Search Documents

By Helga Larravide

A new on-line database of literature about copper has been created through a joint undertaking by the Copper Development Association Inc. and PROCOBRE-Chile, with funding provided in part through the International Copper Association, Ltd. The new database will permit Spanish-speaking technologists to access publications maintained by PROCOBRE-Chile by means of standard keyword searches. In addition, a new Spanish- English thesaurus has been written to enable Spanish-speaking individuals to search d access the Technology and Environmental databases of the Copper Data Center, which together comprise more than 80,000 publications dealing with the production, properties, uses and environmental effects of copper. Planned expansion of the new Spanish literature database is described.

Jan 1, 1999

By Cesar O. Gomez

A procedure has been developed for mounting at random particles of mineral samples to be characterized using image analysis. The procedure is based on the generation of a random distribution of sample particles in particles of a diluent material. and the embedding of this particle mixture in an epoxy resin without disturbing the initial distribution. Two materials with atomic number similar to that of the epoxy resin were successfully used as diluents: activated charcoal and graphite. The proportion of diluent material to be mixed with the sample to have a large number of mineral particles in the field of view while keeping the occurrence of touching particles at an acceptable level was determined empirically. The randomization achieved with the procedure developed in this work was tested using as samples known mixtures of silica and pyrite particles of the same sieve class. The agreement obtained between the mass ratio of minerals used in the preparation of a particular specimen and that resulting from image analysis demonstrates that the procedure developed is successful in producing a specimen where the embedded particles are randomly distributed.

Jan 1, 1988

By W. H. Pomroy

Spontaneous combustion fires in deep metal mines, through relatively infrequent, are nonetheless cause for considerable concern because they pose a direct threat to the safety of miners and are quite disruptive to mine operations. They often occur in remote, inactive, or abandoned sectors of a mine where access for firefighting is difficult or impossible. Over half of all noncoal mine fires that last more than 24 hours are caused by spontaneous combustion. The most common means of fire control for spontaneous combustion fires is sealing and/or Flooding the affected zone. This process is never easy, but it is made especially difficult (and hazardous) if the fire grows in size and intensity to the point where underground fire- fighting crews must wear self-contained breathing apparatus owing to mine air contamination. The Bureau of Mines has developed and in-mine tested a mineworthy fire detection system capable of sensing the earliest traces of spontaneous combustion, thus enabling mine personnel to initiate fire control operations before hazardous atmospheres are created. This paper discusses system design within the context of the harsh mine environment, and describes laboratory and in-mine performance tests of prototype equipment.

Jan 1, 1985

By D K. Weatherley, G R. Ballantyne, S Ali, M Yahyaei, M S. Powell

This paper explores development of a novel ore characterisation method for the precise measurement of practical minimum comminution energy. A monolayer of particles with a narrow size distribution is broken using a precision rolls crusher (PRC); an ore characterisation device developed to overcome the shortcomings of conventional tests. For energy measurement, PRC uses two shaftmounted rotary torque transducers. These transducers acquire precise torque and angular speed data in response to the load applied to the rotating shafts during breakage events, which is converted into energy. The test progressively crushes feed particles down to final product size in many controlled breakage stages. The generation of fines in each breakage stage is then plotted as a function of input energy. The inverse of the gradient of this plot provides the size specific energy (SSE) in kWh/t of material generated below a predefined marker size; -75 μm in this case. The PRC has potential to evolve as a geometallurgical ore characterisation test—it is simple, fast, requires small sample mass (200–300 g), covers a wide feed particle size range (10 mm to 115 µm), and provides ideal SSE measurements that can be used for the calibration of on-site production equipment.

Aug 24, 2022

By E. Stansfield

Coal samples are sometimes taken from a wet spot in a mine, or from an open car or pile shortly after rain, and submitted for analysis in a dripping wet condition. Other samples are taken from a dry spot in the mine, or from an open car or pile after a period of dry weather. Comparison of the analyses obtained in the two cases would be absurd, although the samples might be of essentially the same coat apart from the surface moisture on the one. The analyst therefore attempts to reduce all samples to an equal basis by the operation known as air-drying. Air-drying is practised by the chemist for three reasons: (1) To make it possible to grind the coal to powder. (2) To bring the coal sample to a condition in which it will not change in weight rapidly whilst portions are being weighed out for analysis -in other words, to bring it into equilibrium with the air in the laboratory. (3) To determine the water-retaining power of the coal. Any kind of drying is satisfactory for (1); the coal should be dried more or less according to the humidity at the time in the laboratory for (2); whilst it should be always dried to the same extent for (3). In other words, no method can be satisfactory for both (2) and (3). In this paper the only question considered is (3) -that is, air-drying the coal under standard conditions so that strictly comparable results can be obtained for the water content of coals after air-drying. After a sample of wet coal is exposed, it loses moisture until it is in equilibrium with the air at the time: thus the coal will loose distinctly more water in air of 20 per cent relative humidity, for example, than it would in air of 80 per cent.

Jan 1, 1923

By G. Upadhya

Of late, solidification modeling has progressed considerably to emerge as a viable simulation tool for the foundry engineer. A wide variety of tools exist in the commercial market to cater to the various needs of the design/ foundry engineer. In fact, recent developments in the area of solidification modeling have been so rapid that a comprehensive review of the state-of-the-art is very much needed. In this paper, an attempt is made to summarize the various issues of solidification modeling, at the same time addressing the historical evolution of the subject. The various phenomenological issues covered in this paper include: heat transfer, fluid flow during mold-filling, solidification kinetics and microstructural evolution, quick-analysis schemes for approximations, porosity prediction models, and the phenomena of fluid flow in the mushy zone. Modeling issues related to the development of solidification stresses which lead to defects such as hot tears and the development of artificial intelligence concepts in the area of rigging design are also discussed. Due emphasis is given to the various phenomena which add to the complexity of the whole subject, and the various alternatives available for solving a particular problem. For example, the heat transfer problem can be approached by the use of simple modulus schemes or by solving the conduction equation to obtain a more accurate temperature distribution. Similarly the microstructural evolution can be handled in a deterministic way by use of nucleation and growth models, or in a probabilistic way by use of empirical models. The main goal of this paper is to put the multi-faceted problem of solidification modeling in proper perspective so that it can serve as a guide for future developments in this area.

Jan 1, 1994

By Hayward B. Oblad

The effects of eight independent variables on froth flotation product yield, ash content, and coal recovery were studied using laboratory batch flotation of 0.6 am x 0 coal. The eight flotation variables investigated were air feed rate, pre-dispersion of collector oil, impeller speed, product collection time, initial solids concentration, collector conditioning time, frother (methyl isobutyl carbinol) concentration, and collector (No. 2 fuel oil) dosage. The two-level Plackett-Burman screening design and the three-level Box-Behnken design were used. Within the ranges studied, air feed rate had no effect on product yield. Pre-dispersion of collector oil, impeller speed, product collection time, initial solids concentration, and collector conditioning time showed only minor effects on the product yield and quality. Frother concentration (mg/L) in the process water and collector oil dosage (g/kg) were shown to be the dominant independent variables in coal froth flotation. Flotation experiments that vary initial solids concentration at constant frother dosage (g/kg) confound the effects of frother concentration (mg/L) and solids concentration. The dominating effects of frother concentration and oil dosage on coal recovery and froth product ash content are illustrated with three-dimensional plots. The relationship between froth product ash and coal recovery is also clearly illustrated by the flotation data.

Jan 1, 1985

By B. Erik Ydstie, Dimitrios I. Gerogiorgis, Sridhar S. Seetharaman

"Carbothermic production of aluminium is an important alternative to electrolytic processes and has in fact been identified several decades ago as a potentially feasible and profitable process. The cornerstone principle is to take advantage of the endothermic reduction reaction between carbon and alumina instead of resorting to extreme amounts of electric energy to ionize and reduce aluminium oxide to aluminium. Electric energy is necessary only for heating purposes.The present study focuses on constructing and solving a steady-state electrothermic model for obtaining the spatial distributions for electric potential, electric field intensity and temperature. The complex issues of reaction kinetics and multiphase flow are handled by an approximation and are not addressed at the present stage, due to the lack of complete validated models. Because of its inherent complexity, the reaction slag is considered a pseudohomogeneous layer.An electrothermic simulation encompasses important research challenges, due to the limited knowledge of thermophysical properties for high-temperature multi component molten slags. Therefore, thermophysical property modeling and a systematic compilation of published data is a necessary and major first step towards enhancing understanding of the process fundamentals. Models are obtained by analyzing measurement data from numerous literature references for the density, viscosity, thermal and electrical conductivity and specific heat capacity of the slag.The electric potential, field intensity and temperature distributions obtained reveal interesting maxima which indicate localized superheating and lead to important engineering conclusions. The temperature profile calculated will serve as the foundation for the flow problem solution. This computational study will form a basis for future research towards combining the scopes of microscale CFD modeling and mesoscale process modeling into a unified modeling approach."

Jan 1, 2001

By S. K. Kawatra, S. K. Valluri, S. J. Root

Common carbon dioxide capturing reagents, such as amines and sodium hydroxide, are expensive, toxic, and energy intensive to regenerate. We have added frothers to a sodium carbonate solution in order to increase the surface area available for CO2 transport within the packed bed of a counter current scrubbing column. Addition of frothers has improved the performance of sodium carbonate scrubbing solutions to be on par with sodium hydroxide scrubbing solutions. This novel enhancement of a relatively inexpensive CO2 capture-regeneration cycle shows potential to allow plants to turn a profit by sequestering a waste product. These results are discussed in detail in the following manuscript. INTRODUCTION The combustion of fossil fuels converts chemical energy to thermal energy. CO2 is produced as a byproduct of the reaction. 80% of the world’s electricity is produced by using this thermal energy to power a generator, accounting for 40% of global carbon dioxide emissions. In an effort to stabilize the rising atmospheric CO2 levels, researchers are investigating the application of carbon capture and storage (CCS) systems in power plants. [1] Efforts to capture CO2 at some power plants have been successful, but the cost of installing and operating the required equipment is high. As such, very few power plants have CCS systems. If CO2 can be captured and processed into a product that can be sold at a profit, installing CCS systems in power plants will be a very attractive business decision. In order for the sale of captured CO2 to become a profitable venture, the cost of capturing the CO2 from a flue gas must be reduced. BACKGROUND The most common method for separating CO2 from a flue gas is by passing it through a counter-current packed bed scrubbing column. The flue gas enters the bottom of a column while a solution of a chemical with properties advantageous to the absorption of CO2 is pumped to the top. The fluids interact in a packed bed, where the CO2 is transported from the gas to the liquid. CO2 is an acid gas, so it is common for the scrubbing solution to be alkaline in nature in order to neutralize the carbonic acid that is formed when it is dissolves into water. The exhaust exits the top of the column free of carbon dioxide, which exits the column in the scrubbing solution, reacting or complexing with the absorbent. Figure 1 is a schematic drawing of a CO2 scrubbing column. It shows the molar flowrates and compositions of the gas and liquid at the bottom [1], the top [2], and an arbitrary height in the column [Z]. [2,15] L is the molar flowrate of liquid at any point in in the column. G is the molar flowrate of gas at any point in the column. Since the CO2 is transported from the gas to the liquid, L and G are variable with respect to height. To simplify calculations, the CO2 free molar flowrates Ls and Gs are often used. X is the fraction moles of aqueous CO2 per mole of CO2 free liquid. Y is the fraction moles of gaseous CO2 per mole of CO2 free gas. Figure 2 is a composition diagram of the scrubbing column depicted in figure 1.

Jan 1, 2019

By R. A. Govender, A. Mudau

"Rockbursts continue to be a major contributor to mine accidents and cause of damage to mine excavations, particularly at great depth. The problem of rockbursts has also escalated in civil engineering tunnels driven at depth, due to high levels of in situ stress at such depths. Attempts have been made in the past to mitigate the impact of rockbursts, with rock support remaining the ultimate method for providing stability in rockbursting environments. However, records show that, on many occasions, conventional support elements such as rockbolts, wire mesh, shotcrete, and lacing fail to withstand severe rockburst events.Recently, a support method termed ‘sacrificial’ support was proposed as a potential additional method to prevent rockburst damage, based on observations made after rockburst events in a mine. The philosophy behind a sacrificial support system is that, under dynamic loading conditions, support in the form of a liner must fail; leaving behind, undamaged, what was previously supported rock mass. The sacrificial support concept reported herein is applicable in situations where the source (i.e. seismic event) of the rockburst is located remote from where rockburst damage is likely to occur.Spalling tests based on the split Hopkinson pressure bar (SHPB) technique were conducted to study some aspects of dynamic rock fracturing in tension at high strain rates and the role a sacrificial layer plays in combating dynamic rock failure. A single Hopkinson pressure bar, with a long cylindrical intact rock specimen attached at the bar free end, was impacted by a striker on the opposite free end in order to generate a dynamic stress pulse responsible for spall failure upon reflection from the specimen free end. Different liners and liner combinations were then introduced at the specimen free end as support. Such a simple, yet robust, experimental set-up allowed the potential benefits and failure mechanisms associated with sacrificial support under dynamic loading to be demonstrated and compared with ‘sacrificial support’ behaviour observed in real rockburst events in a mine. Analysis of the results revealed that varying liner thickness and mechanical impedance between rock and support liner play a significant role in limiting rockburst damage."

Jan 1, 2016

By A Karrech, C Schrank, O Gaede, I Canbulat

Strain-based failure criteria have several advantages over stress-based failure criteria: they can account for elastic and inelastic strains; they utilise direct, observable effects instead of inferred effects (strain gauges versus stress estimates) and they model complete stress-strain curves, including prepeak, non-linear elasticity and post-peak strain weakening. In this study, a strain-based failure criterion derived from thermodynamic first principles utilising the concepts of continuum damage mechanics is presented. Furthermore, implementation of this failure criterion into a finite element simulation is demonstrated and applied to the stability of underground mining coal pillars.In numerical studies, pillar strength is usually expressed in terms of critical stresses or stress-based failure criteria where scaling with pillar width and height is common. Previous publications have employed the finite element method for pillar stability analysis using stress-based failure criterion, such as Mohr-Coulomb and Hoek-Brown, or stress-based scalar damage models.A novel constitutive material model, which takes into consideration anisotropy as well as elastic strain and damage as state variables, has been developed and is presented in this paper. The damage threshold and its evolution are strain-controlled, and coupling of the state variables is achieved through the damage-induced degradation of the elasticity tensor. This material model is implemented into the finite element software Abaqus and can be applied to 3D problems.Initial results show that this new material model is capable of describing the non-linear behaviour of geomaterials commonly observed before peak strength is reached as well as post-peak strain softening. Furthermore, it is demonstrated that the model can account for directional dependency of failure behaviour (ie anisotropy) and has the potential to be expanded to environmental controls such as temperature or moisture.CITATION:Gaede, O, Schrank, C, Canbulat, I and Karrech, A, 2014. A strain-based failure criterion for pillar stability analysis, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By Brian Hart, Rong Fan, Roger Smart, Andrea Gerson, Ning Xu

A complete strategy has been developed for identification of the reasons for losses in recovery and/or grade, due to changes or complications in mineralogy and in mineral surface conditioning, and their subsequent correction. The sequence of methods starts with comparison of mineral phases between QEMSCAN/MLA (compositional) and Rietveld XRD (crystalline diffraction) with bulk assay reconciliation. This methodology has recently led to identification of unrecognised amorphous content (12-40 wt.%), previously attributed to crystalline phases, in the fine fraction (<35 µm) of some problematic flotation feeds. Attached amorphous silica, talc- and chlorite-like fines have direct influence on the hydrophobic/ hydrophilic ratio on value mineral surfaces adversely affecting flotation. SEM/EDS is used in the backscattered imaging mode to determine possible problems with liberation (e.g. remnant local locking), not detected in standard liberation analysis, resulting in gangue flotation. EDTA extraction is used to assess bulk feed pre-oxidation and sequential oxidation product loading through the circuit. Changes in circuit solutions are assayed with speciation modelling of precipitates and potentially adsorbing species. ToF-SIMS with principal component analysis is then used to correlate surface species with specific minerals and can be used to assess the effectiveness of specific reagents particularly collectors. This approach identifies unwanted activating species and interference with value surfaces by adsorbed hydrophilic ions, precipitates and fine particles. When the interference or ineffective reagents are specifically identified, remedial action can be targeted. This method has identified residual talc-like layers (<10 nm thick) inducing gangue flotation of pyroxene and chromite in PGM flotation. Recent case studies of application of the full methodology to losses of molybdenite at KUCC and to sphalerite activation in the Cu/Pb circuit at Brunswick Mines with remedial action are discussed.

Jan 1, 2014

By J. M. Mutmansky, C. Lee

"IntroductionRecognition of Coal Workers' Pneumoconiosis (CWP) as a major occupational disease has affected various aspects of the coal mining industry in the United States as well as in almost all major coal producing countries, Regulations related to the control of coal mine dust forced mine operators to modify their mining and ventilation practices. As the coal production record of the last 15 years shows, this had both direct and indirect impacts on the productivity and production costs.To identify the causes of CWP, many research efforts have been made throughout the world. Most of these studies were epidemiological in nature, attempting to pinpoint exposure and seam variables that affected the incidence of the disease. Other studies have been oriented toward the elemental and mineralogical composition of the coal dust in the mine atmosphere and in the miners' lungs. These studies indicate that there may exist some relationships between the characteristics of the coal mine dust and the prevalence of the disease. Some of the variables that are thought to affect the occurrence of CWP are the mass of the dust in the working place, the rank of the coal, the existence of certain trace elements, the free silica content of the coal, and the existence of other minerals in the respirable dust. A more complete description of these previous research studies has appeared elsewhere (Mutmansky and Lee, 1984).The behavior of particles in the human lung is known to be governed by their aerodynamic diameter, which is defined as the diameter of a hypothetical spherical particle with unit density that exhibits the same settling velocity as the given particle. Because of this fact, the aerodynamic size distribution of coal mine dust is one of the parameters to be determined along with the other physical, elemental, and mineralogical characteristics. The objective of this paper is to establish a strategy for providing coal mine respirable dust samples for characterization purposes using instruments that classify according to the aerodynamic diameter. In addition, several findings concerning characterization methods will be presented"

Mar 1, 1989

By Changwoo Lee, Jan M. Mutmansky

Introduction Recognition of Coal Workers&apos; Pneumoconiosis (CWP) as a major occupational disease has affected various aspects of the coal mining industry in the United States as well as in almost all major coal producing countries. Regulations related to the control of coal mine dust forced mine operators to modify their mining and ventilation practices. As the coal production record of the last 15 years shows, this had both direct and indirect impacts on the productivity and production costs. To identify the causes of CWP, many research efforts have been made through- out the world. Most of these studies were epidemiological in nature, attempting to pinpoint exposure and seam variables that affected the incidence of the disease. Other studies have been oriented toward the elemental and mineralogical composition of the coal dust in the mine atmosphere and in the miners&apos; lungs. These studies indicate that there may exist some relationships between the characteristics of the coal mine dust and the prevalence of the disease. Some of the variables that are thought to affect the occurrence of CWP are the mass of the dust in the working place, the rank of the coal, the existence of certain trace elements, the free silica content of the coal, and the existence of other minerals in the respirable dust. A more complete description of these previous re- search studies has appeared elsewhere (Mutmansky and Lee, 1984). The behavior of particles in the human lung is known to be governed by their aerodynamic diameter, which is defined as the diameter of a hypothetical spherical particle with unit density that exhibits the same settling velocity as the given particle. Because of this fact, the aerodynamic size distribution of coal mine dust is one of the parameters to be determined along with the other physical, elemental, and mineralogical characteristics. The objective of this paper is to establish a strategy for providing coal mine respirable dust samples for characterization purposes using instruments that classify according to the aerodynamic diameter. In addition, several findings concerning characterization methods will be presented. Choice of Samplers Most of the gravimetric dust collection devices that can be utilized in a mine environment can be

Jan 1, 1986

By H. Jung, J. Kim, Y. Lee, Y. Seo

"Shale gas has become an increasingly important source of natural gas supply in North America and around the world. Horizontal drilling and multi-stage hydraulic fracturing are the two key enabling technologies for the economic development of these shale gas reservoirs. It is believed that gas in shale reservoirs is mainly composed of free gas within fractures and pores and adsorbed gas in organic matter (kerogen). It is generally assumed in the literature that the monolayer Langmuir isotherm describes gas adsorption behavior in shale gas reservoirs. In this work, we have analyzed several experimental measurements of methane adsorption from the Horn River Shale core samples that obey the Langmuir isotherm. INTRODUCTION In nature, gas shales are characterized by extremely small grain size, extremely low permeability on the order of nano-Darcy (10-6 md), small porosity, and high total organic carbon (TOC). Shale can serve as both source and reservoir rock. The amount of gas in place in shale is strongly affected by the TOC, clays, and the adsorption ability of methane on the internal surface of solid (Martin et al., 2010). Since a considerable amount of gas in shale reservoirs is adsorbed, investigation of gas adsorption can provide critical insights into evaluation of well performance and reservoir characterization. Generally, natural gas in shale reservoirs is stored as free gas in both larger mineral pores and natural fractures, as well as adsorbed gas within organic matter (Leahy-Dios et al., 2011). EXPERIMENT METHOD & THEORY Adsorption Experiment Several experiments were carried out on 9 shale core samples obtained in a vertical well drilled within Horn River basin (Figure 1). The CH4 adsorption isotherms were measured for the different depth. In order to measure the amount of adsorbed gas, the high pressure Belsorp-HP equipment applying volumetric method was used. The temperature was kept at 298 K and pressure was increased up to 18 MPa. Approximately 5 g of crushed sample was used for each measurement."

Jan 1, 2016

By R. HAYDEN, H. B. HALLOWELL, H. O. Hofman

THE object of refining copper in the reverberatory furnace is to obtain a metal which will have the highest attainable degree of malleability, ductility and electric conductivity, and present at the same time a level surface when it solidifies in the mold after casting. These desirable physical properties are governed by the character of the impurities and the forms in which they are present, by the amount of cuprous oxide retained by the copper, by the quantity of gas held in solid solution, by the casting-temperature, and by the thickness of the casting. The effects of impurities, of cuprous oxide and of gases upon the mechanical properties of copper have been studied by Hampe in his classical paper "Contributions to the Metallurgy of Copper." The most recent research into the effect of metals upon the electrical conductivity of copper is that of Addicks.2 The influence of cuprous oxide upon the electrical conductivity has been investigated by Walker&apos; and Addicks.4 The absorption of gases has received&apos; attention by Hampe,5 Stahl 6 and Heyn.7 The effects of casting-temperature have been noted by Stahl.8

Mar 1, 1907

By Gordon A. Irons, H. Y. Hwang

An impinging gas jet on a water surface was studied to understand momentum transfer in oxygen steelmaking. Depth, width and oscillation frequency of the jet cavity were measured and the splashes interpreted with Kelvin-Helmholtz instability and combined Rayleigh-Taylor and Kelvin-Helmholtz instability theory. A model to calculate separate gas and liquid velocities, applying the exact momentum boundary condition, is proposed.

Jan 1, 2004

By R. P. Charbonnier

"To understand the operation of jigs and other separating processes based on differences in gravity, it is desirable to analyse the motion of various particles in given media under specific conditions. A summary of the earlier theories shows that they lead to unsatisfactory or excessively complicated formulae in cases such as coal jigging. By adopting a simplified theory of the motion of particles in a fluid, the size and duration of the initial accelerated motion of a particle falling in hindered settling can be calculated. Based on this mathematical analysis, examples referring to actual coal jigging practice show that it is desirable to prolong and/or repeat, as frequently as possible, the optimum conditions corresponding to an effective acceleration of the particles. The separation is then obtained according to gravity rather than to particle dimensions, as would be the case if the velocity of the particles• were allowed to approach its terminal value. To achieve this gravity separation, it is suggested that the suction phase of the jigging cycle be artificially prolonged and the frequency of pulsations increased as much as possible for washing the coals of smaller sizes."

Jan 1, 1959

By Susan Jacob

The heat of fusion of silver was measured using high temperature differential scanning calorimetry (HTDSC). Heating rate, sample mass, calibration standard and cover gas flow rate were varied to determine their impact on instrument accuracy and reproducibility. Good reproducibility was achieved in most of the runs. Accuracy was not satisfactory in most of the runs, though three runs gave results within 1.7%, 3.3% and 3.5% of the literature value, within the acceptable limits. A larger mass and higher heating rate tend to generate more accurate results.

Jan 1, 2006

By Carl E. Swartz

ALTHOUGH a number of articles appeared during the war advocating the use of cadmium in lead-tin solders, very little information of value can be found in the literature regarding the properties of solders containing cadmium. In most of the published articles the cadmium seems to have been considered merely as a partial substitute for tin in a tin-lead alloy rather than as an essential constituent of a ternary alloy. The primary object of the substitution of cadmium for tin was to lessen the amount of tin required, at a time when the latter was scarce and high-priced, and thus to produce a cheaper solder. While this object was accomplished, the new properties resulting from a change from a binary lead-tin alloy to a ternary lead-tin-cadmium alloy were not given proper consideration in many cases. For the past few years, the American Smelting & Refining Co. has been marketing a very considerable amount of cadmium in the form of lead-tin-cadmium alloys for use as solders for certain special purposes, and the successful use of these solders suggested that if more extensive knowledge were available concerning the properties of lead-tin-cadmium alloys of various compositions their field of usefulness might be materially extended. The investigation described in the present paper was undertaken to obtain this information and, by means of tests under conditions approaching those of practical use, to determine the suitability of cadmium solders for various purposes. CHARACTERISTICS AND REQUIREMENTS OF SOLDERS IN GENERAL General Physical Properties.-When cast into bars, solder should present a smooth and bright appearance free from oxide inclusions and bubbles. Ductility should be as great as possible without sacrificing tensile strength, and vice versa. Hardness and specific gravity are not of any great importance. Melting Characteristics.-The melting or solidification range is important. This statement applies both to the extent of the range and to the actual temperature at which complete solidification occurs. A rather narrow solidification range is desirable in soft solders in order that solidification may take place quickly. The solder should have high fluidity at temperatures only slightly above its melting range. For a

Jan 1, 1928