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By S. Subramanian, K. A. Natarajan, D. N. Sathyanarayana

FTIR spectroscopy is used to study the ad¬sorption of an oxidized starch on hematite, corundum, and quart: substrates. The difference spectrum of the adsorbed starch on hematite indicates surface reactions involving -CH2OH and -COH groups and shows striking similarities with that of the ferric-starch system, suggesting chemical interaction between the iron of hematite and the starch adsorbate. The IR spectra of starch adsorbed on corundum and quart: show no evidence of chemical interaction, although hydrogen bonding is apparent. The extent of adsorption of starch on hematite. corundum, and quartz decreases along the series. The evidence for chemical interaction of starch with hematite is further obtained by the X-ray photoelectron spectra of starch adsorbed on hematite, showing noticeable decrease in peak positions of O(Is) and C(Is) of free starch. The Mössbauer spectrum of hematite with stanch adsorbed on it complements these findings.

Jan 1, 1990

By F. G. Hyde

Passage of the Public Utilities Regulatory Policy Act ("PURPA") in I 978 created an entirely new industry that is referred to today as the Independent Power Producers ("IPP"). Requirements of project owners, environmental compliance, project design, the financial community and most of all, the need to be a low-cost producer presented a unique situation for the sourcing and the utilization of fuels. Depending on the specific type of project being developed, (e.g. coal-fired, wood/biomass, natural gas, petroleum coke or a blend of several fuel types) and the type of boiler design, it is important to acquire fuels that will optimize both the project's operating efficiency and flexibility. This paper will focus on the acquisition of fuel for coal-fired projects, but will describe the necessary steps in the sourcing, contracting for, and the utilization of fuels and transportation resources in the IPP industry today.

Jan 1, 1996

The influence of fuel additives on automobile exhaust emissions was studied using engines currently found in the U.S. vehicle population. The fuel additives used in the experiment were four multifunctional additives and one lead antiknock additive. Experimental work was done to determine both the direct effect of the additive per se on exhaust emissions and the influence of Long-term additive effects on emissions with mileage accumulation. Results showed no significant direct or intermediate effect on exhaust emissions for any additives tested. In subsequent experimental work concerned with the long-term or indirect effects of additives, the detergent-dispersant additives were found to have little influence on emissions when used in conjunction with high-quality oil and motor fuel. The lead (tetraethyl) antiknock additive increased exhaust hydrocarbons approximately 12 to 17 percent during a 4,000-mile accumulation period using a base fuel containing 2 ml of tetraethyl lead per gallon. An unleaded fuel was used during a similar accumulation period with no significant increase in exhaust hydrocarbons with mileage.

Jan 1, 1971

By A. R. Miller

A fuel cell locomotive incorporates the advantages of its competitors, namely catenary-electric and diesel-electric units, while avoiding their disadvantages. It possesses the environmental benefits, at the vehicle, of an electric locomotive but the higher overall energy efficiency and lower infrastructure costs of a diesel locomotive. The natural fuel for a fuel cell is hydrogen, which can be produced from many renewable sources or via nuclear energy, and thus a hydrogen-fuel cell locomotive will not depend on imported oil. Hydrogen produced from renewable primary energies or nuclear energy would provide a totally zero-emissions vehicle, that is, with zero carbon in the energy cycle. A project partnership among Vehicle Projects Inc of the USA, and South African partners Anglo American Platinum, Ltd, Trident South Africa, and Battery Electric, has designed and is launching a series of five prototype fuel cell-powered mine locomotives.

Jan 1, 2012

By W. A. Lang

RESEARCH has been defined as the link between the present and the future. Science, wonderful though its achievements may be, has but scratched the surface of the unknown. Research is directing its attention to winning new facts in order that their application to the processes of today may open up new sources of wealth for the common benefit. Two classes of research investigations are often recognized-fundamental and applied, but these classes merge into each other and it is often hard to distinguish one from the other. Fundamental research is carried out primarily to develop basic facts, but frequently these are found to have immediate economic value, while applied research, specifically aimed at economic values, often necessitates a preliminary fundamental investigation. Both are essential and both should proceed by scientific method. It is obvious in fuel technology that a knowledge of the physical and chemical constitution of the various coals is fundamental to their industrial utilization, and further, a knowledge of the way these coals react under different conditions of temperature, atmosphere, etc., is necessary in solving such problems as storage, combustion, carbonization, gasification, or con-version to liquid fuels. The wide range of coals, the complexity, of their constitution, and the many uses for coal, makes fuel research no simple subject but one with unending possibilities. The Research Council of Alberta, formerly known as the Scientific and Industrial Research Council of Alberta, was established in 1919, to promote the development and conservation of the natural resources of the Province. The work of the Council was arranged in six major divisions: Fuels; Geology; Road Materials; Soils; Natural Gas; and Forest Products. The office and laboratories are located in the University of Alberta. The Council was financed until the depression of 1933 by a separate vote of the Legislature, but since then has been continued, though on a much smaller scale, as one of the activities of the University. It might, however, be noted that although the Council is now in abeyance, a skeleton organization has been maintained so that it can be brought back to active service as soon as conditions warrant. Annual reports are still submitted to the Legislature. Funds have not been made available, however, for the publication of the last five reports.

Jan 1, 1942

By William Phillips

This paper was prepared at the request of Capt. A. F. Lucas, Chairman of the Institute's Committee on Petroleum and Gas, as a preliminary discussion of the fuel oils which are used-in the Southwest, giving their composition, uses, prices, etc. Should it afterward be found desirable, these observations may be extended over a larger area. In this connection, J suggest that samples of all kinds of fuel oils, including various tars, from all over the country, be collected and sent to some testing laboratory for examination. We would be glad to extend the facilities of the laboratory of the Bureau of Economic Geology and Technology, at the University of Texas, for this purpose, and to do the work free of all expenses. After such examinations are made and the results classified and studied, it would be possible to suggest specifications under which fuel oils should be purchased, and to arrive at some conclusions respecting the uniformity of such specifications, with due allowance for climatic and other more or less local conditions. While such specifications do not now depart from a common standard anything like as much as specifications for illuminating oils do, yet there are discrepancies which should not exist. Some of these discrepancies are of lessening importance, due to the pronounced tendency to distill every crude oil that can be distilled with profit, and to send residues into the market for fuel oil. Residues from the refineries are of a more uniform chemical composition and physical nature than many of the crude oils that go direct into the fuel market. The lower flash-point oils are disappearing from the fuel trade and in place of them we are getting oils that do not flash below 220° F., nor burn under 320° F. In the Southwest, it has not been long since we had fuel oils that flashed at as low as 110° F., and the average flash point over a considerable period was 151° F. Now we are using oil that flashes at about 30° lower than the former burning point, which was 256° F. In other words, the flash point has risen, on the average, 100°; and the burning point about 75°.

Jan 6, 1914

By R. E. Gilmore

PREAMBLE THIS PAPER comprises material presented in two separate 'Papers at the British Commonwealth Scientific Specialist Conference on Fuel Research held in London, England, in July, 1950. These papers are now available for publication in Canada, since only essential parts of the conference discussions, in addition to the resolutions resulting therefrom, will be published in the official Proceedings of the Conference. Inasmuch as the information presented concerns Canadian organizations and training facilities for fuel research, it should be of general interest to Canadian scientists, and especially to the Coal Division of the Canadian Institute of Mining and Metallurgy. Part I, the alternate title of which is Facilities in Canada for Fuel Research and for Exchange of Information and Staff, does not include research on peat, oil shale, petroleum oils in general, and natural gas, and omits studies of the geology, constitution, and production of coal. Special reference is, however, made to research on the heavy crude oils and bitumen of the Western Prairie Provinces, and particularly to their production and treatment to produce crudes for oil refinery processing.

Jan 1, 1951

By R M. Ennis, J. C. Botham

This paper is one of a series pre-pared to study the role of fuels and reductants in metallurgical processes, especially from the viewpoint of Canadian requirements. The object of these studies is to provide a reason-ably authoritative interpretation on the interrelation of fuels in light of the considerable changes that have taken place in the Canadian energy field during the past few years. Previous papers in this group have dealt with the problem generally, and specifically in terms of the development of the iron and steel industry of Western Canada. These latter papers, presented at the Symposium on Iron and Steel in Western Canada held in Edmonton, Alberta, on September 8-9, 1959, surveyed the ferrous processes of interest for use in Wes tern Canada, especially with regard to solid fuel requirements. At that time it was evident that there was a need for a similar study of the fuels aspect of the non-ferrous metals industry.

Jan 1, 1961

By SME SME

NORTH AMERICAN TUNNELING 2024 PROCEEDINGS

Jun 23, 2024

By G Burton, S Fityus, J Li, S Vaughan, D Payne

Daunia and Caval Ridge coal mines, owned and operated by BHP, have been co-disposing rejects and dewatered tailings within spoil dumps from the beginning of their operations in 2013 and 2014, with the purpose of minimising environmental impact and geotechnical risk. Following the recent large failures of tailings dams around the world, BHP Coal, through its Coal Tailings Program, plans to transition other coal mines to deliver “dry” tailings and produce mixed plant rejects (MPR) for inpit co-disposal. This will materially reduce future tailings dam risk exposure. Previous laboratory shear strength testing was conducted on rejects with a maximum particles size of 20 mm, and some concerns were raised that this might not represent the mechanical properties of the actual full particle size distribution (PSD) rejects. BHP was also aware that using different technologies to dewater the tailings, such as belt press filters (BPF) and solid bowl centrifuge (SBC), could produce thickened tailings which could significantly modify the physical behaviours of the MPRs, particularly the bonding between particles. Therefore, laboratory testing on both coarse rejects and mixtures of the coarse rejects and dewatered tailings (MPRs), with full PSDs, was carried out. Testing was performed using the large direct shear machine developed by the Australian Coal Association Research Program (ACARP) project C20019 in 2017, as well as a 300 mm diameter triaxial apparatus at the University of Newcastle (UoN). This paper presents details of the laboratory testing program and results for the rejects from the first studied mine of the BHP Coal Tailings Program. It compares the shear strengths measured at full scale with those tested on modified (scalped or crushed) specimens in the past; and discusses the tailings dewatering technique selection from geotechnical aspects based on the testing results, and finally presents some dump and tip head stability analysis results using the testing results.

Jul 1, 2021

By André L. de Vegt

Soil and groundwater beneath a zinc production plant in The Netherlands are contaminated with metals and sulfate. To avoid contamination of nearby drinking water aquifers, a hydro-geological containment system and a biological treatment plant for the extracted ground water have been installed. Currently about 5000 m3/day of groundwater is extracted from a combination of 12 shallow and deep wells. Heavy metals and sulfate have to be removed from the extracted water before it can be discharged into a river. Several water treatment methods have been studied and pilot tested at the site. The preferred and selected process is based on the activity of sulfate reducing bacteria (SRB) and combines sulfate removal and heavy metal removal in one single installation. Anaerobic bacteria reduce sulfate to sulfide resulting in the precipitation of metal sulfides. Excess sulfide Is biologically converted to elemental sulfur. A full scale biological treatment system was started up in May 1992. Design, start-up, commissioning and operational experiences are reported in this paper. Concentrations of metals and sulfate in the SRB water treatment plant effluent are well within the limits set by the Dutch Authorities for discharge to surface water.

Jan 1, 1995

By Richard A. Grieve

A 63.5 metric tons per hour (70 TPH) demonstration coal preparation plant was constructed on the Iowa State University campus, Ames, Iowa, as a part of the Iowa Coal Project funded by the state of Iowa and administered through the Energy and Minerals Resources Re-search Institute. Processing equipment in the plant circuit includes a heavy media separator, concentration tables, separating and dewatering screens, and conveying equipment. Coal samples of size 907 metric tons (1000 tons) with sulfur contents ranging from 2.5 to 8.75% sulfur from seven mines in the state of Iowa have been pro-cessed in the plant. Sulfur reductions have averaged 35%. With ash reduction averaging 45%. Equipment for advanced fine coal beneficiation research is currently being installed in the plant to include a slurry pretreatment circuit, froth flotation, oil agglomeration, pelletization, hydrocyclones, advanced design thickener and disc filtration.

Jan 1, 1978

By Susan Rafalko, Mike Walker, John Sankey, Sherif Aziz, Alex Potter-Weight, Mary Nodine, Frederic Masse

"After several successful projects on the Garden State Parkway and New Jersey Turnpike for support of single-stage MSE (Mechanically Stabilized Earth) walls using rigid inclusions (Controlled Modulus Columns) as an alternate to two-stage MSE walls and surcharge, the Bass River Bridge Widening project presented additional challenges in terms of soil conditions and height of embankment that created opportunities for the design-build ground improvement contractor and its MSE wall-designing partner to enhance their design and construction methods. The specialist contractor decided, in association with the wall system supplier, to perform an independent large scale instrumented test area on the project to demonstrate the ability of the design techniques to model the behavior of the system, as well as the capacity of the rigid inclusions to provide the necessary bearing capacity and settlement control to allow the construction of the highway without any consolidation period. This paper presents a detailed description of the design of the ground improvement system and MSE wall system, as well as the results and conclusions of the monitoring data gathered on the large scale test program. The combination of rigid inclusion ground improvement technologies, such as the CMC system, together with an MSE wall system allows for the rapid and economical construction of high embankment without waiting for a surcharge and consolidation period or the necessity to use a two-stage wall system. In-depth understanding of the design techniques and advantages of this combination will be provided and should be beneficial for any geotechnical engineer or owner looking for innovative solutions to save both time and cost on their projects.1. IntroductionAs development continues on sites with poor ground conditions throughout the world, conventional MSE walls remain a flexible design solution; however, construction of MSE walls in combination with ground improvement is becoming more frequent where extreme differential and/or total settlement prevail due to soft ground conditions. Various techniques have been used in the past in such conditions (e.g. conventional surcharge, staged construction, or two-stage MSE walls), even though these design solutions have typically involved longer waiting times for settlement to occur. As a result, conventional MSE wall design has been combined with a variety of ground improvement techniques consisting of rigid inclusions for an economical and efficient solution with the potential to accelerate construction and limit long term settlement. For the particular subject of this paper, the specialist contractor (Menard) proposed to use CMCs (Controlled Modulus Columns) to support the highest part of the MSE wall. CMCs are grouted displacement rigid inclusions installed in a grid-like pattern using a displacement auger. Before the CMCs are installed, a working platform may first need to be placed to allow equipment to move around the site depending on the ground conditions. Following the CMC ground improvement, an LTP (Load Transfer Platform) is installed prior to the construction of the MSE wall."

Jan 1, 2015

By Bogdan Petkovic, Boban Todorovic

In the early 90's a completely unknown problem was encountered at the converter Department: it was a chronic shortage of the cold copper charge needed for the second operating period. A high temperature operating regime was caused which further provoked a chain of consequences such as a drastic drop of the number of operations in campaigns. The consumption of repair bricks reached the quantity of 8.3955 kg / tonne of anode Cu. In 1994, we won the process of cold material smelting during the "copper" blowing [2]. The number of operations per campaign reached 180-200 again. Also in 1994 we won the process of smelting cold materials to obtain "tin" blowing with the purpose of completing their processing cycle [2]. During the period 1994 – 2007 a total of 107,845 tonnes of cold material were remelted to make copper and 56,794 tonnes were re-smelted to obtain "tin". Upon synthesizing these two processes, a completely new model was achieved in 2005, by Bogdan Petkovic, which entirely utilized all available energy of the Peirce-Smith (PS) converters of the Bor Copper Smelter and now represents the basis of the time cycle. The cold material now enters the converter plant, copper recovery is increased and the method itself is environmentally friendly. 167

Jan 1, 2009

By T. H. North, A. G. Glover, R. J. Pick

"Girth welding operations represent the rate-limiting step in pipeline construction. A joint industry-university program was set up to establish the field welding characteristics of large-diameter, high-strength line pipe.Theoretical work carried out at the University of Waterloo showed that pipe wall thickness and joint misalignment prior to welding has a marked influence on the lifting stresses acting on the root pass of girth welds. Pipe diameter and pipe ovality had negligible effects. Super-position of lifting and residual stress (caused by the fusion welding operation) highlighted regions of the weld bead most susceptible to hydrogen-induced cracking.The field welding characteristics of 1219-mm-diameter, 13.72-mm-wt Grade 483 line pipe were evaluated using a specially designed test rig. The principal test variables were lift height, delay time after root pass deposition, preheat temperature, pipe composition and joint misalignment prior to welding. For any given life, preheat and joint misalignment prior to welding had the most significant effect on cracking tendency.The output of this program has industrial significance and illustrates the beneficial features of university-industry collaboration.IntroductionField welding operations comprise the rate-limiting step during pipeline construction. Crack-free girth welds must be made in a wide range of weather conditions and consequently the field weldability of line pipe compositions directly affects pipeline integrity and construction economics.Pipe-laying practice comprises root bead deposition followed by a skidding operation involving lifting (or lowering) the pipe length onto skid s so that the next pipe length can be aligned prior to welding. Consider pipeline construction using 24.4-m lengths of 1219-mm-diameter , 13.72-mm-wt Grade 483 pipe weighing approximately 10,000 kg. Skidding involves loading a 3-mm-thick root bead by moving the free end of the pipe through vertical distances of up to 700 mm . The likelihood of cracking in these circumstances depends on the inherent crack susceptibility of the pipe composition employed, on the hydrogen content of the deposited weld metal and on how well the joint handles the external stressing caused byskidding."

Jan 1, 1981

By Ronnie X. Gu, Xing Zheng, Gem-Yeu Ma

Due to implementation of the rotator construction method from which a smooth shaft was anticipated, a full-scale pile load test (Osterberg Method) was performed at Pier 14 Pile 9 of the main span of the New Benicia-Martinez Bridge to confirm the design parameters of the rock sockets. Two levels of load cells were fabricated in the reinforced cage of the rock socket. Each level consisted of three 670-mm Osterberg load cells with a total testing capacity of more than 50 MN in both directions. In an attempt to separate side friction and end beari ng, a 75 mm thick compressible Styrofoam material was placed at the bottom of the cage. The pile load test was carried out in four stages. The multi-level multi stage pile load test data was interpreted for casing friction, side friction for two rock strata, end bearing, and residual side shear values under repeated loading in opposite directions. The side friction from the casing in soils at Stage 2 is approximately 9 MN. The end bearing at the tip of the rock socket at Stage 3 was calculated to be approximately 17 MN at a displacement of about 75 mm. The residual side shear resistance for the 10 m 50% RQD rock strata was calculated to be 9 MN or approximately 50% of initial values, after being pushed 0.3 mm upward in Stage 1, 71 mm downward in Stage 2, then 55.5 mm upward again in Stage 3, and finally 105.3 mm downward in Stage 4. The test results surprising ly indicate that the side shear resistances from both low RQD intensely weathered rock and higher RQD slightly weathered competent rock are about the same at approximately 19 MN. This pile load test provides very critical information for confirming deep shaft design and analyses.

Jan 1, 2005

By M R. Hettigner, J Nawrocki, C E. Johnson, P G. Cahill

This study evaluates the effects of both short inter-hole and intra-hole delay times on rock fragmentation and throw. Full-scale test blasts were analyzed at a granite quarry in Talbotton, GA. This analysis provides a representative understanding of timing effects on fragmentation in the field, different from previous lab scale studies that negate the effect of geology. Inter-hole delay times between 0 ms and 25 ms were tested on a series of 4 bench blasts and subsequently examined using photographic fragmentation analysis methods.

Jan 1, 2017

By Sam H. Patterson

Fuller's earth and bentonite are two clay commodities that are interrelated either by mineral composition or use. Because of this interrelation and the sale of both for many different uses, some ambiguity in their classification has resulted. The term "fuller's earth" has no compositional or mineralogical meaning, and it is used more or less as a catchall for any clay or earthy material suitable for certain uses. Most, but not all, of these uses require absorbent properties. Bentonite by geologic definition must have formed from volcanic ash or tuff or the glassy material in volcanic rock; most bentonites consist chiefly of montmorillonite but other clay minerals may be present. In industrial usage the term "bentonite" is applied to any clay consisting chiefly of montmorillonite, irrespective of origin. Georgia and Florida have historically been the leading States in the production of fuller's earth; bentonite has been produced in Alabama on a small scale. The first major use of fuller's earth was in refining of oils. Other materials have replaced fuller's earth for this purpose to a major extent, but many new uses for fuller's earth have been found, and production has increased in recent years. The new uses include absorbent products, insecticide and pesticide carriers, drilling mud, and many others. The bentonite now produced in Alabama is of the "southern," "low selling," or "calcium" type and is used mainly as foundry-sand bond. Most of the fuller's earth mined now is in the Hawthorn Formation of Miocene age; a lesser amount is produced from the Twiggs Clay Member and other beds in the Barnwell Formation of Eocene age. Inactive pits from which fuller's-earth was produced from other formations occur at several localities. The bentonite now mined in Alabama is in beds of Cretaceous age; several years ago bentonite was produced from Eocene beds in this State.

Jan 1, 1972

By T. Nyakudarika

The Unki Platinum Mines concentrator, employing an MF2 circuit configuration which includes fully-autogenous primary milling of run-of-mine (ROM) ore, was commissioned in November 2010. The project was Anglo American Platinum?s first PGM concentrator in Zimbabwe and would form a significant contribution to the group?s platinum production. The project financials demonstrated that the project was operating-cost sensitive. After reviewing the metallurgical testwork, mineralogical examinations, and the history of similar operations, it became apparent that the Unki ore characteristics rendered it amenable to autogenous milling. The primary ball mill, structurally designed for 30 per cent steel load, could be operated at the required initial phase throughput with fully-autogenous primary milling, realizing savings in both power requirements and grinding media consumption. The original mill sizing had been done with fully-autogenous milling in mind, but allowing for flexibility and mitigation in case of varied mining fragmentation. Since attaining steady state, target grinds have been achieved. This paper looks at the Unki ore characterization programme, design considerations, and the operational and control philosophy for a successful comminution circuit, and discusses the design to produce a flexible, low opex, mitigated comminution and overall MF2 flowsheet that is easily expanded in line with the potential for optimum exploitation of the orebody.

Jan 1, 2012

By Arash Nikvar‑Hassani, Timothy Batchler, Lianyang Zhang

Recently, a new hybrid geopolymer/biopolymer (GP/BP) cementitious material was developed for improving the performance of pumpable roof supports in underground mines. This study demonstrates the application of the hybrid GP/BP cementitious material and validates its effectiveness in full-scale. In this regard, eight (8) full-size (0.61 m diameter and 1.52 m height) cribs were produced in collaboration with Minova International Ltd and tested at the National Institute for Occupational Safety and Health (NIOSH) Mine Roof Simulator (MRS) Laboratory. These full-size cribs were produced with different material configurations to evaluate the effect of water to solid (W/S) ratio, Portland cement (PC) content, and BP dosage. The results demonstrated and validated the effectiveness of the hybrid GP/BP cementitious material in increasing the peak and residual bearing capacities of pumpable cribs and eliminating the issue of deterioration when exposed to air compared with the conventional Portland cement/fly ash (PC/FA) cementitious material currently used in practice. On average, the peak uniaxial compressive strength (UCS) and the highest residual UCS after peak of the full-size cribs produced from the hybrid GP/BP cementitious material are 1.90 and 1.33 times of those of the PC/FA-based full-size cribs by one company and 2.32 and 1.66 times of those of the PC/FA based full-size cribs by the other company, respectively.

Feb 6, 2024