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By Isabel F. Barton, Matthew J. Gabriel, CARSON ROBERTS, JOHN LYONS-BARAL, LEON DUPLESSIS, Mark D. Barton

Geometallurgical characterization is increasingly used in the mining industry to model ore types, predict process performance and identify potential recovery issues ahead of time. However, most geometallurgical assessments are based on bench- or laboratory-scale analyses of relatively sparse samples, leaving most of the orebody characteristics known only by inference until the rocks are actually mined. In this pilot study, we test drone- and tripod-based hyperspectral imaging for mapping mineralogy across mine highwalls, dumps and leach pads. The results show that hyperspectral imaging can successfully map the types and distribution patterns of key minerals (especially carbonates, sulfates, clays, other phyllosilicates) and other important features (such as lixiviant ponding on leach pads), bringing geometallurgy into the field to provide crucial inputs to process decisions.

By R Forster

Direct ship iron ore (DSO) operations at Extension Hill in Western Australia’s Midwest region have commenced, with fi rst product railed to the port of Geraldton in July 2011. Reserves are 14.8 million tonnes (Mt) of haematite-goethite ore overlying an Archaean BIF-hosted larger magnetite deposit which Mount Gibson Iron Limited (MGI) sold to other parties in 2006.Some unique geological aspects of the deposit shape DSO mining and processing operations. Owner-operator selective mining, blending, crushing and screening on site will produce three million tonnes per year (Mt/a) of Lump and Fines product to be trucked 86 km to Perenjori, railed 232 km to Geraldton, and loaded aboard Panamax-sized ships through the dedicated iron ore shiploader at the Geraldton Port Authority’s Berth 5 facility.The statutory approvals process for this project formally began in 2004, dominating delays in a predevelopment phase which extended over a longer period than the likely life of DSO operations. The lack of transparency, uncertainties and costs inherent in state government processes have influenced decisions made by MGI while assessing other development opportunities in Western Australia. Potential for additional Reserves exists at Extension Hill, however MGI’s ability to extend the mine life will hinge on statutory approval to explore for and evaluate other DSO resources on surrounding granted mining leases.The nature of the resource and use of existing infrastructure for product transport have enabled MGI to keep operating costs and capital intensity of this project relatively low. A tenacious development approach by MGI and robust project economics have fi nally enabled this site to take its place as a revenue earner beside the company’s other DSO operations at Tallering Peak and Koolan Island.

Jul 11, 2011

By J. R. R. Bowling, A. McFadden, M. Francoeur

The abstract discusses the increasing use of extensive duct-fan systems in underground hard-rock mine development. It highlights the challenges of designing these systems, particularly the risk of partial vacuum and the need for careful booster fan positioning. The paper explores factors influencing the design of these systems, including component limitations, operational wear margins, and power constraints. It also defines the concept of partial vacuum and its impact on ventilation ducts. The authors propose an algorithmic approach for specifying the location and blade pitch of in-line booster fans to prevent system failure.

Mar 17, 2022

By D. Eugene Rannels, Sarah E. Dunsmore

"Dunsmore, Sarah E., and D. Eugene Rannels. Extracellular matrix biology in the lung. Am. J. Physiol. 270 (Lung Cell. Mol. Physiol. 14): L3-L27, 1996.-The lung and other organs are comprised of both cellular and extracellular compartments. Interaction of these components modulates physiological function at the organ, cellular, and subcellular levels. Extracellular components in the gas-exchange region of the lung include both noncellular interstitium and basement membranes. Connective tissue elements of the interstitium in part determine ventilatory function by contributions to tissue compliance and to resistance of the diffusion barrier. The basement membrane underlies cells of both the alveolar epithelium and the capillary endothelium; basement membrane components exert biological effects on adjacent cells through receptormediated interactions. This review emphasizes current knowledge concerning the composition and biological activity of extracellular matrix in the alveolar region of the lung. Matrix synthesis and turnover are also considered. Directions for future research are suggested in the context of current knowledge of the lung and other model systems. EXTRACELLULAR MATRIXEXTRACELLULAR MATRIX is a general term that encompasses components of the basement membrane and interstitial connective tissue. The extracellular matrix has many functions. It provides structural support, compartmentalizes tissues by separating epithelium or endothelium from interstitium, and serves as a physical barrier. Both in vivo and in vitro studies show that extracellular matrices also affect cell shape and function. The matrix elicits a variety of cellular responses, including adhesion and spreading, changes in cytoskeletal organization and differentiation, formation of focal contacts and stress fibers, stimulation of proliferation and migration, induction of polarity and gene expression, alterations in metastatic activity, and outgrowth of cell processes (for review see Refs. 387, 462). Cellmatrix interactions play roles in embryonic development and organogenesis (for review see Refs. 1, 91), in wound healing (for review see Refs. 145, 327), iri metastasis (for review see Refs. 430, 431), and in angiogenesis (for review see Refs. 185, 186). The extracellular matrix is the subject of a large volume of literature. In 1994, over 1,000 articles contained extracellular matrix in the title or abstract. After a brief discussion of key aspects of extracellular matrix biology, this review will focus on the extracellular matrix of the lung."

Jan 1, 1998

By R. Hogg, Y. Lee, D. E. Rannels

"Lee, Yu-Chen, Richard Hogg, and D. Eugene Rannels. Extracellular matrix synthesis by coal dust-exposed type II epithelial cells. Am. J. Physiol. 267 (Lung Cell. Mol. Physiol. 11): L365–L374, 1994.—Although integrity of the alveolar basement membrane may influence progression of lung injury induced by inhaled particulates, little is known about direct effects of coal dusts on the alveolar epithelium or its extracellu¬lar matrix (ECM). Effects of dust on synthesis of cell and ECM proteins by type II cells (T2P) was thus investigated. Three coal dusts (anthracite no. 867; bituminous no. 1451 and no. 1361) and mine dust MIT-3, of respirable size, were studied as a function of dose and time over 3 days of primary T2P culture. On day 1, 750 µg/ml of 867 were required to increase relative synthesis of ECM proteins (ECM/cell). MIT-3, 1451, and 1361 were without effect. By day 3, 867 or MIT-3 increased ECM/ cell 60-100% at 300 µg/ml; 1451 produced modest, dose-dependent stimulation, whereas 1361 remained without effect. None of the dusts caused significant cytotoxicity. The results show dose- and time-dependent effects of well-characterized coal and mine dusts to modify partitioning of newly synthesized proteins into the ECM and suggest that coal dust exposure may modulate structure or function of the subepithelial basement membrane.basement membrane; cell culture; inorganic dust; lung injury; extracellular matrix deposition; pulmonary epitheliumCHRONIC EXPOSURE to coal dust may be associated with development of pulmonary fibrosis and consequent loss of normal lung function (see Ref. 26 for review). Al¬though the pathways of inorganic dust-induced lung injury are recognized to involve an inflammatory re¬sponse, the underlying pathogenic mechanisms are not understood in detail. Acute and chronic responses to dust exposure involve a variety of interacting cells of the immune system, including macrophages, T cells, and B cells, along with pulmonary fibroblasts. These responses reflect direct effects of the dust particles, as well as indirect effects mediated by soluble factors, including cytokines and eicosanoids (see Ref. 41 for review).Studies of pulmonary macrophages and fibroblasts following silica exposure suggest that dust-induced damage at the airway surface may involve cellular injury through oxidant-mediated pathways. Coal dusts and related inorganic particulates can activate the alveolar macrophage (42) to produce fibronectin (15) and cytokines, such as interleukin-1 or tumor necrosis factor (4) and/or other soluble products which act locally (29) to cause acute cellular injury and to initiate the progression of fibrotic lung damage (16). Type I epithelial cells are typically more susceptible than type II cells to oxidant injury. Type I cell damage and subsequent death leads to denudation of the subepithelial basement membrane (2, 21) and can be associated with leakage of plasma constituents from the pulmonary vasculature into the alveolar compartment (13)."

Dec 1, 1995

By Jun Zhu, Jilai Xuel, Tao Li

"Coal gangue is industrial waste containing Al2O3 and SiO2 with great recycling and reuse values. This work is aimed at extracting Al2O3 content in the coal gangue by a process of carbonthermal reduction - alkaline leaching. The Al2O3 and SiO2 contents first became a mixture of SiC and Al2O3 in the process of carbonthermal reduction, and then Al2O3 was separated by leaching in NaOH solution, thus producing the sodium aluminate solution for Al(OH)3 precipitation. The products generated at various stages in the process were inspected using XRD and chemical analysis. The effects of parameters such as reduction temperature, carbon ratio, NaOH concentration, leaching time, leaching temperature, stirring speed, etc were investigated in details.IntroductionCoal gangue is an industrial residue resulted from the process of coal mining and washing, accounting for 100 - 150 kg with 1 ton raw coal mined. The existence of coal gangue in large quantities has become a serious problem for environment pollution. On the other hand, the chemical compositions of coal gangue are Si02 and Ah03 primarily. In China, the accumulation storage capacity of Ah03 in coal gangue is not less than 600 million ton at a rough estimate, which should be considered as an abundant second resource [1]. If the alumina can be recycling and reused effectively from coal gangue, it will not only reduce the imperilments caused by coal gangue, but also yield good economic returns.Generally, the processes of extracting Al2O3 from coal gangue can be divided into acid leaching (vitriol or hydrochloric acid) and alkaline leaching (mostly NaOH) [2]. The acid leaching processes have many problems, such as lower leaching ratio, corroding the equipments, recycling the spent acid hardly, etc. The primary matter of alkaline leaching process is silica dissolving with alumina, which brings perplexing desilication process, alumina loss seriously and higher energy consumption."

Jan 1, 2011

By G. Clarkson, M. Hitch, R. Clarkson

"A novel reagent-free method of extracting gold from gravity middling concentrates in the Yukon placer fields is presented in this paper. This method exploits the malleability of gold by submitting concentrates to grinding in a rod mill. Brittle waste minerals are effectively reduced, whereas malleable gold particles are flattened and are then extracted by classification through sieves. Recoveries in the field using a laboratory-sized rod mill regularly exceeded 90%, whereas correlation laboratory tests indicated recovery to be most sensitive to the mill charge size. This method has broad potential, including application to the gravity circuits of large hard-rock processing circuits.RÉSUMÉ Cet article présente une nouvelle méthode sans agents réactifs d’extraction de l’or dans les concentrés gravimétriques mixtes que l’on trouve dans les districts placériens du Yukon. Cette méthode exploite la malléabilité de l’or en broyant des concentrés dans un broyeur à barres. Les déchets miniers cassants sont bien réduits, alors que les particules d’or malléables sont écrasées puis extraites par classification au travers de cribles. Si les récupérations sur le site à l’aide d’un broyeur à barres de laboratoire excèdent 90 %, les essais de concordance en laboratoire indiquent que la récupération est très sensible à la taille de la charge du broyeur. Cette méthode présente un grand potentiel, notamment une application possible aux circuits gravimétriques des grands circuits de traitement des roches dures.INTRODUCTIONExploiting the high density of gold to separate it from waste materials is the oldest known mineral processing technique. This basic technique is still widely used in gravity concentration circuits today; however, gravity processing invariably results in high-value middlings, especially in the Yukon placer gold fields. In addition to having a uniquely high density, gold is also the most malleable metal. This unique malleability can be exploited to extract gold from otherwise inaccessible gravity middlings.The Yukon placer gold industry has been continuously ongoing since the 1860s, and today produces approximately 60,000 oz t (1.87 million grams) of crude gold annually, most of which is from the Klondike region near Dawson City (Van Loon & Bond, 2014). It is important to note that Yukon placer miners do not use any chemical extraction methods; rather, gravity upgrading methods are the sole processing techniques used. Placer deposits are typically coarse, well liberated, and naturally gravity concentrated and recoverable, thus making more expensive chemical extraction unnecessary (Mitchell, Evans, & Styles, 1997). Furthermore, a strict permitting regime, environmental concerns, lack of expertise, and fear of repercussions from regulators prevent miners from attempting more advanced processing methods, such as flotation or cyanidation. Even simple chemical extractions like mercury amalgamation have not been implemented for decades, with one observer noting that, as many as 30 years ago, “the art of mercury for amalgamating appear[ed] to be dying [in the Yukon]” (Osler, 1983)."

Jan 1, 2017

By D. L. Yopps

Platinum-group metal (PGM) flotation .. concentrate from the Stillwater Complex, MT, was subjected to biooxidation using Thiobacillus ferrooxidans in an effort to break down the sulfide minerals and liberate the ? associated PGM's for subsequent chemical leaching. Bacterial treatment oxidized up to 94 pct of the sulfide present, destroyed the PGM-bearing pentlandite [ (Ni,Fe),9Ss) mineralization, and dissolved most of the nickel in the concentrate. Results showed that increased sulfide oxidation during the biological stage led to improved PGH recovery in the subsequent. chemical leaching stage. cyanidation at 80° c proved to be the best chemical leachant tested. It removed 7.6 pct of the palladium, 94 pct of the rhodium, 97 pct of the gold, but only 34 pct of the platinum from the biooxidized concentrate.

Jan 1, 1991

By M. E. Rossi

This paper discusses the use of Conditional Simulation (CS) models to provide mill feed grade profiles for different time periods. The conventional approach of classifying block estimates as ore or waste generally does not adequately represent dilution, lost ore and the anticipated grade control data, including variability of mill feed from the pit and possible stockpiles. The detailed simulation of grade control practices can be done, but at the Pre- or Feasibility stage of the project may be impractical, since drawing dig limits on multiple benches is tedious and time consuming. Using the Feasibility Grade Control (FGC) method as developed by the Centre for Computational Geostatistics (CCG, University of Alberta-Edmonton), the CS models can be processed quickly to establish dilution and lost ore, and predict daily or short-term feed to the mill. The simulated nodes can be aggregated into selective mining units with adequate representation of likely geometries to be recovered from the pit, to mimic anticipated selectivity. An example from a large copper deposit is shown. The study provides an estimated stream of tonnages and grades fed to the plant by mining periods of interest and based on a specific mine design and schedule. The resulting cash flows support the economic and financial analyses of the Feasibility Study; also leads to improving mine schedules; and aids in developing blending schemes if necessary. INTRODUCTION The conventional approach of separating mineralized material into ore or waste categories does not always include a realistic amount of dilution and ore loss. Also, often it does not provide a good estimate of the grade that will be fed to the mill. If the grade control estimates are unbiased, they will over the long run represent the long-term average of grades fed to the mill; but the anticipated variability of mill feed from the pit and stockpile sources may be misrepresented. Some references on traditional grade control implementations can be found in Chunnett (1982); Davis et al. (1989); Srivastava et al. (1992); and Nowak (1992). Alternative methods based on economic variables improved significantly on the purely grade-based control methods, see Douglas et al. (1994). Further developments involved the use of geostatistical conditional simulations (CS) and profit models, which in several cases have been successfully implemented (Aguilar and Rossi, 1996; Rossi, 1997; Deutsch et al., 2000; Norrena and Deutsch, 2002; Neufeld, 2005; Jewbali and Dimitrakopoulos, 2009). But they can be impractical, mostly due to the lack of understanding of the methodology involved; even if semi-automatic dig limit drawing is implemented, there is always a need for is tedious and time consuming checking and corrections, even if using a single profit model derived from the simulated grades.

Jan 1, 2019

By John Gordon

Rare earth elements (REE) required in modern technological products are found in shale rocks above and below coal seams. Often during the process of mining coal, shale rock adjacent to the seam inadvertently is removed then diverted to landfill sites. Ecologically sound and potentially economic methods of extracting the REEs from these landfills are proposed. Methods include utilizing geomemembrane barrier beneath the landfill site, ion exchanging with moderate pH, slightly acidic, sodium chloride solutions. Sodium hydroxide is utilized to precipitate the REE-hydroxides subsequently converted to REE-chlorides with suitable amount of hydrochloric acid. All acid and base streams are co-produced with efficient membrane/electrolysis technology. Concentrated-REE chlorides are transported tocentralized solventextraction facilities for isolation and purification. Solvent extraction processes also employ the methodology of using co-produced acid/base streams. This paper details minimization of environmental impacts and maximizing economics to produce valuable REEs while increasing the economics of coal mining.

Mar 1, 2018

By A. Dadgar

Extraction of gold and silver from two refractory concentrates using cyanide and bromine reagents was reported at the 12th International Precious Metal Conference (1). The objective of this paper is to present the gold extraction, recovery, and economics for two refractory concentrates using cyanide and bromine reagents. Gold extractions for cyanide leaching (24- 48 hours) and bromine leaching (6 hours) were the same and ranged from 94% to 96%. Gold recoveries from bromine pregnant solutions using carbon adsorption, ion exchange, solvent extraction, and zinc and aluminum precipitation methods, were better than 99.9%. A preliminary economic analysis indicates that chemical costs? for cyanidation and bromine process are $9.50 and $10.50, respectively per ton of calcine processed.

Jan 1, 1989

By Charles L. Parsons

Early in 1912, from information received by the Bureau of Mines, it became evident that quantities of valuable radium-bearing ore from Colorado were being exported for manufacture in foreign countries and that at least part of the manufactured product was being returned to this country and sold at a price entirely incommensurate with that received by the miner and the prospector. Consequently, in line with its efforts to increase efficiency in the mining and treatment of mineral resources, the Bureau of Mines undertook an investigation of conditions. Results of this preliminary investigation were published, in the summer of 1913, as Bulletin 70,a which gave an outline of the radium deposits of the West, the conditions of mining, the wastes involved, and the status of the production of radium from its ores. At about this time newspapers and medical journals were publishing statements regarding the value of radium in cancer therapy. These reports, although many of them were exaggerated, brought out clearly the remarkable virtue of the gamma rays for the treatment of cancer and other malignant growths. In view of the fact that the largest known supplies of radium ore in the world are in the States of Colorado and Utah and on the public lands of the United States, it was deemed highly important for the Bureau of Mines to study the production of radium in detail. Such study, it was hoped, would enable the prospector and miner to obtain a fairer price for the ores and would furnish information necessary in case Congress appropriated funds to develop methods for extracting radium from ore on the public lands under Government supervision, to be supplied at cost to the hospitals of the Army, Navy, and Public Health Service.

Jan 1, 1915

By Qiu Dingfan

The Slurry Electrowinning Process (SEP) is a new hydrometallurgical method and clean technology, Sulfide ores can be treated by the SEP without S02 emission and the sulfur from the sulfides can be recovered in element form which is easy to stockpile and can be transported at low cost. In a special slurry electrowinning cell one can achieve at the same time the leaching of elements from the feed and the electrowinning of metals from the electrolyte, Because the anode reactions are utilized for leaching of some elements the consumption of the energy is decreased, SEP also has the advantage of separation some elements, It is especially suitable for treatment of complex concentrates containing Pb, Cu, Au, Ag and S, which could hardly be accepted by any smelter. In this work, the behavior of different metals in this process has been studied and it was found that the separation of metals in some minerals is possible through the SEP, Beijing General Research Institute of Mining and Metallurgy (BGRIMM) has studied the possibility of the SEP to treat bismuth concentrates containing S, Be and F in laboratory and pilot-test scale as well as in commercial plants, The commercial plant was set up in 1997, It has been in operation since that time, According to the results of laboratory experiments and pilot- plant test, a new plant to treat complex gold minerals was set up in 1998 and is in operation in 1999

Jan 1, 2003

By Vinay Kumar

The disposal of large quantities of electronic scraps generated world wide is causing not only environmental problem but also loss of resources. Therefore, R & D efforts have been made to develop a suitable process for extraction and separation of metals viz. copper, zinc, cadmium and nickel expected from the leaching of e-scraps using solvent extraction process. Different process parameters viz. pH, aqueous to organic ratio, kinetics of extraction, extraction isotherm to establish stage requirement for extraction in continuous mode etc have been studied to optimise the condition for the separation of metals. The studies showed the selective extraction of copper after iron precipitation from the sulfuric acid leach solution of e- wastes containing ~1.0 g/L Cu and minor impurities with 2-hydroxy-5- nonylacetophenoneoxime (LIX 84) above pH 2.0 in single stage. A scheme for separation of cadmium, zinc and nickel has been proposed using di(2-ethylhexyl) phosphoric acid (D2EHPA) under controlled pH of the aqueous solution. The order of extraction was found to be Zn> Cd> Ni.

Jan 1, 2009

By Qingguo Xue, Jingsong Wang, Siyang Long, Jun Zhao, Haibin Zuo

In order to effectively use of low rank coal, the thermally dissolve coal (TDC) was extracted from four kinds of low-rank coals by N-2-methyl-2-purrolidinone (NMP) at high temperature and high pressure. The structures of thermally dissolve coal and residues were characterized by element analysis, FT-IR spectra. The effects of temperatures, coal rank, solid-liquid ratio and extraction time on the extraction yields of TDC were studied, respectively. Moreover, the extraction mechanism of TDC at mild conditions is proposed. The results show that the ash contents of TDCs from four raw coals are significantly lower than that of raw coals, and the volatile contents and H/C are significantly improved. For KL coal, with the increase of temperature, the extraction yield of KL-TDC is improved evidently from 33.75% to 56.25% and the ash content is decreased from 0.57% to 0.49% at 350 °C.

Mar 1, 2018

By M. W. Fabjanczyk, E. G. Alexander

INTRODUCTION The purpose of this paper is to summarise development of design processes used in the 1100 oreoody as a result of experience encountered. Design methods have been developed as a result of the history of ground behaviour, free-standing qualities of cemented back fill and mass blasting techniques. This paper contains an historical review of design methods previously described by Matthews ( 1972 ) , Hornsby and Sullivan (1977 and 19781, Kirkby, Blair and Hutton (19781, and Stewart (1980). The reasoning behind design philosphy changes are discussed and placed into context with methods now adopted. The 1100 orebody is Mount Isa's main producer of copper ore (5 million tonnes per year ) . Proven reserves are 120 million tonnes at 3.2% Cu. Location of the 1100 orebody in relation to overall mine geometry was well described by Dayton (1976). Geology The orebody is located in a series of massive brecciated shale lenses, in either a siliceous or dolomitic matrix, surrounded and separated by a uniform shale sequence. The whole formation is truncated at depth by a faulted contact with a greenschist facies metamorphic sequence below (Figure 1 and Figure 2) Mathias and Clark (1976). The breccia is known locally as silica dolomite and contains nearly all the economic mineralisation. Interfingering of shale and breccia often results in irregular boundaries to the silica dolomite and the ore limits. Geometry The geometry of the orebodies is shown by Figures 1, 2 and 3. Figure 3 also shows the location of the copper orebodies in relation to the lead orebodies. Structure Although the orebody is contained within the massive breccia (u.c.s. 150-250 MPa), it is cut by shear zones sub-parallel to the regional bedding (north-south striking, dipping approximately 60o to the west), and diagonally by major transverse faults (Figure A). These major faults have continuity in excess of 300 metres, with varying amounts of displacement up to 200 metres, and are zones of potential movement.

Jan 1, 1981

By Robert S. Gärtner

The selective aluminum extraction by 3 different calixarenes (p-tert-butyl-calix[4]arene-tetra¬2-acetic-acid-ethyl-ester, p-tert-butyl-calix[4]arene-tetra-2-acetic-acid and p-tert-butyl-calix-[4]arene-di-2-acetic-acid-ethyl-ester) from an industrial pickling bath solution was studied. The pickling bath solution contained hydrofluoric and phosphoric acid as its main components. The aluminum removal was not successful and also no significant extraction of trace metals present was observed.

Jan 1, 1999

By J. E. Sepulveda

Tar sand deposits in the. Stare of Utah contain more than 25 billion barrels of in-place bitumen, Although thirty times smaller than the well-known Athabasca tar sands, Utah tar sands do represent a significant domestic energy resource comparable to the national crude oil reserves (31.3 billion barrels), The term "tar sand" refers to a consolidated mixture of bitumen and sand, Based upon a detailed analysis of the physical and chemical properties of both the bitumen and the sand, a hot-water extraction process for Utah tar sands is currently being developed in our laboratories at the University of Utah. This process involves intense agitation of the tar sand in a hot caustic solution and subsequent separation of the bitumen by a modified froth flotation technique., Experimental results indicated that, for a given tar sand sample, percent solids and caustic concentration were the two most important variables controlling the performance of the digestion stage, These variables were identified by means of an experimental, factorial design, in which coefficients of separation greater than 0.90 were realized. Although preliminary in nature, the experimental evidence gathered in this investigation seems to indicate that a hot-water extraction process for Utah tar sands would allow for the efficient utilization of this important energy resource.

Jan 1, 1978

By M. H. Dehghanpoor, M. Zivdar, M. Torabi

"A hydrometallurgical route was developed to extract metals such as gold, silver, copper, and selenium from anode slime from Sarcheshmeh Copper Complex in Iran. For the extraction of copper by leaching, the anode slime was heated and stirred with 4 M sulphuric acid in the presence of oxygen. Optimal conditions for recovery of copper were temperature 80°C, mixing time 5 hours, and oxygen flow rate 2 L/min, resulting in a copper recovery of 94.47%. Silver and selenium were dissolved by leaching anode slime from which the copper had been removed with nitric acid. For gold extraction, anode slime was heated with aqua regia at 90°, and the gold then extracted with 2-ethyl-hexanol at a concentration of 0.5 M and phase ratio of 4. The extract was then stripped with soda solution at pH=10.5 and a phase ratio of 5. Finally, gold was recovered by precipitation with oxalic acid at a ratio of mass to volume 10 g/L. Total gold recovery was 80%. IntroductionDuring the electrorefining of copper, some metals are accumulated in the byproduct anode slime, which is an important source for recycling and recovery of these metals (Petkova, 1994). In this paper, a hydrometallurgical route is described for the recovery of precious metals from copper anode slime of Sarcheshmeh Copper Complex, which is located in southeastern Iran .Copper anode slime is black or gray powder with a particle size less than 200 mesh. Approximately 2 to 20 kg of anode slime is produced per ton of copper cathode. The slime is characterized by higher amount of Ag, Se, Pb, and Cu compared to other metals and a very low Au content (Khaleghi and Ghader, 2013).The copper anode slimes are composed of 11.69% selenium, 3.93% copper, 5.26% silver, 0.13% gold, and 45% barite, plus lead, tellurium, antimony, sulphur, and silica with small amounts of nickel, iron, zinc, and bismuth. Gold is one of the most important noble metals due to its wide applications in industry and economic importance, so recovery of gold from slime is more appealing than that of other metals. According to the World Gold Council (2013), the demand for gold has increased during the last decade. This increase is due not only to the increasing demands of the jewellery market, but also to the increasing demand for gold in industrial as well as medical applications (Ranjbar et al., 2014)."

Jan 1, 2016

By E. A. Brocchi, P. K. Jena

Complete extraction of copper from Salobo chalcopyrite concentrate can be achieved in less than 10 minutes by chlorination of the dry concentrate with Cl2 at 450 degrees C and in 5 minutes by chlorination of an aqueous slurry containing 5 wt% concentrate at 30 degrees C. In general, slurry chlorination appears to be faster than dry chlorination. The kinetics of dry chlorination of copper sulphide are controlled by an adsorption mechanism with an activation energy of 6.1 kcal/mole. The rate is independent of chlorine partial pressure when pCl2 exceeds 0.4 atm. In slurry chlorination the dissolution of copper sulphide follows a topochemical reaction model and the rate of chlorination decreases with increase in pulp density and also temperature. Dissolved chlorine appears to take part in the reaction in atomic or ionic form.

Jan 4, 1992