Search Documents

By James J. Bean

Although determining and controlling specific gravity of operating medium in a heavy-media plant manually presents no problem, there are advantages to automatic recording and control. The two installations discussed employ the usual method of measurement. Pneumatic control with band control and reset features is used to regulate dilution water and hence specific gravity. Difficulties have been mechanical in nature and associated with obtaining a proper I sample and maintaining tight air connections in bubble-tube piping:

Jan 1, 1950

By Karl Gunnar Holter, Frank Clement

"INTRODUCTION Typically waterproofing of conventionally excavated tunnels has been done by installing pre-fabricated sheet membranes between the primary temporary support lining and the secondary permanent inner lining. The membrane acts as a separation or sliding layer between the linings, which is often desirable. The geotextile installed behind the sheet membrane provides the required drainage and protection of the system. The design of the tunnel lining is strongly influenced and limited by the use of waterproofing sheet membranes. Since primary and secondary linings are separated from each other, forming a double-shell lining system. In that case the secondary lining must be designed for all permanent loads, although the sprayed concrete primary lining continues resists ground and water loads for a long time after construction. Significant progress has been made in sprayed concrete technology over the last two decades, with advanced admixtures, as well as the improved application technology using spraying robots. The development of new admixtures like superplasticizers based on poly-carboxylates, alkali free accelerators and silica fume, enables designers to use permanent sprayed concrete linings (SCL) increasingly for long-term service life. When designed and applied correctly, sprayed concrete can be considered as permanent. The use of spray applied membranes has seen increased use over the last decade in some countries, and demonstrated functionality and cost-effectiveness in several situations. This paper describes the use of the sprayed waterproofing membrane MasterSeal 345, an EVA polymer based product, and the practical experiences from several projects. SPRAY APPLIED WATERPROOFING MEMBRANES The sprayed waterproofing membrane is polymer based and has been especially developed for underground structures. The membrane is applied between primary and secondary concrete linings and develops high bond strength on both sides to the concrete (doubled-bonded)."

Jan 1, 2016

By Kent Zehr

Suncor Energy Inc. is an integrated producer and refiner of oil and gas headquartered in Calgary, Alberta. The bulk of revenue comes from the Oil Sands Group (OSG) operating in the McMurray formation of the Athabasca Oil Sands. Located some 25 kilometers north of Fort McMurray, Suncor OSG began life in 1967 as Great Canadian Oil Sands, the first operator to successfully enter commercial production of synthetic crude oils from the area. For most of the last decade, dramatic growth has been the standard mode of operation for Suncor OSG. Production of synthetic crude first reached 100,000 barrels per day in 1997 and less than five years later is averaging in excess of 200,000 barrels per day. Within this dynamic organization, Suncor Extraction is the business unit that processes run-of-mine ore into clean diluted bitumen for Upgrader feedstock. Extraction also delivers and places the barren sand and process affected water into tailings storage in one of several ponds from which water is recycled to support the various processes. For reference purposes, Extraction on a typical day currently receives more than 400,000 metric tons of oilsand ore, which is all processed to water based slurry for separation in one of two extraction plants. Separated tailings are disposed of as a slurry and the cleaned bitumen froth is diluted with naphtha and sent to tankage for storage until required by the Upgrading Unit. As a consequence, on a typical day Suncor Extraction pumps more than 1,000,000 tonnes of aggressive slurry into and out of the two extraction plants.

May 1, 2003

By C. A. D' Odorico

The zinc pressure leaching (ZPL) plant at Teck Cominco's Trail Operations was started up in 1981 and represented the world's first commercialization of the technology. From the outset, the process was designed to operate using iron-rich Sullivan Mine zinc concentrate. When the Sullivan Mine reached the end of its life in 2002, the ZPL plant underwent a significant process change with the treatment of 100% Red Dog zinc concentrate. Through careful improvements to existing plant processes, controlled changes to plant operating parameters and a rapid adjustment to the modified process by operations personnel, the plant has been successfully converted to processing a feed of 100% Red Dog zinc concentrate. This paper discusses the challenges faced during the conversion and describes the modifications to plant operating procedures, as well as changes to plant processes.

Jan 1, 2004

By R. Shiva Kumar, G. E. Sreedhar, Rajan Kumar, K. Suresh, A. K. Aketi Veera, M. Narasimha, P. S. Jodan

"In most of the coal washeries, Dense Medium Cyclone’s (DMC) are deployed to treat coarse coal fraction in the range of 50-0.5 mm. DMC’s are very popular due to its ability of high tonnage, ease of operation and effective separation at high near-gravity material (NGM) in feed coal. The ease or difficulty of washing is merely depending on the NGM fraction present in run of mine coal. However, the quantitative effect of NGM on DMC performance was not explored in the literature. Hence, in this investigation, the influence of NGM on DMC performance is focused. With the help of synthetically prepared coal mixture, the effect of NGM mass fraction on separation efficiency is studied in three different approaches. Firstly, by increasing the NGM coal fraction systematically from low to as high as possible; second by varying the distribution of NGM coal; and third by varying distribution of particles lying just above and below the near-gravity zone. Washability studies are also carried out to establish the theoretical yield for the prepared synthetic mixtures. Pilot-plant experiments are carried out in a 4-inch DMC with 1.4 operating separation density treating coal in the size range of 4 - 0.5 mm. From results, the partition curves are constructed by both density and size wise distributions. It is observed that at higher NGM coal fraction i.e above 60%, the performance of DMC is very poor with significant coal particles misplacement. In second approach with increased distribution at higher density fractions, the separation efficiency reduces. In third series the distribution of fraction in near-gravity zone doesn’t much effect the separation except the shift in separation density. It is observed that smaller size (-0.5 mm) coal particle having high NGM content seems have a profound effect on DMC performance leading to significant fines misplacement to wrong products."

Jan 1, 2018

By Alicia Esther Ares

The family of Zn-Al (ZA), Zn-Ag and Zn-Al-Ag (ZINAG) alloys offers high mechanical properties, ease of finishing, the advantage of low energy and pollution-free melting. Also, present alternatives to the well developed alloy systems, such as brasses, bronzes, cast irons and aluminum alloys. The main objective of this paper is to measure thermal parameters in ZA, Zn-Ag and ZINAG hypoeutectic and hypereutectic alloys directionally solidified which present columnar, equiaxed and columnar to equiaxed transition structures (CET). Also, estimate the mechanical properties, such as microhardness and tensile parameters and correlate these with the thermal (cooling rate) and structural parameters (grain size and dendritic spacing). The different types of structures were analyzed with optical and scanning electron microscopy. The results showed the influence of concentration, microstructural arrangement and thermal conditions during solidification on the mechanical properties. The results of the present investigation are compared with previous experiments.

Jan 1, 2010

By E. Hasanbas

Vibrating screens and crushers are the workhorses of material sizing. Unfortunately their natural frequency is often in the range of typical supporting structures, thereby making installations prone to vibration problems. Much of the available literature regarding the support of vibrating screens is fairly confusing and outdated. This paper presents the results of utilizing accelerometers and finite element software in the analysis and design of supports for vibrating equipment. It contains data from field studies of vibrating screen and crusher installations, design of new and repair of existing supporting structures, and the correlation between field data and finite element time history analyses. Finally, the paper summarizes a method for analyzing and designing structures subjected to vibratory loads and predicting their behavior.

Feb 23, 2014

By Chenyang Zhang, Zhigang Yin, Wei Sun, Jingxiang Zou, Jianyong He, Yuehua Hu, Zhijie Xu

"In this work, a novel compound 4-Amino-5-mercapto-1,2,4-triazole was first synthesized and its selective adsorption mechanism on the surface of chalcopyrite was comprehensively investigated using UV-vis spectra, zeta potential, Fourier Transform Infrared Spectroscopy(FTIR), X-ray Photoelectron Spectrscpy Measurements(XPS), and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) and first principle calculations. The experimental and computational results consistently demonstrated that AMT would chemisorb onto the chalcopyrite surface by the formation of a five-membered chelate ring. The first principle periodic calculations further indicated that AMT would prefer to adsorb onto Cu rather than Fe due to the more negative adsorption energy of AMT on Cu on the chalcopyrite (001) surface, which was further confirmed by the coordination bonding energies of AMT-Cu and AMT-Fe based on the simplified cluster models at a higher accuracy level (UB3LYP/Def2TZVP). The bench scale results indicated that the selective index improved significantly when using AMT as a potential chalcopyrite depressant in Cu-Mo flotation separation.INTRODUCTIONFroth flotation is one of the most important processes to separate valuable minerals from gangue by taking advantage of differences in the physical chemistry of their surface properties(Laitinen et al., 2014), particularly in their surface hydrophobicity. Hydrophobicity differences between valuable and gangue minerals could be regulated by adding different chemical additives (surfactants)(Kor, Korczyk, Addai-Mensah, Krasowska, & Beattie, 2014), such as collector and depressant. It could be conducted economically to selectively separate and enrich the complicated and/or poor ores, by adopting appropriate surfactants. For example, the beneficiation of molybdenite usually relies on a two-stage process to realize flotation separation of molybdenite from other unwanted sulphide ores(Wie & Fuerstenau, 1974). In the first step, a bulk molybdenite concentrate is produced by utilizing kerosene/ diesel oil and pine oil/alcohols as collector and frother, respectively. Second, sodium hydrosulphide, sodium cyanide, ammonium sulphide, or Nokes reagent are adopted as depressants in the separation stage. However, these depressants are usually toxicant and cannot meet the requirements of environmental protection. A large number of efforts have been taken to develop alternative environmentally-friendly depressants (Ansari & Pawlik, 2007; J. H. Chen, Lan, & Liao, 2013; Li et al., 2015; Yin, Sun, Hu, Zhai, & Guan, 2017; Yin, Sun, Hu, Zhang, Guan, Liu, et al., 2017; Yin et al., 2016). Although some novel and environmental-friendly depressants have been reported to achieve good performance in Cu-Mo flotation separation at a laboratory scale, there are still some challenging problems, including toxicity, high price or poor performance in practice, which severely limit their practical applications in Cu-Mo flotation separation on a commercial scale."

Jan 1, 2018

By Godfred Amponsah, Mehrdad Razavi

Slope failures very commonly occur during a long period of heavy rainfall and groundwater rise. The failures pose a substantial risk to people, infrastructure, and equipment downslope. In the recent past, the mining industry has faced an increase in tailings dam failure due to several reasons including pore pressure increases in the dams. Many failures have been observed to occur during times of water level fluctuations but the critical factors that influence the initiation of slope failures still need to be adequately clarified. To investigate these factors, laboratory experiments were conducted on model sandy slopes to determine pore pressure-induced slope failure initiation. This study also presents a method to examine water seepage through soil slopes using an ultraviolet (UV) dye and a UV flashlight. The small-scale model test simulation demonstrated failures induced by either water percolation from the upslope tank at a constant level or by raising the water level at intervals. A bottom chamber fully filled with water to replicate groundwater rise was also simulated. The soil slope was monitored at every stage to study the deformations and behavior until failure occurred. Results gathered from the controlled laboratory conditions were useful for the verification of the numerical modeling method created in the computer program Slide. The analysis showed that slope failure always occurred when the toe was fully saturated. High pore pressures and seepage forces reduce the shear force at the toe to almost zero causing it to slide. A comparison of slope height to water level also indicated an average of 96% water level to cause a failure. At this point, the soil slope is fully saturated and has no matric suction. The findings in this study show that, by monitoring the moisture content of slopes, failures can be predicted.

Feb 1, 2024

By Nikolaos Petropoulos, Changping Yi, Daniel Johansson, Håkan Schunnesson

The effect of jointing on fragmentation by blasting was investigated experimentally and numerically. Firstly the experimental results were presented. Then the numerical modelling based on the experiments was performed. The same conclusions can be obtained based on both experiments and numerical modelling.

Feb 1, 2020

By P. D. Barrette

This paper deals with the flow of granular materials in bins. A hybrid Lagrangian-Eulerian numerical model is introduced. The model is based on Particle-In-Cell (PIC) advection, and continuum equations describing a Mohr-Coulomb criterion. Experiments were conducted to test and verify the performance of the numerical model. Tests were done using three types of particles. Measurements of material properties and flow rates were carried out. Video records were also obtained and used to examine flow patterns. The results indicate that the numerical simulations produce deformation patterns and flow rates which are in good agreement with the experimental observations.

May 1, 2007

By J. R. Kadambi, J. Furlan, Kucukal E.

"Hydrocyclones are used in various industrial applications, including mineral processing and tailings management, to separate or classify solid particles and/or liquid droplets from multiphase feed. The fluid flow in a hydrocyclone (used in mineral processing) was investigated numerically and experimentally using particle-image velocimetry (PIV) and refractive index matching techniques. Two turbulence models were used in the calculations: the k–? model and the Reynolds stress model. Particle image velocimetry measurements were taken at various spatial locations along the cyclone. Computational results were validated globally using pressure and flow-rate readings at the boundaries, and locally by comparing the PIV velocity-vector maps and profiles.RÉSUMÉ On utilise les hydrocyclones dans diverses applications industrielles, dont la minéralurgie et la gestion des résidus, pour séparer les particules solides et/ou les gouttelettes liquides de l’alimentation polyphasée, ou pour les classifier. Une étude numérique et expérimentale sur l’écoulement des fluides dans un hydrocyclone (dont on se sert en minéralurgie) a été menée à l’aide des techniques de vélocimétrie par images de particules (PIV, de l’anglais particle image velocimetry) et d’appariement des indices de réfraction. Deux modèles de turbulence ont été utilisés dans ces calculs, à savoir le modèle de turbulence k–? et le modèle aux tensions de Reynolds (RSM, de l’anglais Reynolds stress model). La valeur de la PIV a été mesurée à diverses positions spatiales le long du cyclone. Les résultats de ces calculs ont été validés globalement à l’aide de relevés des pressions et du coefficient d’écoulement d’une extrémité à l’autre de l’hydrocyclone, et localement à des coordonnées spatiales spécifiques en comparant les cartes et les profils du vecteur vitesse PIV.INTRODUCTIONA hydrocyclone is a piece of equipment used to separate and/or classify solid particles or liquid droplets from liquid solid or liquid-liquid feed. Versatile in application, hydrocyclones have been widely used in industrial applications including the food, oil, power generation, chemical, and mineral processing industries. The first hydrocyclone was introduced in 1891 by Bretney to purify various liquids (Bretney, 1891). Hydrocyclones have a relatively simple design with no moving parts, which leads to an efficient separation process."

Jan 1, 2017

By Chinmay Shingote, Robert Visintainer, Renjie Ke, Jaikrishnan R. Kadambi, John Furlan

Hydrocyclone separators are some of the most widely used instruments in a variety of industrial applications. Their major functions are to sort, classify and separate solid particles and liquid droplets within a multiphase flow system. Research studies employing both experimental and numerical methods recognize that the performance of a cyclone is related to its geometric dimensions as well as the inner flow pattern. Although many successes have been achieved over the past years, the majority of investigations only focused on the simplified design of cyclone geometry and on single-phase flow. Therefore, this study set out to investigate the flow field in a new-design hydrocyclone and used particle image velocimetry (PIV) to explore the complex swirling flow behavior inside the cyclone within an air core. The flow field inside the cyclone was also studied by computational fluid dynamics (CFD) simulation using a commercial CFD package. Different turbulent models were tested in this study with a moderate-size mesh, and the interface of liquid phase and air phase was predicted by the volume of fluid (VOF) model.

By Chinmay Shingote, Robert Visintainer, Renjie Ke, Jaikrishnan R. Kadambi, John Furlan

Hydrocyclone separators are widely used in various industrial applications in the oil and mining industries to sort, classify, and separate solid particles or liquid droplets within liquid suspensions, which are considered to be multiphase systems. Numerous valuable studies have been conducted in recent years to investigate the flow fields inside hydrocyclones. However, much of the information regarding the performance of cyclones in the literature has limitations and much of it cannot be considered as completely applicable to most real-world applications; many of the studies investigated the flow fields within extremely simplified hydraulic designs that are not representative of the complex geometries or large sizes which are typical in industry. Therefore, in this study, the two-phase flow system inside the actual hydraulic geometry of a milling circuit hydrocyclone is explored with the aid of both computational and experimental techniques (particle image velocimetry (PIV)). More specifically, the flow field with an air core has been investigated. In addition, the air-liquid two phases flow in a hydrocyclone might cause some challenges on both the computational and experimental sides. Two turbulence models are utilized in the numerical calculations: the Reynolds stress model and large eddy simulation. The computational studies are mainly focused on the local flow behavior and the prediction of the dimensions and shape of the air core. Different section planes of hydrocyclone are selected as planes of interest and divided into several fields of view (FOV) for PIV measurements. Two-dimensional experimental velocity vector maps are obtained in each of the fields of view. The computational results are validated globally using pressure and flow rate readings at the boundaries and locally by comparison to the PIV velocity vector maps and profiles.

By J. R. Kadambi, C. Shingote, J. Furlan, R. Ke

"Hydrocyclone separators are widely used in various industrial applications in the oil and mining industries to sort, classify and separate solid particles or liquid droplets within liquid suspensions, which are considered to be multi-phase systems. Numerous valuable studies have been conducted in recent years to investigate the flow fields inside hydrocyclones. However, much of the information regarding the performance of cyclones in the literature has limitations, based in some part on the respective current-available theoretical models, and much of it cannot be considered as completely applicable to most real-world applications; many of the studies investigated the flow fields within extremely simplified hydraulic designs that are not representative of the complex geometries or large sizes which are typical in industry. Therefore, in this study, the two phase flow system inside the actual hydraulic geometry of a milling circuit hydrocyclone was explored with the aid of both computational and experimental techniques (Particle Image Velocimetry). In this study, the flow field with an air core has been investigated; in essence, the research was a two-phase problem, which caused some challenges on both the computational and experimental sides. Two turbulence models were used in the numerical calculations: the Reynolds Stress Model and Large Eddy Simulation. The computational studies are mainly focused on the prediction of the dimensions and shape of the air core. Different section planes of the hydrocyclone were selected as planes of interest and then were divided into several fields of view (FOV) for PIV measurements. Two dimensional experimental velocity vector maps were obtained in each of the fields of view. The computational results were validated globally using pressure and flow rate readings at the boundaries and locally by comparison to the PIV velocity vector maps and profiles. Keywords: Computational fluid dynamics (CFD); Hydrocyclone; Particle image velocimetry (PIV); Reynolds Stress Model (RSM); Large Eddy Simulation (LES). INTRODUCTION A hydrocyclone is a device used to separate a solid-liquid, liquid-liquid, solid-gas, or liquid-gas suspensions into at least two separate density or particle size components. Hence, the flow field of the hydrocyclone is generally considered a multi-phases flow system. Application of hydrocyclones have been used in numerous industries including oil, drilling, metal working, and mineral processing since 1891, when E. Bretney obtained the first patent for the predecessor design of all contemporary hydrocyclones. A modern hydrocyclone typically consists a cylindrical section at the top where the liquid is being fed tangentially, and a conical chamber attached to the bottom of the cylindrical section, as shown in Figure 1. The characteristics of the feed stream that is injected into the cylindrical chamber play a significant role in hydrocyclone operation. The inlet is tangential relative to the cylindrical chamber and hence causes a centripetal force in the flow field which is considered as the primary separation mechanism."

Jan 1, 2017

By S. Eck

In previous work the influence of the casting speed on the flow field and the shape of the solidification front in an industrial 0.82 x 0.25 x 0.8 m³ bronze caster had been investigated. Both numerical and experimental model represented 1:1 the real caster geometry. A comparison of the results of both numerical and experimental models for the flow during the casting process showed a good agreement in the qualitative velocity fields (flow direction and vortex formation). This work represents a parameter study of the numerical model with variations of the turbulence conditions at the inlet in order to clarify their influence on the flow field in the caster. In order to find the best boundary condition at the inlet, the numerical calculations for water have been compared with the measured flow fields in the water model. The new boundary conditions were then applied to the numerical model of the bronze casting process.

Jan 1, 2009

By Frank J. Tolonen

BENEFICIATION of iron-bearing formations is one of the major problems of research at the Michigan College of Mining arid Technology. Funds for this purpose hate been supplied by the State of Michigan supplemented by contributions of labor and some supplies from the Federal Government during the depression. The iron-mining companies have cooperated in securing samples and have also furnished much valuable information relative to the various formations.

Jan 1, 1937

By Y. Champoux, N. Atalla, R. Oddo, C. Lesage

"Percussion drills are the source of the most serious noise problems in mining activities, due to their extremely high noise levels(114-122 dB(A)) and widespread use(Bartholomae and Stein, 1988). Percussion drills will continue to be widely used to drill small diameter holes in hard rock because no other method seems to be economically avail-able to replace them (Boillat et al., 1993).Many studies (Danière, 1991; Hawkes etal., 1977a; Jensen and Visnapuu, 1972;Leblond et al., 1976; Milette, 1989) were con-ducted to determine the major noise sources of percussion drills. The exhaust air of pneumatic drills, the hammer, the bit in contact with the rock and the drill rod have been identified as the major noise sources. A muffer can be used to reduce the exhaust noise and the hammer can be enclosed. The bit noise is considered to be of concern only at the beginning of holes. When all the available methods are used to reduce the noise of a percussion drill, the drill rod vibrations become the dominant noise source (Hawkes and Burks, 1979). However, the noise levels generated by this source remain high and future efforts should concentrate on reducing its radiation.Works by Hawkes and Burks (1979) and Hawkes et al. (1977b) for the U.S. Bureau of Mines provide the most complete description on the noise and vibration of percussion drill rods.The longitudinal and bending waves are the two most important types of elastic waves generated in drill rods. Among these, only the longitudinal waves contribute to the drilling rate. The bending waves are caused by non-centralized impacts, drill rod curvature and non-uniform bit/rock interface. Drill rod noise is generated by Poisson’s ratio expansions and contractions of the rod as the longitudinal waves travel up and down it and by transverse rod motions induced by bending waves. The radiation efficiency is much higher for bending waves than for longitudinal waves. Most of the impact energy is transformed into longitudinal waves, as expected for axial impacts. The evaluation of the relative contribution of longitudinal and bending waves to noise generation poses a very difficult problem for experimental, analytical and numerical approaches. It is, however, an important issue because the relative contribution of these two waves will guide future noise reduction efforts. It seems that very little can be done to reduce the noise radiation of the axial waves without affecting the drilling rate. The main difficulty that analytical and numerical approach-es face, in the evaluation of the relative contribution of the two waves, is that there is no adequate theory for predicting the bending vibrations from the factors that cause them. The experimental approach has, thus, been limited to test fixtures that do not adequately represent the boundary conditions, as well as by measurements obtained under real operating conditions from which it is difficult to establish the relative contribution of the two types of waves. For example, Hawkes and Burks (1979) and Hawkes et al. (1977b) used a test fixture with free-free boundary conditions and made no clear link with measurement under real operating conditions. Rather, they have based their discussion on a simple model. Many authors assume that fexural waves are the main noise source on drill rods. However, measurements have been somewhat contradictory and researchers are still unable to state with certainty that this is indeed the case (Lednik et al., 1988)."

Jan 1, 1997

By M. I. Brasileiro

The use of experimental design to the study of mixtures has found a wide range of applications, even in laboratory scale or in industrial development works. The aim of this work was to maximize granite sawing waste content in ceramic tiles using experimental design. Based on the raw materials, specific formulations were developed using the experimental design. The raw materials were mixed and sample bodies were produced using uniaxial pressing. The sample bodies were fired and characterized in terms of water absorption, mechanical strength and X-ray diffraction. Regression models were adjusted relating the water absorption and mechanical strength with the amount of raw materials. The results showed that the methodology of experimental design maximize the content of wastes incorporated in ceramic tiles formulations. Formulations containing up to 40% of waste can be used for the production of ceramic tiles.

Jan 1, 2009

By D. Neuschiltz, M. Witthaut, R. Cremer

"Metastable (Ti,Al)N coatings with fee structure have been shown to exhibit superior performance as compared to TiN under conditions of wear at elevated temperatures due to their better oxidation resistance and hardness. The oxidation resistance of these coatings increases significantly with increasing Al-content. However, the deposition of (Ti,Al)N films with Ti/ Al ratios below about 30/70 leads to a hexagonal structure which is not suitable for tribological coatings. Only little is known about the location of the cubic to hexagonal phase transition and hence about the optimum composition of (Ti,Al)N hard coatings.To determine the position of this transition, Tii-xAlxN films with different Ti/Al ratios were deposited on high speed steel at substrate temperatures between 100 and 700 °C by means of reactive MSIP. The composition of the films was determined by electron probe microanalysis (EPMA) and X-ray photoelectron spectroscopy (XPS), the crystallographic structure by thin film X-ray diffraction (XRD).It could be shown that in case of deposition temperatures of 300-700 °C a two-phase region exists in the metastable TiN-AlN phase diagram, which expands with increasing temperature, wheras at 100 °C substrate temperature no two-phase region was observed. But in opposition to the phase diagram known from literature, which is based on thermodynamic estimations, the detected two-phase region is narrow for typical PVD temperatures, thus allowing the deposition of cubic single-phase Al-rich (Ti,Al)N hardcoatings for tribological applications. Based on these results, a new Ti1-xAlxN film with x = 0.62 has been developed, which showed an increase of oxidation resistance by a factor of 4."

Jan 1, 1998