vaa + Vbb — 2Vab _ (c — x)2 kT l0g x(i - 2C + x The free energy may also be written in terms of /La and B, the chemical potentials or partial free energies per alom:

Jan 1, 1949

By H. R. Kempthorne

"The Property of Bevcon Mines Limited, including a recently acquired adjoining south group, occupies an area of 2,625 acres in northeast Louvicourt township, Abitibi county, Quebec. It is situated 17 miles east of Val d'Or at the junction of provincial highways 58 and 59.Gold was first discovered in the area in 1931 by the late S. B. Jowsey on the present property of Buffaddison Gold Mines adjoining to the west. However, it was not until the winter of 1944-45 that diamond drilling encountered encouraging results on the Bevcon claims. During the period 1946-1948 a shaft was sunk to 1,000 feet and considerable development undertaken from the 500-foot to the 1,000-foot levels. Between 1947 and 1950 approximately 24,000 tons of dump ore and 48,000 tons of ore by stoping were milled at Perron Gold Mines. The favourable results of these tests prompted the decision to construct a milling plant at Bevcon. The mill began operating in July 1952, and presently has a capacity of 800 tons per day. In 1953 the shaft was deepened to 1,600 feet and is currently (1955) being driven to 2,225 feet.Total production of gold to the end of 1954 has been 101,024 ounces from the milling of 697,427 tons of ore of an average grade of 0·163 ounces per ton.GeologyThe Bevcon orebodies occur in a granodiorite stock which has an east-west length of approximately 4 miles and a maximum width of 1 1/2 miles. The property covers the central portion of the stock and its contacts with the Keewatin volcanics. Approximately one-third of the northern contact and one-half of the southern contact are contained within the Bevcon claims. The granodiorite has been cut by acid (feldspar porphyry) and basic dykes trending east-west. A younger diabase dyke, 300 feet wide, strikes northeasterly across the property 1,000 feet east of the shaft.The main ore zone, striking east-west, lies between the more northerly porphyry dyke and the north granodiorite-greenstone contact. It has been extensively sheared, fractured, altered, and mineralized by gold-bearing solutions. It is approximately 2,000 feet Jong from the west boundary towards the diabase dyke. The shaft is centrally located and passes through the south contact of the ore zone at the 500-foot level. The zone increases in width and trends northerly with depth, due to the porphyry and greenstone contacts having average dips of 80 degrees and 70 degrees respectively to the north. Thus on the uppermost or 500-foot level the width is 150 to 200 feet, and at the present bottom level at 1,600 feet the width is 400 to 500 feet.Another gold-bearing zone has been indicated 200 to 400 feet south of the main ore zone by limited surface drilling."

Jan 1, 1949

By J. W. Baker

"The Kerr-Addison mine is on the northeast shore of Larder Lake in the township of McGarry, District of Timiskaming, Ontario. It lies just south of the highway leading to the town of Kirkland Lake, 25 miles to the west.The property was first staked in the summer of 1906, by a party of prospectors led by a Dr. Reddick of Ottawa. Subsequent assessment work resulted in the erection of a 20-stamp mill in 1908. Gold from this mill was used in the first gold coins to be minted in Canada. The operation did not prove successful, however, and mining was suspended. In 1914 a consider-able amount of underground development was undertaken by the Associated Goldfields Co., without success.In 1936 Kerr-Addison Gold Mines Co. carried out large-scale sampling from four adits driven into the hillside at the mine. Results were not satisfactory, but it was decided to drill one last deep diamond drill hole from surface. The hole cut a wide section of gold ore. With this encouragement, further development outlined a large tonnage of ore, and a 500-ton mill was put into production in May, 1938. In 1939, its first full year, the mine produced 54,480 ounces of gold and 2,732 ounces of silver. By 1955 the mill had been expanded to a rate of 4,549 tons daily, and in this year 427,193 ounces of gold and 23,490 ounces of silver were produced.From 1938 to the end of 1955 the total production, from 17,473,797 tons milled, has been 3,607,462.74 ounces of gold (0.2064 ounces per ton), and 182,278.56 ounces of silver, with a total value of $131,073,037."

Jan 1, 1949

By G. D. Ruttan

"LYNN LAKE, in northern Manitoba, has become Canada's second nickel-producing area. The discovery by Sherritt Gordon Mines of nickel ore in an entirely new district was the result of systematic prospecting of a belt of volcanics and sediments situated 100 to 150 miles north of the Company's former copper-zinc mine at Sherridon, Manitoba.Prospecting in this area was begun in 1937 and continued each year until 1941, when Austin McVeigh, a company prospector, found a patch of sulphides on a gabbro outcrop near a small lake named Lynn Lake. Samples from this sulphide indicated nickel and copper in significant amount. In 1943, magnetometer work disclosed a number of weak anomalies in low ground near the discovery. In 1945, staking was followed by geophysical surveys and diamond drilling, which continued through 1947. During this period the A, B, E, EL, and Corebodies were located and partly outlined. The discovery of the high-grade ""EL"" orebody in January 1947 was the turning point in the estabishment of the mine. Subsequent development, including additional exploration on surface and under-ground, evolution of a new metallurgical process, financing, erection of a mining and milling plant, hydro-electric power development, building of a rail line from Sherridon (by Canadian National Railways) and a refinery at Fort Saskatchewan, Alberta, culminated in August 1954, when the first shipment of nickel left the refinery. This paper, presented at the 1955 Annual General Meeting of the C.l.M. in Toronto, was one of a symposium covering the whole operation."

Jan 1, 1949