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By Anievas JB, Sevillano AC

This paper describes the acquisition, exploration, development, initial operation and subsequent financing of the Bulawan mine by means of a listing on the Toronto Stock Exchange of a subsidiary of the parent company, Philex Mining Corporation.Located on the island of Negros in the Philippines the property is unique on at least two counts: it is a disseminated gold deposit that occurs in a region of predominantly porphyry copper mineralisation; and it is a gold deposit that is mined by a bulk method of extraction (front and block cave) instead of the normal selective mining methods.

Jan 1, 1997

By J. B. Dilworth

OUTCROPS of coal have bees discovered is many localities is the Philippine archipelago, and practically all of the larger islands contain deposits of this mineral. Very little prospecting has been done to determine the value of the various coal-bearing areas, but so far as known, the largest and most promising fields are found : (1) is northern Cebu; (2) is the small island of Batan, a part of the province of Albay is southeasten Luzon; (3) is the somewhat larger island of Polillo, off the east coast of Luzon, and (4) is southern Mindoro, sear the small coast tows of Bulalacao. Northern Panay, south-central Cebu, and various localities is southern Luzon, Masbate, Negros, and Mindanao also afford evidences of the existence of coal-beds, the extent and value of which have not yet bees proved. The general position of these islands and districts is shows on the map of a portion of the Philippine Islands, Fig. 1. Some of these coal-fields have been known for many years (coal was discovered is Cebu 1827 and is Batas is 1842),1 and several futile attempts were made by the Spaniards to operate mines is these districts. But owing to many circumstances, chief among which were indifferent management, the political unrest of the islands, natural difficulties of transportation, and those inherent in the mining of steeply-inclined and somewhat irregular seams, no considerable output was ever obtained from any of these mines, and the fuel required is the many departments of industrial and political life has continued to be drawn largely from Australia and Japan. These conditions exist to a great degree at present, and though much interest is the coal-deposits of the Philippines

Jan 1, 1909

By John A. Haggman

Philippines is a country that is richly endowed in mineral wealth. In 1988, Climax Arimco Mining Corp. (CAMC) geologists found the Dinkidi porphyry gold-copper deposit in Nueva Vizcaya province. It is the most significant mineral discovery in that country in recent times. To date, the company has defined indicated resources of 124 Mt (136 million st) of 1-g/t (0.029-oz/st) gold and 0.4% copper. This includes a high-grade core of 7.9 Mt (8.7 million st) of 6-g/t (0.175-oz/st) gold equivalent. Total contained metal is 124.4 t (4 million oz) of gold and 499 kt (1.1 billion lb) of copper. Dinkidi's discovery resulted from initial geologic reconnaissance and recognition of the intrusive complex that is exposed at surface and anomalous in its topographic expression. This was followed by systematic exploration. This includes extensive gradient array induced polarization (IP), ground magnetics, geochemical sampling and diamond drilling. This later defined a further 16 satellite porphyry targets in the Didipio region. Climax was been granted a Financial and Technical Assistance Agreement contract with the Philippine government. It allows 100% foreign ownership of mining projects. After four years of negotiations, Climax was the first company to have such an application granted. Some 120 applications from numerous international mining companies are waiting for approval following implementation of new Philippine Mining Act of 1995. Exploration history Didipio is located 200 km (125 miles) north of Manila at an elevation of about 700 m (2,300 ft) in the remote Sierra Madre mountains. This region remains mostly unexplored. The property is accessed by 25 km (15 miles) of logging track from the town of Cabarroguis, Quirino. The area experiences an average rainfall of about 3,000 mm (118 in.) a year. Most of it falls during the July-to-November typhoon season. Didipio was first recognized as a gold province in the 1970s when native Ifugao and Ilongot hunters discovered alluvial gold in the region. The region had been prospected over the years by local companies. They were mostly prospecting for alluvial gold. However, in 1988, Climax Mining geologists identified the potential of an obscure razorback ridge protruding from the alluvial valley floor. This ridge, later named Dinkidi by Climax, was the site of several small- scale tunnels. Locals had mined narrow quartz stockwork veining and sluiced soft argillic alteration zones, using irrigation canals and sluice boxes to catch free gold.

Jan 1, 1997

By R. S. Hearon

The image of the open-pit miner in the eyes or the Environmentalist has never been very outstanding. The phosphate industry, whose history in Florida reaches back to the late 1800's, can-not be credited until recently with a large number or accomplishments in terms of protection or the environment to change this image. This lack of action was not deliberate or in opposition with the desires of the public. In the formative years, there was little or no public and the companies found it necessary to build towns to house their employees and their families, towns which remained in existence until the late 50's and early 60's or formed the core of present large communities. Neither these pioneers nor most subsequent resource developers considered themselves un-thinking spoilers, nor were they so regarded by their contemporaries. Instead, they acted in a manner consistent with their environmental circumstances and intellectual heritage. Early Americans did make mistakes in using the land but the mistakes became apparent only in the opinion of later generations. Over the past five to ten years, there has been a new self-awareness in the industry with regard to environmental responsibilities brought about, in part by a continuing onslaught of new regulations with jurisdiction over our activities. Part of the new regulations are aimed at industries as a whole while many, particularly state regulations, pertain specifically to the phosphate mining industry. Why all the new regulations? The reasons are encased in a complex web of activity but stem primarily from a new public awareness of its environment. More and more of our youth have become interested in the environmental science areas such as biology and ecology. The tremendous growth rate in both the population and industry has made personal issues out of subjects such as atmospheric inversions and water shortages which previously were abstract concepts. The State has grown from a population of 1,500,000 in 1930 to approximately 9,000,000 people today. This personal impact and general lack of knowledge on the part of the public concerning economics has resulted in big business no longer being held in awe, often in contempt and generally in suspicion where environmental concerns are encountered.

Jan 1, 1978

By Ingvar Ymén, Alexandra Lundmark

"The depressive effect of dichromate on galena was evaluated with chemical experiments and small-scale depression experiments at a pH of around 12. The depressive effect was measured with Dynamic Vapor Sorption (DVS), which measures the water uptake of a sample as a function of the % relative humidity. The depression is due to PbCrO4PbO, which in the presence of Ca2+ and SO4 2- forms a more or less amorphous solid solution (Pb,Ca)(CrO4,SO4)PbO, which clogs to the surfaces of the ore. Free Pb2+- ions are needed for depression to occur and at high pH Pb2+ - hydroxide complexes, supply enough Pb2+ - ions to precipitate (Pb,Ca)(CrO4,SO4)PbO. In air CO2, precipitates CaCO3 which slowly lowers pH, precipitating more (Pb,Ca)(CrO4,SO4)PbO and CaCO3 on galena. Similar experiments where performed with five alternative depressors whereof phosphate, which forms an amorphous precipitate of approximate composition Pb3Ca13(PO4)10SO4, gave the best results. Phosphate was tested in laboratory scale flotation experiments giving encouraging results.INTRODUCTIONWithin Boliden Mines, concentrating of copper and lead from complex sulfide ores is performed by bulk flotation, meaning that copper and lead are concentrated in the same product. Downstream, copper and lead are separated by flotation of chalcopyrite, and depression of galena. Boliden has for many decades used sodium dichromate to depress galena (reference 1). Dichromate is both toxic and carcinogenic and Boliden has for many years investigated several alternatives. So far, however, the best results have been obtained with dichromate. Since Boliden has tried to substitute dichromate for a long time without finding a process as effective, Boliden decided to clarify the function of dichromate in the depression of galena and on the basis of the outcome find alternative depressors with similar function. This study was given to RISE Bioscience and Materials / Surface, Process and Formulation as a consultancy assignment. This paper presents the outcome of the combined efforts of Boliden and RISE."

Jan 1, 2018

By Jinrong (Patrick) Mang

Three of the most challenging problems in phosphate beneficiation are discussed: flotation efficiency, resource conservation and environmental impact. Some new flotation machines offer the opportunity of reducing power and reagent consumption significantly, while increasing specific capacity many fold. Efficiency might also be improved dramatically by replacing the "double float" process with a single-collector scheme. Model based software control is a powerful tool for improving overall plant efficiency. Recovery of phosphate values from the phosphatic clays could extend phosphorus reserve life significantly. phosphate recovery from the slimes might be achieved by sizing-flotation, selective flocculation and bioleaching. Reducing the volume of phosphatic clays produced is another key stop to minimizing phoephate logs. Such a reduction may be realized by floating at finer cut size. Although an ideal' dolomite separation process is yet to be developed, a cationic flotation process may prove to 'be economically feasible. Loss of phosphate in the desliming stage is the major problem with most of the flotation schemes for removing dolomite.

Jan 1, 1995

By L. Telfer

Summary During Palaeozoic time, there were deposited in the Canadian Rockies four beds of phosphate rock, ranging in age from Mississippian to Jurassic. Two of these beds are of probable economic importance if some means of separating the phosphate from the gangue can be devised. All the more important beds of phosphate rock so far discovered are just behind the front ranges of the Rocky mountains, within fifty miles of the prairie lands of Alberta. Mining conditions are favourable, with an abundance of timber and ample power available. The phosphate beds are all of the sedimentary type, and they all occur, apparently, at the same stratigraphic horizons over a wide area. The conditions necessary for deposition evidently occurred at several different periods in geological time, and were widespread. The most important factor appears to have been the condition of the land surface surrounding the basin of de-position. Both oolitic and nodular phosphate were laid down under nearly similar conditions. Introduction Following the discovery of phosphate rock in Idaho and Montana, search was commenced in Canada to determine whether formations of similar age in the Canadian Rockies carried similar beds of phosphate. The most widespread search has been that undertaken by the mines department of the Consolidated Mining and Smelting Company of Canada. The following paper will discuss some of the results of this exploration.

Jan 1, 1933

By Musa Karakus

The sedimentary iron ores of Alsace-Lorraine, France have very high phosphorous contents that average 0.7% and are as much as 2.19% P. Ores from the Tucquegnieux and Joeuf mines have been studied by cathodoluminescence microscopy, X-ray diffraction, scanning electron microscopy, and electron microprobe analysis in order to fully characterize the mineralogy, size, shape, and distribution of the deleterious phosphate grains. The phosphorous occurs as collophane, a carbonate fluorapatite, in ten morphological forms, most abundantly as microcoprolites, but also as intraclasts, concentric layers, and cortices in ooids, phosphate replaced ooids and bioclasts, phosphatiC shells, fossil infillings and internal molds, fish teeth, phosphatiC laminae, and cements between the goethite ooids. About 95% of the phosphate grains are sufficiently large that relatively fine grinding fol'lowed by reverse flotation would be expected to be effective in significantly diminishing the phosphorous content of the concentrates.

Jan 1, 1989

By R. D. Grove

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and therefore only assist in recalibrating the operators' vision when major deviations occur. An image analysis system has been developed by IMC Fertilizer to improve upon the accuracy and precision of the composition estimation process. It still relies upon the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. This paper describes the system and its use and presents comparative results for various process streams.

Jan 1, 1993

By H. W. Breathitt

World demand for phosphate rock has increased significantly in the past fifteen years. Prior to the early 1960's, most of the world production was obtained from Florida, North Africa, and Kola. As the 1960's arrived, new mines in North Florida and Eastern North Carolina, as well as expanded production in the Western United States, .increased domestic production. Many new mines overseas have also become significant. This includes countries such as Senegal, Togo, Israel, Spanish Sahara, and Jordan. Limited production, often as by-products, has been noted in South Africa, Brazil, and other countries. In recent years, and even recent months, we have learned of many new areas being considered as potential sources of phosphate rock. This includes Australia, Saudi Arabia, Mexico, Colombia, and Brazil. Many other developing countries have discoveries and are considering their new deposits, often with difficult beneficiation problems, as potential sources of phosphate. These factors all relate to expanded world, population and the demand for more fertilizer products to produce food. In this paper, four areas of the world with different types of phosphate deposits are briefly reviewed to contrast the ore beneficiation problems to Florida procedures--long considered the "standard" of the industry, at least for most of the United States' domestic production. Agrico has three large operating mines in Florida with total production capacity exceeding seven million tons per year. Here, pebble phosphate (+14 mesh material) is produced without the use of flotation, whereas all of the material finer than 14 mesh is subjected to flotation beneficiation to upgrade into high grade concentrates.

Jan 1, 1977

By N. Edmonson

An examination of the statistics of the world phosphate fertilizer industry since 1980 reveals an increasing tendency for fertilizer manufacturing activity to concentrate in phosphate rock mining areas. The economic justification for this resource-oriented strategy is clear. The choice between shipping phosphate rock, a comparatively low-value product, and shipping more valuable finished fertilizers will always be resolved in favor of the latter if cost considerations control the decision. The historical existence of substantial phosphate fertilizer manufacturing capacity oriented toward fertilizer-consuming activities and dependent on imported phosphate rock shows that narrow cost considerations have not always determined the industry's location. One is entitled to ask what conditions have changed to precipitate the observed relocations, and how permanent these changes are. These questions are the subject of this investigation.

Jan 1, 1995

By Andrew S. McCreath

THE manufacture of pig iron for conversion into steel by the Bessemer and open-hearth processes, is now one of the most important industries of the United States. It is necessary that iron intended for this purpose should be very pure, and especially must it be comparatively free from phosphorus. Great care must therefore he exercised in the selection of proper ores, flux, and fuel. Only such ores as are practically free from phosphorus can be used, and pure fuel is as much a necessity as pure ores; though hitherto iron men have paid comparatively little attention to this point. During the course of my work as chemist for the Second Geological Survey of Pennsylvania, I had occasion to examine some of the bituminous coals of the State for phosphorus, and the results obtained are so interesting that I venture to present them to the notice of the members of the Institute. The coals are arranged in geological order according to the different beds, and the table shows the percentage of phosphorus in the coal and also in the coke. The greatest number of specimens have been selected from the Pittsburgh bed, because it is the principal coal-bed of Southwestern Pennsylvania, and most of the mineral fuel which is mined along the Youghiogheny and Monongahela rivers, to be used in the coke ovens of the Connellsville region and in the blast furnaces and mills of Pittsburgh and its vicinity, and to be shipped to Western and Southern markets, comes from this bed. It will be noticed that many of the specimens examined contain

Jan 1, 1880

By James B. Cathcart

Marine phosphorite deposits occur in Brazil, in the Bambui Group of late Precambrian or Early Cambrian age. The phosphorite is laminated, isoclinally folded, and is composed of black, elongated apatite pellets and quartz grains cemented by quartz and muscovite. Abundant, narrow quartz veinlets cut through the rock at right angles to the elongation direction of the pellets. The phosphorite is 0 to 80 meters thick and contains 5 to 30 percent P205. The deposit is elongate towards the northeast, and the central, thickest, and richest part is bounded by faults. Measured reserves are about 250 million tonnes that average about 13 percent P205. Preliminary testing indicates that grinding, scrubbing, and desliming will produce a material usable for fertilizer manufacture at a cost competitive with imported phosphate fertilizers.

Jan 1, 1977

By Anivaldo Chevane, Leonardo Xerinda, Rogério Sendela, Andre Vilanculos

Moatize Coal Mine is located in Tete Province, in centre of Mozambique. The deposit contains Gondwana allochthonous coals, and has a large amount of mudstone and siltstone banding. Phosphorus levels in the coal can be high which impacts the use of the coals in steel making where phosphorus is considered a contaminant. The Chipanga seam in the Moatize deposit shows considerable variability, vertically within the seam and laterally across the deposit. The data available from the exploration work indicates that the phosphorus is predominantly present as Apatite but the Crandallite minerals also are significant. The concentration of phosphorus varies with coal particle density with the highest phosphorus levels found for the mid density coal which also shows the highest likely levels of apatite or fluorapatite. Crandallite minerals show higher potential concentrations in the Lower density coal..

Oct 3, 2019

By A. E. Cameron

The theory of atomic distribution of the stranger atoms in the space lattice of the solvent metal has been well developed by Rosenhain. It has long been known that the addition of one metal to another to form a solid solution increases the strength and hardness of the solvent metal. This increase is practically proportional to the amount of added substance up to the limit of solid solubility. To account for this increase in hardness and strength, Rosenhain assumes that the stranger atoms occupy positions on the solvent metal space lattice. Atomic attractions about the stranger atoms will not be the same as in the case of the pure metal, and there will thus be a disturbance of the orderly arrangement of the atoms on the space lattice, or a distortion of the lattice. Such a disturbance would interfere with the ease of slip along the planes and would thus tend to promote strength and hardness. Rosenhain notes that not only may there be a local disturbance of the lattice about the stranger atom but there may well be also a measurable change in the dimensions of the lattice as a whole. The relative amounts of local and general distortion of the lattice will depend upon the nature of the lattice itself. As Rosenhain says, "If the lattice is comparatively soft and flexible the distortion is likely to be largely local. In a stiff lattice, however, local distortion will be resisted and there will be a correspondingly increased general distortion."

Jan 1, 1927

By M I. Pownceby, N Karimian, A Frierdich

These may be found with goethite through mechanisms including direct substitution or coprecipitation of nanocrystalline phases. Understanding P incorporation in goethite has significant implications for Australia’s iron ore industry as it lowers their commodity value. The current study tests a novel low-temperature technique to extract P impurities from synthetic goethite phases under O2-free ambient conditions by utilising Fe(II)-catalysed recrystallisation. The objective of this study was to examine the effect of the Fe(II)-catalysed recrystallisation of goethite on the geochemical behaviour (mobility and speciation) of co-associated P. To achieve this, we tracked changes in labile P (aqueous and 1M NaOH extractable) concentrations over time in goethite suspensions which were reacted with Fe(II)aq for 14 days under circumneutral pH conditions and room temperature conditions. Temporal changes in Fe mineralogy were investigated via synchrotron-based X-ray absorption spectroscopy. Iron K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy confirmed goethite as the only mineral phase in P-free treatments while goethite (~86 per cent) and feroxyhyte (~14 per cent) were the main phases in 1.0 per cent P-containing treatments after a 14- day reaction with Fe(II)aq. According to our findings, the treatment of P-goethite with Fe(II) for a duration of 7–14 days, followed by a 24-hour extraction of the reacted solids using 1M NaOH, results in the removal of approximately 79.5 per cent of the initial P content. This removal encompasses both the aqueous fraction (~4.5 per cent) and the surface adsorbed fraction (~75 per cent) from the 1 per cent P-bearing mineral phase. Notably, this approach demonstrates an improvement in P extractability, with approximately a 10 per cent increase compared to the 1 per cent P-goethite sample that was not reacted with Fe(II).

Sep 18, 2023

By John Hanna

Recently. researchers at The University of Alabama have developed a two-step method for the treatment of phosphorus sludge that includes bulk removal of phosphorus by physical separation techniques followed by remediation of the residual P4 in the sludge using a novel wet air oxidation technique known as "HSAD", Tests made on samples of the electric furnace phosphorus sludge have demonstrated that essentially complete and fast removal of the P4 in the sludge can be achieved by the HSAD wet oxidation treatment, Further studies were made to determine the applicability of the two-step process on sludges of various origins. P4 contents different pre-treatment and storage conditions, The present work discusses the mechanisms and factors controlling the HSAD wet air oxidation remediation approach.

Jan 1, 1992

By T. Fujita

The removal of phosphorus is essential 1n order to increase the recycling of steelmaking slags for their manganese, iron and lime contents. This study aims at establishing the phosphorus mineralogy and its distribution in steelmaking slags, the effect of slow cooling, and the methods of phosphorus removal. A series of steelmaking slag samples was prepared at different cooling rates, and the mineralogy, chemistry and grain size of the samples were investigated with SEM/EDS and x-ray diffraction. The test results using high gradient magnetic separation are discussed.

Jan 1, 1988

By E. Fregeau-Wu

The major obstacle in recycling steelmaking slags to the blast furnace is their phosphorus content. Removal of the phosphorus, which is primarily associated with the silicate and phosphate phases, would allow for greater recycle of these slags for their iron, manganese, and lime contents. Calculations show that separation of the silicates from the oxide phases would remove nearly 90% of the phosphorus from the slag. The variable grain size of the as-received slag made liberation by fine grinding difficult. Therefore, slow-cooling experiments were undertaken to improve the grain size distribution. The grain size distributions were determined using in-situ image analysis. The samples were ground to their apparent liberation size and high gradient magnetic separation was used to separate the magnetic oxides from the nonmagnetic silicates and phosphates. Liberation analysis and modeling was performed on selected separation products for discussion of benefication characteristics.

Jan 1, 1995

By Ewan Wingate, Ranjit Prasad, Yanjun Liu

The use of phosphorus by mankind is long established. From use in agriculture, foods, high tech electronics, and more recently in EV battery cathode production, one cannot escape its impact on today’s society. This paper will review and describe the circular journey of phosphorus through its value chain from the mining operation of phosphate ore through beneficiation into downstream chemicals production and finally into the EV battery cathode production space. This will include a review of phosphoric acid production from phosphate concentrate using wet process route and thermal route. The wet process route discussed will be via dissolution of phosphate concentrate by sulphuric acid. The thermal route will discuss thermal decomposition of phosphate concentrate using submerged arc furnace to produce yellow phosphorus followed by its combustion to produce phosphorus pentoxide and subsequent hydration to produce phosphoric acid. It will also discuss briefly other phosphate derivatives for specialty chemicals and recovery of phosphorus units from wastewater treatment plants, sewage sludge and incinerator ash. Finally, the paper will discuss the use of phosphorus in EV batteries in the form LFP cathode materials and its production. It will also briefly discuss the LFP battery recycle.

Sep 11, 2023