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By David P. Reddick

Economics is a social science dealing with the allocation of scarce resources. In modern times the “science” was identified by Adam Smith in his book, The Wealth of Nations, written in 1776. Mr.Smith, highly influenced by the Mercantilists of the 17th and 18th centuries, identified the “Invisible Hand” which would lead every individual to pursue selfish rewards in purchasing goods. He speculated these selfish motives would result in the best good for all. Price would be determined by barter, at a point where self-centered customers and vendors were mutually satisfied. Today, Smith’s theory is known throughout the world as “Capitalism” but most often termed “Free Enterprise” in the United States.

Jan 1, 1992

By Xinli Wang, Matthew Andriese, Jiann-Yang Hwang, Zhiwei Peng, Byoung-Gon Kim

"The microwave reflection loss (RL) of ferric oxide is studied in the temperature range from 297 to approximately 1400 Kat frequencies of 915 and 2450 MHz. It is shown that the maximum microwave absorption with RL of -38.46 and -35.97 dB can be obtained for ferric oxide having thicknesses of 0.03 and 0.01 m at 915 and 2450 MHz, respectively. The maximum absorption peak with RL below -10 dB is in a 250 K temperature range from 723 to 973 Kat 915 MHz, which shifts to the range between 823 and 1073 K at 2450 MHz. This migration is in good agreement with the variation of the dielectric loss tangent of ferric oxide.IntroductionMicrowave irradiation has distinguishing characteristics such as volumetric and selective heating compared with conventional methods, leading to extremely broad applications in materials heating and processing [1-5].The efficiency of microwave heating was found to be dependent on various factors, such as microwave power [6], frequency [7,8], radiation time [8], applicator geometry [8], sample microwave absorption properties and position as well as dimension [9-11 ], etc. Among these parameters, sample dimension plays an important role but is usually neglected by researchers in microwave processing of materials. In fact, although numerous studies have been directed toward the utilization of microwave energy to assist materials heating and processing, few reports were released on the effect of sample dimension [12,13].This is because all aforementioned factors influencing microwave heating generally exert interactive effects to each other during the heating process, making clarification of the effect of sample dimension difficult. Therefore, it is necessary to propose a parameter or concept for quantifying the effect of absorber dimension on microwave heating, increasing heating efficiency."

Jan 1, 2013

By Ronaldo Câmara Cozza

Iron aluminide alloy; Ball-cratering wear testing; Rolling abrasion; Wear volume; Coefficient of friction

Jul 31, 2018

By Cristiano José Scheuer

Experiments were carried out aiming to study the influence of micro-abrasive wear test variables and plasma treatment parameters, on the tribological characteristics of low-temperature plasma carburized AISI 420 steel. The first part of this study was conducted in order to evaluate the influence of abrasive particle size, normal load and counter body rotation speed on carburized sample wear behavior; and the second part was conducted in order to evaluate the treatment temperature and time effect on carburized samples wear behavior. Plasma carburizing treatments were performed at 8 and 12 h, for temperatures ranging from 350 to 500°C; and at constant temperatures of 400°C for times between 12 to 48h, and for 450°C for times of 4 to 16h. Micro-abrasive wear test were performed by mean of a calowear ball-cratering equipment using a polished ball of AISI 52100 steel rotating at 80, 120 and 160 rpm, for sliding distances from 2.6 to 104.2 m. Alumina abrasive particles with sizes of 0.05, 0.3 and 1.0 ?m were employed. The normal loads applied on this study were 0.1, 0.3 and 0.5 N. Carburized sample was characterized by mean of OM, XRD and hardness measurements. Worn crater characteristics were evaluated by confocal laser microscopy. Results showed that the transient wear regime prevails along the outer layer length (composed by Fe3C and ?’C), and the steady-state wear stabilizes in the diffusion layer region (composed by ?’C). It was verified that the wear rate and wear coefficient decreases with treatment temperature in the range of 350–450°C and increase for 500°C. It was also verified that the wear rate and wear coefficient decreases with treatment time in the range of 12–36 h (for 400°C cycle) and 4–12 h (for 450°C cycle), and increase for larger treatment times due the chromium carbide precipitation. It was also found that the wear coefficient increases with the increase of abrasive particle size, and decrease with the increase in counter body rotation speed and normal load. Lastly, the analysis of the worn craters indicates the occurrence of grooving and micro-rolling abrasion wear mechanisms.

Aug 17, 2017

By Joe D. Allison, Tom D. Baugh

The analysis for total cyanides (CN, or the cyanide due to the combination of free, weakly associated and refractory cyanide complexes) is required by most regulatory agencies for determination of effluent compliance. This method requires a distillation of the sample at low pH's and is most often sent to contract laboratories at a high time and monetary cost. This paper describes a new micro­distillation apparatus which allows for a multiple of CN,"' analyses to be carried out simultaneously saving both time and money. It can be used in the field, since only electrical power is required for the method. While not being appropriate for reporting values to the respective regulatory agencies as of yet, it is quite valuable for screening a large number of samples prior to submission of the samples to a contract lab for "official" reporting.

Jan 1, 1990

By Vaughan R. Voller

"The wide range of length and time scales found in solidification processes are outlined and discussed. Methods for Direct Microstructure Simulation (DMS) are introduced. Key features in sharp interface and phase field models are presented. Concepts in micro-macro solidification modeling are covered. Basic details of microstructure and segregation models are provided. A description of a recent segregation micro-macro model is presented in detail.IntroductionA solidification process involves the containment of a liquid region, which, due to cooling, transforms over time to form a fully solid product. The development of the solid microstructure and the segregation of solute components during this transformation are controlled by phenomena that occur across a wide range of length and time scales. A ""successful"" model of a given solidification process needs to account for these phenomena. Standard models of solidification employ a discrete grid of node points and associated volume elements in the special domain, with a discrete time step to track the transient changes of nodal values, describing the composition and microstructure. Through the use of such models significant progress has been made towards a complete understanding of solidification process and phenomena (see the conference proceedings in Refs [1-9]). As solidification models become more sophisticated, however, they all run into the problem of resolving the full range of disparate space and time scales.Two approaches can deal with this problem1. Direct Microstructure Simulation (DMS) where the grid size and time step are chosen to scale with the smallest length and time scales of the given problem.2. Micro-macro modeling where the grid size and time step scale with the macroscopic process scale and phenomena at smaller scales are accounted for via sub-grid modeling and volume averaging.Currently full DMS of solidification is beyond the reach of available computer power and the application and development of micro-macro models is an important and critical research area."

Jan 1, 2001

By S. S. Yuan, Q. Z. Zhu, J. F. Shao

"This paper aims at enriching a homogenization-based anisotropic damage model for hard rocks under complex loading. A new damage criterion is proposed to capture material strain softening. Within the framework of irreversible thermodynamics, we are particularly concerned with two strongly coupled dissipative mechanisms: frictional sliding and damage by microcracking, which usually take place at cracks within cohesive geomaterials under compression. Focusing on the representative elementary volume containing multiple crack families, the free enthalpy of the matrix-cracks system is obtained. Importantly, a back-stress term is involved in the local stress applied to microcracks. This back stress plays the hardening/softening role in the friction criterion which is formulated at local scale. Strain hardening owns to the accumulation of frictional shearing and dilatancy while strain softening is caused by crack growth. The multiscale damage model is used to simulate laboratory tests on the Westerly granite under true triaxial compressions. INTRODUCTIONWhen subjected to compressive loads, hard rocks present nonlinear mechanical behaviors and induced material anisotropies. In that process, two main dissipative mechanisms have been largely identified: damage by crack growth and frictional sliding along closed crack faces, which are usually strongly coupled to each other on crack scale. Theoretical investigations have shown that the damagefriction coupling analyses allow explaining a large number of experimental phenomena involved in brittle or quasi-brittle materials. Concerning constitutive modeling, the standard Eshelby’s solution-based homogenization procedure for heterogeneous materials was recently applied successfully to describing the mechanical and poromechanical behaviors of cracked frictional solids."

Jan 1, 2015

The current understanding of the mechanics of rock fracturing during smooth blasting is largely empirical and qualitative due to an inability to model the dynamic process at the fundamental level. In order to overcome this difficulty, a numerical simulation of smooth blasting is performed using the Dynamic Lattice Network Model. This model is capable of simulating material inhomogeneities and the dynamic evolution of fragmentation at the micromechanical level. In this study, smooth blasting techniques are numerically analyzed to characterize the development of the damage rock zone during explosive fracturing.

Jan 1, 1995

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. Alternatively, the organic efficiency parameter does consider process economics; however, it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach is introduced which reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure which reflects a better use of performance data. INTRODUCTION Partition curves are commonly used in the characterization, evaluation, and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, and density separators. Graphically, the partition curve depicts the recovery of particles as a function of a physical property on which the separation is based (e.g. particle density, size, magnetic susceptibility, etc.). Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic “S” shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout (or bypass) values, the midpoint slope, and the separation cut point (property value with 50% recovery). Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of the calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, since a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point (i.e. an infinitely large slope). One common formulation of this slope, the Ecart Probable (Ep), is derived by evaluating the slope between the 25% and 75% recovery points:"

Jan 1, 2015

By Leonard Obert

THE CRACKING AND POPPING of rock, often heard by men working underground, for years has been interpreted as a warning of danger and unstable ground. However, not until 1939 was it discovered that rock under stress generates subaudible and sometimes audible seismic disturbances (referred to as "micro-seismims" 4), which can be detected with the use of a suitable seismic apparatus. Since that date laboratory and field investigations have been in progress to ascertain to what extent this phenomenon can be utilized to detect, localize, and determine the magnitude of areas of instability in and around mine openings and to predict if and when failure will occur. These investigations have included a determination of the types of problems to which the method is applicable and the effect of rock type, geological defects, such as joints, fractures, faults, and other uncontrollable factors, on the reliability of results. Six reports have been prepared covering the investigations conducted between 1940 and 1952 (4-9). 5 These reports describe some of the characteristics of micro-seismims, as determined from both laboratory and field tests; the equipment used to pick up and record micro-seismims; the general test procedure and method of analyzing results; and applications of the method to specific mining problems.

Jan 1, 1957

By Taufiq Hidayat

Accurate description of complex phase equilibria provide the foundations for the improvement of non-ferrous pyrometallurgical smelting and recycling processes. Recent advances in microanalysis and experimental techniques enable accurate phase equilibria characterisation. Quantitative microanalytical techniques including Electron Probe X-ray Microanalysis and Laser Ablation ICP-MS enable the concentrations of major and minor elements present in different phases in samples to be accurately measured providing data that cannot be obtained using bulk chemical analysis techniques. High-temperature equilibration experiments coupled with the subsequent analysis of elementary reactions at micro- and macro-scales ensure the attainment of equilibrium conditions, and therefore, ensure true phase equilibria information is obtained. Examples of the application of the improved methodology on the investigation of phase equilibria of low-order and complex, multi-component gas/slag/matte/metal/solids Cu2O–PbO–ZnO–Al2O3–CaO–MgO– FeO–Fe2O3–SiO2–S systems and the distribution of minor element are provided. The experimental study is closely integrated with thermodynamic database development for the above system. Example of implementation of the research outcomes into industrial operations is demonstrated.

Many types of micro-organisms inhabit iron ore deposits contributing to biogenic formation and conversion of iron oxides and associated minerals. Bacteria such as Paenibacillus polymyxa are capable of significantly altering the surface chemical behaviour of iron ore minerals such as haematite, alumina, calcite and silica. Differing mineral surface affinities of bacterial cells and metabolic products such as proteins and polysaccharides can be utilised to induce their flotation or flocculation. Mineral-specific bioreagents such as proteins are generated when bacteria are grown in the presence of haematite, alumina, calcite and silica. Alumina-grown bacterial cells and proteins separated from such cells were found to be capable of separating alumina from haematite. Biodegradation of iron ore flotation collectors such as amines and oleates can be effectively utilised to achieve environmental control in iron ore processing mills.

Jan 1, 2009

By Jaeheon Lee, Jae-Chun Lee, Doyun Shin, Minseuk Kim, Hyunsik Park

"The appropriate treatment of cyanide waste water is becoming an emerging issue because of the toxic residue and large quantity produced from gold processing plants. In the present article, we designed and operated a continuous biological cyanide treatment system using domestic sewage sludge and various microorganisms including a cyanide-producing and degrading bacterium, Chromobacterium violaceum. The synthetic wastewater containing 50 mg/L of cyanide was pumped continuously into the reactor at a flow rate of 500 mL/d for 21 days. When 50 mg/L of cyanide was fed, the cyanide concentration in the effluent of the reactor inoculated with activated sludge (S-50) decreased by 7.5 mg/L in the effluent. The other reactors did not show significant cyanide degradation and the reactor inoculated with C. violaceum showed increased cyanide concentration in the effluent. The microbial community in the reactors was analyzed by 16S rRNA-gene based pyrosequencing technique to investigate microbial response to cyanide addition and operation time. The microbial community analysis shows that the phylum Proteobacteria was detected in the reactors showing significant cyanide degradation (S-50), while Firmicutes and Bacteroidetes was dominant in the other reactors with very low cyanide degradation. Proteobacteria could not compete when the other phyla Firmicutes or Bacteroidetes were inoculated. This study shows the feasibility of the biological cyanide treatment system for gold processing plants and contributes new fundamental knowledge about the microbial community in the biological cyanide treatment system. INTRODUCTION Cyanidation has been widely used to recover gold from ores or secondary resources since first proposed by MacArthur and Forrest in 1888 (MacArthur et al., 1888) and it is used in many states of the USA, including Nevada, Arizona, California, Colorado, and Idaho (Laitos, 2012). Cyanide compounds are highly toxic and create serious problems for wildlife and water management (Solomonson, 1981; Donato et al., 2007). Furthermore, because many countries have imposed strict standards for cyanide discharge (USEPA, 1985), it is essential to develop a cost-effective and environmentally friendly technology for treating cyanide-containing wastewater."

Jan 1, 2018

By Z. M. Dai

Microorganisms in AMD (Acid Mine Drainage) were enriched in 9K culture medium. The enrichment was applied to leach copper pyrite after the microbial community structure and metabolism was stable. Before and after bioleaching, the microbial DNA was extracted and applied to RFLP (restricted fragment length polymorphism) analysis to demonstrate the relationship between the leaching efficiency and the change of microbial community. Atomic absorption spectrometry results showed that when concentration of the pulp was 10% and pH were 1.5, 2.0 and 2.5, the leaching rate were 56%, 57% and 34% on the 18th day respectively. These results indicated that the rise of pH resulted in the decrease of leaching rate. In lower pH condition, the growth of microbe was faster: when pH was 1.5, the microbial cell number reached to 1.4×107cells/mL on the 9th day; while pH was 2.5, the microbial cell number decreased to 4×106cells/mL. The analysis of microbial community structure showed that Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans were dominant species before bioleaching (account for 43% and 32% respectively). And after bioleaching, these two species were still dominant when the initial bioleaching pH were1.5 and 2.0. While the initial bioleaching pH was 2.5, the proportion of these two species decreased. These results demonstrated that the initial bioleaching pH would affect the microbial community structure in bioleaching system at room temperature, and this affect could lead to different copper pyrites bioleaching efficiency.

Jan 1, 2014

By Chandra Sekhar Gahan

The present study aimed to investigate the depyritization of coal using iron oxidizing and sulphur oxidizing acidophilic chemolithotrophic microorganisms in an iron free 9K growth medium at varying pulp densities. Three different coal samples used in the shake flask study from three different countries such as domestic anthracite (Korean), Indonesian and Chinese lignite. Experiments were carried out in batch at a controlled temperature of 35 °C and varied pulp densities of 8%, 10% and 12% (w/v) with a working volume of 100 ml containing 10 ml of microbial inoculum and 90 ml of the iron free 9K growth medium. Coal samples were crushed and ground to fine size fractions <100 microns by attrition mill wet grinding. The progress in the experiments were followed by the regular measurements of pH, redox potential, viable planktonic cell count, residual Fe2+ ion concentration, amount of acid addition and amount of slaked lime addition. The pyritic sulfur removal percentage varied between 90-95% with highest sulfur removal with China coal (95%) followed by Korean Coal (93-94%) and slightly lower level for Indonesia coal (90%). However the pyrite oxidation was highest for Korean coal ranging between 78-80% followed by a similar level of pyrite oxidation of 50-61% for the Chinese and Indonesian coal. It was found that 10-12% pulp density would be fairly feasible for all the different coals tested leading to an economical process. Another benefit from this study is the iron free 9K growth medium, which will reduce the operation cost and overall it?s an environment friendly process.

Sep 1, 2012

By H. Sarvamangala

Selective separation of alumina, silica, calcite and apatite from hematite was achieved through microbiologically induced flotation and flocculation in presence of bacteria (B.subtilis) and that of hematite from apatite after interaction with yeast (Saccharomyces cerevisiae). Bacterial and yeast metabolites containing extracellular proteins were characterized from mineral-grown cell free extract. Bacteria and yeast can adhere to mineral surfaces and influence subsequent separation of the minerals. Bacteria functioned as a stronger depressant for hematite, while yeast cells depressed apatite at neutral pH. Selective affinity of the bacterial and yeast cells towards the mineral surface was observed through adsorption studies. Extracellular proteins (EP) were isolated from B.subtilis and yeast. The protein profile of the EP of bacterial and yeast cells grown in presence and absence of minerals was studied. This study has demonstrated the utility and amenability of microbially-induced mineral beneficiation of iron ores through bacterial and yeast cells and their metabolic by products.

Sep 1, 2012

By K. A. Natarajan

"Interaction with microorganisms results in significant surface chemical changes on minerals. For example, chemolithotrophs such as Thiobacillus ferrooxidans and Thiobacillus thiooxidans significantly alter the surface chemistry of several sulfide minerals such as pyrite, chalcopyrite, sphalerite and galena. Heterotrophic bacteria such as Bacillus sp. could alter the electrokinetic properties of oxide minerals such as hematite, alumina, silica, kaolinite and calcite. Microbe-mineral interactions could thus be beneficially utilised in mineral beneficiation as different from bioleaching. Microbially induced mineral beneficiation unlike bioleaching deals with interfacial phenomena at mineral-solution-bacteria interfaces and surface chemical changes are brought about at very rapid rates amounting to a few minutes resulting in mineral separations in an aqueous medium.In this paper, the role of acidophilic chemolithotrophs such as Thiobacillus thiooxidans and neutrophilic heterotrophs such as Bacillus polymyxa in the beneficiation of sulfide and oxide minerals is illustrated. Mechanisms of bacterial attachment on various sulfide and oxide minerals are outlined with respect to the influence of bacterial interaction in bringing about mineral surface hydrophobicity or hydrophilicity. The role of bacterial cells as well as metabolic products such as bioproteins and exopolysaccharides in significantly altering the surface chemistry of sulfide minerals such as sphalerite and galena and oxides such as hematite, alumina, silica and calcite is discussed with probable mechanisms. Possibilities of generating mineralspecific bioreagents are outlined with respect to bacterial adaptation to mineral substrates."

Jan 1, 2003

By M. N. Chandraprabha

This paper discusses the role of the mineral-adapted acidiphilic microorganism Acidithiobacillus ferrooxidans in the beneficiation of arsenopyrite-containing multisulfides (pyrite and chalcopyrite) and the bioremediation of the resulting arsenical waste water. It was found that adaptation to minerals alters the surface properties of the microorganism. Bacterial adaptation to arsenopyrite and controlled bacterial adhesion to mineral surfaces lead to selectivity in arsenopyrite separation. Bioremoval of arsenic ions (both arsenite and arsenate ions) by Acidithiobacillus ferrooxidans is also discussed. Key words: Acidithiobacillus ferrooxidans, Bioremediation, Arsenopyrite beneficiation

Jan 1, 2009

By K. A. Natarajan

The utility of yeast, Saccharomyces cerevisiae, in the separation of quartz from hematite is demonstrated. Yeast cells, as well as their metabolites, functioned as flotation collectors, depressants or flocculants and dispersants for hematite and quartz. Interaction between yeast and the above minerals resulted in significant surface chemical changes, rendering quartz surfaces hydrophobic and hematite hydrophilic. Mineral-specific extracellular proteins and exopolysaccharides were secreted by yeast cells when grown in the presence of quartz and hematite, respectively. Quartz could be efficiently separated from hematite through microbially induced flotation and selective flocculation.

May 1, 2012

By Sudhir C. Dhara

An attempt has been made on the concentration of Platinum Group Metals (PGM) from the converter matte material by microbial .leaching. Biological oxidation of base metal sulfides such as iron, copper, nickel and free sulfur present in the matte material using Thiobacillus ferrooxidans is an alternative method to concentrate the PGM-and gold. The method which produces a platinum group metals concentrate is comparable to chemical processes and electrochemical process.

Jan 1, 1995