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By I. Ward, E. Milosavljevic, M. Botz

"The silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide in leach solutions that contain primarily free cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method overestimates the concentration of free cyanide and underestimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric (MP) titration method for determining WAD cyanide that overcomes issues associated with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper, and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, analytical results obtained with the new MP-WAD method were found to be within about ±5% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.IntroductionThe silver nitrate titration method is widely used to estimate the concentration of cyanide in leach solution for purposes of cyanidation process control. Cyanide determined by silver nitrate titration is commonly referred to as “free” cyanide, but frequently should be referred to as “titratable” cyanide. By definition, free cyanide is the sum of the concentrations of aqueous hydrogen cyanide HCN(aq) and the cyanide anion CN- (ASTM, 2010). Titration will only yield a reasonably accurate measurement of free cyanide when metal-cyanide complex concentrations (e.g., cadmium, copper, mercury, nickel, silver and zinc) in solution are low. In other words, titration will only yield a reasonably accurate measurement of free cyanide if the solution primarily contains free cyanide."

Jan 1, 2015

One of the earliest and continuing challenges in driving sustainable development in large scale resource industry projects is around the issue of assessment û how do you measure the sustainability of a mineral operation? One of the key road blocks when confronted with this challenge is the temptation of technical folks to reach for a definition of sustainability or sustainable development. But definitions, by definition, have boundaries and limitations that serve to constrain thinking û they limit the thinking of what we can achieve with sustainability (it also acts as a barrier that constrains innovation). Rather than seeking definitions, better understanding of the core perspectives around sustainability and their application to the minerals industry provides a much more powerful platform from which to conduct assessments. But it is only when these perspectives are combined with the right framework and supporting techniques that the complex becomes doable. With the support of the perspectives and the framework, various assessment and measurement methodologies can be used; the challenge is communicating to stakeholders the sustainability character of the project in ways that are meaningful and to which people can connect. Assessment is not about finding the best or most accurate methods that fulfil strictly academic and possibly abstract requirements. The challenge is to help people understand what the impacts are, and what the value contributions will be, in a format and language that make sense in their world-view.

Jan 1, 2009

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By Jesse Puller, Ken W. Mills, Owen Salisbury

"An underground coal mine located in New South Wales has a target coal seam located 160-180 m deep directly below a 16-20 m thick conglomerate unit that has been associated with significant periodic weighting events on the longwall face. As part of the investigations to better understand the causes of periodic weighting at the mine, inclinometers capable of measuring horizontal shear movements through the full section of the overburden strata were installed ahead of mining at two locations approximately 1 km apart above the centre of two longwall panels. These inclinometers were monitored as the longwall approached each site. This paper presents the details of the installation, the results of the inclinometer monitoring at both sites, and the insights that these measurements provide for overburden behaviour about longwall panels.Horizontal shear movements were observed to develop on shear horizons that correlate closely across the two sites suggesting a mechanism that is consistent across a large area of the mine. Shear movements were observed to develop on a single horizon near the top of the conglomerate strata that was mobilised almost immediately after initial formation of the longwall goaf at a distance of 425 m ahead of the longwall face. The direction of horizontal movement was consistent with the relief of the major principal horizontal stress. As the longwall face approached each inclinometer, other horizons within the upper part of the overburden strata begin to shear with the upper strata moving toward the approaching goaf more than the lower strata. Within the last 30 m of longwall approach, tilting of the strata associated with the increase in vertical subsidence toward the extracted goaf caused a change in the style of deformation with tilting and reverse shear offsets.INTRODUCTIONLongwall mining is recognised from subsidence monitoring, surface extensometer measurements, and various other observations to cause significant disturbance to the overburden strata directly above the extracted goaf of each longwall panel. Disturbance to the overburden strata beyond the limits of each longwall panel is not so well understood. Subsidence monitoring indicates that horizontal movements beyond the edges of the extracted longwall panel are generally greater in magnitude than vertical subsidence and horizontal movements may extend up to several kilometres from the edge of the panel in some circumstances (Reid 1998, Reid 2001, Hebblewhite et al 2000, Mills 2001, Mills 2014). The mechanics of how these movements are accommodated within the overburden strata is only poorly understood and there are few direct measurements."

Jan 1, 2015

By William Petruk

An investigation was conducted to determine types of particles that tend to be recovered in concentrates by mineral beneficiation. It was found that, in concentrates of the same grade the proportion of desired mineral occurring as apparently liberated grains varies widely. In contrast the proportion is nearly constant when the grains considered are apparently liberated grains plus unliberated grains in particles composed largely of the desired mineral. It was also found that the types of particles which tend to be recovered in concentrates are dependent upon the concentrate grade. Hence it is much more important to determine the characteristics of recoverable particles and to measure the percentage of mineral that occurs in recoverable particles. than to measure the percentage of totally liberated mineral. A relationship between concentrate grade and type of particle that tends to be recovered in concentrates was established.

Jan 1, 1989

By W. Petruk

Mineral liberations that would be obtained by grinding an ore to a specific size can be predicted by analyzing unbroken ore pieces, and mineral liberations in ground ores and mill products can be determined directly by image analysis. Predictions of mineral liberations are made by measuring size distributions and textures of mineral grains by image analysis, and using liberation models. Ground ores and mill products are analyzed to determine the proportion of mineral that is liberated, and the data are used to evaluate mineral behaviour during mineral beneficiation. The liberation data for minerals in a suite of mill products from a circuit are processed by a materials balancing technique to calculate recoveries of minerals in different types of particles throughout the circuit. The liberation-materials balance data define mineral recoveries; define the behaviour of an ore in a concentrator, pilot plant or bench test; and indicate whether recovery improvements are possible and/or feasible.

Jan 1, 1991

By Gary Cavanough, Stuart Addinell, Hector Parra

Drilling deep, straight, accurate holes in hard rock to achieve efficient blasting is a challenge for the mining/quarrying industries with short holes normally drilled using “top hole hammer” (THH) and deep holes using “down the hole Hammer” (DTH).

Jan 1, 2013

By H Kurth

"The focus of this paper is on measuring the composition to improve mill feed quality to minimise the processing of waste, optimise process performance, reduce processing costs and minimise the generation of tailings.Technologies used since the 1990s in the cement and coal industries for measuring conveyed materials have been operationally proven and effectively derisked. Despite this the acceptance by the minerals industry has been very slow except in iron ore. Real-time penetrative full stream measurement using prompt gamma neutron activation analysis (PGNAA) for multielemental analysis and microwave transmission for real-time moisture analysis provide representative, tonnage weighted dry weight per cent results on a minute by minute basis. Analysis is unaffected by particle size, dust, layering/segregation, mineralogy and belt speed. The technologies are explained and performance examples given. The benefits derived from real-time compositional analysis are predicated upon a good understanding of deposit geology, mineralogical associations, waste to ore interfaces, amenability to mining, metallurgical processes and downstream customer requirements. Processing may include basic preparation in the case of direct shipping ores, minor beneficiation using simple upgrading methods, or concentration using more complex processing systems such as flotation, leaching or many others. The value of real-time data from primary crushed conveyed flows, using analysis of increments smaller than a single haul truck’s load, is very beneficial in process plants aiming to reduce waste processing, increasing feed grades and increasing metal recoveries. Grade variability can be utilised to divert conveyed increments of waste, direct shipping ore (DSO) quality material bypassing beneficiation, and subeconomic material amenable to upgrading diverted for further preconcentration by particle separation (sorting, heavy medium etc). Paybacks of a few months have been commonly achieved where the real-time technologies have been applied in the minerals sector. The paper outlines proven applications and case studies and proposes some innovative applications.Citation:Kurth, H, 2016. Measuring and Utilising Ore Quality Variability Using Real-time On-belt Elemental Analysis to Improve Mill Feed Quality, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 239–244 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By S. Mason

Many organizations are realizing that continual improvement in health and safety relies on addressing the potential for various forms of human error. Of these, violations are often the most frequent form associated with accidents. These occur when an individual, or individuals, deliberately contravenes established and known safety rules. They have been associated with up to 90% of accidents and incidents in some industries and yet rarely receive the systematic attention they deserve in the promotion of safety. This paper presents underlying motives which cause violations. These can vary significantly from mine to mine and from job to job. Managers need some measure of attitudes to determine the underlying motives behind violations if they are to determine effective strategies for promoting safe behaviour. Questionnaires form the starting point to address attitudes and the motives behind rule violations. The choice of the most suitable questionnaire, however, will vary from organization to organization. Guidelines on the choice of questionnaire are offered.

Jan 1, 1998

By G Tranell, E Pastor-Vallés, A Vallejo-Olivares, J B. Pettersen

Metals are essential for the sustainability transition and decarbonisation of society. Yet, it will be paramount to produce them sustainably and minimise the affiliated resource and energy use and the associated emissions. In the circular economy, the metallurgical industry should recycle existing material stocks, and improve its utilisation of wastes, residues and side streams. This increases the complexity of processes, as they become both (often multi-fraction) waste treatment as well as material production processes and brings complexity to the assessment of environmental benefits. Assessing the environmental impact of technological developments frequently is supported by life cycle assessment (LCA). While the method is well documented, its implementation involves several methodological choices that deserve reasoning and analysis, such as how to define the product when former wastes are turned into new products, the selection of impact methodology when converting emissions to environmental indicators, the definition of system boundaries and co-product allocation and the interpretation of sensitivity and uncertainty in final outcomes. In this exploratory study, we investigate how the variation of LCA set-up affects the environmental burden of the system. We consider a metallurgical process where a mix of hard-to-recycle aluminium-containing streams is used to produce aluminium cast alloys in a rotary furnace. Remelting with salt-fluxes allows recovering metals from partly oxidised/contaminated streams, such as dross, bottom ash and industrial shavings, but at the expense of generating significant amounts of salt-slag/salt-cake hazardous waste. The study considers different system alternatives such as landfilling the salt-slag residues versus valourising them into salts, aluminium concentrates, ammonium sulfate and non-metallic-compounds to be used by the metallurgical, construction or chemical industries. Practical recommendations are outlined to facilitate the implementation of LCA in assessing the potential benefits of the circular economy in the metallurgical sector.

Aug 21, 2024

By Patrick J. Coleman, John C. Kerkering

Problem: Mining in the United States remains one of the most hazardous industries, despite significant reductions in fatal injury rates over the last century. Coal mine fatality rates, for example, have dropped almost a thousand fold since their peak in 1908. While incidence rates are very important indicators, lost worktime measures offer an alternative metric for evaluating job safety and health performance. The first objective of this study examined the distributions and summary statistics of all injuries reported to the Mine Safety and Health Administration from 1983 through 2004. Over the period studied (1983 2004), there were 31,515,368 lost workdays associated with mining injuries, for an equivalent of 5,700 person years lost annually. The second objective addressed the problem of comparing safety program performance in mines for situations where denominator data were lacking. By examining the consequences of injuries, comparisons can be made between disparate operations without the need for denominators. Total risk in the form of lost workday sums can help to distinguish between lower and higher risk operations or time periods. Method: Our method was to use a beta distribution to model the losses and to compare underground coal mining to underground metal/nonmetal mining from 2000 to 2004. Results: Our results showed the probability of an injury having 10 or more lost workdays was 0.52 for coal mine cases versus 0.35 for metal/nonmetal mine cases. In addition, a comparison of injuries involving continuous mining machines over 2001 2002 versus 2003 2004 showed that the ratio of average losses in the later period to those in the earlier period was approximately 1.08, suggesting increasing risks for such operations. Discussion: This denominator free safety measure will help the mining industry more effectively identify higher risk operations and more realistically evaluate their safety improvement programs. Impact on Industry: Attention to a variety of metrics concerning the performance of a job safety and health program will enhance industry's ability to manage these programs and reduce risk.

By H Kurth

Mining geologists utilise many technologies to map, sample, measure, model and plan before and during the mining process. Predicted ore quality rarely corresponds with feed quality determined by process operators. Objectively measuring conveyed material quality accurately in real time avoids disagreements over mined ore quality and generates opportunities to improve mill feed quality.This paper discusses the well proven PGNAA (prompt gamma neutron activation analysis) technology used in the GEOSCAN-M elemental analyser that is ideally suited to measuring composition of primary crushed conveyed material in real time. Representative, continuous, fully penetrative measurements are unaffected by particle size, belt speed, mineralogy, dust or layering on the conveyor. Material can be directed to processes or stockpiles by utilising measurement increments of typically one to five minutes and then activating diverters to direct increments to the correct location. Waste, low-grade or deleterious material can be rejected to waste dumps or stockpiled for later processing. Material meeting a product specification can bypass unnecessary processing. Paybacks in weeks have been achieved for such applications. Process operators are able to control the blend of ores fed into the mill to improve processing performance and use measurements for ore reconciliation and metal accounting. Utilising the technology to upgrade ore quality after mining and before processing is beneficial in improving plant economics.The technology has been successfully utilised in base metals, ferrous metals and industrial minerals. Mining geologists can determine ore quality being produced in real time and modify the ore quality prior to milling. Ore feed quality measurements are also used by process operators in optimising plant performance. The elemental content can help identify geometallurgical domains as well as other major changes in quality, which may affect processing. This paper outlines proven applications and case studies and proposes some innovative applications.CITATION:Kurth, H, 2017. Measuring ore quality using real-time on-belt elemental analysis – more than grade control, in Proceedings Tenth International Mining Geology Conference 2017, pp 213–220 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By S A. McManus

With the advances in software speed and capability, many of us now are running multiple scenarios on entire models rather than just testing small areas or a few blocks. In the authors experience both the geological and geostatistical academic theory and our rules of thumb, often prove un-useable or incorrect in the real world we work in. The only way to truly validate and tune our models is to complete the entire model and ‘see if it works’. If it lacks some property we were expecting, then we need to find out why and/or run different scenarios to see what changes. This is not always possible with tight project timelines but we find ourselves doing more and more of this sort of thing, and in so doing, understand that every deposit is different and requires its own ‘rules’ to get valid and useful results. For the purposes of this paper, this process is termed Empirical Geostatistics. Take Clayton Deutsch’s ‘all realisations all of the time’ concept a step back. Before you even think of simulating, test the alternate realisations generated by alternate parameters such as different domaining, varying search neighbourhood parameters etc.

Mar 22, 2022

By F Brenguier, R A. Lynch, G Olivier

The seismic velocities of intact rock are dependent on the applied stress. Unfortunately, the low susceptibility of seismic velocity to stress changes mean that changes in seismic velocity have to be measured extremely accurately to infer stress changes from them. Previously, it was thought that measurements of this accuracy could only be made with active sources or repeating earthquakes. In this paper, we show that the noise generated by mining activity can be used to construct virtual seismic signals with which we can measure changes in seismic velocity accurately enough to see the short- and long-term effects of a production blast on the surrounding medium. The time-dependent velocity variations achieved with this method show that the blast caused weakening of the rock mass for the rock within a radius of 200 m of the blast. The weakening is healed by confining stresses over a period of five days, after which permanent changes in the seismic velocity can be seen. The size and spatial distribution of the seismic velocity changes were compared to modelled changes in static volumetric stress, which supported the notion that seismic velocity changes can be used to measure the redistribution of stress after a blast. The results of this study indicate that this method can be a powerful tool to evaluate the evolution of stress in a mine at a relatively low cost as the data that it uses would normally be discarded.CITATION:Olivier, G, Lynch, R A and Brenguier, F, 2016. Measuring the redistribution of stresses resulting from new excavations with ambient seismic noise correlations, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 873–878 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Matthew Thurley

Optimisation and control of comminution, pelletization, and agglomeration processes is a complex task with large potential for gains in productivity, energy efficiency, and particle size distribution quality. One factor in realising these gains is the requirement for fully-automated online particle size distribution measurement. Moreover, online particle size distribution measurement that is based on the particles on the visible surface and can avoid or mitigate substantial errors that result from under-sizing overlapped particles and over-sizing areas of fines particles. Literature review indicates a body of substantially 2D photographic based particle size measurement systems that suffer from a large number of significant errors except in the simplest case of a monolayer of particles under good illumination with limited color variation in the material. In order to measure the visible particles on a pile there are a number of requirements including; avoiding particle delineation errors due to variation in material color and shadows, detect overlapping versus non-overlapping particles, and identify areas of fine particles as fines and not large rocks. Results are presented using a fully-automated online measurement system of crushed rock on conveyor belt using a 3D surface laser profile. The system provides continuous online measurement and results are shown on over four hours of production after the primary crusher. Size distribution results are calculated using volumetric estimation of the particles on the surface of the pile. The results show a strong capability to discriminate size variation especially in the 10% and 20% passing values. Furthermore results show that if areas of fines are misclassified as large rocks, and overlapped particles misclassified as small rocks, then a near complete loss of discrimination occurs for the P10 and P20 values which become largely constant values.

Jan 1, 2014

By David E. Hardt

"One of the critical variables to be controlled during arc welding is the size or geometry of the weld pool. The measurement of pool geometry has become an increasingly important problem with the advance of welding automation and control, and this paper addresses that problem. The basic concept of pool size estimation via measurement of pool dynamics is presented. The theory underlying this concept is discussed and is followed by a review of the current work in this area. It is concluded that pool dynamics can be characterized by natural frequencies of oscillation, for stationary welds, and that these can be measured by appropriate signal processing performed on the arc voltage. However, it appears that only full penetration welds show a strong correlation between weld size and natural frequency. Also, the extension of these results to the realistic case of moving welds has yet to be considered in detail. Nonetheless, this method of in-process measurement for real-time weld process control is still quite attractive where applicable since it can be accomplished simply by modifying the arc current schedule and by signal processing of the arc voltage.INTRODUCTUIONThe study of welding process control has been dominated by research into methods of in processing sensing of the weld pool geometry. While it has been shown feasible to measure the topside pool geometry using video methods [1,2], the penetration or backside bead width have remained elusive quantities. This is particularly true if a topside sensor location is required.The concept of using weld pool motion as a pool geometry sensing method was proposed by Hardt et al. [3] and later demonstrated by Hardt and Zacksenhouse [5] and Richardson and Renwick [6]. The concept is based on the fluid dynamics of a pool constrained by a solid container and by significant surface tension forces (i.e. a small shallow pool, not a ""pond"" or ""lake""). Such a pool, if subjected to external forces, will exhibit a surface motion is a function of that force, the properties of the fluid, the surface tension, and the shape of the container. Thus, if this motion can be excited and measured, and the relationship to the pool geometry determined, a means of sensing pool shape will exist."

Jan 1, 1986

In 2009 Newmont Mining Corporation?s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Jan 1, 2012

By Arthur F. Taggart

MR. CHAIRMAN: Congratulations! Your four-ring milling show this year was a dandy. It cleared our minds, for a few hours at least, of what Hitler, Hirohito, the New Deal, and the tribe in the Treasury are trying to do to strangle American enterprise. We mustn't forget this, but it's a relief to get our thoughts away from it occasionally. GRINDING-There was a further contribution to the excellent work that the Allis-Chalmers laboratory staff has been doing for the grinding fraternity in compiling-and publishing-a carefully quantitative list of comparative resistances of ores and other materials to comminution (T.P. 1579, Bond-Maxson). A diagnostic accuracy of ± 10 per cent was claimed for estimates based on these figures. Are they really that good? How about some of you men in the field writing M&M about it?

Jan 1, 1943

By Carolina Arriel Pedroso Dias

Neste trabalho, tiras de aço inoxidável duplex UNS S32205 foram laminadas a morno a 600°C com 60% e 80% de redução e, em seguida, foram recozidas a 1050°C durante 300 s. A tira como fornecida (laminada a quente industrialmente e recozida) também foi recozida para efeito de comparação. Avaliou-se o comportamento mecânico das amostras como fornecida, 60% e 80% por meio de ensaios de tração e microdureza Vickers, obtendo-se 779 MPa, 730 MPa e 807 MPa de limite de resistência a tração e 265 HV, 244 HV e 256 HV de microdureza Vickers para as três condições descritas, respectivamente. Outros ensaios de microdureza foram realizados ao longo da superfície do corpo de prova fraturado em tração, indicando um aumento da dureza nas regiões mais próximas da fratura. O aumento da dureza na região de estricção indicou o aparecimento da martensita induzida por deformação para as amostras laminadas a morno. Usando a derivada da curva tensão verdadeira em função da deformação verdadeira, (ds/de), avaliou-se o comportamento de encruamento do aço para as três condições. Juntamente com os exames por microscopia eletrônica de alta resolução e difração de raios X, buscou-se uma interpretação dos mecanismos de deformação plástica envolvidos no processo de encruamento. Em determinados estágios, observou-se uma mudança da inclinação para um regime estável, indicando a ocorrência de outros mecanismos de deformação plástica, diferentes do escorregamento de deslocações. A martensita induzida por deformação foi considerada responsável pelo aumento da taxa de encruamento do aço, i.e., por ser obstáculo à movimentação das deslocações e por postergar a formação da estricção.

Oct 30, 2017

By A. S. Ratnayake, H. C. S. Subasinghe

In this study, we review the role of mechanical activation in the pyrometallurgical, hydrometallurgical, and electrometallurgical processing of titanium feedstock. Mechanical activation has been shown to decrease the activation energy of chemical reactions, thus enhancing process efficiency and product quality by reducing processing time and energy consumption. Pyrometallurgical processing is energy-intensive and time-consuming. Hydrometallurgy is costly, requires high-grade feed material, and generates toxic waste. Waste generation and process complexity are the major drawbacks of electrometallurgy and solvent extraction. Bioleaching via a mechanically activated pyrometallurgical process can be identified as an alternative method, but the lengthy processing time is the major disadvantage. Mechanically activated titanium concentrate can be used in a finely tuned combined metallurgical process to overcome the challenges and drawbacks in these technologies.

Aug 3, 2023