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By Arash Saeidi Rashk Olia, Dunja Perić

The increasing demand for renewable energy has attracted attention to energy geostructures as means of extracting clean geothermal energy from the ground. To further advance the understanding of soilstructure interaction in energy piles analytical solutions considering the self-weight of the pile were derived. These solutions were then incorporated in recently-derived thermomechanical weightless solutions to provide comprehensive analytical solutions for axial displacement, strain and stress in single energy piles. This was accomplished by comparing responses of energy pile under different loading scenarios that reflect presence and absence of the self-weight. Results of mechanics-based analysis revealed that the self-weight of energy piles embedded in stiff soils has no significant contribution to displacement, strain and stress that develop under thermo-mechanical loads. Overall, the significance of the self-weight contribution depends on the magnitude of thermal load as well as the soil-pile interface stiffness. The stiffness of end restraints imposed to the pile head and tip were also found to play an important role in contribution of self-weight in induced thermomechanical stresses in energy piles.

Oct 1, 2022

By P. N. Anyalebechi

The effects of Si (0.19-0.52 wI. %), Fe (0.20 wI. %-0.44 wI. %), and Cr (0-0.10 wI.%) on the response of ingots of aluminum alloy 3004 solidified at different rates (O.IO°C/s to 30°C/s), to homogenization heat treatment have been investigated. Response to homogenization was determined by quantifying the following microstructural parameters: (i) amount of Mn retained in solid solution; (ii) types, relative amounts, sizes, size distributions, shapes, and chemical compositions of second phases; (iii) extent of the alpha-transformation (i.e., AI6(Fe,Mn) --7 (XAI12( Fe,MnhSi) reaction; (iv) dispersoid formation; and (v) alleviation of dendritic microsegregation. Of the three alloying elements investigated, Si had the greatest effect on the response of aluminum alloy 3004 to heat treatment. Increase in Si content, fineness of cast microstructure, and homogenization temperature facilitated alpha-transformation reaction, dissolution of Mg2Si, loss of Mn supersaturation, and formation of AldFe,Mn)3Si and Mg2Si dispersoids.

Jan 1, 2008

By Shaojun Bai

Siderite ore with high phosphorus content was reduced isothermally at 1,050° C with pulverized coal and different dosages of sodium carbonate. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energydispersive analysis of X-rays (EDAX) were used to characterize the samples. The influence of sodium carbonate on the carbothermic reduction process was investigated. Sodium carbonate and its dosage played a considerable role in the carbothermic reduction. The iron particle size in the reduced ore was below 20 µm, and fayalite was abundant without sodium carbonate additive. With a mass ratio of Na2CO3-to-ore of 5% additive, the iron particle size in the reduced ore was generally above 50 µm, and the diffraction intensity associated with metallic iron in the XRD pattern increased. The effect of sodium carbonate on the phase transformation of fluorapatite during carbothermic reduction was also addressed via thermodynamic calculations and aqueous leaching experiments. The results showed that the fluorapatite was not reduced to P2 at 1,050° C, and a portion of the fluorapatite was converted to soluble phosphate. The reduction of siderite can be catalyzed by adding an appropriate amount of sodium carbonate. This catalytic activity was caused by an increase in the reducing reaction activity of FeO and the acceleration of the carbon gasification reactions. The decrease in phosphorous content in the iron concentrate was attributed to an improvement in the separation of the iron phase from the slag phase when sodium carbonate was added and with the formation of soluble phosphate.

By M Olsson, U Nyberg, K Widenberg, P Svedensten, F Ouchterlony

During 2007 and 2008, the project Optimal Fragmentation in Blasting II was conducted at the Långåsen quarry of NCC Roads AB near Arlanda. The main goals were:an evaluation of the effect of using electronic delay detonators (EDDs) in quarry blastinga validation of the design curve concept introduced at the Vändle quarry.Five production blasts were monitored. After a first trial round, the remaining four rounds each had about 100 Ø89 mm holes in a 14–19 m high bench charged with site mixed emulsions. In rounds 1 and 2, a tighter pattern than normal was used in one half of the rounds, raising the specific charge there from 0.7 to 1.0 kg/m3. Non-electric initiation was used with two holes per 25 ms delay in-row and 67 ms between rows. In rounds 3 and 4, electronic delay detonators were used instead, with 10 and 5 ms in-row delays respectively.The monitoring encompassed drill hole collaring and alignment, in-hole deviations, the rock structure in the bench faces from 3D imaging, first row burdens, etc. Eleven 400 t samples were taken from the muck piles and sorted in the quarry and sieved in the laboratory (lab). The lab data made up a fines tail that was grafted onto the in-pit sorting data to form sieving curves for the test piles. These curves were then compensated for the absence of boulders to construct the sieving curves for the blasted muck pile.These have been used to derive fragmentation model formulas for the non-electric rounds, also called design formulas. They are based on blast geometry, charging data and the properties of the rock mass. The formulas may be used to estimate the effect of changing blasthole pattern, borehole diameter and stemming length for example.The use of EDDs gave several unexpected results. In comparison with non-electric initiated rounds with a somewhat lower specific charge the fragmentation was much coarser; x50 increased from 160 to 200 mm. The effect of raising the specific charge in the non-electric initiated rounds from 0.72 to 0.99 kg/m3 was a much finer fragmentation; x50 decreased from 160 to 120 mm.CITATION:Ouchterlony, F, Nyberg, U, Olsson, M, Widenberg, K and Svedensten, P, 2015. Effects of specific charge and electronic delay detonators on fragmentation in an aggregate quarry – building fragmentation model design curves, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 727–740 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Murat Alkan

In this study, a self-propagating high-temperature synthesis (SHS) and following acid leaching techniques were carried out to produce boron carbide (B4C) powder. First, B2O3 was obtained through calcinations of H3BO3 at 1073 K for 2 hours. Then, the glassy B2O3 obtained was crushed and sieved. In the SHS experiments, different amounts of B2O3, Mg and C black were used. The SHS product was obtained in the form of black, spongy solid. In the leaching step, the SHS product was leached in a HCl solution to eliminate the MgO and Mg3B2O6. The effect of acid concentration on the selective leaching was studied at different concentration range, solid/liquid (S/L) ratio, and temperature. The products obtained were characterized by using X-ray diffraction, chemical analysis and SEM techniques.

Jan 1, 2009

By Arash Saeidi-Rashk-Olia, Dunja Peric

Energy piles are gaining increased popularity due to a growing demand for clean energy. To further advance the understanding of soil-structure interaction in energy piles, recently-derived analytical solutions have been implemented to investigate the impact of stratigraphy on the soil-structure interaction. This was accomplished by comparing the measured and predicted head displacements, axial strains and stresses in an energy pile embedded in the actual homogeneous and layered soil profiles, as well as into synthetic homogeneous soil profiles. The analytical solutions for homogeneous soil profile captured the smooth experimentally observed response versus depth very well. In the case of a layered soil profile, the corresponding analytical model was capable of capturing nuances in trends of axial stress and strain versus depth at the interface of different layers. The analytical predictions for the layered profile appear to be slightly less accurate than for the homogenous profile. The experimental data obtained from the layered profile appear to be a bit more scattered than those from the homogeneous profile. In the former case, the interplay of the individual soil layers with the pile occurs while maintaining the continuity of the pile stress and displacement at the interface of different layers. The response throughout each layer of the layered profile is quantitatively different than the corresponding homogeneous response. Nevertheless, qualitatively the response throughout each layer of the layered profile is similar to the response of the pile embedded in the corresponding homogeneous layer.

Sep 8, 2021

By Ozdemir. O.

Magnesium additions to aluminum enhance strength and hardness, lowering density, and improving corrosion resistance. However, during melting and casting processes, significant amounts of magnesium are lost due to selective oxidation. Preventing these losses would reduce the production cost and improve the quality of the final product. The effects of strontium addition on the oxidation behaviour of aluminum-0.5% and 1% magnesium alloys were investigated by monitoring sample weight gains with time with a thermogravimetric balance at 750°C. Sample cross sections have been examined using Field Emission Gun Scanning Electron Microscope.

Jan 1, 2004

By Diane F. Baker, Cathy Aimone-Martin

A series of small-scale explosive experiments were conducted in a perlite mine near Socorro, New Mexico. These experiments were a joint effort between Los Alamos National Laboratory, New Mexico Institute Of Mining and Technology, Southern Methodist University, and Defense Nuclear Agency. The purpose of these tests was to measure the changes in the shock wave and seismic coupling as a function of depth of burial and structural setting. The size of the explosive charges ranged from 1 to 68 kg. Over 1150 measurements of velocity and acceleration were made on thirteen experiments using three component sensors. The sensors were placed to maximize the azimuthal coverage as well as to provide data at a variety of ranges from ~1 to 130 m A few far field measurements were made at ranges of ~2Êkm. While the bulk of the measurements were made on the surface, high g accelerometers were placed in one instrumentation borehole to provide some free-field measurements. Preliminary results indicate that significant differences in the amplitudes of signals can occur when the location of the explosive charges are changed by only meters. Part of the observed difference is attributed to variations in the rock immediately adjacent to the charge affecting the shock coupling; and part to the effects of the site characteristics.

Jan 1, 1994

This paper describes basic parameters, such as surface forces and film elasticity, affecting the stability of foams (two-phase froths). We used the thin film pressure balance (TFPB) technique to measure the surface forces in foam films stabilized with various frothers such as pentanol, octanol, methyl isobutyl carbinol (MIBC), and polypropylene glycol (PPG). The results were compared with the foam stabilities measured experimentally and the film elasticities calculated using a new model developed by Wang and Yoon (2006). It was found that at low electrolyte (NaCI) concentrations foam stability is controlled by both film elasticity and surface forces (or disjoining pressure), the relative contributions from each changing with frother type and concentration. Further, the kinetics of film thinning was studied at a high electrolyte concentration. The results obtained in the present work showed that the major role of a frother is to decrease the hydrophobic force rather than to increase the film elasticity. This conclusion is drawn from the observation that at the typical frother (MIBC) concentrations employed in flotation, frother additions cause sharp decreases in hydrophobic force while causing relatively little changes in film elasticity.

Jan 1, 2006

By Serhat Özdemir, Derya Öz Aksoy, Pınar Aytar Çelik, Ahmet Çabuk, Sabiha Koca, Hüseyin Koca

In carbonate flotation, oleate has been used for many years as a collector in industrial scale. Compared to sulfide minerals, the flotation of carbonate minerals requires more collector consumption and has lower yield and selectivity. It has been previously shown that surfactin provides higher yields in smaller amounts than oleate in the bioflotation of calcite as one of the carbonate minerals. In this study, the usability of surfactin as a flotation collector for magnesite was investigated. For this purpose, the adsorption of surfactin on the magnesite surface was inspected with analyses such as FTIR, SEM–EDS, contact angle, and zeta potential measurements. In addition, the effect of surfactin on the surface tension of water was also revealed. The same analyses were also performed for oleate as a reference point. All flotation experiments were performed without optimizing with both collectors. FTIR results showed that the surfactin, like oleate, was chemically adsorbed on the magnesite surface. Surface tension analyses showed that the surface tension of water decreased to approximately 32 N m− 1 at 10− 4 M oleate concentration, and this value decreased to below 25 N m− 1 at the same surfactin concentration. According to contact angle measurement results, the contact angle of magnesite was 85° after the surfactin adsorption of 2 × 10− 4 M concentration, while this value remained at 46° for oleate. Finally, according to flotation experiments, high temperatures and high collector dosages are necessary for acceptable flotation recovery with oleate, yet surfactin can produce the desired result at ambient temperatures and lower collector amounts.

Dec 13, 2022

By Sutham Niyomwas

The Fe-TiC composite powder was synthesized in situ by carbothermal reduction of ilmenite. The standard Gibbs energy minimization method was used to calculate the equilibrium composition of the reacting species. The effects of the reaction temperature (1300 °C - 1500°C) and milling time of precursors on the Fe-TiC conversion and powder morphologies were investigated using XRD and SEM method. The synthesized products showed that composite with iron matrix and titanium carbide as a reinforced phase was formed.

Jan 1, 2006

By Lijuan Chen

During the detoxification of chromium-containing slag by Achromobacter sp. CH-1, anionic surfactant Sodium Dodecyl Sulphate(SDS) and its mixed systems with different Tween surfactants(Tween 20, Tween 60 and Tween 80) were used to promote the interaction between the bacteria and the chromiumcontaining slag and the rate of acid-soluble Cr( ? ) leached from the slag. The effects were evaluated by the surface tension, the pH of the leaching solution and the leaching rate of total Cr( ? ) from the slag. The results showed that the surfactants systems improved Cr(VI) leaching and its detoxification of chromium-containing slag. The mixed surfactants of SDS combined with Tween surfactant revealed better effectiveness of detoxification than SDS only. When the mass ratio of SDS to Tween 80 was 1:1, the rate of Cr( ? ) leached from the slag increased by 12%.

Jan 1, 2009

By D. G. Lee

Diesel particulate matter (DPM) often contains small amounts of metal as a minor component but this metal may contribute to adverse health effects. Knowledge of the mechanism for particle formation as well as the size preference of the trace metals is critical to understanding the potential for health concerns. To achieve this, the size and the composition of each particle should be optimally measured at the same time. Single particle mass spectrometer (SPMS) would be the best tool for this objective. In this paper, we therefore will introduce new findings about the mechanism and distribution of the trace metals in DPM, derived from a study where an SPMS was used to analyze freshly emitted DPM. KEY WORDS : Single particle mass spectroscopy, Diesel particulate matter, Characterization, Metal contents

Jan 1, 2006

By H. Yen, D. E. Walsh, H. K. Lin

"Comminution circuits are widely used in nonferrous and precious metals milling. Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) fines, are unavoidably produced and report to undersize products in the classification circuit, i.e., flotation or leach feed, while tramp grinding steel (TGS) reports to classification oversize products and returns to the grinding mill, building up in the circulating load. In laboratory studies, TGS reduced grinding efficiency significantly, the impact being dependent upon the size of the TGS present in the mill. Because iron fines adsorb flotation reagents effectively, iron fines increase reagent consumption and reduce flotation recovery. Iron fines are also capable of reducing gold recovery in cyanidation circuits via a cementation reaction. When using filtered gold solution from the cyanidation circuit of an Alaskan gold mine, the gold concentration in solution was reduced by 0.2 to 2.6% over various reaction periods when iron fines were present in the solution.IntroductionComminution circuits are widely used in copper, lead, zinc, nickel, cobalt, molybdenum and precious metal mills. Flotation and leaching processes are usually preceded by comminution (crushing and grinding) circuits in order to liberate valuable minerals for effective separation, concentration or dissolution by the subsequent flotation or leaching processes.Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) powder, are unavoidably produced and report to undersize products in the classification circuit (flotation or leach feed), while tramp grinding steel (TGS) reports to oversize productions during classification and returns to the grinding mill, building up in the circulating load. Variables affecting the amount of metallic iron powder and TGS produced in a comminution circuit include ore hardness, grinding mill operating conditions, comminution circuit design and the metallurgy of the steel used for manufacturing crusher liners, mill liners and grinding media. As one example, a comminution circuit product of 80% passing 200 mesh at the Pogo Mine, AK is estimated to contain approximately 2 kg/t of metallic iron. A finer grind will generally produce a comminution circuit product with higher metallic iron fines content."

Jan 1, 2015

By Luisa Alfieri, Giorgio Fantauzzi, Sergio Notarianni, Spencer Cavagnet, Alessandro Damiani

"The new tunnels of the Copenhagen ""Cityringen"" will be excavated, at Kongens Nytorv square, crossing over the existing M1 and M2 metro lines. After the crossing, the tunnels will underpass the historical building of the Magasin du Nord and adjacent masonry buildings, with a minimum tunnel cover of about 4.5 m. The tunnels have an internal diameter of 4.9m and are being excavated through earth pressure balanced Tunnel Boring Machines in mixed face.The Magasin du Nord estate is characterized by a very complex structure, with different blocks built in different times. An assessment of the condition of the building and its sensitivity to tunnellinginduced ground movements has been conducted through a fully coupled soil-structure interaction analysis; based on the results of this analysis, mitigation measures have been designed.INTRODUCTIONThe Copenhagen Metro Cityringen is expected to be running in July 2019 and will consist of two single tracks in a twin tunnels, each approximately 16 km in length, for transporting up to 243,000 passengers on an average work day. The Cityringen includes 17 underground stations with island platforms, 4 crossover facilities and 3 construction and ventilation shafts. The tunnels is being excavated using earth pressure balanced Tunnel Boring Machines and have an internal diameter of 4.90 m.The intersection with the existing M1 and M2 metro-line will take place at Kongens Nytorv and at Frederiksberg. According to the design alignment, in Kongens Nytorv the new tunnels will pass over the existing M1 and M2 ones; as a result of this, the tunnels will underpass the historical building of the Magasin du Nord and the adjacent masonry building hosting a Mc Donald’s with a minimum cover of about 4.5m.In the framework of Risk Assessment for sensitive buildings, the effects of tunneling-induced ground movements on the Estates ØS0437 (McDonald’s building), ØS0428 (Magasin du Nord) and ØS0004 (Hviids Vinstue) were evaluated. To achieve this goal a fully coupled soil-structure interaction has been considered and the entire excavation process has been reproduced in a 3D model where the abovementioned buildings have been modeled. In this way, a risk assessment analysis was performed evaluating directly the effects of the excavation in terms of settlements and variations of the internal forces as far as the excavation process proceeds. In figure 1, a picture of the construction of Kongens Nytorv station, with Magasin du Nord and Mc Donald’s building on the background, is presented."

Jan 1, 2016

By J. F. Cuderman

In situ experiments at the Department of Energy's Nevada Test Site (NTS) have extended the technology of propellant-based fracturing to include liquid- filled, uncased boreholes. Previous work had developed the technology for liquid-free, uncased wellbores. Test results show that fracturing behavior is considerably more complex in liquid- filled boreholes than in the liquid-free case. Compared to liquid-free boreholes, liquid-filled boreholes have faster pressure risetimes and lower peak pressures, large hydraulic-type fractures propagating several meters beyond the end of the test zone, numerous oscillations in the pressure history, and variable types of fracturing within a single test region. Multiple fracturing is initiated in the wellbore of a fluid-filled borehole when the proper propellant mixture is used but, unlike fluid-free wellbores where up to eight fractures propagate, only one to three hydraulic- and/or shear-type fractures propagate. Hydrodynamic effects involving liquid compression during borehole pressurization appear to be responsible for the differing phenomena observed in fluid- filled boreholes.

Jan 1, 1986

By M. Tang, X. Tong

"SynopsisSlime coating is one of the most common ways for serpentines to contaminate metallic mineral concentrates during traditional flotation of coarse sulphide particles. This could pose quite a complicated and challenging problem in the case of some types of low-grade and finely disseminated Cu-Ni ores bearing high serpentine contents. This is the case for the copper and nickel sulphides from the Yunnan Mine, China. Previous batch flotation tests of this ore resulted in satisfactory recoveries of 86.92% Cu, 54.92% Ni, and 74.73% Pt+Pd, and concentrate grades of 4.02% Cu, 3.24% Ni, and 76.61 g/t Pt+Pd. However, the MgO content in these concentrates was more than 19%. In the current study, microflotation tests and settling rate tests were introduced to investigate the effects of a combination of strong collectors (a 2:1 weight ratio of butyl xanthate and butyl ammonium dithophosphate) on entrainment of serpentines in metallic mineral concentrate, as well as visual observations of the concentrates in suspension using still photography. All test results indicated the presence of serpentines entrapped in the hydrophobic flocs that resulted from these collectors, even with the use of effective gangue depressants. These strong collectors are used to flocculate the ultra-fine sulphides by forming loose and ‘fluffy’ hydrophobic flocs. However, these hydrophobic flocs may also be able to load or entrap some serpentine slimes into the concentrate, and this entrained serpentine could be harder to remove by using depressants or intensified conditioning than serpentine slime coating on the particle surfaces.IntroductionSerpentine minerals, which have the generalized composition (Mg,Fe)3Si2O5(OH)4, can be easy to crush and grind due to their convoluted and bent layered structures. These serpentines can hinder the enrichment of some metallic minerals and dilute their concentrates by entrainment during flotation. The resulting high pulp viscosities, slime coatings, and high content of dissolved ions adversely affect the flotation recoveries of copper and nickel sulphides, and high levels of MgO entrained in the concentrates lead to heavy penalties from smelters. Since the quality of nickel flotation concentrate depends heavily on its MgO content (generally less than 6–7% for No.1 or 2 grade nickel concentrate according to the standard requirement from National Nonferrous Industry), reducing the entrainment of serpentine during flotation is becoming more and more pressing. Previous research has focused on the collectors and depressants that are commonly used in copper-nickel flotation, as well as their interaction mechanisms."

Jan 1, 2015

By M. Normandin

The performance of various polymers and other macromolecules used to flocculate red mud particulate materials in the Bayer process can be evaluated on the basis of their efficiency to achieve adequate settling velocity and turbidity level, The Jar Test is widely used in the mineral industry to determine the efficiency of solid-liquid separation processes, particularly for gravity settler of the Bayer process. However, a high level of variability is found in the data obtained by this methodology, In this study, different parameters of the cylinder test procedure are evaluated to determine their role in the overall variability of the method, As demonstrated by laboratory testing, the overall variability can be considerably reduced by good laboratory practices.

Jan 1, 2005

By Javier Illanes Pizarro, Gustavo Huerta Valer, Jorge Cárdenas Miranda

Bench stability is the basis of sustainability in an open pit mining operation. Taking care of the pit walls while maintaining fragmentation results can prove a challenge. In this study, technical proposals have been developed for extra hard rock mass (UCS>175MPa) with presence of unfavorable structural planes in high copper grade zones. The base case shows low compliance of fragmentation results and a significant loss in berm width, with over size boulders causing low primary crushing rates. Paradigms in current drill and blast design were overcome to improve fragmentation results and achieve objectives.

Feb 6, 2023

By Justin Lukens, Di Stasim Jeffrey, Frank Di Salvo

Columbia University’s Manhattanville Campus expansion includes the construction of two new business school buildings. The new buildings require development of an entire city block bound by 12th Avenue, W 131st Street, W 130th Street and Broadway in Upper Manhattan. A support of excavation (SOE) package was first released, followed by a foundation package. The SOE package consisted of approximately 100 soldier piles and 280 anchors, up to 215’ long, to support a cut anywhere from 30’- 50’ below street level. The foundation package alone included approximately 1600 drilled micropiles. Given the breadth of the work scope, Hayward Baker Inc and Moretrench joint ventured on these two projects to bring sufficient knowledge and work resources to complete the work in an efficient and timely manner. This included working with the Owner/Engineer to propose different means and methods for construction to significantly reduce the schedule while meeting the design intent, such as large diameter (36” diameter) augercast piles in place of conventionally drilled soldier piles and large hollow-bar micropiles (103/51 bars) in lieu of pressure-grouted micropiles. The anchors, ranging from 3 to 22 strands, were used for earth retention through both soldier pile and lagging walls and existing slurry walls. These anchors were complicated based not only on their size and length, but also the need to drill some of them under the historic Studebaker building. The overall magnitude of the project with considerations to resource management and material lead times will be addressed, highlighting critical strengths provided by the Contractor to ensure project success. The scope of work discussed in this paper was executed under two separate competitive bid contracts. The first contract included the support of excavation work and the second contract included the foundation package. The support of excavation comprised of drilled soldier piles (performed by Case Foundation as a subcontractor to the JV), driven soldier piles, driven sheet piles, hollow bar tiebacks, multi-strand tieback anchors and micropile soldier piles. The foundation package consisted of drilled micropiles. Due to the large scope of work and critical schedule requirements of the project, the JV had to think outside the box and present value engineered alternates to expedite installation durations.

Jan 1, 2019