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By V. A. Marple, K. L. Rubow

"4.1 IntroductionIn previous chapters impactors have been described as useful instruments for classifying particles by their aerodynamic diameters and for measuring particle size distributions. These impactors can be used most reliably if the user has some understanding as to how the impactor classifies particles and what parameters are important in this classification process. This understanding can best be obtained by a theoretical inspection of inertial principles.This chapter reviews the most recent theoretical impactor work and the latest theoretical efficiency curves. Procedures are then given for using these efficiency curves in the design and evaluation of cascade impactors. Finally, several examples are given comparing theoretical and experimental efficiency curves, pointing out when the theory can be used with great confidence and when the theory should be used only as a guideline.Due to the rather simple principle of operation of an inertial impactor (i.e., the impingement of a jet of particle-laden air on a flat plate) the impactor readily lends itself to theoretical analysis. Three notable works in the early 1950,s were those of Davies and Aylward (1951), Davies et al. (1951), and Ranz and Wong (1952).Davies and Aylward (1951) used a method of conformal mapping to obtain an analytical solution to Euler's equation for the flow of a frictionless fluid through a rectangular impactor. Numerical calculations were then carried out whereby the equations of motion of the particles were solved in a stepwise manner, leading to a determination of the efficiency curves. Since this theory assumed potential flow, the effect of Reynolds numbers on the characteristics of the impactor could not be determined.Ranz and Wong (1952) used an approximate flow field to calculate the efficiency of both round and rectangular nozzle impactors. In the vicinity of the stagnation point, the flow field was assumed to be that of frictionless stagnation flow. Here, the resulting equation of motion for the particles was found to be in a form similar to equations for free vibration with viscous damping. Therefore, the known solutions of the vibration equations were applied directly to the problem and the efficiency curves calculated. This solution technique, however, could not take into account the various geometric variations such as the jet-to-plate distance in the determination of the efficiency curves.The work of Ranz and Wong (1952) was later modified by Mercer and Chow (1968) and Mercer and Stafford (1969) so that the rather simple flow fields of Ranz and Wong (1952) could be used to account for various jet-to-plate distances. The same techniques, however, were used to determine the impactor collection efficiency curves."

Jan 1, 1986

By R. Barany

The heats of formation of goethite, ferrous vanadate, and manganese molybdate at 298.15° K were determined by solution calorimetry. For formation from the elements, the heat values were -133.7 ±0.3 kcal/mole for goethite, -453.8 ±0.5 kcal/mole for ferrous vanadate, and -284.8 ±0.2 kcal/mole for manganese molybdate. For formation from the oxides, the heat values were -0.9 ±0.1 kca1/mole for goethite, -19.4 ±0.3 kca1/mole for ferrous vanadate, and -14.6 ±O.l kcal/mole for manganese molybdate.

Jan 1, 1965

By R. Barany

The heats of formation of gehlenite and talc were determined by hydro-fluoric acid solution calorimetry. The results are reported in terms of the constituent oxides (?H298.15 = -31.1 ± 0.5 kcal/mole for gehlenite and ?H298.15 = -44.9 ± 0.3 kcal/mole for talc) and in terms of the constituent elements (?H298.15 = -952.8 ± 0.7 kcal/mole for gehlenite and ?H298.15 -1,415.5 ± 1.4 kcal/mole for talc).

Jan 1, 1963

By Alla D. Mah

Relatively pure aluminum nitride (AIN) recently has been prepared in sufficiently large amounts to permit a variety of experimental studies.4/ Several mechanical and chemical properties have been investigated, which show that this substance has good potentialities as a container for liquid aluminum, gallium, and boric oxide. The present work by the Bureau of Mines was undertaken to obtain thermo-dynamic data pertinent to the calculations regarding thermal stability and reactivity of aluminum nitride. The following measurements were made: (1) determination of the heat of formation from the elements at 298.15° K.; (2) determinations of the heat capacity over the temperature range 51° to 298.15° K. and the evaluation of the entropy at 298.15° K. therefrom; and (3) determinations of the heat content over the temperature range 298.15° to 1,800° K. These data are combined to obtain free energies of formation from the elements between 298.15° and 2,000° K.

Jan 1, 1961

By L. B. Pankratz

Enthalpies above 298° K were determined for AgCl to 1,400° K and for AgBr to 1,200° K by copper-block calorimetry. Before melting, both compounds showed an anomalous increase in enthalpy, an effect associated with lattice defect formation. Melting points and heats of fusion were determined to be AgCl, 730° K and 2,945 cal/mole; AgBr, 700° K and 2,030 cal/mole. The heat capacity of both melted substances decreased with increasing temperature over the entire liquid ranges investigated. Enthalpies above 298° K were tabulated at even temperatures along with derived entropy increments and heat capacity values. The results were combined with the known heats of formation and entropies at 29.8.15° K to obtain values of the heats and free energies of formation over the range 298.15° to 1,400° K for AgC1 and 298.15° to 1,200° K for AgBr.

Jan 1, 1970

By V. A. Nieberlein

This paper presents the results of research undertaken to recover titanium and columbium by low-temperature chlorination of low-grade columbium-bearing ilmenite concentrates, and to simultaneously remove chlorinated impurities from the volatile chlorides without resort to distillation. Coke-reduced ilmenite was chlorinated at 400° to 500° C., and the resulting TiC14 was free of most impurities before condensation. A heated purification column was used wherein various packing materials reacted chemically or physically with the impurities which passed through them in the vapor phase. A nearly water-white TiC14 product was obtained directly. The principal impurities in the titanium tetrachloride were: 0.02 percent Fe, 0.01 percent V, 0.05 percent A1, 0.04 percent Si, and 0.07 percent Cb. This is a less pure product than commercial TiC14. Most of the columbium was recovered as crude CbC15, requiring further refining.

Jan 1, 1960

By B. W. Naugle

Twenty-nine sole-heated-oven expansion teats were made on 9 different coals, and apparent specific-Brevity tests were made on 12 of the resultant cokes. The coals, which ranged in dry, mineral-matter-free fixed-carbon content from 58.7 to 81.1 percent, were tested over a rather wide range of moisture content and dry-coal bulk density to determine the separate effects of these variables on linear coal expansion. The experimental data support the follow expression relating "as-tested" coal bulk density, moisture content, and linear expansion, [ER = (1-MR) (1+Et) - 1; BDt] where ER = fractional expansion at a reference bulk density of 55.0 lb. of 1 percent moisture coal per cu. ft., Et = fractional expansion at Mt and BDt, MR = reference moisture content = 0.01, Mt = moisture content, "as-tested", BDR = reference bulk density = 55.0 lb. per cu, ft., BDt = bulk density, "as-tested", 1b. per cu. ft.

Jan 1, 1957

By R. V. Rahfuse

Noncaking 0- by 2 -inch subbituminous coal from New Mexico was gasified with air and steam at 205 prig using a stirred-bed producer to determine coal losses by entrainment in the gas for this low-sulfur, high-ash coal which contained 20 percent particles smaller than 1/16-inch sieve size. The use of fine-sized coal has particular importance because most production from mechanized mines is smaller than 2-inch size. This initial attempt showed technical feasibility for gasifying New Mexico subbituminous coal containing small-sized particles in fixed-bed producers without excessive coal loss by entrainment. Dust loss averaged about 2 percent of moisture-free coal, most of which was recovered from the gas. Ash clinkering was controlled by adding 1,010 lb/hr steam to reduce tempera¬tures in the combustion zone. Yield of low-Btu fuel gas, 150 Btu per scf, dry, amounted to 69,800 scfh from 1,490 lb/hr coal (as received) and 3,450 lb/hr air (dry).

Jan 1, 1974

By James V. Luxner

The airflow and methane distribution patterns developed in an equipment-free entry 6.5 feet high and 12 feet wide, ventilated by line brattice operated blowing to or exhausting from the face, were determined by the Bureau of Mines for varying conditions. Results of these studies show that blowing line brattice systems of face ventilation are more effective than comparable exhaust systems. The face ventilating efficiency of any line brattice system is dependent upon the method of ventilation, the face distance, the tight rib distance, the volume of air delivered to the end of the line brattice, and the volume of methane released at the face. Experimental results indicate that maximum face ventilation efficiency is achieved when the inby terminus of the line brattice is installed 5 feet from the face and at a distance less than one-third the entry width from the nearest rib. Analyses of data are based upon the ability of a face ventilation system to dilute methane in the immediate face area.

Jan 1, 1969

By J. Howard Bird

The purpose of this publication is to describe the power-distribution system of the mine and refinery of the Duval Sulphur & Potash Company at Carlsbad, N. Mex. This distribution system has been excellently predesigned to meet requirements and fit special conditions encountered at the property. In presenting the material, the authors point out various features that would be desirable for incorporation in other systems under similar conditions. Central location of switchgear in pressurized vaults and ventilation of such equipment with filtered air prevent salt accumulations and contribute to trouble-free operation. The simplification of power-distribution circuits and overload protection, as a result of centralization of switchgear, the use of individual control circuits enclosed in conduit (which aids troubleshooting), and central location of control panels, are factors which contribute to efficient, safe operation. Those features are applicable to many operations where fire or explosion hazards are encountered, or where dusty conditions may exist, as well as in operations where numerous individual drives are involved.

Jan 1, 1959

By Leroy E. Schulze

A review of development and a reevaluation of uses of the hydraulic air compressor are suggested by the constant changes in technology, which frequently make an old art valuable in solving current problems. Contacts with research workers in various branches of engineering indicate that this older method of producing compressed air may not be familiar to some or that its salient features might be useful in solving problems involving uses of compressed air. Briefly, a hydraulic air compressor may be described as an inverted siphon, consisting of an intake head where water and air are mingled, followed by a gravity-fall tube in which air is intimately mixed with the water and is compressed as the water pressure increases during the fall down the tube, then a separating, or stilling, chamber in which air bubbles rise to the surface of the water and collect in the upper portion of the chamber at a pressure equal to the weterhead maintained by the height of water in the discharge leg of the circuit. The water, which now contains only the fraction of air that has gone into solution, passes out of the separating chamber and rises up the discharge leg to the surface, which is, of course, at some suitable distance below the level of the intake. Present-day applications include (1) utilizing low hydraulic heads, which otherwise have little commercial values; (2) utilizing low hydraulic heads in reclamation work to supply compressed air, or in some instances to produce a small suction, for air-lift pumping (or for operation of air motors), with minimum attendance and without need for electric power; (3) utilizing medium heads, as at dam and lock installations, to produce compressed air for pneumatic operation of airlifts, gates, valves, and rubber gate seals; (4) utilizing underground waters, as in mines, to produce compressed air for general mine use; (5) using this method of isothermal compression of air in combination with standard compressors wherever hydraulic head is available, thereby securing the advantages of low-temperature intake to the mechanical compressors and reduction of moisture content below that of atmospheric air; (6) development of large air supply at pressures up to 150 p.s.i.g., which, after performing work in reciprocating or centrifugal expansion cylinders, is available at temperatures approximating -50° F. Possibilities in freezing and reheating should be mentioned which may prove economical for obtaining uniformly dry air for process work, wind-tunnel tests, or large air-conditioning installations, such as ventilation of underwater traffic tunnels, and may be economic for supply of supercharged air to gas-turbine plants.

Jan 1, 1954

By S. J. Aresco

The Bureau of Mines has been active in promoting the purchase of coal for Government use under specifications that define the requirements in terms of heating value of the coal, expressed in British thermal units, and the composition as shown by proximate analyses. To these, when required, are added the ash-softening temperature, the free-swelling index, and the Hardgrove grind-ability index. Under most of these specification contracts the bidders guarantee the quality of the coal, and that guaranteed by the successful bidder becomes the standard of his contract. The deliveries are sampled in accordance with instructions4 issued by the Bureau of Mines; the samples are analyzed in the Bureau laboratory to determine whether the coal is of the quality guaranteed by the contractor; if it is not, a price adjustment is made. Analyses of the delivered coal and tipple samples (samples collected at mine tipples as coal is being loaded into railroad cars or trucks) provide valuable data for use in evaluating future bids. In addition, the continuous sampling of coal as delivered is a check on the practical results obtained in burning the coal.

Jan 1, 1965

By Roy S. Nutter

An expert system advisor consultant to assist a coal mine section foreman is described in this report. The system is designed for an underground continuous miner section that is being specifically used for longwall development. The system provides three methods of operation that include normal operational mode for use underground, a training mode for use in training section foremen under controlled classroom conditions, and a demonstration mode that is free running. The Face Decision Support System or FDSS, is designed to interface with section environmental monitoring equipment and section production monitoring equipment that may appear in the future. This provides automated reprioritzation of the section foreman's job list from the system. The system 1S written in LASER which is written in C and is operated under the UNIX operating system. The objective of the entire FOSS system is to ensure that no job or piece of information important to safety or to production is forgotten because of the immediate problems confronting the section foreman.

Jan 1, 1988

By S. D. Maksimovic

The use of vertical surface degasification boreholes with bleeder systems and the use of a timbered bleeder system to degasify gob areas were studied by the Bureau of Mines. This report describes three gob degasification studies conducted in the Pittsburgh coalbed. One study was conducted to determine the number of panels degasified with one large borehole. The study showed that the borehole provided degasification for three panels. Another study was conducted during the retreat of a 35-acre panel with a single-entry and a two-entry bleeder system and a large surface borehole. A major portion of methane emitted from the panel was carried away by the bore-hole, leaving the bleeder entries relatively free of methane. The last study was made to determine the effectiveness of a timbered bleeder system. The bleeder entries successfully degasified the gob area when enough entries were available and adequate pressure was available to force the air through roof falls.

Jan 1, 1980

This appendix contains the list of equipment, their corresponding number and their specifications with the quotations from the vendors/ manufacturers who can supply this equipment. The listings are arranged by process plant areas.

Jan 1, 1979

By George S. Rice, F. B. LANEY, A. J. Lanza, Edwin Higgins

Under its organic act the Federal Bureau of Mines is directed to conduct investigations relating to the improvement of health conditions in the mineral industries. This report describes the lead and zino deposits and the mining methods employed in the sheet-ground area of the Joplin district, Missouri, and discusses the causes and the methods of abating rock dust in the mines, the chemical and physical characteristics of the dust, and the quantities present in mine air. Although the preliminary investigation included a number of the "soft-ground" mines, the writer spent the larger part of his time in the sheet-ground mines, for in them alone was siliceous dust found in appreciable quantities. Some results of the preliminary investigation have been published by the Bureau of Mines in Technical Paper 105.a The territory covered in t~lCpreliminary investigation, during the period between November 7 and December 6, 1914, embraced parts of Jasper, Lawrence, Newton, and Greene Counties, Mo., and outlying districts in Kansas and Oklahoma. The remainder of the field work, to which 84 days during the period from February 9 to July 19, 1915, were devoted, was confined to the sheet-ground mines, the most important of which are situated in the vicinity of Joplin, Webb City, Carterville, and other smaller near-by towns in Jasper County, Mo.

Jan 1, 1917

By R. R. Hornor, Harry E. Tufft

The purpose of this bulletin is to point out some of the benefits and economies to be derived by selecting, preparing, storing, preserving, and utilizing mine timber more carefully and to give some specific information on certain preservatives and processes suitable for mine timber.

Jan 1, 1925

By Joseph L. Condon

High-speed movies were taken of crater experiments in two-dimensional plates of Tennessee marble to study craters being formed primarily by stress-wave action. The contribution of gas action to the cratering process was minimized because the two-dimensional models did not contain the expanding gases from the explosive. Four burdens were studied for solid plates and one burden for a segmented plate. After cratering, the plates were reassembled for dye penetrant studies of fracturing. Flyrock velocities were calculated and related to the degree of fracturing, and compared with those from quarry shots. In general, the smallest burdens produced the highest flyrock velocities and the least amount of fracturing. Flyrock velocities compared favorably with initial flyrock velocities in quarry blasts, but did not show step accelerations due to gas effects as did the quarry blasts. The test with a segmented plate was used to simulate cratering in a jointed material and showed that stress-wave effects can be important for crater formation in jointed rocks.

Jan 1, 1972

By J. E. Murphy

Purification of samarium metal by sublimation and by vaporization from a low-melting metal flux, at the same temperature, were compared. Vaporization proved more effective for removing impurities such as magnesium, calcium, and manganese. Recovery of samarium, however, is more rapid by sublimation because of its constant rate of distillation.

Jan 1, 1970

By Henry W. Busch

Determination of the aldehyde content of Diesel-engine exhaust gas has proved rather cumbersome and unsatisfactory when carried out in its entirety in field investigations; therefore, studies were conducted with a view to developing methods by which samples might be collected in the field and trans-ported to the laboratory for analysis. Experience also indicated that aldehyde samples collected in water solution and then transported to the laboratory sometimes underwent serious changes in composition if several days elapsed between sampling and analysis. Polymerization of the aldehydes, which takes place readily in dilute aqueous solutions, may have been the cause of such changes. Because of these difficulties, experiments were conducted to find a suitable stabilizer or preservative for dilute aqueous solutions of the aldehydes that occur in Diesel-engine exhaust gas, so that in field studies a known volume of gaseous sample might be collected and brought into contact with water, and the resulting solution of aldehydes analyzed in the laboratory at some later time with reasonable certainty that the results would represent the composition of the original sample,

Jan 1, 1949