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By Brijes Mishra

This paper presents a correlation of acoustic emission (A.E.) with physical and mechanical properties of different types of rock and coal specimens which were tested under aegis of a consultancy project from a Columbian Mining Company. In this study, three types of rocks which are sandstone (Arneisca), siltstone (Arciolita) and claystone (Limolita) and two different types of coal were tested. The tests were carried out under constant loading rates according to ASTM Standards for determining Young?s Modulus and Poisson?s Ratio. In both cases a MTS electro-hydraulic loading system was used. Mode of failure in each material was characterized by the acoustic emission and the results were substantiated by the deformation characteristics of the materials during failure.

Jan 1, 2006

By D. A. Beattie

Talc is a commonly encountered gangue mineral in metal sulfide flotation. Talc is naturally hydrophobic, resulting in high recoveries if polymeric depressants are not used to specifically reject this MgO containing mineral. We have studied the adsorption of a selection of polymers onto talc using a variety of techniques. Adsorption isotherms have been determined using ex situ depletion techniques and in situ ATR-FTIR spectroscopy has been used to determine adsorption kinetics. Adsorbed layer thicknesses have been determined for the polymers on cleaved talc surfaces using the AFM. The effect of the adsorbed polymer layer on the properties of the talc surface has been quantified through contact angle measurements and single mineral flotation tests. Distinct correlations are observed between the adsorbed layer properties and the flotation performance of the polymers. These observations are discussed with reference to the bubble-particle attachment process and the molecular structure of the polymers.

Jan 1, 2006

By A. Wahab Khair, W. M. Devilder

"This paper presents an analysis of fragment size distribution and characteristics of fracture surface in coal cutting using a rotary coal cutting simulator. Coal cutting by a drum type continuous miner was simulated in the laboratory. A series of tests along both the face and butt cleat direction of coal under different operating and in-situ conditions were performed. In each experiment the cut surface was photographed microscopically and the coal cuttings were collected and sized. Data were used to show how and to what extent various parameters effect size distribution of the coal cutting and how this correlates with the characteristics of the fracture surface. This study resulted in establishing a number of distinct correlations between the size distribution and fracture surface. These correlations were primarily based on the degree of interaction between adjacent bits and the amount of bit-coal interaction taking place on the cutting path. Some of the major results of this study are as follows:Zones of bit-coal interactions proved vital toward understanding the effect the conical bit has on the fragmentation process. This in turn led to the identification of areas which are responsible for the production of fines and generation of respirable dust.The various parameters employed in the coal cutting experiments which showed a strong effect on the coal fragment size distribution were: bit type, bit spacing, depth of cut, in-situ stresses, and cleat orientation. Bit angle and cutting head velocity exhibited the least effect and no correlation was established.From this study it is obvious that the key to achieving efficient coal fragmentation is to limit the degree of bit-coal interaction that takes place throughout the bit path while causing maximum interaction between adjacent bits. Accomplishing this not only increases the percentage of large fragments produced but limits the amount of secondary crushing that takes place in the bit path thus resulting in decreasing fines and consequently, the amount of respirable dust generated.Over 2,000 continuous mining machines (introduced in the 1950's) equipped with conical bits or point attach bits account for well over half of the United States' production from underground coal mines. Today, competition in the coal industry has increased, due mainly to coal market conditions and legal restrictions, thus placing an emphasis upon increasing production, efficiency and health/safety of the workers. Mine operators are always interested in finding the most efficient performance of continuous mining machinery to produce the largest amount of size of coal at the lowest cost. An increase of fine material sent to the cleaning plant can seriously overload the plant to the extent that plant efficiencies deteriorate significantly (1). Also, the difficulty and expense of cleaning very small particles often cannot be done economically and thus, thousands of tons of coal are sent to the refuse pile because of costly or ineffective cleaning facilities. It has been said, ""the efficient extraction of coal or rock implies breakage into a size range that contains a minimum quantity of very small sizes"" (2). All known fragmentation theories concur that more fragmentation requires more energy (3). So, the importance of reducing fines is already evident from an outlook upon efficiency.Now, let's consider another view point., duet generation."

Jun 1, 1988

By Roy J. Helfinstine

One of the most urgent needs in the field of coal combustion is the ability to predict the performance of a coal from knowledge gained from small-scale tests. Numerous types of analyses and tests are conducted on coal, including the proximate and ultimate analyses, heating value, varieties of sulphur, ash analysis, ash fusion temperatures, free swelling index, petrographic analysis, and Gieseler plasticity. The Illinois Geological Survey has made an intensive study of the value of these tests for judging the performance characteristics of the coal as actually utilized. To date, three reports 1 2 3 have been is- sued, and another is being prepared. The present paper briefly summarizes some of the results found in the studies.

Jan 1, 1949

By B. Yarar

Samples of coal from an adit in the Fording River District of British Columbia showed hydrophilic properties between depths of 0-24.5 meters and was naturally hydrphobic at higher depths. Laboratory experiments indicated that weathered samples (i.e., those mined at 0-24.5m) could be upgraded by froth flotation at pH<2 following slimes removal. The i.e.p. of samples varied regularly between pH=1.6-4.1, the weathered fractions being at the lower end of the pH scale. These values followed a pattern comparable with the flotation behavior of samples. A patchwise structure for coal surfaces determining the resultant disjoining pressure, which in turn determines flotation-non flotation relationships is postulated.

Jan 1, 1982

By Robson Aguiar de Macedo

O estudo de ligas livres de Pb envolvendo o emprego de junções metálicas sob altas temperaturas tem recebido atenção especial, sendo desenvolvidas novas ligas com qualidade e desempenho adequados. Ligas Bi-Ag consistem em alternativas promissoras para a substituição das ligas de solda contendo Pb para tais aplicações, por isso devem ser melhor caracterizadas sob o aspecto de estruturas brutas de fusão. Assim, o presente trabalho objetiva investigar a liga hipoeutética Bi-1,5%Ag (%em peso) solidificada unidirecionalmente sob regime transitório de fluxo de calor. Será analisada a influência dos parâmetros térmicos de solidificação como velocidade de solidificação (VL), taxa de resfriamento (?) gradiente de temperatura (G) na microestrutura e na evolução de dureza da liga citada. Para determinação do perfil de dureza, foram realizados ensaios de dureza Vickers. Para obtenção e caracterização das microestruturas presentes no fundido Bi-1,5%Ag, fez-se o uso da microscopia ótica e da fluorescência de raios-x. Uma estrutura de dendritas facetadas de Bi circundadas pelo eutético Bi-Ag prevaleceu ao longo do lingote Bi-1,5%Ag. Verificou-se um aumento gradativo dos espaçamentos dendríticos primário (?1) e secundário (?2) à medida que a distância da base refrigerada foi aumentada. Em geral, os valores de dureza diminuíram para maiores valores de ?1 e ?2.

Aug 7, 2018

By N. O. Taylor

THE failure, by swelling, of several cast aluminum-zinc, spiral, pump rods, used to circulate water in a constant-temperature bath, brought up the question as to whether the presence of tin in varying quantities would have any appreciable influence in controlling this action. Previous workers had found the same difficulty with aluminum-zinc alloys, due to their swelling in water or solutions of electrolyte^.^ It was known that pure aluminum was practically insoluble in concentrated sulfuric and nitric acids, presumably due to the formation of an oxidized film on the surface. Concentrated sulfuric acid had little or no effect on pure zinc and tin and concentrated hydrochloric acid would attack all three metals. These facts aroused curiosity as to the probable reaction of the ternary alloys of these metals, and tests were made to determine their resistivity to the action of common laboratory reagents. Samples, covering the entire range of the ternary series of aluminum, zinc and tin alloys, were made up from good grades of the commercial metals.2 The materials were melted, at as low temperatures as possible, in graphite crucibles in a gas-fired crucible furnace. Graphite crucibles were used in preference to clay, to prevent the absorption of silicon by the aluminum, as found by previous workers. The melted materials were stirred thoroughly with pine sticks in order to ensure complete mixing and the greatest possible freedom from oxidation, and were cast in sectional, iron molds giving bars % in. in diameter and 5 in. long.

Jan 1, 1927

By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017

By K. S. Raja, B. Pesic, S. Kshetri

"We investigated the electrochemical corrosion behavior of commercial permanent magnetic material (NdFeB alloy) in 0.1 M NaH2PO4 solution (pH:4.75) containing 0 – 1000 ppm of chloride at room temperature (298 K). The material was evaluated in magnetized and demagnetized condition with different surface preparations such as: Ni-Cu-Ni coated, uncoated (bare), and anodized (in fluoride containing ethylene glycol at 60 V for 15 minutes to form a thick nanoporous oxide surface). The nickel coated magnetic sample showed reasonable pitting corrosion resistance up to 100 ppm chloride addition. The uncoated samples showed passivity in chloride free phosphate solution. Chloride additions caused pitting and the pitting protection potential was equal to the corrosion potential with 100 ppm chloride addition. Demagnetization did not alter the electrochemical polarization. However, the passive film formed on the magnetic sample showed higher charge carrier density than the film formed on the demagnetized sample. INTRODUCTIONSintered NdFeB permanent magnets exhibit excellent magnetic properties such as large energy product [(BH)max > 450 kJ/m3], high saturation magnetization (1.6 Tesla), and high coercivity (1.2 – 2.08 x 106 A/m) (Sugimoto, 2011). However, the NdFeB magnets are prone to corrosion attack because of the presence of Nd-rich intermetallic phases, such as Nd4Fe (Jurczyk & Jakubowicz, 2000). Nd-rich and B-rich intermetallic phases are distributed in a matrix of Nd2Fe14B tetragonal ferromagnetic compound in a permanent magnet. Generally, several types of Nd-rich phases are present in the magnet with Fe:Nd ratios ranging from 1:1.2 to 1:7. The volume fractions of Nd-rich and B-rich (Nd1+xFe4B4 type) phases are about 10% and 7% respectively (Li, Ma, Li, & Wang, 2011) . Among these intermetallic phases, Nd-rich phase has the most active electrochemical potential. Therefore, dissolution of this phase occurs in preference to other phases by galvanic corrosion when exposed to moisture. Since Nd-rich phases are present at the grain boundaries of the Nd2Fe14B matrix, corrosion leads to disintegration of the magnet."

Jan 1, 2012

By M A. Rhamdhani, R Z. Mukhlis

Removing the ledge formation in the Hall-Heroult cell during the electrolysis process may significantly reduce the energy requirement of the aluminium production process. In the absence of the ledge, however, the sidewall-material types become heavily restricted since the cryolite is very corrosive at the electrolysis temperatures. This paper study the corrosion behaviour of sintered nickel ferrite, nickel aluminate, and magnesium aluminate refractories (as possible candidates for sidewall material) in molten aluminium and cryolite melts with various alumina content at 980°C. Immersion tests of refractories with various porosity were conducted to assess the suitability of the refractories in the corrosive environment of the electrolysis cells. Microstructural change of the refractory after immersion were analysed using secondary scanning electron microscopy (SEM). Sampling of the melts were taken at 0, 10 min, 30 min, and each hour up to 6 hrs, and subsequently analysed by Inductively Coupled Plasma (ICP) spectroscopy. Based on the projected concentration of the refractories constituents in the melts, it was predicted that the corrosion rate of NiFe2O4, NiAl2O4 and MgAl2O4 in cryolite with 11 wt per cent Al2O3 were 461 × 103, 1.03 × 103, and 798 × 103 cm/a, respectively. Much lower corrosion rate of 2.3 cm/a for NiFe2O4, 2.6 cm/a for NiAl2O4 and 0.3 cm/a for MgAl2O4 were predicted if the refractories in contact with aluminium melts. Erosion played an important role in the corrosion as the concentration of the refractory constituents in the melts were beyond its solubility limit. It is therefore crucial to increase the densities of the refractory and improve its wetting characteristics.

Aug 21, 2024

By L. A. Cornish, J. W. van der Merwe

"The hydrofluoric acid (HF) industry in South Africa uses normalized mild steel (SA 516 Gr 70) for the storage and distribution of its technical-grade product (70% HF). The technical-grade acid is split from the anhydrous hydrogen fluoride (AHF) product during distillation just after HF is produced, in a stainless-steel-lined kiln, from the reaction of calcium fluoride (CaF2) with sulphuric acid (H2SO4). Uniform corrosion of the storage tanks is mitigated during commissioning by contacting the steel with 70% HF. A corrosive reaction takes place (2H+ + 2F- + Fe - H2 + FeF2) to form scale inside the tank which diminishes the attack of the steel by fresh HF, thus prolonging the service life expectancy of the vessels. This iron fluoride scale in the vessel grows continually, resulting in corrosion of the vessels continuing at a predictable rate (approx.0.5 mm/a) since the first commissioning of the tanks at Necsa in 1993. In early 2012, an increase in the average corrosion rate of the tanks to 3 mm/a measured at and below the liquid band in the storage vessels was noted. Three months later the corrosion rate had increased to 30 mm/a, just before the first leak from the tank was detected. The tanks were decommissioned shortly afterwards and an investigation revealed that the rapid corrosion was due to the presence of increased levels (>50 ppm) of nitric acid (HNO3) in the tanks, which attacked the fluoride layer protecting the steel.The oxidation characteristics of high concentrations of HNO3 with low concentrations of HF on stainless steel surface treatment are well documented. The effects of low levels of nitric acid on the corrosion of steels in sulphuric acid are also known, but no suitable published data currently exists on corrosion by high HF concentrations with low HNO3 concentrations. Establishing the rate and mechanism of corrosion by HNO3 (0.1 to 1%) in 70% HF is currently a high priority for the HF industry in South Africa and will become increasingly important in the near future due to depleting fluorite reserves and cheaper, but less efficient, processes producing H2SO4 with higher impurity levels, which were not anticipated in the original plant design. The aim of this study is to simulate the corrosion conditions in the plant on a laboratory scale in order to establish the corrosion characteristics of the steels used in the HF plant, which are increasingly exposed to the HNO3 impurities that tend to concentrate in the final technical-grade HF acid product."

Jan 1, 2016

By P J. Borrington

Offering 1000 hour salt spray protection, the KEYCOAT 1000 coating presents no chipping, cracking or deformation when hammered or flexed through 90 degrees or more. This cost-effective metal protection system features lubrication performance equal to molybdenum disulphide and Poly Tetra Fluoro Ethylene (PTFE) grease providing complete anti-seize protection whilst aiding assembly and disassembly. In addition, the coating is impervious to acids, alkalis, solvents and attack by oils and all fuels. KEYCOAT 1000 has been exhaustively tested in three main industry sectors - automotive, heavy earthinoving vehicles and chemical - where it lias been proven to outperform conventional systems in all respects and as the film formed is less than one thousandth of an inch thick (typically 20 microns), it rarely presents the engineer with any tolerance difficulties. KEYCOAT 1000 is one of a w ide family of products which offer protection and lubrication to a wide industry base, from aerospace to food and with temperatures ranging from minus 190 C to plus 30 C.

Jan 4, 1997

By R. B. McIntosh, S Ramanchuk

A brief description is given of the process used by Sherritt Gordon Mines Limited to recover cobalt metal from nickel-cobalt sulphides. A description of the equipment with the operating conditions is presented with an evaluation of the corrosion test results for various stainless steels and other acid resistant materials for the part of the process involving the sulphuric acid leaching of nickel-cobalt sulphide slurry under air pressure. SINCE 1954 the Sherritt Gordon ammonia leach process has been used at Fort Saskatchewan to recover nickel metal, copper sulphides and cobalt-nickel sulphides from nickel concentrate produced at Lynn Lake, Manitoba. 'To develop a process for recovering cobalt and nickel from the cobalt-nickel sulphides, studies were carried out in the Sherritt Gordon laboratory and pilot plant and, late in 1957, continuous acid leaching of sulphides was started in the refinery. In September 1958 the present equipment

Jan 1, 1961

By Guangshi Li, Xionggang Lu, Xueliang Xie, Xingli Zou, Yuyang Bian, Hongwei Cheng, Kai Zheng, Changyuan Lu

The corrosion resistance and corroded microstructure of MgO-C refractory in molten slag are investigated by immersion test in muffle furnace at 1600 °C . The microstructure and chemical compositions of the specimens after erosion experiment are characterized by scanning electron microscope (SEM) and energy dispersive X-ray (EDX). The results confirm that the oxidation of graphite is the most important degradation mode of MgO-C refractory. The structure of the refractory material is damaged due to the decrease of graphite, as a result, the periclase substrate reacts with the molten slag directly. The corrosion process is controlled by the dissolution of the refractory materials into slag, low melting point oxides are therefore generated which lead to the damage of MgO-C refractory finally.

Jan 1, 2015

By I. Murray, N. Geoffroy

"Buried pipelines, tanks and other similar equipment are almost always present on large scale industrial sites, including in the oil and gas fields. However, as the proverb “out of sight, out of mind” suggests, it is easy to overlook proper maintenance procedures and simply assume that corrosion protection measures in place are working correctly. Unfortunately, this is not always the case, leading to significant environmental damage and loss of production. This paper describes several cases from various industries where buried equipment failed because of corrosion, sometimes with catastrophic results. It also presents various strategies, based on experience and new research, to help predict and prevent damage to underground metallic structures.INTRODUCTION Metallic underground structures are extremely common in industrial and commercial settings for numerous reasons. Burying pipes, tanks, wires and other similar equipment has numerous advantages: it provides significant protection from mechanical damage, frees up ground space that can be used for other purposes, requires little to no support structure and is generally more esthetically pleasing. However, this last benefit can also be considered the most significant disadvantage of underground equipment: becoming invisible and forgotten. While every engineer is aware of the importance of preventive maintenance, it is also human nature to somewhat forget about equipment that is hard to inspect and assume that everything is fine. This is unfortunately not always the case and failures in industrial settings can have extremely serious consequences. While economic aspects immediately come to mind (loss of production, cleanup cost, etc.), failure of underground equipment also results in an environmental and therefore public relations nightmare, especially in the oil and gas field. Leaks that would have been considered negligible in the past can now make national headlines and perfect reliability, while probably impossible to achieve, is now the goal of most companies. While environmental damage (real or perceived) is most often associated with leaks in the oil and gas industry, it can also affect the mining world. For example, the authors have worked on a project where a buried slurry pipeline had ruptured in the ground, causing a release of perfectly inert tailings. While the economic loss was low, the leak was reported in local media and caused a public relations problem."

Jan 1, 2017

By D. J. Jr. McAdam

RESULTS of investigation of corrosion-fatigue of metals at the U. S. Naval Engineering Experiment Station have been presented by the author in four papers. 1,2,3,4 In those papers references were given to the work of Haigh in 1917.5 The investigation at Annapolis included a variety of ferrous and non-ferrous alloys. The experiments showed that even slight corrosion simultaneous with fatigue may cause failure at stresses far below the ordinary endurance limit. The experiments also showed that, for most metals, severe stressless corrosion prior to fatigue is much less damaging than even slight corrosion simultaneous with fatigue. The term "corrosion-fatigue" was restricted to mean the simultaneous action of corrosion and fatigue. The combined effect of corrosion followed by fatigue was called "prior-corrosion fatigue." A stress-cycle graph representing corrosion-fatigue is a curve approaching a horizontal asymptote, the ordinate of which may be called a "corrosion-fatigue limit." To avoid confusion in later discussion, the term "endurance limit" will be restricted to mean the fatigue limit obtained by tests in air with specimens as free as possible from stress concentration and from corrosion. The endurance limit as thus obtained presumably represents an inherent property of the metal.

Jan 1, 1929

By C. L. Mantell

ALTHOUGH SO common and well known a metal, tin is really a less abundant element than many of those less familiar and usually ranked with the scarce or rare elements, such as cerium, yttrium, lithium, beryllium., titanium, zirconium and vanadium. The color of tin is white, with a slightly bluish tinge. When it is compared with nickel, the latter metal is brown. When placed alongside of tin, chromium is definitely blue. Tin is whiter than silver or zinc. Exceedingly thin films of tin show various shades of brown by transmitted light. The metal has a brilliant luster, and when mirror-polished, has high light reflectivity. The luster depends to a large extent upon the pouring temperature at which the metal is cast. If the temperature be, too high, iridescent colors may show on the surface. These are the result of oxide film formation. If the pouring temperature be too low, the surface is dull. Small amounts of foreign metals, such as lead, arsenic, antimony and iron, decrease the luster of tin and impart a yellowish tinge to the metal. The structure is decidedly crystalline. The cast metal is a mass of crystals. When a bar of tin is bent, it emits a characteristic creaking sound. This is called the "cry" of tin, resulting from the grinding of the crystals one against the other during the bending of the metal. Tin metal may lose its crystalline structure by cold working, but grain growth occurs rapidly under the influence of heat. Metal which has been cast at a low temperature may become amorphous as the result of mechanical work. If such material be heated to temperatures well. below the melting point, say at 110° C. for a half hour or for a few minutes at 150° C. recrystallization occurs. If the surface of tinned plate, tin foil, or tin metal in cast form be etched with hydrochloric acid containing a little free chlorine, attack occurs at the intercrystalline faces. The surface shows patterns resembling the frost flowers on window panes in winter. The etched appearance is called moiré metallique. Fine dendritic surface crystals of tin may be obtained by casting the metal on a surface of polished steel. In commercial tin plate, the intercrystalline boundaries are shown by fine grooves or channels, which result from the method

Jan 1, 1929

By Olga Frank-Kamenetskaya

The experimental results of study of atmospheric corrosion processes on Saint-Petersburg bronze monuments surface, received in situ and by means of simulating experiments, have been discussed. Influence of the time factor on corrosion film (patina) mineral composition has been analyzed. Direct dependence between patina mineral composition and environmental conditions has been proved. The sequence of patina phases crystallization has been established. Effect of the chemical composition and heterogeneity of artistic bronze and also monument surface structure on the rate of corrosion process has been regarded. The time variations of mass of the crystallized in the hydrochloric acid vapor phases have been investigated. The kinetic laws of their development at the initial stage of formation, indicating simple (non chain) reactions, have been revealed.

Jan 1, 2006

By C. Blawert

The corrosion properties of the skin and the bulk of semi-solid processed and high pressure die cast AZ91 alloy were studied in 5% NaCI solution by (a) analysing the corrosion morphology, (b) measuring electrochemical polarization curves, (c) performing electrochemical impedance spectroscopic measurements, and (d) immersion tests at constant pH-values. Using XRD, LM, SEM and EDX to evaluate the microstructure of skin and bulk specimens, the corrosion results were related to the microstructures of the particular alloys. However, microstructure and corrosion performance were found to be similar for both production processes, and only slight but distinct differences were found. Generally, the skin corrosion properties are inferior to those of the bulk, with the exception of the high pressure die cast AZ91 alloy, where the finer microstructure of the skin layer exhibits a better performance as showed by impedance studies and confirmed in long term immersion tests.

Jan 1, 2004

By C. Blawert

In previous studies of various HPDC magnesium alloys we found that the corrosion properties of the skin are inferior in comparison to the bulk, However, this is surprising as one would expect better corrosion properties for the finer microstructure of the skin, In a more detailed study using 2 and 6 mm thick sections from HPDC AZ91 step plates, the corrosion results of the original skin, the slightly removed skin and the bulk were compared, Indeed, the corrosion measurements including potentiodynamic polarization, long term polarization resistance measurements and electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin. An explanation for this corrosion behavior was found, on the one hand, in the microstructure concerning especially the amount and distribution of the 13-phase and, on the other hand, in the composition, including the distribution of the most important alloying element Al and of some impurities such as Fe.

Jan 1, 2005