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By J. O. Marsden, C. Green

In 2003, a high-temperature pressure leaching circuit to treat copper sulfide concentrates was commissioned at the copper/molybdenum operation at Bagdad, AZ. In late 2007, a medium-temperature pressure leaching circuit was commissioned at the Morenci mine in Arizona. The Morenci circuit was shut down in mid-2008, following a fire in the autoclave circuit. The onset of the global financial crisis in late 2008 resulted in significant changes to the operating profile in the Southwestern United States with respect to concentrates production, concentrates treatment, acid production and acid consumption. As a result of these changes, the Morenci concentrator was shut down, and the pressure leaching circuit remained offline. In late 2014, the increasing acid requirements in the Southwestern United States prompted a reevaluation of the Morenci concentrate leaching facilities. As a result, the pressure leaching circuit was restarted in high-temperature (200 °C) mode in May 2015 and has operated successfully for three years since recommissioning. This paper describes the current pressure leaching circuit configuration and the factors leading to the successful application of copper sulfide concentrate leaching at this location.

By Bradford C. Wesstrom

The extraction of metals from Copper Refinery Slimes may involve many different processes. This paper describes the use of pressure leaching for decopperizing of copper refinery slimes at the El Paso Refinery. Process equipment will be described, along with the process chemistry, unit operations and unit processes associated with the decopperizing process. Copper contained in the raw slimes ranges from 15-35%. After autoclaving less than 1 % copper remains.

Jan 1, 2000

By P. S. Dash

With implementation of stringent environmental regulations, ultra clean coal technology development programs have gained significant importance worldwide. As far as Indian scenario is concerned, most of the coals present in India are of drift origin and low grade, containing high mineral matter varying from 15% to greater than 50%. The inorganic or ash constituents of Indian coals are finely disseminated through the organic or carbonaceous constituents so, that commonly used physical beneficiation techniques are of only limited value in affecting separation. Chemical processes involve addition of chemicals, which react with the mineral matter and allow its easy removal. The present study envisages the effect of aqueous alkali leaching followed by acid washing on the removal of mineral matter from two different captive coals of Tata Steel at elevated temperature and pressure. The experiments are conducted at desired conditions using a bench scale pressure reactor set up having proper data acquisition and control system. The research study revealed, that it is possible to reduce the ash content up to 70% by this method. The alkali content of the product clean coal does not increase whereas the silica and alumina content reduces by nearly 58% and 62% respectively. Significant reduction in the phosphorus content is observed after the acid treatment. The crucible swelling number of the feed coal improves after the treatment. The mechanism of demineralisation was evaluated by analyzing the coal samples before and after the alkali and acid treatment using scanning electron microscope (SEM). Because of the acidic nature of the silicates and aluminates, they dissolve into the NaOH solution and form sodalite. Sodalite is partially soluble in the alkali solution. The hydrates formed during alkali treatment are partially removed due to acid wash. This study in overall provides an insight into possible alternative methods of beneficiation for removal of ash from high ash Indian coals.

Sep 1, 2012

The primary (sulphide) resources at Aphrodite are refractory in nature, requiring an oxidation process stage to be introduced to facilitate extraction of the gold. The company is investigating the use of pressure oxidation (POX) as the oxidation method for processing of high grade gold bearing concentrate it plans to produce at Aphrodite. POX has been used extensively around the world for the past 30 years and continues to be the favoured option for a number of refractory gold plants currently in the design and construction stages. Initial pressure oxidisation testing investigated the effect of temperature, pressure and grind size on a bulk flotation concentrate prepared from Alpha lode material. The concentrate averaged 47.3 g/t gold and was prepared from a composite of core samples averaging 1.49 g/t gold. Sub-samples of the concentrate were subjected to POX for 1 hour resulting in rapid oxidation during this very short period. Testing undertaken showed that there was a significant increase in sulphide oxidisation at higher temperature (220°C) and pressure (2,500 k/Pa) for the two grind sizes (75 and 20 microns) evaluated. The proposed flowsheet, OPEX and CAPEX are critical aspects for project development.

Jan 1, 2014

By Alexander V. Epiforov, Stanislav V. Balikov

This paper describes of processing tests of 8 flotation concentrates containing precious and base metals by pressure oxidation (POX) method. Concentrates 1 and 2 were gold-copper concentrates. Zinc and silver were by-products in these concentrates. These concentrates were processed by POX with following cyanidation of POX solid residues, copper solvent extraction and zinc carbonate precipitation. The recoveries of gold, copper, silver and zinc from these concentrate were 98, 99, 30 and 99%, respectively. Concentrates 3 and 4 were lead-zinc concentrates. Silver was by-product in concentrate 3. Gold, silver and copper were by-products in concentrate 4. Concentrate 3 was processed by POX with following reduction smelting of POX cakes for primary lead recovery and zinc carbonate precipitation from POX solution. The recoveries of lead and silver into ingot were 96 and 98%, respectively. The recovery of zinc was 99%. Concentrate 4 was processed by POX with following zinc carbonate precipitation and reduction smelting of POX cakes. Copper was precipitated from the POX solution using sodium sulphide prior zinc precipitation. The recovery of zinc into carbonate concentrate was 99%. The recoveries of lead, gold and silver into lead bullion were 95, 99 and 98% respectively. The recovery of copper into sulphide concentrate was 99%. Concentrate 5 was gold-pyrite concentrate, and concentrates 6-8 were double refractory gold-arsenopyrite concentrates. Silver was by-product in these concentrates. These concentrates processed by POX and CIL. The recovery of gold from concentrate 5 was 98%, and from concentrates 6-8 was 85-90. Low gold recovery from concentrates 6-8 was associated with preg-robbing factor. The recovery of silver from gold-sulphide concentrates did not exceed 10-20%. The low silver recovery was associated with argentojarosite formation that is resistant to cyanidation. The flowsheets for complex processing of precious and base metals sulphide flotation concentrates based on this test work results were proposed.

Jan 1, 2018

By M. A. Gomez, V. Yahorava, J. A. Strauss

"It is accepted widely that pressure oxidation (POX) is the most appropriate technology for processing of arsenic containing refractory gold ores. However, studies on the stability of various iron-arsenic precipitates formed during POX are limited. Since the behaviour of these phases could have significant practical implications for gold processing plants, it is important to study them in isolation. This paper compares two synthetic precipitates, basic ferric arsenate sulphate (BFAS) and basic ferric sulphate (BFS) in terms of their formation, behaviour during hot curing and cyanidation, as well as their environmental stability. BFS and BFAS were synthesised hydrothermally at 205°C and their mineralogy was confirmed using various techniques. During synthesis, the addition of H3AsO4 into an aqueous Fe2(SO4)3-H2SO4 mixture significantly decreased the iron yield to BFAS in comparison to BFS under equimolar initial iron and acid concentrations. The BFAS dissolution kinetics was slightly faster, as compared to BFS, during subsequent hot curing. Cyanidation test work on the washed synthetic precipitates indicated that the lime consumption of BFAS was three times lower in comparison to BFS, while cyanide consumptions were comparable. Fresh BFS and BFAS precipitates, as well as their cyanidation residues, were found to pass the respective environmental tests in terms of arsenic release.INTRODUCTION Pressure oxidation (POX) is generally viewed as the most appropriate technology for the processing of arsenic-containing refractory gold ores due to the stabilisation of arsenic in the leach residue (Dutrizac & Jambor, 2007; Gomez et al., 2008; Harris, 2003; Collins, Berezowsky, & Weir, 1988). Detailed laboratory studies indicated that several Fe(III)-arsenate type compounds may be formed under typical conditions of autoclave treatment of refractory gold ores (Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2010; Gomez, Becze, Cutler, & Demopoulos, 2011). The basic ferric arsenate sulphate (BFAS) phase (Gomez et al., 2008), also known as Type II ferric arsenate (Swash & Monhemius, 1994) or Phase 3 (Dutrizac & Jambor, 2007), is one of the most common arsenic-bearing products (Harris, 2003; Dutrizac & Jambor, 2007). BFAS precipitation is viewed as one of the best routes for arsenic stabilisation and performed equally well to scorodite during environmental stability tests (Harris, 2003; Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2011)."

Jan 1, 2017

By M Fisher, P Bradley, D Rogers

New England Antimony Mines has operated the Hillgrove Gold Plant at Hillgrove in New South Wales since 1969, producing stibnite and arsenopyrite products by selective flotation. Gold is present in the ore as fine free gold, gold associated with stibnite and gold associated with arsenopyrite, with some ten to 20 per cent of the gold reporting to the antimony stream and 35 - 50 per cent reporting to the arsenopyrite stream. Opportunity to process the arsenopyrite concentrate for onsite recovery of the gold values to improve upon the ten per cent recovery achieved by conventional cyanidation was recognised and subject to comparison with biological oxidation, roasting, nitric acid oxidation, low temperature oxidation (Activox«) and conventional pressure oxidation. Following further testwork and a feasibility study, a 7500 tonnes per annum concentrate feed pressure oxidation autoclave circuit was constructed at Hillgrove and commissioned in October 1999. The plant has operated at the close to design capacity since commissioning whilst optimising various operational and metallurgical aspects. The last three years has seen the process achieve an overall gold recovery of greater than 90 per cent for oxidised concentrates.

Jan 1, 2002

By G. Simmons

Santa Fe Pacific Gold Corporation (SFPGC) conducted pressure oxidation pilot plant studies at Hazen Research, Inc. on the Twin Creeks refractory carbonaceous gold ores during 1993 and 1994. Previous laboratory investigations demonstrated very good gold recoveries of 90 to 95%, using CIL cyanidation after batch pressure oxidation. However, results from the pilot plant showed that several ore types responded very poorly, with gold extractions of only 45 to 75%. Since these poor recoveries were unexpected, pilot plant testing was suspended for approximately four months while extensive research activities were conducted to determine the cause(s) and identify potential solutions. This paper describes the batch and pilot plant test results, the research activities that eventually identified the cause of the gold recovery problem, and the final semicontinuous and continuous pilot plant operations that confirmed possible solutions.

Jan 1, 1997

By J. Gathje

Normal process development for pressure preoxidation treatment of refractory gold ores starts with laboratory batch autoclave tests, followed by operation of a continuous autoclave pilot plant for confirmation of the various process options. This scheme will generally provide good information showing the effects of such variables as grind size, time, and temperature, and will indicate whether autoclave preoxidation will produce solids that are amenable to cyanidation for gold recovery. However, several recent test programs conducted over the last three to four years have shown that the cyanide leaching responses of treated solids from the batch tests can differ considerably from those achieved by the continuous pilot plant autoclave. Examples are provided to demonstrate these differences and to show the importance of extending the laboratory investigations to include the use of a semicontinuous autoclave test procedure. A test case is cited in which this procedure provided data that could not be obtained from batch tests.

Jan 1, 1995

By Raymond L. Lowrie

Deregulation, as authorized by the Energy Policy Act of 1992 (PL102-486) allows free-market competition in the electric-utility industry. As the act unfolds, though, uncertainties abound about the type, degree and direction of impacts throughout the affected economy — from fuel suppliers to electricity generators and from power distributors to energy consumers. Instead of having a familiar base of captive customers and electricity prices fixed by negotiation with state public utility commissions, utility companies are preparing for open, free-market competition. They are looking at all areas, including fuel supply, to cut costs to remain competitive. Humorous anecdotes are told about utility companies shunning insiders for senior executive positions. Instead, they are opting for people from the telephone or other industries with deregulation experience. And there are light-hearted stories about a trend away from traditional electric-company names, such as the name of a city or state followed by Edison or Power and Light, to space-age names, such as Ameren, Entergy, Illinova or Unicom. No one wants to be left behind or be perceived to be left behind.

Jan 1, 1996

By H. J. McQueen

Pressure welding is a solid state joining technique that depends on bringing the parts into sufficiently close contact that inter-atomic bonds are achieved. Pressing is more effective at elevated temperatures where plastic flow causes the asperities to collapse; improved application conditions are derived from hot-work research to clarify temperature and strain rate dependence of hot strength and ductility. The substructure evolution systematically studied in hot working to determine dynamic recovery or recrystallization is applied to clarifying that developed in welding. The various processes are affected differently by work-piece geometry and final shape requirements. In addition to pre-cleaning of the surfaces, the plastic flow helps disperse the remaining oxide layers as was originally exemplified in blacksmith hot forging of layered sword blades and in bellldie welding of wrought iron tubes. The presentation critically compares the utility for various materials and configurations of simple pressure, ultrasonic application, diffusion, explosive, rotary and linear friction and friction-stir processes. Diffusion bonding (primarily Ti) with light cleaning, low pressure, little distortion in protective furnace atmosphere contrasts strongly with the heavy upsetting in friction welding, or complex alloy mingling and substructure variations in friction stir joints.

Jan 1, 2011

By AUDLEY H. STOW

I. INTRODUCTION. THE general drift of the discussion as to the relative merits of pressure- and exhaust-fans has resulted, if we may judge from the prevailing practice, largely in favor of the latter. The subject has been hitherto treated, however, with special reference to highly gaseous mines, the effect of the form of ventilation upon dust-explosions having been too little considered. Even in mines containing practically no gas, dust-explosions may occur; and if, as I believe, pressure-fans are to be preferred for their effect upon dust, it may be worth while to reopen the debate, and to challenge the advisability of exhaust-ventilation under certain conditions. There are several forms of colliery-ventilation, which may be described as follows: Plain or simple pressure-ventilation, in which the fan acts as a pressure-fan, and the movement of coal is unobstructed at the surface by doors or equivalent devices in drifts or shafts, the traveling and haulage thus being in the return-current. Plain exhaust-ventilation, in which the fan acts as an exhaust-fan, the movement of coal being likewise unobstructed at the surface, and the traveling and haulage being in the intake. Obstructed pressure-ventilation, in which the movement of coal is obstructed at the surface, in order that the traveling and haulage may be in the intake. Obstructed exhaust-ventilation, in which the movement of coal is obstructed at the surface, in order that the traveling and haulage may be in the return. The apparent advantages in running a fan "pressure" during working-hours, and " exhaust" between shifts, seem to justify the recognition of this combination as a standard form of ven-

Feb 1, 1909

By Karen J. Dawson, Francisco Johnson

"Pressure-grouted high strength helical displacement piles are a recently developed pile type that can be useful in conditions where noise or vibrations must be low or where access or clearance is limited. However, there is no information in the literature that can be used to estimate the soil resistance of these piles or production rates. To fill this information need, this paper presents a New Jersey installation case history and the results of static axial and lateral load tests on both pressure-grouted and ungrouted high strength helical piles at the case history site and trial installation locations in New Jersey and Washington State. Piles between 25 and 50 feet long comprised of steel shaft diameters of 4.5, 5.5, and 7 inches with equivalent grout column diameters ranging from 12 to 22 inches were tested. Lateral loads of up to 100 kips and axial compression loads of up to 700 kips were applied. The results of the load tests are compared to predictions of lateral deformation and axial resistance.INTRODUCTIONHelical piles have long been recognized as a useful foundation type in situations where noise and vibrations must be limited, or where there are access or clearance restrictions. Relatively well-documented design methods and torque to capacity correlations have been developed for the most commonly used helical piles, which are relatively small (typically shafts of 6 inches or less) with corresponding low load carrying resistance.With the increased need to construct in congested urban environments, there is incentive to develop helical piles with higher axial resistance. Seismic and other loading conditions also require lateral resistance, which is low for the typically small helical pile shafts. One method of increasing the soil resistance, both axially and laterally and at relatively low cost, is to place grout around the shaft. Injecting the grout under pressure through the hollow helical pipe section and out a grout port or ports located near the toe of the pile has the potential to increase the pile resistance significantly above that which can be achieve by gravity grouting. Not only does the pressurized grout push out against the surrounding soil, but the rotating helix helps to distribute the grout laterally. Unfortunately, little information is available in the literature to help designers estimate the resistance of grouted helical piles in general and none is available regarding pressuregrouted helical piles."

Jan 1, 2016

By Takashi Miyamoto, Hideo Nakae, Hideki Yamaura, Takeshi Yanagihara

"For the production of partially composed metal matrix composites, namely discontinuous MMCs, using a casting· process, the interpenetrated phase composites with SiC particles were fabricated by pressureless iDfiltration using molten Al-Si alloys. This process is based on a wetting phenomenon, therefore, we discussed the technique based on the reactive wetting. The SiC particles coated by diluted water glass were sintered in a mullite Tammann tube and simultaneously infiltrated with molten Al-Si alloys in air at 1173~1573K. As for the improvement of the wettability between the SiC and the liquid aluminum alloy, Fe3O 4 powder was mixed with the water glass due to the thermit reaction between Fe3O4 and molten aluminum alloy. In some experiments, pure aluminum powder was placed on the sintered SiC to increase the interfacial area and the chemical reaction between the sintered Sic. and the melt. By combining these conditions, we succeeded in the complete infiltration without pressure at 1173K.IntroductionAs is well known, the mechanical properties of metal matrix composites (abbreviated MMCs) are superior than that of ordinary metals. However, their use has not been widely accepted because the production cost is very high due to their poor machinability. Therefore, the production of partially composed, namely discontinuous MMCs, by as the Lanxide process [l,2] has been investigated for many years. The Lanxide process, it takes a long time, sometimes up to 10h, in a nitrogen atmosphere for the infiltration. Therefore, the cost will be higher for common use. On the other hand, a high 'pressure process has been adopted for the production of discontinuous MMCs by the Toyota Motor Corp.[3]."

Jan 1, 2000

By Sergio Romo, Gerardo Fuentes, Adriana Garcés

Refractory ores with gold entrapped in a sulfide matrix, must be processed in a first stage with chemical or physical treatment in order to liberate the gold for a subsequent step with cyanide. The goal of this research was to compare the refractory behavior of a gold concentrate treated using two pretreatment methods: pressure oxidation and fine grinding. Gold concentrate from Viacha Mining in Bolivia, assaying 50.11 gpt, with a P80 of 131 ?m was used. The concentrate contains arsenopyrite and pyrite as main sulphides in the matrix. A preliminary test with cyanide resulted only 13.5% of gold extraction with 4 hours of stirred leaching. Using an autoclave oxidation with sulphuric acid and 12 bar oxygen pressure at 220°C pretreatment, the cyanide gold extraction increased to 69.0% in 4 hours. When material was ground in a pulverizer, producing a P80 of 20 ?m and the product directly cyanided, stirred leaching gave a gold extraction of 65% in 4 hours. For both techniques, the effect of temperature, sulfur produced in autoclave oxidation, optimization of the cyanide and the nature of residues were also studied.

Jan 1, 2014

By S. A. Falconer

Much attention and publicity has been given, during recent years, to grinding, classification, flotation, and thickening. The various technical papers, and symposiums held to discuss these important phases of milling, have contributed to a better under- standing of the fundamental principles and operating variables involved. Another important part of milling- to the flotation operator-is a treatment step to which frequently too little attention is given-" conditioning," or the treatment the ground mineral pulp receives before it enters the flotation machines. Conditioning" is a hackneyed and frequently misused term, commonly employed to describe the pretreatment of surfaces of minerals in ore pulps or mill pr6ducts prior to froth flotation. In general, such pretreatment is for the purpose of changing the flotation characteristics of these mineral surfaces to enable them to respond in some desired predetermined manner when subjected to flotation. Taggartl states that the function of conditioning is "either to insure selective collector coating of one mineral species while another species is not; or to take such steps as will compensate for departure there from."

Jan 1, 1949

By Yisa Liu, Lili Xu, Shina Li, Kang Li, Jiong Dong, Zichen Yin, Ruixin Ma

With the evolving landscape of gold mineral resource development and utilization, the easily treatable gold resources are continuously decreasing, while refractory gold minerals are becoming the most important resources in the field of gold extraction. In these original ores, most of the gold is encapsulated in the lattice of pyrite and arsenopyrite, resulting in difficulty of gold transfer into the solution during the leaching process. The most effective method to solve the problem of insufficient contact between gold particles and leaching reagent is oxidation pretreatment before leaching. Different from traditional high-temperature roasting, concentrated sulfuric acid was used as both an oxidant and leaching agent in a sulfideencapsulated refractory gold ore to decompose the pyrite in the curing environment to expose the gold and improve the leaching efficiency. The experimental results showed that under the conditions of liquid solid ratio 3:1, curing temperature 240 °C and the reaction time 1.5 h, the weight loss rate and iron removal rate of the ore sample reached the highest value of 60.01% and 99.68%, respectively. The main phase of curing residue was Fe2( SO4)3, and silica was nearly the only phase after washing. At the same time, by combining the sodium thiosulfate system gold leaching method, the gold leaching rate increased from 3.67% to 81.30% before and after pretreatment with concentrated sulfuric acid.

Feb 19, 2024

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By Corby G. Anderson

Hydrometallurgical technology for the pretreatment of refractory gold concentrates has been developed at Sunshine Mining and Refining Company. It employs a patented nitrous-sulfuric acid pressure leaching process which' was proven industrially at the Sunshine refinery. Additionally, pretreatment for removal of antimony and some other impurities is done with alkaline sulfide leaching. This paper will discuss the successful application of these two technologies for pretreatment of a refractory gold concentrate prior to CIL gold recovery. A complex gold concentrate composed of pyrite, arsenopyrite and stibnite was tested. Results of antimony leaching in alkaline sulfide media will be discussed including some details of a novel and selective recovery method for gold leached by polysulfide or thiosulfate" Also, the factors important in and the results of the application of nitrogen species catalyzed pressure leaching to refractory gold concentrates will be detailed.

Jan 1, 1996

By C. Hartford, T. Holmes

Bulk-solids handling systems are often the most over-looked component and thereby weakest links in a processing plant’s value chain. Since their performance can dictate that of the entire operation, they actually deserve special attention. When designing a liquid handling plant, density and viscosity are well known and commonly used as design parameters. Bulk solids however, differ. While the design process is similar, the relevant parameters in handling bulk solids are instead friction, cohesive strength, compressibility, and permeability. These then vary depending on the mineralogy, particle size distribution and shape, moisture content, storage time-at-rest, temperature, and consolidation pressure. With so many variables, it becomes important to characterize each individual bulk solid across the full range of representative process conditions within the handling system, plant wide – or if you are not very lucky, suffer the consequences of poor material flow. Measuring flow properties and applying them correctly in bulk solid handling system design reduces project risk, saves significant capital, and drastically increases throughput, especially when done in the early stages of a project. Keywords: Flow Properties, Bulk Solids, Process Conditions, System Design

Jan 1, 2020