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By Juan Pablo Henríquez, Sebastian Lozano, Constanza Soto, Gonzalo Segura, Carlos Torres, Danko Morales

The Atacama Kozan underground mine, located in Tierra Amarilla, Atacama, Chile, was facing over-excavation and slow progress in drift construction, issues associated with the use of traditional explosive, ANFO. The presence of water in the blast holes required as well the use of cartridged emulsions, which extended loading times and increased operators’ effort. With loading times ranging around 76 minutes and lower advanced rate, Enaex Underground proposed the use of a pumpable emulsion-type explosive to optimize blasting, enhance safety, and streamline the operational process. This explosive is loading into the blasting holes using an UBT equipment (Unidad Bombeable para Túneles in spanish). This equipment allows mechanized loading, adaptation to small and medium diameter boreholes, ensuring compatibility with varying drilling profiles, integration with Atacama Kozan’s operational equipment and improvement in environmental and occupational conditions, with a measurable reduction in contaminant emissions and worker exposure risks. The implementation of this emulsion-based explosive allows an increase in productivity in drift development. A notable effective advance rate of 95% to 96% was achieved, alongside a reduction in overbreak in 7%, and a decrease in loading time to 40 minutes. Additionally, there was a 40% occurrence of drilling half cast, contributing to contour drift quality. The operation also benefited from a cleaner and safer working environment, enhancing operator ergonomics and reducing the need for jetanol and compressed air.

Jan 26, 2026

By B. Petri, N. Rouse

"Air overpressure monitoring procedures and instrumentation guidelines which apply to production blasting in underground limestone mining are not readily available. The industry also lacks an applicable source for air overpressure levels that are produced by blasting operations in underground limestone mines. As such, there was no available background data from which the expected overpressure levels from production blasting in a new underground limestone mine could be predicted. During the development phase of the mine, it was imperative that newly constructed underground structures be capable of withstanding the overpressure produced by blasting in nearby production headings. To ensure the structures could withstand the blast-induced overpressure, a study was conducted to record empirical overpressure data and develop a model which could be used to control air overpressure levels by the production crews. This document describes the procedures used to develop the model, the development of the model, and the applicability of the model for predicting underground blast overpressures. INTRODUCTION A developing underground limestone mining operation required that a ventilation wall be built to house the permanent mine fans. At the time of the study, the mine was a single-level room and pillar operation with a 7.9 meter (26 ft) high roof, 13.7 meter (45 ft) wide entries, and 13.7 meter by 13.7 meter (45 ft by 45 ft) pillar dimensions. The mine is accessed via a 396 meter (1300 ft) long decline and 100 meter (330 ft) deep ventilation shaft. The ventilation wall was to be partially constructed of autoclaved aerated concrete blocks, for which dynamic strength data from explosives loading were unavailable. The company ownership feared that airblast may affect the wall due to the close proximity of the working faces. Therefore, the company management asked that the overpressure levels be estimated and compared with the designed wall strength. Few studies that apply to explosively-driven air overpressure levels in underground production blasting were found through a literature review. Therefore, the logical approach to assess the overpressure levels was to monitor the blast pressures at the site and conduct a thorough evaluation of the data. As a result of this study, the equipment setup and monitoring procedure used to record the airblast data is described. Finally, the experimental data gathered during the monitoring program is presented, trends and findings from the data are discussed, and recommendations for further study are presented."

Jan 1, 2015

By S. Chai

Waste dumps are widely used to discharge stripped mine wastes in open pit mining methods. As mining progresses, the height of the waste dumps will increase gradually, which may induce sliding failure once the height exceeds a critical value. Therefore, estimation of the maximum dumping height is crucial to the life-cycle use of a waste dump. However, published information about the maximum height of mine waste dumps are extremely rare. In this study, the maximum dumping height is estimated based on the strength-reduction technique by numerical simulations. The influences of dump geometry and properties on the maximum height are investigated. The results show that the maximum dump height decreases as the dump slope inclination angle α or the unit weight of dump materials γ increases, but decreases when the shear parameters of dump materials (cohesion c and internal friction angle ϕ) increase. The maximum height starts to increase with the ground inclination β when shear failure occurs at the interface between the dump and the base. Furthermore the effects of the dump width B, Young’s modulus E, and Poisson’s ratio μ of dump materials on the maximum height are almost insignificant. Good agreement was found between numerical results available in the literature and those obtained in this study.

Oct 1, 2022

By Geo. D. Furse

"The information that has accumulated regarding the geology of the McIntyre mine is the result of work by several geologists and, as might be anticipated, their conclusions have varied. The writer has been at the mine only a few years and due to wartime conditions has not been able to study and review the mine's geology as thoroughly as his predecessors. Where the writer's conclusions differ from those of previous authors, it should be noted that he has been unable to re-map all the workings in which flow contacts are exposed, but has endeavoured to describe the structure as indicated by the evidence he has been able to observe. He wishes to thank H. G. Skavlem and H. S. Robinson for their constructive criticism of this paper, and McIntyre Porcupine Mines, Limited, for permission to present it. A list of references is appended.The McIntyre mine is in the central part of the Pearl Lake section of the Porcupine gold area. It includes the ""bed of Pearl lake, twenty-two claims to the north of the lake, and the Platt Vet lot to the southeast. It is bordered on the west by the Hollinger and on the east by the Coniaurum property. The chief ore-bearing veins on the upper levels lie very close to the north shore of the lake, but some occur under the lake, and others of lesser importance are found to the southeast. The most important veins are Nos. 3, 5, 7, 10, and 25. Some of the veins extend into the Hollinger. on the west and others cross the east boundary into the Coniaurum. The total production since the commencement of milling in 1912 to the end of March 1947 has been $168,448,218 in gold and silver from the milling of 17,690,963 tons of ore."

Jan 1, 1954

By M. E. Wilson

"The property of McWatters Gold Mines, Limited, is in the east-central part of Rouyn township and about 6 miles east-southeast of the town of Rouyn. It includes 35 claims, the group of 5, staked originally, and 30 claims acquired in later years. The Rouyn-Val d'Or road and the Noranda Senneterre branch of the Canadian National railway both pass within a few hundred feet of the mine.The group of claims in which the mine occurs was first staked in 1922, but gold was not discovered until August 1932 when a schistose zone including veins of quartz carrying considerable free gold was laid bare in a stripped area in the northeastern part of claim R.11604. Diamond drilling undertaken in 1932, and continued into 1933, shouwd that the gold extended for at least 1,000 feet along the strike. A 3-compartment shaft was sunk to 418 feet in 1933. A mill having a capacity of 50 tons a day was constructed in 1934, and enlarged to 150 tons in 1935. Production began in 1934 and continued without interruption to June 1944. Except for a few diamond drill holes, there have been no operations on the property since that time. The maximum depth of the mine workings is 1,50) feet. A total of 368,013 tons of ore having a value of $3,946,752 and an average grade of $11.04 was mined during the years of operation.GEOLOGYThe ore mined from the property occurred within the south limb of an eastward plunging syncline of volcanics and sediments cut off on the north by the Cadillac-Bouzan Lake fault. Because the rock formations within the syncline have been severed from those outside with which they were originally continuous, their correlation is based almost wholly on lithological similarity. They include an irregular middle zone of conglomerate and greywacke underlain by north and south bands of andesite agglomerate and andesite tuff, in which lenticular bands of pillowed andesite are included."

Jan 1, 1954

By J. Jin, J. D. Miller

"Bubble attachment at hydrophobic surfaces is of critical importance in the flotation recovery of mineral resources and fundamental experimental results have been reported in the literature describing the details of film thinning, rupture, and displacement. Now, for the first time, bubble attachment phenomena are examined using Molecular Dynamics Simulations (MDS). The simulation involves a nitrogen bubble containing 906 nitrogen molecules in a water phase with 74,000 water molecules at the hydrophobic molybdenite (001) surface. During the simulation period of 1 ns, film rupture occurs and the nitrogen bubble attaches to the molybdenite (001) surface, resulting in a contact angle of about 90o. In contrast, the film is stable at the hydrophilic quartz (001) surface and the bubble does not attach. Contact angles, determined from MD simulation after stabilization of the three phase line of contact, are reported and these results agree well with experimental and MDS sessile drop results. In this way, film stability and bubble attachment are described with respect to interfacial water structure for surfaces of different polarity. For example, the interfacial water molecules for the hydrophobic molybdenite (001) surface have relatively weak interactions with the surface when compared to the hydrophilic quartz (001) surface, as revealed bythe presence of a 3 A water exclusion zone at the molybdenite/water interface. INTRODUCTIONAttachment of air bubbles to mineral particles is of fundamental importance in understanding flotation separation phenomena. It is well known that attachment of an air bubble at a hydrophobic surface includes film thinning, film rupture, and film displacement (Somasundaran, 2006; Wilson, Adlard, Cooke, & Poole, 2000). Experimental techniques, such as high speed video, can catch the process of bubble attachment at a mineral surface (Drelich & Miller, 2012; Niecikowska, Krasowska, Ralston, & Malysa, 2012). However, molecular scale information to examine the phenomena has not yet been reported."

Jan 1, 2016

By Stéphane Robert

This document presents estimates of future "total cash cost per ounce" and "minesite cost per tonne" that are not recognized measures under United States generally accepted accounting principles ("US GAAP"). This data may not be comparable to data presented by other gold producers. These future estimates are based upon the total cash costs per ounce and minesite costs per tonne that the Company expects to incur to mine gold at the applicable projects and do not include production costs attributable to accretion expense and other asset retirement costs, which will vary over time as each project is developed and mined. It is therefore not practicable to reconcile these forward-looking non-GAAP financial measures to the most comparable GAAP measure. A reconciliation of the Company's total cash cost per ounce and minesite cost per tonne to the most comparable financial measures calculated and presented in accordance with US GAAP for the Company's historical results of operations is set forth in the notes to the financial statements included in the Company's Annual Information Form and Annual Report on Form 20-F, for the year ended December 31, 2009, as well as the Company's other filings with the Canadian Securities Administrators and the SEC.

May 1, 2011

By Ronald D. Boyer

"Early in the design stage of Meadowlands Xanadu, the client’s project director informed me that “after construction, nobody is going to come to Xanadu to see the foundations.” My response was, “Well, that’s good, because the only reason someone would come to see the foundations is if there is a problem with them.” The client’s real message was clear: the money for the project would be better spent on architectural design components and interior finishes that would attract high-end tenants and entertainment seekers. The foundations, however, were challenging. The sheer size of the Xanadu development, the varying depths to rock, the loading conditions associated with the different structures, and the construction sequencing required the use of multiple deep foundation types and specialty foundation contractors. Xanadu, when completed, will consist of over 2.5 million sq ft of entertainment venues, restaurants and retail stores; America’s first i n d o o r s n o w dome; North America’s tallest (287 ft high) Ferris wheel; and four parking decks. Finished grades for Xanadu were essentially within about 1 to 2 ft of existing grades at the site, except for a 5 acre wetlands area, which received about 8 ft of new fill. Before the current construction, the approximate 75-acre Xanadu site was occupied by the Continental Airlines (now Izod) Arena, on-grade parking lots and the wetlands area. The Arena property is part of the New Jersey Sports and Exposition Authority (NJSEA) Meadowlands Sports Complex, which also includes Giants Stadium and the Racetrack, and is located in East Rutherford, N. J. Subsurface ConditionsThe site subsurface conditions include fill materials underlain by organic silt and peat (former marsh deposits or “meadowmat”), varved clay, glacial till and shale bedrock. The Xanadu site had been a marsh until the Sports Complex was created by filling in the early 1970s. The fill consists of dredged materials from Lower New York Harbor imported by hydraulic pipeline from the Hudson River. The fill also includes “historic fill,” defined as nonindigenous material deposited to raise the topographic elevation of a site, such as construction debris and other nonhazardous solid waste, and was generally encountered in thicknesses ranging from 8 ft to 18 ft. Within the previously developed portion of the site, a layer of marsh deposits consisting of peat and organic silt was encountered beneath the fill in thicknesses ranging from two ft to seven ft. Within the existing wetlands area, the marsh deposits were up to 10 ft below existing grade. The varved clay stratum was six ft to 36 ft thick. The depth to shale rock increases from approximately 15 ft near the west side of the site to approximately 80 ft near the south side. Groundwater was tidally influenced and varied from about 6 to 12 feet below both existing and proposed grade."

Jan 1, 2009

By J. G. Pippenger

Rio Tinto Coal Australia (RTCA) developed the Meandu Mine in Queensland, Australia in 1983 to supply thermal coal to the adjacent and newly constructed Tarong Power Station (TPS). In designing the mine, RTCA selected Meandu?s best economic reserves for a 27-year life based on station owner Tarong Energy Corp.?s (TECs) estimated life for TPS. That 27-year plan changed dramatically in the early 2000s when TEC approved life extensions to TPS?s four existing units plus construction of a fifth unit. After reviewing Meandu?s remaining reserves, RTCA decided the nearby Kunioon reserve offered the more economic option for maintaining deliveries beyond 2010. Those plans changed again in 2007 when TEC chose to purchase the Meandu Mine and nearby reserves. TEC then selected Thiess Pty Ltd. (Thiess) to continue operating Meandu until the new mine at Kunioon could be developed. After assuming operation of the mine in 2008, Thiess began a review of Meandu?s remaining reserves and found considerable coal available with economic potential. Working jointly with TEC, Thiess performed several analyses on Meandu and subsequently the Kunioon coal reserves. The results changed TEC?s decision from expediting Kunioon?s construction to instead continuing Meandu?s operation for up to 15 additional years.

Jan 1, 2011

By C Dowding, C Aimone-Martin, P Abeel

This paper presents measurement and analysis of the dynamic response of a five-storey building to very high frequency excitation (>100 Hz) from blasting vibrations originating from a contiguous excavation of rock. Velocity response measurements in the rock and on the structure were employed to calculate the time-correlated dynamic displacement response of the building to blasting. Time-correlated structure response measurements are needed to advance the understanding of the response of urban structures to high-frequency excitation. Current regulations and understanding are based upon measurements of the response of one- to two-storey residential structures by 10 to 40 Hz excitation. The extension of these observations to taller structures when excited by high-frequency excitation needs to be investigated further.Measurements show that the amplification patterns at the ground level and top of the structure match or are lower than that observed by the US Bureau of Mines (Siskind et al, 1980) for the shorter residential structures. They decrease with increasing peak particle velocity. From the measurements, the global transverse shear strains found by differentiating ground floor and top displacements were calculated to be 12 µstrains. Time-correlated bottom and top of structure displacements show that building response may be more reflective of wave propagation up the structure than whole-structure inter-storey drift.In addition, a 3D model was used to compare computed displacements and strains to measured results. Modelled responses varied considerably, both in magnitude and location of the maximum strain. No conclusion can be made regarding the best 3D model to employ to simulate building response. More data such as motions measured at many points in the structure are needed. Maximum inter-storey transverse shear strains calculated with the model were found through the acceleration excitation and were less than 12 µstrains for 37 mm/s rock motion excitation. The inter-storey transverse shear strains calculated with rock displacement input were less than that found with the acceleration excitation.CITATION:Dowding, C, Aimone-Martin, C and Abeel, P, 2015. Measured and modelled response of a multistory, urban structure to high-frequency blasting excitation, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 211–220 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By K. Mallikarjuna Rao

There are several methods available to estimate deflection and ultimate Capacity of laterally loaded piles. In this investigation an attempt has been made to verify the existing methods for prediction of ultimate lateral resistance and deflection with the laboratory and field test results reported in the literature. A 75 pile loading test data obtained from the literature was used to evaluate two methods designed to predict the ultimate lateral resistance of rigid piles and three methods designed to predict the lateral deflections of rigid piles and four methods designed to predict the lateral deflection of flexible piles subjected to lateral loads. The accuracy and precision of each method is quantified statistically. The statistical results of the overall analysis indicate that the mean values of the ratios of predicted to measured lateral capacities vary from 0.62 to 1.14 with an average of 0.88. However, the settlement predictions were much more widely scattered than the ultimate load predictions and in general all the methods have a tendency to under predict the deflections. A new method is proposed by modifying the Broms's method to estimate the lateral deflections of free headed rigid and flexible piles separately. The proposed modified methods were found to be reasonably good in comparison to existing methods and to overestimate deflections.

Jan 1, 1996

By G Cavanough, A Olsson, J Rock, A C. Torrance

There are various methods currently in use to determine detonation performance of bulk explosive products including velocity of detonation (VOD), high speed photographic analysis, fragmentation analysis and unconfined detonation of samples. For assessment prior to detonation the current practice is limited to a measurement of cup density. This paper presents additional techniques that have been developed to provide measurement and assessment of bulk explosive products. Techniques applicable prior to detonation include a mobile laboratory to allow on-site chemical and physical analysis of sensitised products and ‘in-hole density’ measurement to monitor the in-hole density during sleep time. Assessment of detonation performance is achieved using detonation pressure sensors. These sensors allow measurement of detonation pressure, average VOD, propagation time and magnitude of the pressure induced in the explosive column by detonation of adjacent blastholes.CITATION:Cavanough, G, Torrance, A C, Rock, J and Olsson, A, 2015. Measurement and assessment of bulk explosive products, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 477–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A K. Raina, V M. S R Murthy

Rock mass response in blasting is an important element to determine the performance of a blast along with its other outcomes. The near-field monitoring for rock mass response analysis is vital for determining the behaviour of a blast; however, due to costly and cumbersome methods involved in such measurements the subject has received scant attention so far and the publications on this account are perfunctory in nature. This paper presents a non-destructive method to monitor the blast-induced pressure in the rock mass at a distance from a blasthole. The methodology of monitoring and a few examples of actual field monitoring are detailed in this paper. The responses of the rock in the near-field of a blasthole under dynamic loading have been documented to predict fragmentation and throw. The proposed method has also been used in limited cases earlier by the author to predict flyrock using a semi-empirical method and trajectory equation. The pros and cons of the method are discussed while throwing light on the actual response and the prediction of fragmentation and throw of blasted rock.CITATION:Raina, A K and Murthy, V M S R, 2015. Measurement of blast-induced pressure in bench blasting and deciphering explosive performance through rock mass response analysis – a methodology, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 501–508 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By R. V. Kumar

"The use of sensors to monitor gaseous species in industrial processes is discussed. All of the existing systems have disadvantages. Sensors, based upon solid electrolytes, which can be placed directly into the gas stream are attractive but many also respond to oxygen, need to be sealed at high temperatures and require a separate reference. This paper describes sensors, usually based upon two electrolytes, which do not respond to oxygen and do not require high temperature gas seals or separate references. The application of these sensors to the measurement of carbon dioxide, sulphur dioxide and trioxide and hydrogen chloride is described. These sensors can be placed directly into the gas stream at elevated temperatures.IntroductionOn-line gas sensing is becoming more important as concerns regarding the environment mount. There are many established techniques for monitoring gases in industrial processes, with applications in safety monitoring, chemical analysis or process and emission control. Flue gas analysis involves the greatest technical complexity, requiring several sophisticated capital-intensive spectroscopic instruments for different species as well as needing highly skilled operators. There are also several instruments, based upon aqueous electrochemistry, which are available for the analysis of the gases S03, S02, N02 but these require that the gases are sampled at high temperature and cooled, prior to analysis. These instruments cannot be considered as giving on-line measurements of the gas composition. Furthermore, the power requirement of these instruments frequently precludes battery operation for field and domestic use."

Jan 1, 1997

By J. A. Bakken, M. Tangstad, P. A. Eidem

In the submerged arc production of ferromanganese, sillicomanganese and ferrochromium, the coke bed characteristics play an important role. The basic mechanisms of electric current conduction in the coke be dare not yet fully understood, but important parameters are the material resistivity of coke and the contact resistance between the coke particles. Preliminary tests indicate that the contact resistance is of great importance to the bulk resistance of the coke bed. An apparatus measuring the material resistivity and contact resistance of carbon materials has been developed. Both graphite and industrial coke have been tested. The material resistivity tests were performed on single particles to ensure that the effects of pores and cracks were included and the contact resistances were excluded. Two geometries were tested to obtain the contribution of the contact resistance to the total resistance of two connecting particles. The tests were performed in an inert atmosphere at temperatures and current levels found in industrial submerged arc furnaces. The results show that the method has a satisfactory reproducibility. It was found that the contact resistance is about 10 times higher than the resistance of the material when two particles are in perfect contact and that the resistivity of SSAB coke is more than 10 times higher than that of the graphite at room temperature, but with increasing temperature the difference decreases. For SSAB coke the general trend is that both the resistivity and the contact resistance decrease with increasing temperature.

Jan 1, 2007

By L Tatnell, R Mackay, A Tolooiyan

The multi-reversal direct shear test (MRDS) method is commonly used to measure the residual shear strength of soils. However, when the standard direct shear (DS) apparatus is used, the MRDS method is prone to two major sources of error: load cap tilting and specimen loss. These two sources of error can cause erratic behaviour in the residual shear strength curve, making it difficult or even impossible to determine the correct residual shear strength value of the specimen being tested. This paper presents the results of new modifications to the standard DS apparatus that prevent load cap tilting and specimen loss. Consolidated drained testing was performed on highly-over consolidated cohesive soil samples from a Latrobe Valley open pit mine, with results obtained from the modified DS apparatus showing a great improvement in the residual shear strength profile compared to those obtained using the standard apparatus. Large numbers of reversals (up to 14) conducted on a single specimen in the modified DS apparatus showed no notable load cap tilting and no specimen loss occurred. The modifications are easily applied to the standard DS apparatus, and analysis and correction of the data are simple.CITATION:Tatnell, L, Tolooiyan, A and Mackay, R, 2014. Measurement of residual shear strength using a modified direct shear apparatus, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 425–434 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By Moelans. N.

A method using an ex-situ electrochemical measurement device was developed to determine the oxygen potential of non-ferrous metallurgical slags. The electrochemical cell consists of the molten slag sample, an inert Ir electrode, a stabilized Zr02 solid electrolyte and a NilNiO reference electrode. Different slags from non-ferrous pyrometallurgical processes were analysed at I 100 and 1200 °C and pO2values between 10-3 and 10-12 bar were obtained. The measurements were evaluated with thermodynamic calculations and using processing considerations. It was found that the reproducibility and stability of the measurement was significantly improved by shielding the molten slag from the atmosphere by a thin layer of carbon, especially for slags with a low oxygen potential.

Jan 1, 2003

By N. Moelans

A method using an ex-situ electrochemical measurement device was developed to determine the oxygen potential of non-ferrous metallurgical slags. The electrochemical cell consists of the molten slag sample, an inert Ir electrode, a stabilized Zr02 solid electrolyte and a NiINiO reference electrode. Different slags from non-ferrous pyrometallurgical processes were analysed at 1100 and 1200°C and pO2 values between 10-3 and 10.12 bar were obtained. The measurements were evaluated with? thermodynamic calculations and using processing considerations. It was found that the reproducibility and stability of the measurement was significantly improved by shielding the molten slag from the atmosphere by a thin layer of carbon, especially for slags with a low oxygen potential.

Jan 1, 2003

By BHAMIDIPATI S. SASTRY, KATTAMURI PAVAN KUMAR, ADITYA PANDEY

Several laboratory methods are available to determine the thermal conductivity of rocks, but most of them are complex and cumbersome. The present study explains the working principle of Lee’s apparatus, which is relatively simple, easy to fabricate and use, and provides consistent results. In the present study, thermal conductivities of sandstone cores obtained from an Indian coal mine are determined using Lee’s apparatus. An approach is discussed to determine the temperature gradient of sandstone specimens while cooling and is used to calculate thermal conductivity. The thermal conductivities of different sandstone specimens have values between 2.37 and 2.59 Wm−1°C−1. For different sandstone cores obtained from the field, properties including specific gravity, specific heat capacity, thermal diffusivity and porosity, along with thermal conductivity, were determined and highlighted in this study.

By M. Botz

For leach solutions containing primarily free cyanide, the silver nitrate titration method is a rapid and acceptably accurate means of analyzing for cyanide. However, in leach solutions containing elevated levels of copper, the titrimetric method significantly over-estimates the concentration of free cyanide and under-estimates the concentration of weak and dissociable (WAD) cyanide. The authors have developed a modified potentiometric titration method for determining WAD cyanide that overcomes issues with high copper levels in solution. The new MP-WAD method involves addition of a chemical ligand to the sample prior to silver nitrate titration to fully release cyanide bound to copper. Once released from copper, cyanide in solution is no longer affected by the presence of copper and titration results are quantitative rather than empirical. In multiple laboratory trials with synthetic solutions and complex actual leach solutions, accurate WAD cyanide measurements were achieved using the MP-WAD method. Analyses obtained with the new method were found to be within about ±10% of analyses obtained with the USEPA OIA-1677 WAD cyanide analytical method.

Feb 27, 2013