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By S. Q. Zhu

A newly developed coal flotation collector ZFC and its flotation characteristics for five different coals were introduced in this paper. ZFC is an emulsion composed of 27% diesel oil, 70% water and 3% surfactants. The main surfactant is synthesized with oil which is environmental favorable and reproducible. Compared flotation experiments show that, at the same dosage, ZFC give 2%~5% recovery promotion than typical collector with only a slightly ash content increment, but saving 70% diesel oil. Zeta-potential and Wetting heat measurement indicate that the surfactant helps the interactions between oil and coal particles, the industrial application tests in several coal preparation plants demonstrate that ZFC is suitable both in technical and economical aspects.

Jan 1, 2014

By Richard H. De Voto

The McDonald Gold Project and two satellite gold deposits near Lincoln, Montana, contain at least 9.9 million ounces of gold and 30 million ounces of silver. The McDonald gold deposit alone contains 7.2 million ounces of gold reserves that can be open-pit mined and processed by cyanide heap leaching at a projected cash operating cost of $190 per ounce. The deposit is predominantly oxidized with no chance of acid production, and can be mined, operated, and reclaimed with minimal permanent environmental disturbance other than the creation of an open pit filled with a fresh-water lake which would support trout. The Seven-Up Pete Joint Venture, the owner of the McDonald Gold Project, commenced permitting of an open-pit, heap-leach operation in November 1994. In 1998, Montana citizens passed an anti-cyanide, open-pit mining initiative, 1-137, which banned any new open-pit gold mine which uses cyanide processing, The Venture has conducted extensive studies, including metallurgical testing of the treatability of McDonald ores with alternative lixiviants, and has determined that all other mining and metallurgical treatment systems are vastly uneconomical in the recovery of gold and silver from the McDonald deposit. Therefore, the Venture's proposed open-pit mining and cyanide heap-leach processing is the only technology that can be applied economically to the McDonald deposit. Further, the analyses convincingly demonstrate that the proposed open-pit, cyanide heap leaching technology results in maximum resource conservation of this valuable and unique deposit and poses far less risk to human health and the environment than any of the alternative technologies.

Jan 1, 1998

By Akira Yazawa

In the field of pyrometallurgy, the equilibrium evaluation has recently become easy by use of thermodynamic software, but it is strongly desired to estimate the amounts of non-equilibrium minor components to simulate practical processes. However, simple physico-chemical technique can not be applied to evaluate practical non-equilibrium components for many reasons. As an engineering solution for postulated equilibrium system, the activity coefficient is modified and introduced as the simulation parameter referred to as the "adjustment coefficient." This modified thermodynamic calculations were adopted to various sulfide roasting processes where many solid phases are participating and the system is not necessarily in equilibrium. Successful simulation was realized by assigning suitable adjustment coefficients for minor components which form a pseudo solid solution in the calcine. Some examples from sulfation roasting and dearsenizing roasting were discussed. In the smelting system, the loss of copper in slag is caused by equilibrium and non- equilibrium reasons, that is, chemical dissolution and entrainment of copper in slag. The total copper content of slag was simulated by use of the adjustment coefficient for entrained copper.

Jan 1, 1998

By Todd Schrauf, James Scott, Mark Smith

"Cyanide heap leaching of gold ores in areas with extremely low winter temperatures requires special considerations to prevent freezing of the leach solution. Factors that impact the solution temperature include ore temperature at the time of stacking and during operation, burial of drip irrigation lines, use of geomembrane covers and heating of the leach solution. Thermodynamic modeling was performed to simulate expected ore and solution temperatures under different operating strategies for Kaminak Gold’s Coffee gold project in the Yukon Territory. Mean monthly temperatures at the site ranged from a low of -22.5 °C (-8.5 °F) to a high of 13.6 °C (56.4 °F), while in situ ore temperatures ranged from -0.5° to about -1.5 °C (31 ° to 29 °F). The modeling results were used to optimize the operational parameters and indicated that a combination of drip line burial and heating of the leach solution during the winter months was required to maintain solution temperatures above freezing during the initial years of stacking, although as the size of the heap increased, heating was no longer necessary.Modeling objectivesThe successful operation of a cyanide heap leach under extremely cold winter temperatures requires the implementation of operational strategies to prevent freezing of the leach solution and the ore within the heap. Thermodynamic modeling of the heap provides the means to quantify the effectiveness of these different operational parameters on maintaining the required operating temperatures to avoid freezing within the heap. The operational parameters that were evaluated with the model included:"

Apr 1, 2016

By Ibrahim Alp, Ersin Yazici, Oktay Celep, Haci Deveci

Low extractions (<80%) in cyanide leaching impose the application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting, alkaline leaching) prior to cyanide leaching to achieve acceptable recoveries. The effectiveness of the selected pre-treatment method is linked intimately with inherent mineralogical properties of ore. In this study, a refractory silver ore assaying 145 g/t Ag was subjected to various pretreatment tests in an attempt to eliminate its refractoriness. Direct cyanidation of the ground ore (d80: 65 µm) produced a low silver extraction of only 29.5% over 24 h indicating its high refractoriness. Previous studies have shown that silver occurs mainly as Sb/As containing sulfide minerals such as pyrargyrite (Ag3SbS3), tetrahedrite (Cu12Sb4S13) and proustite (Ag3AsS3), which do not respond well to cyanide leaching. Also, silver-containing minerals are closely associated with and/or encapsulated in other mineral phases that can restrict the contact of cyanide with silver. Therefore, alkaline leaching (using 3 M of Na2S, NaOH or KOH solution) and ultra-fine grinding as pre-treatment methods were tested to improve the extraction of silver. All the alkaline leaching tests were carried out for 3 h at800C. Neither NaOH nor KOH leaching produced the desired effect on the extraction of silver (i.e., ~30%). Even, a sharp decrease in the extraction of silver (i.e., 10%) was observed in Na2S leaching. On the other hand, ultra-fine grinding (UFG) (d80: 3 µm) substantially improved the extraction of silver in cyanide leaching (95% Ag at 24 h after UFG). It can be inferred from these findings that the refractoriness of the ore is essentially physical in character (i.e. the encapsulation of silver presumably in non-sulphide minerals such as barite and quartz).

Jan 1, 2014

By H. W. J. P. Neomagus, J. R. Bunt, D. L. Botha, N. T. Leokaoke

Coal briquetting traditionally makes use of high-dosage, nonpolymeric binders (such as coal tar pitch or molasses) or polyvinyl alcohol (PVA) at low dosages for the binding of fine and ultrafine coal. Due to constraints associated with the manufacturing and cost of PVA-bound briquettes, a novel polyacrylic binder was developed that could possibly be added in low dosages at room temperature. A set of formulations of two polyacrylic components (components A and B) was developed, from which an optimal binder mixture was determined. This formulation comprises 40wt.% component A and 10wt.% component B with a 0.04wt.% cross-linking additive, and the balance water. The uniaxial briquette compressive strength was used to obtain the optimal binder mixture. The binder mixture was added to the coal powder in dosages from 0.1 to 1.2wt.%. Mechanical tests and thermogravimetric analysis in an oxidized environment at a maximum temperature of 930°C were conducted. Binder-bound briquettes were compared to binderless briquettes and PVA-bound briquettes. Briquettes made from the polyacrylic formulation had uniaxial compressive strengths double that of the binderless briquette yield strength, as well as the minimum recommended compressive strength of 0.375 MPa. The organic binders did not affect the combustion of the briquettes, since the results compared well with the binderless briquettes. The polyacrylic formulation is considered to be a possible substitute for PVA in terms of mechanical and thermal properties and raw material cost.

Mar 1, 2021

By G. Akdogan, P. Mutimutema, M. Tadie

The South African gold mining industry has a legacy of abundant tailings dams, which have attracted the attention of investors because of their potential as a cheaper secondary gold resource. In this we investigate study gold recovery from a refractory calcine tailings dam. Bulk mineralogy of the tailings silicates and iron oxides to be the most abundant phases. Scanning Electron Microscopy (SEM) showed gold to exist in submicrometre and micrometre sizes, as free gold, and associated with arsenic, sulphur, and silicates e.g. quartz and talc. Gold recovery by direct cyanidation was low at 17.3%. Mechanical (ultra fine grinding P80 -16μm) and chemical (alkaline, NaOH) pre-treatment and microwave roasting and microwave-assisted cyanide leaching were investigated to increase gold recoveries. Ultrafine grinding was the most effective, producing recoveries of 66.5%. NaOH pre-leaching of ultrafine milled material increased recovery to 71.5%. Alkaline pre-leaching overall increased recoveries for non-pretreated material, making this process the most preferred because it is less costly than ultrafine grinding. Microwave roasting and microwave-assisted leaching did not achieve higher recoveries than alkaline pre-treatment or fine grinding. The investigation highlights and confirms that chemical treatment with NaOH is a powerful tool for gold extraction from refractory tailings.

Oct 1, 2022

By D. E. Roberts

Over 425 million used automotive oil filters are discarded in the United States each year. Estimates prior to this research claim that 10% are recycled with the remainder typically being landfillcd. Surveys conducted with ferrous scrap users and oil filter processors as part of this research reveal that at least 15% are currently being recycled as ferrous scrap. Oil filter scrap is not being used by many operations because of concerns with scrap consistency and quality. These concerns stem from trials conducted in the infancy of the oil filter recycling movement. Consistent scrap quality depends both on the content of the used oil filters and the processing technique used to produce the scrap. Technology has advanced since the first recycling trials were conducted by steelmakers. Several different types of scrap are available, including pucks, bricks, cubes, and shred. This research conducted at the University of Missouri-Rolla investigated the content of used oil filters and compares the recyclability of different oil filter sizes and designs. Filters vary by application and vary between manufacturers for a particular application. An understanding of the scrap itself as well as the concerns and problems of both oil filter recyclers and oil filter processors is necessary to increase the number of used oil filters being recycled.

Jan 1, 1996

By L. Tejeda, J. R. Donald, R. Parra, J. Duran, P. H. Lauzon

"Crucible slag tests were employed to evaluate different refractory brick classes for the Cerro Matoso electric furnace. Comprehensive analysis was conducted to evaluate the crucible erosion and characterize any slag/refractory reaction products.The classes of refractories investigated were:•,tar-impregnated magnesia;•,rebonded fused grain magnesia-chrome;•,direct bonded magnesia-chrome;•,alumina-chrome;•,picrochromite; and•,magnesia-alumina (spinel).It was concluded that tar-impregnated MgO bricks were the most suitable for the slag chemistry and furnace environment according to corrosion and infiltration resistance. A picrochromite (MgCr2O4) brick performed exceptionally well with regards to erosion resistance, however, the slag infiltrated extensively through the brick pores. Alumina-chrome, direct bonded magnesia-chromite, and spinel (magnesia-alumina) bricks were evaluated as not suitable for use in the furnace."

Jan 1, 1999

By W. R. SHAHAN, W. R. Reed, J. P. Rider

Roof bolter operators may be exposed to high respirable dust concentrations on continuous miner sections with blowing face ventilation when bolting is performed downwind of the continuous miner. One solution to reduce the high respirable dust concentrations is to use a canopy air curtain (CAC) to deliver clean air from a filtered blower fan directly to the bolter operators under the canopies. The influence of CAC installation on the airflow and dust dispersion around the location of the roof bolter operator can be evaluated by using computational fluid dynamics (CFD). 

By E. E. Maurer

Kerr-McGee has operated the Ambrosia Lake uranium mill since startup in 1958. Tonnage milled per day has varied from 3500-7000 tons. The mill capacity is currently rated at 7000 tons per day. The process consists of two parallel circuits following crushing and sampling, \\lhich include open circuit rod mill grinding, sulfuric acid leach, cyclone classification, and counter-current washing circuits of sand classifiers and slime thickeners. Pregnant solution is clarified and polished by precoat pressure leaf filters prior to amine solvent extraction. Yellowcake is precipitated from the pregnant strip solution with ammonia, filtered and dried.

Jan 1, 1972

By N. Dhawan

In the last decades, High Pressure Grinding Roll (HPGR) has gained significant importance in hard rock processing due to numerous metallurgical benefits such as energy savings, particle weakening, preferential damage of coarse particles, and preferential comminution-liberation. There are a limited numbers of lab-scale HPGR units throughout the world. The laboratory-scale HPGR machine at the University of Utah is first-ever lab-scale machine designed by late Dr Klaus Schönert, the inventor of HPGR. This HPGR is constructed with two counter-rotating hardened tool steel rolls, each 200 mm in diameter and 100 mm in width. The HPGR unit is equipped with eight sensors and a robust control system, which serves as an ideal system for fundamental studies and lab-scale testing. In HPGR operation, throughput, energy and product size distribution are intricately linked to specific grinding pressure, roll gap and rolls speed. The nip angle existing during the operation determines the volume of feed material above the rolls that is pulled into rolls without slip. In this paper, scale-up factors and some of the existing models have been reviewed. A number of experiments have been carried out with limestone and a slag material. The influence of operating variables and their complex relationship has been studied.

Sep 1, 2012

By Kevin Ashley

Because toxicities may differ for Cr(VI) compounds of varying solubility, some countries and organizations have promulgated different occupational exposure limits (OELs) for soluble and insoluble hexavalent chromium (Cr(VI)) compounds, and analytical methods are needed to determine these species in workplace air samples. To address this need, international standard methods ASTM D6832 and ISO 16740 have been published that describe sequential extraction techniques for soluble and insoluble Cr(VI) in samples collected from occupational settings. However, no published performance data were previously available for these Cr(VI) sequential extraction procedures. In this work, the sequential extraction methods outlined in the relevant international standards were investigated. The procedures tested involved the use of either deionized water or an ammonium sulfate/ ammonium hydroxide buffer solution to target soluble Cr(VI) species. This was followed by extraction in a sodium carbonate/sodium hydroxide buffer solution to dissolve insoluble Cr(VI) compounds. Three-step sequential extraction with (1) water, (2) sulfate buffer and (3) carbonate buffer was also investigated. Sequential extractions were carried out on spiked samples of soluble, sparingly soluble and insoluble Cr(VI) compounds, and analyses were then generally carried out by using the diphenylcarbazide method. Similar experiments were performed on paint pigment samples and on airborne particulate ?lter samples collected from stainless steel welding. Potential interferences from soluble and insoluble Cr(III) compounds, as well as from Fe(II), were investigated. Interferences from Cr(III) species were generally absent, while the presence of Fe(II) resulted in low Cr(VI) recoveries. Two-step sequential extraction of spiked samples with (?rst) either water or sulfate buffer, and then carbonate buffer, yielded quantitative recoveries of soluble Cr(VI) and insoluble Cr(VI), respectively. Three-step sequential extraction gave excessively high recoveries of soluble Cr(VI), low recoveries of sparingly soluble Cr(VI), and quantitative recoveries of insoluble Cr(VI). Experiments on paint pigment samples using two-step extraction with water and carbonate buffer yielded varying percentages of relative fractions of soluble and insoluble Cr(VI). Sequential extractions of stainless steel welding fume air ?lter samples demonstrated the predominance of soluble Cr(VI) compounds in such samples. The performance data obtained in this work support the Cr(VI) sequential extraction procedures described in the international standards.

Jan 1, 2009

By F. Dinter, C. McGregor, Q. G. Reynolds, L. Hockaday

The necessity of reducing greenhouse gas emissions to limit the impact of anthropogenic climate change means that all industrial processes should investigate their options towards decarbonization. Iron, steelmaking, aluminium, and cement production produce the most industrial emissions. Although most research focuses on decarbonizing these industries, minerals processing industries must be decarbonized to achieve net zero emissions goals by 2050. Incorporating renewable energy sources and avoiding the combustion of fossil fuels are two ways to reduce greenhouse gas emissions. This paper reports on the results from a dynamic process model developed to investigate the feasibility of concentrating solar thermal pretreatment of manganese ores to pretreat carbonate-rich manganese ores for increased ferromanganese smelter productivity and reduced greenhouse gas emissions. The results indicate that pretreated ores reduce the energy requirement for smelting significantly for some ores and lowers total carbon dioxide emissions by 13 to 19% compared to the traditional smelting route. A high-level economic evaluation shows that solar thermal treatment is financially viable for low cryptomelane, high braunite ore that is common in the Kalahari Manganese Field.

Dec 11, 2024

By Eleonardo Lucas, Christ Barriga

The use of saline water, a product of the sea water osmosis process, for the processing of the mineral from the Bayovar Mine in Peru, is part of the process of final disposal of the studied tailings. In this sense, this paper presents an experimental program implemented for the correct evaluation of this fine low-density phosphate tailings, the behavior of six solids contents prepared in the laboratory with limits between the range 8.5% to 21% were analyzed. The results achieved, from settling and consolidation tests by hydraulic consolidation test, attested to the effectiveness, in addition to being representative, based on the analyzes and comparisons instituted and the definition of the compressibility and consolidation characteristics of the phosphate tailings of the evaluation.

Sep 30, 2022

By K. Premlall, R. M. Dire, H. Bissett, D. Delport

Tungsten carbide is a fine grey powder. It can be formed into shapes by compacting with the addition of a binder. Spherical particles are generally preferred in additive manufacturing as they pack together more efficiently than non-spherical particles, promoting a uniform powder bed density, better flowability, and elimination of internal cavities and fractures, resulting in a better quality of final product. The particle shape of powders can be transformed into spherical through the process of spheroidization. However, due to its high melting point, tungsten carbide could be difficult to spheroidize. Tungsten carbide was spheroidized using an inductively coupled radio frequency plasma at various plate powers between 9 and 15 kW. The influence of additional H2 in the sheath gas on the chemical composition of the tungsten carbide product was also investigated by means of XRD, which indicated that WC is converted to W2C at higher H2 concentrations. Optical analysis of SEM micrographs indicated that the spheroidization ratio increased with increased plasma energy.

Apr 1, 2021

By L. J. Su, J. Y. Zhang, P. W. Gu, J. F. Xu

Surface tension of mold flux is a key factor affecting optimum casting conditions. A thermodynamic model was developed to determine the surface tension of mold flux containing fluoride based on the ion and molecule coexistence theory of slag structure and Butler’s equation. The relationship between composition and surface tension was investigated by this model. Results indicated that the calculated values showed good agreement with literature data, and the average error was 8.19%. The surface tension value of the CaO–Al2O3-based mold flux was larger than that of the CaO– SiO2-based mold flux. The surface tension in a multi-component system decreased with increasing contents of SiO2, CaF2, and Na2O, which are considered surface-active components. This trend was more significant in the CaO–Al2O3-based mold flux.

Dec 11, 2024

By J-F. Béland, N. Parson

Aluminum extrusions are widely used for automotive crash management systems due to their superior specific energy absorption capabilities, as compared to steel. The Al-Mg-Si alloy series can be readily extruded into complex multi-hollow profiles, as required in crash systems, and can be used to target a range of desired strength levels. This paper focuses on the development of an axial crush test protocol and evaluation of the crush performance of common 6XXX series alloys for a variety of tempers. The observed crush behaviour is then compared to tensile test results.

Jan 1, 2015

By D van der Spuy, T Kewe, K Keet, N Moffatt, A P. Paine

The Blue Cube Mineral Quantifier Inline (MQi) instrument uses reflective light spectroscopy and advanced chemometrics to measure mineral or elemental grade in a slurry line. The instrument takes scans continuously and sends data to the DCS or PLC control system.Controlling the concentrate grades on a flotation circuit using low-frequency measurements can be difficult or impossible, especially on a circuit that has fast process dynamics. The ability to rapidly measure changes in grade makes it possible to continuously manipulate the flotation circuit operating parameters such as level, airflow and reagent addition set points to optimise plant performance throughout changing conditions.At Barrick’s Porgera mine in Papua New Guinea the flotation circuit feeds sulfide concentrate slurry to a pressure oxidation circuit. In order to maximise gold recovery in the flotation plant and increase performance in the pressure oxidation process, there is a stringent requirement to maintain a stable and optimum sulfur grade. The gold recovery is directly affected by the sulfur grade as most of the gold at Porgera is submicroscopic and associated with the sulfides (disseminated?pyrite).Porgera considered various points in the flotation circuit for installing Blue Cube analysers. This was part of a plant upgrade to improve process control. Due to budget constraints it was decided to initially only install one Blue Cube analyser on the final concentrate stream of the flotation circuit measuring sulfur, sulfides, gold and particle size. The accuracy of the calibration results were very good for all these properties. The sulfur measurement was used in an advanced control system to optimise and stabilise the grade. The paper presents comparisons between mineral grades determined using analytical laboratory analyses and the online Blue Cube data measurements, as well as benefits achieved by measuring grade online. An analysis of the plant data before and after installation of the Blue Cube and the advanced process control upgrade indicate that the flotation recovery increased by 1.98 per cent.CITATION:Kewe, T, Moffatt, N, Strobos, P, van der Spuy, D, Paine, A P and Keet, K, 2014. Evaluation of the Blue Cube MQi slurry analyser for application in an advanced control system for the optimisation of a gold sulfide flotation circuit, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 357–362 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By MOHAMMED AMINE BELMI, ANAS DRIOUCH, ABDELAZIZ LAHMILI, LATIFA OUADIF

The mineral industry uses significant amounts of water in processing. Thus, sustainable practices with the processing of ores are of critical importance. An impact tester was used to measure the adhesion force between particles and a glass disk [1,2]. A removal force was caused by the impact of the disk/particle containing a puck with a stopper. Johnson-Kendall-Roberts (JKR) theory [3] was used to determine the interfacial energy between the particles and the substrate. Capillary condensation of water can occur between the particle and surfaces in humid environments. The adhesion of particles on rough surfaces has been studied previously [4-10]. The research presented herein combines both variables to separate particle types with minimal water usage.