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By A. Wahab Khair

"This paper presents an analysis of fracture mechanisms in coal subjected to bi-axial state of stresses, indentation of laterally confined coal specimen. Coal specimens were loaded to failure by the straight wedge indenters at various lateral confinement pressures. Strain distribution and acoustic emission characteristics of coal specimens under stress were recorded. The influence lines of vertical forces acting on the horizontal straight boundary of the coal specimen for each type of wedge indenter have been established using holographic interferometry technique. The effects of wedge indenter angle, confinement pressure, and coal anisotropy on fracture types, failure modes, and post-failure conditions were studied. The results indicated that combined application of holographic interferometry and acoustic emission monitoring techniques is not only suitable ·for studying deformability of heterogeneous and microscopically discontinuous material under stress but it also enhances the mode of fracture during the post failure stage. INTRODUCTIONOne of the relevant processes in the coal cutting technology is the application of indentation theories. Since most cutting tools in the coal industry are wedge shaped most of the indentation research is found for a wedge shaped tool.A wide range of behavior is found in different rocks subjected to the wedge penetration. A rock which is elastic brittle at standard pressure might become elastic plastic at high confining pressure (Gnirk and Cheatham, 1963). It was also observed that some rocks will merely be crushed and indented by a wedge whereas others will crack and form chips, furthermore the existence or non-existence of chips depends mostly on the geometry of the indenter, type of rock and the depth of penetration (Evans and Murrel, 1958). However, coal cutting technology is mostly explained by models which use rigid wedge to penetrate into a brittle material in which both crushing and chipping will occur (Evans and Murrel, 1958, 1962)."

Jan 1, 1988

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By Suresh Chikati, Gangadharan Santhanam

Twin tunnels were constructed to a length of 863m using TBM in one of the underground metro projects. The tunnels pass through complex geological conditions (soil, rock and mixed conditions). This paper presents the consideration of volume loss and the corresponding ground settlement associated with the excavation of twin TBM tunnels by analytical and numerical methods. Empirical methods were used to calculate the ground settlement induced by the excavation of twin tunnels. The ground settlement values were directly derived from the two parameters: the volume loss and trough width parameter. These parameters are calculated based on the geological conditions at the tunnel face and tunnel overburden. The finite element software, Plaxis 2D was used to model the soil parameters with appropriate geological conditions. Twin tunnel excavation is simulated in Plaxis 2D and the effect of tunnelling on the ground was simulated by percentage volume loss. The suitable line contraction value was applied to the tunnel linings to simulate the volume loss. The surface ground settlement was directly obtained from Plaxis 2D. Instrumentation arrays were proposed along the twin tunnel alignment, to provide the ground settlement monitoring data within the influence zone of tunnelling activities. The derived ground settlement values from analytical and numerical methods were compared with the actual field instrumentation and monitoring data. From the field instrumentation data, the actual volume loss values were calculated. The compatibility of ground settlement and volume loss calculated using analytical and numerical methods and those measured using field instrumentation data is discussed in this paper.

Sep 1, 2022

By Mariana H. Staia

Thermodynamic calculations based on the free energy minimization method were performed for the system Ti-Fe-Mn-0-C1-C in order to evaluate the chemistry associated with the chlorination of an ilmenitic concentrate using CCl4. In the calculations various weight ratios of FeTi03/ CC14, a , were considered, which varied between 0.32 to 0.98 at temperatures ranging from 673 K to 1273 K , at atmospheric pressure. The results obtained indicated that the operating conditions for a process in a packed bed reactor, which implies the chlorination of both Fe and Ti, are 0.39 < a < .49 at T 1173 K.

Jan 1, 1993

By T. Hayashi

A sophisticated process of extracting ultrafine sulfide mineral particles of under 1µm size suspended in clay slurry has been developed through studies of electrochemical properties of particle surface. Experimental procedure and data of the process applied to some clay ores containing sphalerite and pyrite, and molybdenite and other sulfide minerals are reported. Discussions concentrated on the function of process reagents, particularly on various modifying reagents, and on the effect of dispersed or flocculated state of ultrafine particles in slurry which affect significantly the performance of the process.

Jan 1, 1982

By D. A. Meyn, R. L. Holtz, C. S. Pande, M. A. Imam, D. J. Singh

"Various theoretical and experimental techniques used to search and develop new metal hydride systems suitable for hydrogen storage are described. The main theoretical technique under study makes the use of electronic structure of the candidate materials. Microstructural characterization techniques like transmission electron microscopy are being used to study the hydride formation. Novel processing techniques for material preparation such as those needed to produce thin films or amorphous phases are also being utilized. The techniques are illustrated with results from Pd, FeTi and Mg2Ni systems.IntroductionOf the four methods of hydrogen storage, compressed gas, cryogenic liquid, metal hydrides, and gas-solid adsorption, the metal hydride storage method is more attractive from the point of view of high volumetric density and safety. Compressed gas storage has disadvantages of extreme pressure, weight, and volume requirements, whereas storage of hydrogen as cryogenic liquid is unattractive due to the requirements of extremely low temperatures and high consumption of primary energy. Moreover, the number hydrogen atoms present in a volume of 10- 22 Cm3 (nH) in liquid hydrogen state (- 20K) is 4.2 whereas number of hydrogen atoms that can be accommodated in a free volume of 10-22 cm3 of various hydrides are as follows: LiH--5.9, TiH2--9.2, ZrH2--9.2, VH2--l0.2. High hydrogen concentration is usually associated with a large H/Metal atomic ratio but is also a function of structure."

Jan 1, 1994

By Charles I. Richman

Aquispirillum magnetotacticum (AM) is gram-negative hetrotrophic bacteria that belongs to a class ,of magnetotactic bacteria that have an ecological niche in marine marches and fresh water swamp sediments. Thiobacillus Ferrooxidans (TF) is a Gram-negative, acidophillic chemoliths that may have similar chemical conditions within the cytoplasmic membrane as Aquaspirillum M. to support growth of Magnetosomes. Magnetosomes are cellular bodies that accumulate under slightly aerobic conditions. Magnetotactic motion occurs in an external magnetic field and depends on the medium viscosity. The Atomic Force Microscope equipped with a magnetic tip shows the presence of Magnetosomes in these bacteria strains. The size, shape of magnetosomes in AM and TF strains are characterized.

Jan 1, 1998

By SAMUEL A. LOLON, ADITYA JUGANDA, JURGEN F. BRUNE, JR. GREGORY E. BOGIN

Historically, there have been many events of mine fires and explosions recorded in the United States and other countries that have demonstrated the existence of explosive methane-air mixtures, herein referred to as explosive gas zones (EGZs) [1]. The risk of mine explosions can increase if these EGZs migrate out from the gob into the surrounding mine entries — a phenomenon known as gob breathing. A number of 3D computational fluid dynamics (CFD) simulations using various magnitudes and periods of barometric pressure variation have indicated that the EGZ outgassing potentially occurs due to lags in pressure, which are strongly influenced by mine conditions and ventilation systems. Early-warning systems with real-time pressure monitoring and the application of gob ventilation boreholes are recommended to detect and mitigate explosion hazards from gob outgassing.

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005

Gas-liquid contacting in the packed bed is a common operation in metallurgical reactors. Research has shown that, unlike wetting flow, non-wetting liquid flows in the form of discrete droplets or rivulets. Thus, modeling of the liquid phase as a continuum is in contradiction to the observations. Also, for the non-wetting case, continuum models have failed to describe liquid flow path when the liquid source is a point source. The aim of the current work is to put forward a combined Lagrangian-Eulerian approach to model the liquid and gas flow in the packed bed. Liquid is assumed discrete and modeled using a force balance approach. Gas is assumed to be interpenetrating continua and modeled using k-emodel for turbulent flow. Structured packing is assumed and x- ray imaging technique is used to visualize liquid flow lines in the bed. Simulation results for liquid flow path compared with the experiments.

Jan 1, 2006

By Chen Song

In the experiments of purifying the solution of chlorine leaching from nickel concentrate with N235, the effects of organic phase composition on purifying efficiency have been studied. From the results obtained, the optimal organic phase composition is found to be 25%N235+12%isomerous alcohol +63%sulfonic kerosene (VIV) and the saturated content of cobalt in organic phase is7.95 g*dm3. And then the serial experiment is carried out. The results show that at the given organic phase composition, the purified solution contains p(Ni) >200 gm dm3, p(Ni)l p(Co) >50000 and the contents of Cu, Fe, Mn, Zn meet the technical criterion of standard nickel electrolyte. The cobalt chloride solution contains p(Co) >I10 g L-1, p(Co) lp(Ni)>50000 and the enrichment of cobalt has been achieved.

Jan 1, 2006

By Alok Tripathy

A simulation code called SIMJIG and the user interfaces have been developed using discrete element method (DEM) and the .NET platform respectively for the jigging process. DEM platform is used for tracking of particles in the jigging operation. DEM uses the net force balance on the particles to track the trajectory of the particle. Simulation results are compared with experimental results obtained by jigging of low grade iron ore lumps. Two different iron ore samples one from Chatishgarh and one from Odisha were used for the experimental studies. The Alljig? stratification test rig meant for batch laboratory experimental studies has been used in the present work. The behavior of different sizes of material on jigging has been examined. Later, the particle size behavior during jigging at different layers of the jig bed has been studied. Further stratification profile across the jig bed has also been studied. It was observed that simulation results are matching quite nicely with the experimental results. The SIMJIG simulator developed in the present study could be used for predicting the performance of the jigging operation effectively. Keywords: DEM, gravity concentration, jigging, iron ore, simulation

Sep 1, 2012

By P. Zhang, W. D. Xiao

"A process mineralogy study was conducted to guide the development of a process for the extraction of vanadic oxide (V2O5) and aluminum compounds from bone coal and its ash as well as the production of byproducts. Results show that to extract the targeted metals at higher recovery rates, one must find a suitable agent capable of destroying the structure of the mica and breaking down the lattices in which these metal-bearing minerals occur. For such minerals, metal extraction efficiency is usually low if the approach is simply adding an oxidant that cannot destroy the structure. In this research, a byproduct fluosilicic acid (H2SiF6) at 20 percent concentration from an operating phosphate fertilizer plant was found to be powerful and effective for the leaching of vanadium-bearing minerals such as mica. This environmentally friendly process improved the leachability of valuable constituents in the bone coal significantly, with the leaching rate of V2O5 increased to 94 percent, from 83 percent, and that of aluminum oxide (Al2O3) increased to 75 percent, from 40 percent. X-ray diffraction and chemical analyses showed that the structure of mica can be destroyed using fluosilicic acid either alone or in combination with sulfuric acid. Based on the process mineralogy study, a processing flowsheet was tested, which resulted in a final V2O5 powder product with purity of 99.2 percent and an overall recovery rate of higher than 85 percent. The flowsheet consists of leaching, ion exchange and ammonium precipitation. With this process, various byproducts could also be generated, including aluminum fluoride, cryolite, aluminum sulfate, calcium sulfate, ammonium chloride, sodium chloride and cement admixtures.IntroductionVanadium is an important rare metal broadly used in the production of steel alloys and nonferrous alloys as well as in the chemical field as a catalyst. Vanadium-bearing bone coal and clays are abundant in China, and they contain other valuable metals such as aluminum. Bone coal is a type of carbonaceous shale. The vanadium-bearing minerals mainly exist in mica, kaolin, iron oxides, tourmaline and garnet. According to previous studies (Xiao, 2007; Xu, 1989; Xu and Chen, 1991; Ji and Xu, 1991; Chen and Xu, 1992; Xu and Heng, 1992), vanadium occurs from the isomorphous substitution of V3+ for Al3+ or Fe3 + in the crystal lattices of mica, tourmaline, garnet, dolomite and aluminosilicate minerals. In iron oxide and kaolin minerals, vanadium appears as an adsorption form. The isomorphous substitution of vanadium is more stable in tourmaline, garnet and silicate minerals. Therefore, vanadium in bone coal may exist in three phases: vanadium-containing kaolin and oxides, vanadium-containing mica, and tourmaline and garnet (Xu and Chen, 1993; Xu and Zhang, 1993; Xu and Wang, 1994; Feng, et al., 2005; Lin and Fan, 2001)."

Jan 1, 2015

By Hai-Xing Fang, Bing Xie, Hong-Yi Li

"In the duplex melting process, chromium forms chromium spinels, the study of which will help to exploit the Hongge ores (rich in chromium) in the Panzhihua-Xichang area in China. Mimicked chromium slag was synthesized. The oxidation and decomposition mechanism of the Fe-Cr spinels contained was studied in a sodium roasting process. The effects of temperature, roasting time, amount of soda added and filling reagents were investigated. The leaching-reduction-precipitation-calcination procedure to extract Cr2CO3 was optimized. The results showed that the optimized roasting temperature was 1000~1020°C with a stoichiometric Na2CO3 addition and without any filling reagents. Roasted materials were leached with distilled water and were filtered to obtain a chromium-containing solution, which was adjusted to pH 1.60-1.80. A reducing reagent, NaHSO3, was added in a stoichiometric ratio and the solution was then adjusted to pH 7.25~8.25. Maximum Cr2O3 precipitation was obtained and the precipitate was calcined at 1050°C for 2h to obtain Cr2Ü3 with recovery rate over 96%.IntroductionChromium is widely applied in the metallurgical industry, in refractory materials and in the chemical industry with its particular properties of hardness, wear-resistance, high temperature resistance and corrosion resistance [1]. There is no free state of chromium in nature and chromite is the main chromium containing mineral [2], China is poor in chromium resources, despite its large demand, and there are few deposits of high grade of chromite ores except in some regions in Tibet and Xinjiang province [1, 4]. Hongge, one of largest titanomagnetite mines in Panzhihua-Xichang area, is a polymetallic deposit mainly containing iron and titanium; it is also associated with various beneficial elements such as chromium, copper, nickel, etc. [3]. As investigated in Reference 3, the chromium reserves of Hongge ores are so large that it is of great importance to study how to extract the chromium from them."

Jan 1, 2012

By Dong Yang, Jicai Han, Xiaoshuang Guo, Tichang Sun, Zhengyao Li

Straw charcoal was used as a novel reductant in the co-reduction roasting of laterite ore and red mud. The influence of the reductant dosages, co-reduction temperature, and co-reduction time were investigated. Results showed that a powdered ferronickel product of 1.81wt.% nickel and 81.40wt.% iron was obtained under straw charcoal dosage of 15wt.% and roasted at 1250 °C for 80 min. The corresponding recovery of nickel and total iron were 97.21wt.% and 98.87wt.%, respectively. The performance of straw charcoal was also compared to that by the conventional coke reductant. Results showed that ferronickel particles using straw charcoal were larger in size than coke, mainly due to the lower S (0.14wt.%) and ash content (3.80wt.%), which could not hinder the agglomeration of the ferronickel grains, and lower melting point that producing liquid phase and promoting ferronickel particles growth. In addition, the gasification reactivity of straw charcoal is better than that of coke, which is beneficial to the iron oxide reduction and the recovery of iron. To conclude, straw charcoal is a promising reductant for the co-reduction of laterite ore and red mud in coal-deficient areas.

Aug 12, 2021

By Patricia Negrini Siqueira Poveda, Leonardo G. A. Silva

Thermoplastic materials are sensitive to ultraviolet radiation (UV), which can cause structural changes, causing variation in mechanical properties and appearance. UV range between 250 and 400 nm is considered the most aggressive to polymers, and prolonged exposure to it results in breakage and/or crosslinking chains. Light stabilizer additives, blockers or absorbers are added to the polymers for protection in order to extend the life of the final product. The choice of the adequate light stabilizer additive system depends on factors such as resin final application, thickness, geographic location of exposure, presence of fillers in the composition, contact with chemicals, among others. This study evaluates different additive systems: conventional organic, inorganic nanotechnologyc base and the synergy between them when applied to polyethylene considering carbonyl index and UV/VIS results after aging by QUV chamber.

Mar 1, 2017

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada&apos;s Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By Italo Onederra, Miguel Araos

"In order to characterize non-ideal explosives, the explosives industry rely on unconfined velocity ofdetonation tests and where possible underwater pond tests. The information obtained from such tests isquite helpful, however it cannot tell us much about the dynamics of the detonation reaction process. The detonation process has been studied for ideal explosives and the reaction zone length have been measured. However, for non-ideal explosives, that type of information is not available. Therefore, the primary aim of this work was to capture the detonation process of a non-ideal explosive using high speed video camera to determine the zone length."

Jan 1, 2017

By Jochen Petersen, Thandazile Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques. The anodic dissolution process has been established to be a seven-electron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions. The number of electrons transferred in the carbonate and sulphate salts suggests that the sulphur is oxidised to a thiosulphate intermediate and the copper and iron released as Cu+ and Fe2+. The Cu+ and Fe2+ is subsequently oxidised in solution in non-Faradaic reactions. The deportment of Fe2+ and S2O32- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, however observations made on the mineral surface after leaching do not support the formation of elemental sulphur. Scanning electron microscopy and energy-dispersive spectroscopy analysis of the mineral surface suggest presence of an iron–sulphur surface layer completely free of copper under the ammonia–ammonium sulphate conditions, an iron-rich surface layer under ammonia–ammonium perchlorate solutions and absence of surface layer build up under ammonia–ammonium carbonate solutions. INTRODUCTION Hydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different approaches to hydrometallurgical treatment of chalcopyrite can be carried out. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base-metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilisation of copper(I) and copper (II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation 1 (Beckstead & Miller, 1977a):"

Jan 1, 2015