Search Documents

By P. D. Kovscek

The Bureau of Mines has tested a low-thrust water-jet-assisted rotary drill. This work was performed to evaluate the performance of a water-jet-assisted drill operated at thrust levels typical of a handheld manual-thrust operation. Prior work by the Bureau had indicated that using water-jet assist with high-thrust drilling applications would increase drilling rate. Small-diameter holes were drilled in five different types of rock. Thrust and water pressure were varied as the drill rate was monitored. The test results indicate that drilling rates increase with increasing water pressure and thrust. The water jet has more effect on reducing the specific energy when drilling in the harder rocks than in softer rocks. Variation in drill rate for a given rock sample is attributable primarily to the material heterogeneity within the sample. One rock type (Greenwich sandstone) could not be drilled efficiently with the water-jet-assisted drill.

Jan 1, 1988

By D. N. Nilsen

A mathematical modeling method was developed by the Bureau of Mines for the prediction of the principal equilibrium species in the solvent extraction of copper. The use of models for predicting the amount of metal extracted can reduce the amount of experimental work required to characterize a system for purposes such as optimization studies. Models were developed for the extraction of copper from ammoniacal sulfate and carbonate solutions with commercially available extract ants commonly used by industry. Results from laboratory shakeout tests compared well with predictions of the equilibrium concentrations of copper and pH values. For example, the loading of copper onto the solvent was predicted for most cases within ±S pct of the measured values, and the pH to with-in ±O.l pH unit in sulfate systems and ±O.2 pH unit in carbonate systems. Both mechanistic and empirical extraction equations were developed from laboratory data for copper and ammonia. The empirical-based models were slightly more accurate than were the mechanistic-based mod-els. Industrial level concentrations of the aqueous and organic constituents were used in this work. Independent variables included copper concentration, ionic strength, and initial pH of the aqueous phase; extractants, diluents, and their concentration in the organic phase; and temperature.

Jan 1, 1988

By Thomas M. Barczak

This report describes a study that examined load transfer mechanics in longwall shield supports as part of the Bureau of Mines research program to optimize support design and utilization. The objectives of this study were to determine the contribution of the leg cylinders and the caving shield-lemniscate assembly towards full shield vertical and hor-izontal load resistance capability and to determine how the interaction of these members affect overall shield response. Load-displacement characteristics of the leg cylinders and the caving shield-lemniscate assembly, independent of the full shield, were evaluated from controlled displacement tests in the Bureau's mine roof simulator and responses were compared with full shield responses to identify load transfer mechanics. It is concluded from this research that the participation of the caving shield-lemniscate assembly significantly affects the response of the shield support. It is likely that the caving shield-lemniscate assembly is not participating fully in current shield designs because of translational freedom in the numerous pin joints. It is also concluded that the shield will respond differently to different boundary condi-tions resulting from interaction with the strata. This report describes load transfer mechanics of shield supports and the implication of these research findings on shield design and utilization.

Jan 1, 1988

By S. A. N. Sheya

Many gold-bearing ores in the Western United States also contain small amounts of mercury. The presence of mercury creates potential pollution and health hazards during several steps in gold processing. An investigation was undertaken by the Bureau of Mines to develop techniques for removing mercury from cyanide mill solutions by selective electrowinning to reduce the potential hazards. Sixty-five percent of the mercury was selectively electrowon from synthetic carbon strip solution at applied potentials of 1.00 to 1.50 V when using a mercury-coated platinum or copper plate cathode. Increasing the active surface area by using mercury-coated copper wool resulted in up to % pct of the mercury being electrowon from mill carbon strip solutions that contained 1.9 to 20 ppm Hg, 20 to 345 ppm Au, and 0.35 to 39.5 ppm Ag. About 98 pct of the silver was electrowon with the mercury onto the mercury cathode. Gold extraction ranged between 0 and 20 pet. Results of the investigation showed that choice of cathode material was critical to the success of the process. Selectivity was not achieved using uncoated steel wool cathodes.

Jan 1, 1988

By M. N. Plis

This report describes the initial results of long-range research on bit life conducted by the Bureau of Mines. Three commercial bit designs -a round-nose radial, 60° conical, and 90° conical with tungsten carbide (WC) inserts -and five experimental bits were tested. Four of the experimental bits were radial designs using polycrystalline diamond compact (PDC) inserts. The fifth was a 90° conical with an oversize WC insert. Bits were worn on a high-silica sandstone typical of coal mine roofs. The bits were mounted on a 34-in-diam drum section that provided a bit speed of 565 ft/min. Cutting forces were measured on a modified vertical slotter using a three-axis force dynamometer and recorded on an FM magnetic tape recorder. Changes in cutting forces, bit weight, and airborne dust due to gradual abrasive wear and catastrophic insert failure are presented. Tabulated and graphed data, photographs of the progression of bit wear, and selected qualitative visual and auditory observations of the bits taken throughout the experiment are found in the appendixes. The results show that bit life ranged from approximately 16,000 ft for the WC round-nose radial bit to over 125,000 ft for a PDC round-nose radial. Performance, in terms of bit life, cutting forces, wear rate, frictional sparking, machine vibration, and noise was in general best with the PDC bits, followed by the rotating WC bits, with the nonrotating WC bits (round-nose radial and locked 60° conical) being the worst. The results show variations in the included tip angles of new conical bits have an insignificant influence on bit performance when the effects are averaged over the life of the bit. In addition, new bits were generally found to entrain more primary respirable dust for a given cutting distance than worn-out bits. It is hypothesized that this is due to the difference in frictional behavior between new and worn bits. The results from these tests are being used in the Bureau's cutting system model (CSM).

Jan 1, 1988

By R. H. Church

As part of the research effort of investigating the effects of microwave energy upon the chemical and physical properties of different minerals and ores, the Bureau of Mines has conducted basic research into identifying those properties of minerals that are affected by microwave energy, namely, the dielectric constant and loss tangent. These properties were determined utilizing the theory of microwave propagation in a coaxial waveguide filled with a dielectric material and measuring the input impedance with an RF impedance analyzer that operates from 1 MHz to 1 GHz. By knowing the microwave frequency and filling the waveguide with a powdered mineral, the dielectric properties of the mineral sample were determined. From these dielectric properties, theoretical microwave heating characteristics of each mineral could be calculated. These same mineral samples were then irradiated by a 915 MHz 30 kW variable power microwave oven and dielectric heating studies were performed. A comparison of the theoretical heating characteristics and the results from actual dielectric heating studies was conducted to evaluate the dielectric property measurements on each mineral. This report presents the results of the Bureau's research in identifying the dielectric properties of low-loss minerals according to the mineralogical classification scheme along with their irradiation studies. Though far from complete, this study represents some of the more frequently encountered low-loss minerals.

Jan 1, 1988

By Alex C. Smith

This report describes laboratory studies conducted by the Bureau of Mines to evaluate the effectiveness of 10 additives to inhibit the self-heating of coal. Aqueous additive solutions were applied to a bituminous coal with a high spontaneous combustion potential, and the minimum self-heating temperatures (SHT's) of the dried coal-additive mixtures were determined in the Bureau's adiabatic heating oven. The relative effectiveness of the additives was determined by the observed changes in the minimum SHT's of the mixtures, or by the time required for the sample temperature to reach 150" C, compared with the untreated coal and a coal-water blank. Sodium nitrate, sodium chloride, and calcium carbonate were found to be the most effective inhibitors, followed by ammonium dihydrogen phosphate, calcium chloride, ammonium chloride, sodium acetate, and potassium chloride. Two additives, sodium formate and sodium phosphate, promoted the self-heating process. Differential scanning calorimetry experiments on the coal-additive mixtures showed that reactions occurred between the coal and some of the additives, but these reactions did not influence the self-heating process.

Jan 1, 1988

By B. D. Hanson

An interactive computer program has been developed by the Bureau of Mines which enables the user to identify the effect of cutting system changes on relative dust generation for longwall shearer drums. The program simultaneously evaluates machine and coal seam parameters, and those parameters which the user can control. The user can change one or more of these parameters at a time to determine their effect on relative dust generation, cutting forces, and/or cost. The program is written in the BASIC programming language. A complete program listing is included along with user instructions and sample outputs. This program is a more comprehensive version of the relative dustiness index (REDI) program described in Bureau Report of Investigations 8979.

Jan 1, 1988

By Paul W. Jeran

Subsidence over a series of longwall panels undermining sloping terrain in southwestern Pennsylvania was monitored to verify the Bureau of Mines subsidence prediction model for the northern Appalachian coal region. Comparison of the field data to model output shows close agreement. Vertical movements over each panel ceased with the mining of the adjacent panel. Horizontal movements were significantly affected by topographic slope. The distribution of horizontal strains over each panel were similar, with a zone of compression occurring over the center of each panel. The zones of compression were flanked by zones of tension toward the rib. The magnitude of the tensions were affected by the slope. The strains developed at the completion of each panel were not significantly altered by the mining of subsequent panels.

Jan 1, 1988

By John J. Sammarco

As part of a project to automate coal extraction, computer control of a continuous mining machine test bed has been developed and tested by the Bureau of Mines. A computer system and control software were developed for accurate positioning of the conveyor elevation and swing, stabilizer jack, gathering head, and shear elevation. Tramming actions are also controlled by the computer. The computer system was designed to access data from sensors installed on a continuous miner and to interface with the existing control circuits of the miner. Testing in free space was used to characterize the operation of the machine. From this information, control algorithms were written and stored in the computer. The ability to control each function of the continuous miner with a high degree of accuracy and stability was successfully demonstrated in a series of tests in free space and in mining a block of simulated coal. In the mining of simulated coal, the cutting drum was instructed to position the shearer at the top of the block and shear down to the bottom under closed loop control. The cutting drum came within 0.27 in of the top and within 0.49 in of the bottom of the block for this shearing test.

Jan 1, 1988

By J. I. Paige

The effect of fluoride inclusions on the properties of titanium produced from the Bureau of Mines-developed induction slag melting process is of concern to the titanium industry. The objective of the research was to determine the effect of removing the nonconductive molten calcium fluoride (CaF2) slag used as an insulator between the titanium and the segmented copper crucible. The data were obtained from single-induction-melted ingots prepared with no CaF2 insulating slag and an ingot prepared with the normal addition of 4 pct CaP2 slag. The results showed that the mechanical properties of single-induction-slag-melted and annealed Ti-6AI-4V alloy exceed the minimum values specified in "Aerospace Materials Specification for Titanium Alloy Bars and Forgings AMS4928H." High-cycle, tension-tension fatigue testing yielded similar results. The data from 44 of the 45 specimens were contained within the typical scatter band for fatigue data on wrought Ti-6AI-4V alloy. Although the removal of the insulating slag is a desirable change, the data from the specimens with the previously standard 4 pct slag addition showed no detrimental effect from the slag inclusions.

Jan 1, 1988

By W. K. Tolley

The Bureau of Mines is testing super critical fluids as solvents to selectively extract valuable components from complex matrices. Materials recovered during supercritical fluid extraction are often highly purified. Using laboratory apparatus designed specifically for supercritical fluid research, Bureau re-searchers have measured the solubility of titanium tetrachloride (TiCI4) in supercritical, liquid, and gaseous carbon dioxide (C02), CO2, a commonly used supercritical fluid, is inert, inexpensive, and nontoxic. Supercritical CO2 formed a single phase with TiCl4 at 45° C and 1,500 psig. When the solution was heated at constant pressure beyond 55° C, TiCl4 precipitated from the fluid. Results showed that TiCl4 solubility in supercritical CO2 is not controlled by the vapor pressure of the solute.

Jan 1, 1989

By Thomas M. Barczak

This Bureau of Mines report investigates shield mechanics by describing the elastic response and interaction of shield components to applied vertical and horizontal displacements for various canopy and base contact configurations. This research provides information on generalized shield mechanics, which is applicable in describing the behavior of all two-leg shield supports. Utilizing mechanics of materials concepts and known kinematic relationships for two-leg shield supports, free-body diagrams are constructed for each shield component illustrating internal axial, shear, and bending moment responses required to maintain equilibrium for each load case evaluated. Predicted shield (component) responses are verified by controlled displacement of instrumented longwall shields in the Bureau's mine roof simulator (MRS). Conclusions drawn from these analyses include shield structural responses are significantly dependent upon canopy and base contact configurations. Applied displacements also significantly affect shield responses. Horizontal displacement produces different responses than those produced by vertical displacements. The direction of horizontal displacement is also significant in evaluating shield response. Applications of shield mechanics to in situ support monitoring are also discussed. An objective of this research program is to establish unique shield responses to identify in situ load conditions.

Jan 1, 1989

By J. Drew Potts

The U.S. Bureau of Mines identified respirable dust sources and controls on four continuous auger mining sections, two with relatively low dust levels and two with high levels. Factors adversely affecting dust levels included auger equipment design, continuous haulage, and low seam height. Dust controls included ventilation practices and spray systems. Maximizing airflow seemed to reduce dust levels most. Air leakage and shock loss can be reduced by constructing stoppings with brushed-on mortar containing fiberglass and by keeping areas between curtains and ribs free from obstructions and storing equipment not essential for face activities in outby crosscuts. Curtain configuration, setback distance, and installation can also affect dust levels. Use of both blowing and exhausting curtains is the most effective configuration. Setbacks from the face should not exceed 15 ft. Installing brattice curtains at least 5.5 ft from ribs, when entries are 26 ft wide, minimizes velocity head. Installing curtains tightly against the mine roof and floor helps maintain a forward airflow movement in the center of the mine heading; curtain overlap can create a tighter seal. The wet-auger spray system also effectively controls dust, provided the mine is already exercising good ventilation practices.

Jan 1, 1989

By John E. Pahlman

The U.S. Bureau of Mines has continued its investigation of chemical additive drilling fluids that produce a zero surface charge (ZSC) on a rock to better define the boundary conditions of the phenomenon. Laboratory drilling tests were performed on Minnesota taconite, Tennessee marble, and Sioux Quartzite using diamond-impregnated coring bits or tungsten carbide spade bits. Drilling fluids were made from chemical additives such as inorganic salts, cationic surfactants, cationic polymers, acids, or nonionic polymers in either distilled, deionized water (DDIW), mine pond water, mine well water, or tap water. These additives were tested below, at, and above their respective ZSC concentrations. Penetration and bit life improvements obtained with ZSC concentration solutions ranged from 88 and 56 pct, respectively, to over 650 pct and over 400 pct, respectively, for the additives tested. Polyethylene oxide (PEO) was found to be the best additive for ZSC-controlled drilling because a continuous range of PEO solution concentrations produced the enhanced ZSC-controlled drilling performance.

Jan 1, 1989

By A. E. Isaacson

The U.S. Bureau of Mines determined the effect of common sulfide minerals on the corrosion rates of various types of ferrous alloy grinding media. Data obtained from this study will aid in determining the contribution of any electrochemical reactions between sulfide minerals and grinding media to the total grinding media consumption. Common sulfide minerals used in this study were chalcopyrite, galena, and sphalerite. In the presence of oxygen, chalcopyrite was found to increase the corrosion rate, galena was found to decrease the corrosion rate, and the effect of sphalerite was dependent upon the type of grinding media. Possible electrochemical reactions of these minerals in the presence of grinding media are suggested.

Jan 1, 1989

By J. N. Greaves

Investigations were conducted by the U.S. Bureau of Mines to develop flowsheets for the recovery of tungsten and gold from four Alaskan scheelite-bearing ores. Basic gravity concentration and cyanide leach tests were performed on all samples. About 46 pct of the tungsten and 30 pct of the gold from one sample were recovered in a gravity concentrate containing 24 pet W03 (tungstic oxide) and 119 troy ounces per short ton (tr oz/st) Au. Froth flotation of the gravity concentrate resulted in separate tungsten and gold products with grades of 38 pct W03 and 2,720 tr oz/st Au and recoveries of 60 and 97 pet, respectively. Additional gold was recovered from the gravity and flotation tailings by cyanidation. Overall recoveries of tungsten and gold from this sample were 28 and 94 pet, respeetively. A flowsheet with mill design parameters was developed that consisted of (1) free gold and scheelite recovery by gravity methods and froth flotation and (2) fme-grained gold recovery by cyanide leaching of reground gravity and flotation tailings, followed by a carbon-in-pulp (CIP) circuit. Data were developed from the Bond mill work index, gold and tungsten flotation, conventional and high-rate thickening, cyanide leaching, and CIP adsorption tests.

Jan 1, 1989

By Larry A. Lass

The U.S. Bureau of Mines, in cooperation with the Iron Range Resources and Rehabilitation Board, investigated the potential of using northeastern Minnesota papermill waste sludges as a binder for Mesabi Range iron ore (taconite) concentrate. Sludges from five different commercial papermill waste treatment operations were evaluated in laboratory tests. Except for the coarsest sludge, all were fairly easy to blend with the taconite concentrate using conventional mixing methods. The coarsest sludge had to be reslurried at 2 pct solids before adding it to the concentrate in order to obtain pellets without visible sludge clumps. Drying and grinding the sludges made them less effective as binders because of a lower degree of rehydration. On a dry weight equivalent basis, twice as much raw sludge binder was required to obtain similar pellet physical properties as with bentonite; however, the pellets made with raw sludge had superior metallurgical properties. Over 30 pct higher reduction rates and over 1500 C higher softening temperatures were obtained with sludge binder than with bentonite. Sludge D, which had the lowest fiber and the highest alkali metal content, resulted in the lowest reducibility enhancement. Even though more raw sludge was required than bentonite, the sludges have virtually no value, and therefore may provide a cost-effective additive binder for producing improved metallurgical-quality pellets. Large-scale testing has not been done to confirm these laboratory results.

Jan 1, 1989

By Jon I. Voltz

The U.S. Bureau of Mines has conducted fundamental coal fragmentation studies to evaluate the effects of impact energy and direction of bedding planes on dust generation, size distribution, and impact-output energy relationships. Product size distributions were obtained for the fragmented samples by screening to minus 150 mesh. The minus lS0-mesh fines were analyzed with a light scattering photometer with a measurement range of 176 to 1.9 /.tm. Increased input energy produced a significant increase in the weight of plus 3/8-in material for impact perpendicular to the bedding planes. No significant trend was observed for parallel impact. Impact direction had little influence on dust size distribution, and input versus output energy relationships. As expected, total airborne dust measured at time of impact and percent particulates below 11 /.tm in size generally increased with increased input energy for both directions of impact. Energy used for sample fragmentation increased with increased energy input.

Jan 1, 1989

By Gary P. Sames

This U.S. Bureau of Mines study was conducted in eastern Kentucky drift mines as part of an ongoing research program to characterize the outcrop barrier zone. "Hillseams" were identified as the dominant geologic cause of roof instability unique to the outcrop barrier zone, with many roof fall injuries and fatalities attributed to them. Hillseam is the eastern Kentucky miners term for weather-enlarged tension joints that occur in shallow mine overburden where surface slopes are steep. Hillseams are most conspicuous within 200 ft laterally of a coalbed outcrop and under 300 ft or less of overburden. Hillseams form by stress relief, and therefore tend to parallel topographic contours and ridges. They can intersect at various angles, especially under the nose of a ridge, and create massive blocks or wedges of roof prone to failure. Examples of hillseams are described in both outcrop and in coal mine roof to establish their geologic character and contribution to roof failure.

Jan 1, 1989