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By T. Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques and controlled bulk leaching studies. The anodic dissolution process has been established to be a sevenelectron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions, which suggests that the sulphur is oxidized to thiosulphate and the copper and iron released as Cu+ and Fe2+ in these systems. The deportment of Fe2+ and S2O3 2- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, supporting formation of different sulphur species as proposed for the sulphate and carbonate salts. Scanning electron microscopy and energydispersive spectroscopic analysis of the mineral surface after leaching indicate presence of an iron–sulphur surface layer completely free of copper in the sulphate system, an iron-rich surface layer in the perchlorate solutions, and absence of surface layer build-up in carbonate solutions. XRD analysis of a bulk leach residue from leaching in ammoniaammonium sulphate solutions showed the surface layer to be mostly amorphous (90%). The crystalline content (10%) is composed of 95% polymorphs of anhydrous iron oxide hydroxide FeO(OH). Choice of ammonium salt and the hydrodynamic environment of leaching have been shown to influence the presence or absence of the surface product, as well as its nature. IntroductionHydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different routes for hydrometallurgical treatment of chalcopyrite can be followed. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilization of copper (I) and copper(II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation [1] (Beckstead and Miller., 1977a):"

Jan 1, 2016

By I. S. Escobar

Copper, particularly the oxygen-free grade Cu-OFP, is a candidate material for containers for the long-term isolation and disposal of high-level radioactive waste (HLW) in underground repositories. After having been buried for a few hundred years, all oxygen will have been consumed in the repository, and corrosion of the copper will be caused entirely by contact with dissolved sulfides. Chloride is another potential corrodant, but in deep repositories where groundwater is neutral or slightly alkaline, the effect of chlorides can be ignored on thermodynamic grounds. Thus, the corrosion of copper in the presence of sulfide ion and under reducing conditions has been studied using cyclic voltammetry and Tafel slope measurements. It is possible to determine the effect of sulphide ion on copper corrosion resistance which is minimized at low temperature and also at low sulphide concentration. The presence of anions such as HCO3 under environmental conditions produces a beneficial effect because these ions are inhibitors.

Jan 1, 1999

By Jianzhong Li, Yunkai Wang

Lead substrate anodes are widely used in the electroplating and electrolytic field. However, with the change of internal stress, the oxide films are gradually generated on the surface of lead anode. Their structure and stress properties were studied during the oxidation by means of Raman spectra, XRD, SEM. The result showed that the diffraction peaks of lead were mainly found at the initial oxidation stage. With increasing oxidation time, Pb diffraction peaks were weakened and the diffraction peaks of PbO/PbO2 strengthened remarkably. When the oxidation time was above 10 min, monoclinic PbCrO4 was also generated in the oxide film with CrO4 2 ions solution as electrolyte. Raman spectra revealed that Raman peaks of PbO/PbO2 were gained. In addition, Raman peaks of PbCrO4 at 830–840 cm−1 were found using the CrO4 2 ions as electrolyte. Based on the relationship of the internal stress of oxide film and Raman peaks shift, PbO/PbO2 induced obvious stress generation in CrO4 2 ion electrolyte. The nucleation style of oxidation film was 3D progressive nucleation at first. After the peak current, it turned to be 3D instantaneous nucleation. In the oxidation process, the internal stress of PbO/PbO2.

Mar 1, 2017

By T. Mulpeter, G. Deschênes

Sadiola Gold Mine is an open pit operation located in Mali and owned by Anglogold Ashanti Ltd, Iamgold Corporation and the State of Mali. A conventional cyanidation process (cyanidation/CIP) treats 15,000 tpd (of a mixture of oxide and sulphide ores) at an average grade of 3 g/t Au. In 2002, the increasing tonnage of sulphides caused an increase in production costs and a decrease in gold extraction (from 95% to 70-76%). Because of the short retention time of the leach circuit (18 hours) and the refractory nature of the sulphides, gold leaching kinetics are critical. A laboratory investigation was initiated to evaluate actual plant practice and identify a means of improving the gold leaching rate. The study was conducted on a "soft" sulphide gold sample containing 4.96 g/t Au, 0.4 g/t Ag, 2.5% pyrite, 1.2% arsenopyrite, and 0.2% pyrrhotite with a P80 of 74microns. Pre-leaching significantly influenced the gold leaching rate. A short pre-leach (2 hours) performed at pH 8, a DO of 8 ppm, and with 300 g/t lead nitrate added at the start or the end, produced the preferred conditions. Pre-leaching for more than 2 hours was detrimental to gold extraction. The cyanide concentration had to be maintained at 450 ppm NaCN to reach a maximum gold extraction within the retention time of the circuit. A maximum extraction of 81.3% Au was obtained in 20 hours (leach residue at 0.97 g/t Au). A high level of dissolved oxygen in the pre-leach was not of any benefit. Extension of gold leaching beyond 20 hours indicated that all leachable gold had been extracted by that time. Plant modifications were made to allow leaching of oxides and sulphides in separate circuits. Treatment of oxide ores is now performed at a higher rate. Sulphides are processed at a lower throughput, with 300 g/t lead nitrate, to allow a retention time of 22 hours. Combined throughput remains the same, and total gold recovery has increased from 76% to 80% for an additional gold production of 16,000 ounces per year.

Jan 1, 2005

By Tianjiao Luo

The electroless copper plating process for continuous carbon fiber using CuSO4?5H2O as the main salt and formaldehyde as reducing agent was experimentally studied, including the effects of pH values and concentration of chelating agents, stabilizing agents and reducing agent on the electroless plating process. The surface morphology and the composition of coating were investigated by means of Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS), and deposited the coating thickness was measured by way of dissolution. The results indicated that the pretreatment of carbon fiber before plating was so important. This pretreatment could prevent the formation of the black cores, furthermore, it could form many active absorption cores with Ag as the center on the carbon fiber surface. Used the optimized parameters in this process, which led to a stable solution for plating, a homogeneous copper coating was conducted with the carbon fiber plated with favorable mechanical performance and high adhesion strength.

Jan 1, 2006

By E. D. Gálvez, L. A. Cisternas, A. López-Valdivieso, F. Lucay

"The floatability of molybdenite fines in saline solutions was investigated through microflotation studies using a modified Hallimond tube. In addition, the effect of pH and gypsum precipitation from calcium ions (Ca2+) and sulfate ions (SO4 2-) ions in saline water on the recovery of the molybdenite was analyzed. It was found that the floatability of molybdenite fines significantly increased with the ionic strength of the saline solutions and is independent of pH above 0.5 mol/L ionic strength. The high floatability of molybdenite in saline solutions is explained as being due to the low electrostatic repulsion between bubbles and the edges of molybdenite particles, which is exceeded by interactions due to van der Waals and hydrophobic forces. The precipitation of Ca2+ and SO4 2- ions as gypsum had a detrimental effect on the natural floatability of molybdenite because of gypsum crystal attachment on the faces of the molybdenite particles. This precipitation phenomenon may be initiated in copper–molybdenite flotation circuits that use recycled saline water, like seawater containing Ca2+ and SO4 2- ions.IntroductionWater availability is a significant factor in mining projects. Water, particularly fresh water from rivers and underground water, is becoming a scarce resource for mining operations and new projects. Under these circumstances, the use of water with high concentration of salts in flotation plants is becoming increasingly important (Cisternas and Moreno, 2014). The use of seawater has been studied as a sustainable solution for many mining companies in dry areas located near the sea. Notably, using seawater in mining operations is how mining companies in Chile have coped with the problem of water resources (Cisternas and Gálvez, 2014). In 1930, small plants in Chile used seawater to float chalcopyrite from high-copper-grade ores. In 1975, the results of tests in pilot plants for the flotation of copper minerals with seawater were reported. It was found that froth formation in seawater at pH 9.5 was suitable to make the rougher circuit work properly, even without frothers. The Cenizas mining group successfully floated chalcocite, bornite and chalcopyrite in the Las Luces plant in Taltal in Chile using seawater (Moreno et al., 2011). Minera Centinela (Antofagasta Minerals S.A. Chile) is currently processing porphyry copper ores using a seawater mixture consisting of 20 percent fresh seawater and 80 percent recycled water. Lower consumption of flotation reagents was reported in both seawater and salt water. In addition, studies performed with synthetic seawater showed that certain frothers increase the froth volume, whereas others decrease it. Additionally, the froth produced with seawater carries a high amount of gangue, and low-quality concentrates are obtained, requiring more cleaning stages."

Jan 1, 2015

By K. Wu, X. Yuan, R. Du, C. Chao

"Lump coals are currently employed to replace part of coke in the COREX melter-gasifier for ironmaking. In order to optimize the process, the pyrolysis kinetics of Datong coal used in the COREX process was studied. A sectioning method is proposed to overcome certain shortcomings of traditional methods for studying the pyrolysis of coal. Based on the sectioning method and the characteristics of the coal pyrolysis process, the temperature range was divided into three intervals. In the first, the adsorbed gas and water of crystallization were removed; in the second, the coal was transformed into semi-coke; and finally, the semi-coke was further coked. Three models of reaction were then established to study the different stages of the pyrolysis process: an interfacial chemical reaction model, a random pore model, and internal diffusion with shrinking volume. The results showed that the experimental data fitted the models well, with all correlation coefficients (r2) exceeding 0.97. Finally, the mechanisms of reaction and kinetic parameters for each temperature range were derived, which laid a necessary foundation for optimizing the usage of non-coking coal in the COREX process. IntroductionIn view of environmental concerns and the shortage of good-quality coking coal, the COREX process was designed as a new ironmaking technology, attracting wide attention (Fang et al., 2005). In this process, lump coal and a small quantity of coke are directly charged into the melter-gasifier, where a high-quality reducing gas is generated for the reduction of the iron ore (Kumar et al., 2009). In contrast to the conventional blast furnace (BF) process, non-coking lump coal is used as the reducing agent and as the energy source, and the iron charge consists of lump ore and/or pellets, which results in the elimination of the coke oven and sintering plant as well as a decrease in investment (Kumar et al., 2009; Liu et al., 2012).Although the COREX process has made great progress, in current production practice the energy consumption greatly exceeds that of the BF, and it requires a certain amount of coke to maintain permeability of the semi-coke bed (Wang et al., 2008). In addition, the process consumes a lot of good-quality lump ore and lump coal. The pyrolysis of coal is the first step in most coal conversion processes, such as carbonization, gasification, and combustion (Aboyade et al., 2013). The reaction behaviour of lump coals in the COREX melter-gasifier is crucial, as it determines energy utilization and gas composition, as well as the metallurgical properties and particle size of the semi-coke produced (Prachethan et al., 2011; Zhang et al., 2014). In order to optimize the process and improve its competitiveness, the pyrolysis kinetics of Datong coal used in Baosteel’s COREX C-3000 facility was studied."

Jan 1, 2016

By Sayan Sarkar

HAMR (Hydrogen Assisted Magnesiothermic Reduction) process is a promising alternative route of titanium production, which is convenient due to reduction at relatively lower temperatures below 750 °C and usage of cost-efficient TiO2 as the starting material. A crucial step involved in this process requires the Mg reduction of TiO2 subjected to H2 atmosphere which produces porous TiH2 along with residual magnesium impurities. Before the final heat treatment and deoxygenation steps for consolidation of the Ti powder, leaching plays a significant role in the removal of Mg impurities. In this report, we present a systematic study on the role of acid concentration (HCl), temperature and the kinetics of MgO dissolution. In addition, we also report the controlling mechanism during kinetics of MgO dissolution in acid. This parametric study will provide a platform to ensure very low Mg content that meets with ASTM standards during production of Ti in the HAMR process.

By Ranjeet K. Singh

Kelsey Centrifugal Jig was found to be promising for the beneficiation of fine coal particles. The present study was aimed at in-depth understanding of the separation features of Kelsey Jig through detailed experimentation. Beneficiation of fine coal of size 150 x 300 µm was studied in a laboratory Kelsey Jig. The thickness of the ragging bed is found to be an extremely crucial parameter apart from the other process parameters such as rotational speed and pulsation frequency. A constant pulp density (25% solids) of the feed slurry was maintained in the study. The feed rate was also kept constant at 50 kg/hr dry solids. Silica sand of size -1.68+0.85 mm was used as ragging material to avoid the pegging of internal screen having an opening of 425 µm. The rotational speed was found to have significant effect on the depth of the ragging bed and its porosity, which influenced the separation performance considerably. Pulsation was identified as the key factor in stratifying the coal bed and defining the misplacement as well as ragging bed porosity, which influenced the mass yield and quality of the products. Beneficiation studies were carried out with rotational speed varying between 900-1000 rpm while pulsation frequency was kept within 850-925 rpm. In a single pass through the Kelsey Jig 7-8% (absolute) reduction in the ash content of the feed material was observed at more than 55% mass yield. High rotational speed, moderate pulsation, and low ragging bed depth favored good cleaning. A high bed depth was found to facilitate rejection of high ash materials. It was established that Kelsey Jig is effective in fine coal cleaning though a controlled operation is required in order to achieve superior performance. Keywords: enhanced gravity separator, g-force, separation performance, ragging material, coal beneficiation

Sep 1, 2012

By B. Y. Tuo

This article presents results of studies performed to determine the feasibility of using low-grade limonite ores from Yunnan deposit. Laboratory tests and commercial trials have shown that the magnetic separation can be performed with a high high-grade concentrates. The quality of the preparation concentration meets the requirements for blast-furnace smelting. The results as a whole demonstrate the feasibility of utilizing bank limonite ore. Yunnan limonite?s magnetic separation, roasting magnetic separation and flotation experimental study shows that grade of the ore grade can been from 32.91% heighten to 58.64%, a recovery of iron is 90.87%, productive rate is 51% through orthogonal test optimization; roasting magnetic separation can obtain that the grade of iron preparation concentrate is 61.16%, recovery is 67.39%, productive rate is 36%. As far as economy and enviormental protection is concerned, strong mag-netic suggested a more appropriate process. Keywords: Limonite; Roast; Magnetic separation

Jan 1, 2014

By Fernando Nunes da Silva

Wear mechanisms of materials that constitute the equipments and operating parts in the pre-salt area during the production of petroleum and gas can include corrosion, corrosion-cavitation and corrosion-cavitation-erosion. In the laboratory, it is realizable, but at times it is inaccurate to reproduce or visualize some of these mechanisms due to the real complexities caused by hydrodynamic flows, and the physico-chemical and mechanical non-linearities. The main objective of this work was to study coupons of low carbon steel under laboratory conditions, such as corrosive, cavitative-corrosive (CO2) and corrosive-erosive (CO2 + SiO2), in a stirring aqueous saline solution (0 and 5.0 m/s) at two levels of temperature, with bubbling of gas (5.0 L/min) and contaminated with or without (2.5 % mass), by solids particles of SiO2. The surface of the coupons subjected to upstream flow (0° in a cylindrical generatrix of coupon), and downstream flows (180º) were analyzed by profilometry. The measurements of roughness and waviness of all coupons were statistically analysed using Statgraphics® Centurion XVI, at a confidence level of 95% and significant differences observed in some matrices were discussed.

Jul 31, 2018

By Liaqat Ali Shah, Muhammad Farooq, Zait Ullah Shah, Francisco Rolando Valenzuela-Díaz

Bentonite collected from Nowshera (Pakistan) was treated with NaCl, and the < 2-μm clay fractions were separated by sedimentation process. The textural changes in NaCl treated purified bentonite were compared with raw and physically purified sample. It was detected that the NaCl-treated purified bentonite and the sample purified by simple sedimentation, respectively, consist of sodium-montmorillonite and calcium-montmorillonite as a major clay mineral. The honeycombed-type morphology was observed for both the purified samples; however, the particles of NaCl treated purified bentonite were relatively in a compact form. The particle sizes of both the purified samples were found considerably smaller. The high volume percent of the fine particles was noticed in the NaCl-treated purified bentonite. This attributed that the sodium exchange has a valuable impact on the bentonite dispersion in aqueous media during particle size measurement. The relatively high mesopore area/volume and micropore area/volume and specific surface area (SSA) were detected in purified samples. The NaCl-treated purified sample showed relatively high mesopores area/volume than the sample obtained by simple sedimentation. These changes seem to be originated from either high montmorillonite contents and/or the smaller particle size, which might be produced after the layer rearrangement during the interlayer cation replacement by Na+ ions. The large SSA and high porosity of purified samples particularly the NaCl-treated bentonite suggest their potential use as adsorbents, catalysts, pharmaceuticals, and cosmetics.

Jan 7, 2021

By J. Ma

Vanadium ore is widely distributed in black rock series (Fan, Zhang and Ye, 2004) in many provinces of China, which accounts for 87% (Zuo, Peng and Dugang, 2001) of vanadium reserves in China. In Cambrian black rock series in south Qinling Mountain, there are large or medium-sized sedimentary deposits such as Zhongcun vanadium deposit, Yinhua vanadium deposit, Qianjiaping vanadium deposit, Xiajiadian gold-vanadium deposit and Lengshuigou vanadium deposit. The vanadium is distributed in other minerals mainly in the form of isomorphic replacement. These types of ore are characterized by no independent vanadium mineral, low grade and vast reserves. Now in China the vanadium extraction technology is backward with low utilization rate of resources. The difficulties of vanadium extraction from black rock series are that the enrichment by means of mechanical beneficiation is difficult; the cost of direct chemical extraction is high and the emission of waste gas from pyrogenic process does not conform to environmental protection standard. Therefore the study of vanadium occurrence, the improvement & optimization of vanadium extraction technology and the realization of pollution-free and low-cost extraction of vanadium from black rock series are of great and realistic importance for environment-friendly exploitation & utilization of vanadium resource in China. The study is based on carbon content in ore of Cambrian black rock series in south Qinling Mountain. Two kinds of ore are selected. Vanadium ore with low carbon content (TC<1%) is taken as Sample 1 while vanadium ore with high carbon content (TC>10%) as Sample 2. Based on analysis of ore?s lithologic features and vanadium?s occurrence, a vanadium extraction technological process characterized by selective grinding, low cost and no pollution is proposed.

Jan 1, 2014

By K. Biswas

For the pillars, which have been standing long after mining, the stability depends much on the weathering action in the presence of mine moisture. From the field observations, it has been found that this weathering action becomes critical in terms of pillar stability if the coal seam contains partings or binders in it. The weathering action degrades both the partings and coal in terms of their load bearing capacity as the mine moisture penetrates into them. This paper investigates the effect of weathering action on coal and partings in the laboratory. In the field, the strength profile in the coal and the partings and the effect of time (in terms of the pillar age) on them have been studied by using borehole penetrometer. In this paper, an attempt has also been made to establish formulae for time dependent strength of coal and partings.

Jan 1, 1997

By Fanke Meng

Electrolyzing oxides of titanium, aluminum and niobium could prepare high-Nb bearing TiAl alloy (Ti-45Al-9Nb) at 1500°C. The chosen electrolysis voltage is 3.5V, which is lower than reducing voltage (~4.7V) of electrolyte CaF2, but higher than that of titanium, aluminum and niobium oxides. The investigation shows that compared with traditional methods, this method for preparing high-Nb bearing TiAl alloy is of many advantages such as few steps, friendly environment, low energy consumption, low cost and high current efficiency.

Jan 1, 2009

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

Study on Basic Theory of the Grain Settlement in Fluidised Bed This paper takes thick goal grains (less than 1.5 cm) as research object. According to different densities and particle sizes, thick goal grains are divided into 20 kinds of narrow density and narrow size level average grains. Free settling and hindered settling tests are respectively carried out in ?100 fluidised bed thick goal separators. Hindered settlement includes hindered settling velocity test and measurements of suspension density. Results show follows. (1) Fluid state in separator belongs to transition region. Alien&apos;s law is the appropriate formula of thick coal particles free settlement terminal velocity. (2) The main factors affecting hindered settling velocity are the number of solid particles in medium and the structure feature of the particle group. The bigger volume fractions of solids ? is, the smaller decreasing velocity coefficient of particle hindered settlement ¯ becomes. In the organism from bottom to top, density of suspended particles in fluidised bed gradually decreases, but near the top of the suspended particles, the density increased slightly. With increase of density and size, suspension density reducing extent increases from bottom to top of separators.

Sep 13, 2010

Beneficiation and dephosphorization of refractory oolitic hematite ore are investigated in this paper. It is shown that single magnetic separation, gravity separation or flotation is unable to recover iron effectively from the ore due to the complex mineralogy. The joint separation by spiral chute-shaking table shows a prospect for the treatment of the ore. An iron concentrate with 58.67% iron grade and 51.93% recovery is obtained by the joint separation of spiral chute and shaking table under the fineness of ?0.074mm 90% and dispersant dosage of 2kg/t for a sample ore of 37.51% Fe and 0.88% P. However, P content in the concentrate is still up to 0.52%. Dephosphorization from the concentrate is hence carried out. The final iron concentrate assaying 59.26% Fe and 0.056% P is obtained when the concentrate obtained by joint separation is leached by sulfuric acid of 1% (mass fraction) with solid percentage 10% at room temperature for 10min.

Jan 1, 2014

By Y. Luo

"It is generally known that spontaneous combustion potential is a function of coal rank, with low-rank coals having high susceptibility to self-ignition and high-rank coals having low potential. To establish this functional relationship and use it as an engineering tool to identify the propensity of coal to self-heat, both rank and spontaneous combustion potential should be quantified. ASTM D388 is normally used to classify coals by rank, but this classification system can only serve a qualitative analysis. To classify coals by their potential for spontaneous combustion, the self-heating temperature (SHT) method originally developed by the U.S. Bureau of Mines (USBM) was used by Litton and Page (1994) to correlate coal rank with spontaneous combustion potential. In that method, the SHTs of coal determined by an adiabatic experiment are linked with proximate analysis results through a proposed concept known as the “moist fuel ratio.” This ratio is a function of moisture, volatile matter and fixed carbon, all of which have widely different content percentages in different ranks of coal and have strong relationships with coal rank. However, the method is highly empirical, and there is large standard deviation between experimental data and calculated results. The equation correlating the coal quality parameters to determine SHT should be improved with more experimental data.This paper reports on the development of a new system for predicting the spontaneous combustion potential of U.S. coals, based on coal composition data from the U.S. Geological Survey’s coal quality database. First, the user is provided with a quantified classification of coal rank. Second, based on experimental SHT data covering a wide range of ranks from lignite to low-volatile bituminous coal, the original USBM correlation for predicting SHT is improved for the respective rank of coal. The relationship between the rank and SHT of U.S. coals was developed and plotted. The plot diagram can be used for a quick estimate of the SHT of a U.S. coal and as a cost-effective tool for the initial risk assessment of a new mine development."

Jan 1, 2015

By Mingmei Zhu, Lang Hu, Yu Wang, Hongpo Wang, Congjing Zhang

Magnetic field has a great effect on the crystallization behavior of mold flux and properties of the flux film between mold and strand, on which the surface quality of strand was deeply depended in continuous casting process. Therefore, studying the change law of the crystallization properties of mold flux in magnetic field is of great significant. In the present work, based on intensity of the applied magnetic field with the range from 0mT to 60mT, the crystallization ratio, crystal size and mineralogical phases of the flux film were discussed. The results show that crystallization ratio increases with the increasing magnetic field intensity, and the crystal size becomes bigger at the same time. The magnetic field promotes the crystallization ratio and growth speed of the crystallized grains of mold flux. However, magnetic field doesn’t change types of the mineralogical phases.

Jan 1, 2015