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By R. L. Grayson, W. E. Wallace, M. D. Attfield, A. Q. Wearden, P. Bolsaitis, R. D. Kennedy, M. J. Keane, J. C. Harrison

"Respirable high-silica particles from four coal mines. a clay mine and a tunnelling site were analysed for silicon vs aluminum composition by performing scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDS) at electron accelerating voltages of 20 kiloelectron volts (keV). The same particles were analysed at 5 keV to determine possible differences in surface vs bulk composition. In some cases high-silica particles exhibited a decrease in the ratio of silicon to aluminium K-alpha line intensities with decreasing electron beam accelerating voltage. This behaviour is consistent with aluminosilicate surface contamination or occlusion of a silica particle. Some 20 high-silica particles were analysed from each of 10 samples. Powdered aluminosilicate glass was used as a control for the behaviour of silica with a homogeneous distribution of aluminium in the particle. Significant differences were found between the control and sample means for an Illinois bituminous coal mine dust, two western and one central Pennsylvania bituminous coal mine dust low-temperature ashes. and a clay mine and mill dust sample, but not for an anthracite coal mine dust and two central Pennsylvania bituminous coal mine dust low-temperature ashes. INTRODUCTIONRESPIRABLE dust quartz content commonly is measured on bulk samples by using i.r. spectroscopy or X-ray diffraction. For research purposes, individual particle-by particle SEM-EDS analysis at 20-30 keV electron beam accelerating potential may be used also. Such measurements have not provided an unambiguous association of quartz content with occupational pulmonary disease prevalence in exposed workers (WALTON et al., 1977). Rather, there is evidence that coal rank modifies the relationship between dust exposure and pneumoconiosis development (WAL TON et al., 1977; ROBOCK and BAUER, 1990; ATTFIELD and MORRING, in press). SEM-EDS analysis was performed to measure the silicon fraction, Si/(Si +Ai), at 20 and at 5 keV on high-silica particles to determine if some respirable quartz particles generated by mining exhibit heterogenous composition with depth (WALLACE et al., 1990), which might affect the bioavailability of the quartz surface."

Dec 1, 1995

This manual is for use by mine operating personnel and vehicle manufacturers in the selection and proper use of automatic fire protection systems for underground metal and non-metal mining vehicles. Most of the currently available systems are manually operated, dry chemical fire suppression systems. When properly designed, installed, and maintained these systems have proven to be effective both in fire suppression and in withstanding the rugged mine environment. Portable fire extinguishers and manually actuated systems have provided adequate protection for most of the reported fire incidents. However, there have also been incidents where injuries and property losses would not have occurred if the vehicle had been protected with an automatic fire protection system. The need for reliable automatic systems exists when the operator is not present, especially when the vehicle engine is running without the operator in the cab; and also in cases where the operator leaves the vehicle to fight a small fire with a portable and is then forced to abandon the vehicle because the small fire becomes uncontrollable. In the later cases manual systems on the vehicle are never actuated. Although these incidents have been relatively few in number in the past, the increasing use of mobile diesel powered equipment and the related importance of personnel safety, high costs of the mining vehicles, and high cost of down time warrant consideration of automatic fire protection systems. The fire history data and the design concept discussed in this manual were developed under the Bureau of Mines Contract H0252038 which is part of the government's mining research safety program. The purpose of the contract was to develop a low cost, reliable, prototype automatic fire control system for underground vehicles. The industry needs were determined through an extensive mine visitation program, and the prototype system was demonstrated on a vehicle in an underground mine fire test. The system developed under this contract was specifically designed for a load-haul-dump. However, the design concept is applicable to the full general class of mobile underground mining equipment.

Jan 1, 2011

By James P. McGee

Preliminary calculations show an economic advantage in using nuclear energy to supply the endothermic heat required for gasifying coal. It should be noted that the various assumptions used in preparing these calculations must undergo further evaluation through additional engineering design and research. The proposed system for gasification is the indirect process cycle with helium heated in a nuclear reactor and passed through an exchanger-type gasifier for the reaction of coal and steam to form CO (carbon monoxide) and H2 (hydrogen gas).

Jan 1, 1960

By John E. Miller

A high accuracy Burnett apparatus for use at 12,000 psi and 0° to 65° C has been constructed at the Bureau of Mines Helium Research Center. The apparatus is patterned after Burnett's original apparatus, but the working pressure is much higher and elastic distortion can be essentially eliminated. An operating procedure to permit faster experimental measurements is suggested.

Jan 1, 1967

By Mark Flower

A 20L ignition test chamber has been used to test suspensions of 7 UK and world traded coals in air and O2/CO2 mixtures typical of oxy-combustion conditions. The coals varied in rank from sub-bituminous to bituminous and were tested in varying concentrations from the ignition limit to 400g/m3. Following each successful test the combustion residue was collected, weighed and analysed within a thermogravimetric analyser, allowing Q factors to be estimated. The ignition limit varied slightly in air, but was mostly around the 200g/m3 level. With the exception of Coal C, which was much harder to ignite, it correlated roughly with coal rank. The ignition limit changed significantly with O2 concentration when in mixed O2/CO2 gases. Only a few high volatile coals ignited in 21% O2/CO2 v/v, and then only with a 2500 J, rather than a 1000J, igniter. An increase in O2/CO2 levels to 30 or 35% gave ignition patterns similar to those carried out in air with a further increase to 40% having little additional effect. In addition the minimum ignition concentration decreased with increase in O2. Heterogeneous combustion or gasification of the coal by CO2 appears to be confirmed by comparing weight loss results for air and O2/CO2 mixtures respectively for an equivalent peak pressure rise.

Jan 1, 2009

By H. H. Hill

"The wide publicity that is given to the discover; of new oil fields has led many people to believe that our supply of crude petroleum is practically in- exhaustible and that in order to keep pace with the demand for petroleum products, it is only necessary to drill a few more wells in some of the south-western states. It is not generally realized that, although many famous fields have been developed in Oklahoma, Kansas, Texas and Louisiana during the past few years, the production of crude oil in 1919 was not sufficient to meet the demand and it was necessary to import approximately 53,000,000 barrels from Mexico.Continued efforts are being made to recover a larger percentage of the oil underground by improvements in methods of drilling and in handling producing properties. Improvements are also being made in methods for handling the oil after it has reached the surface which will result in reducing losses through leakage and through evaporation. These methods for cutting down waste in production and storage, if universally adopted, will no doubt result in appreciable increases in our supply of crude oil."

Nov 1, 1920

By K. C. Dean

A semiquantitative test for the presence and identification of cesium and rubidium in rocks, clays, and mineral waters has been developed by the Bureau of Mines. The test can be used in the field, as a guide for the prospector, geologist, or mining engineer engaged in location or development [w]ork. It comprises two simple spot tests of a solution prepared from the [m]ineral sample. Phosphomolybdic acid, added to a drop of the test solution, [d]etects cesium, rubidium, and potassium in quantities as low as 60 parts per [m]illion. Silicomolybdic acid, added to a second drop of test solution, enables the operator to distinguish between cesium and/or rubidium and potassium. Test procedures, equipment requirements, and limitations of the method are described in this report. Cesium and rubidium were discovered in 1860 and 1861 by Bunsen and Kirchhoff with a spectroscope. The elements usually occur together, particularly in granite and granitic pegmatites. Rubidium does not occur as an essential constituent of any known mineral, yet it is found as a minor element in so many minerals that rubidium is 16th in abundance in the earth's crust. Cesium, which ranks as the 37th most abundant element, is the principal component of pollucite and a minor element in a wide variety of minerals.

Jan 1, 1960

By K. L. Erickson, Gerald A. Munson

"The need for spodumene as a source of lithia for war purposes led to the exploitation of the Edison pegmatite deposit 1-1/2 miles southeast of Keystone, S. Dak. The operation was conducted during 1943 and 1944 by the Lor Mining Co., Rapid City, S. Dak. Spodumene concentrates in the ratio of 15:1 were recovered by hand picking from a sorting belt. This method was expensive and wasteful of spodumene, owing to the small size of the crystals.Data4/ obtained by the Bureau of Mines indicates that blunging with hydroflouric acid or sodium hydroxide is a prerequisite to selective flotation. Results of tests by Denver Equipment Co., Denver, Colo., indicate that economic recoveries can be obtained in an alkaline circuit after desliming.At the request of the Lor Mining Co., K. L. Erickson, metallurgical engineer, was permitted to work in the pegmatite research laboratory to verify previous investigations and to determine problems that might be involved in commercial milling. The ensuing investigation indicated that electrolytes in the mill water produced a profound inhibiting action on the flotation of Edison spodumone.An investigation of mill water from various sources showed that some waters are suitable for the process and others are not. Subsequent testing showed that all of the available waters are suitable after treatment. The flotation of the Edison spodumene in an alkaline circuit after desliming and using oleic acid as collector is efficient and economical when the water does not contain impurities.In its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B.Moon, chief, conducts preliminary examinations, performs the actual exploratory work, and prepares the final report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests. Both these branches arc under the supervision of Dr. R. S. Dean, assistant director.As the work was of a practical nature, samples from possible mill-water sources in the southern Black Hills were obtained, and commercial softening and demineralizing methods were investigated. Data on various waters tested are given in table 1."

Jun 1, 1946

By Donald H. Mullen, Walter R. Storms

"INTRODUCTION The Copper Flat area of the Central mining district, Grant County, N. Mex., has been visited by numerous engineers 4/ of the Bureau of Mines and geologists 5/ of the Federal Geological Survey. In December 1944 the Bureau. 6/ proposed that geophysical work be done in that area in order to locate favorable sites for future company exploratory and development work. This geo-physical work was begun early in 1945 but never fully completed because of insufficient funds. The engineers who made the survey recommended that more work be done, especially to locate the bottom of the Copper Flat laccolith by resistivity-depth surveys. All known minable zinc-lead ore bodies had been found above this laccolith in the Copper Flat mine, but it was thought that other minable ore deposits should occur in favorable limestones beneath it. The geophysicists also recommended core drilling beneath the laccolith.In the summer of 1946, following some mapping by S. G. Lasky of the Federal Geological Survey, funds were appropriated for a Bureau of Mines project in the Copper Flat area. The project was completed in June 1947. 8/"

Apr 1, 1948

By E. F. Ferrell

Gold was recovered from scrap electronic 60-40 (tin-lead) solders by drossing with aluminum or zinc at elevated temperatures. The gold, together with other metallic impurities, collected in the dross phase which could then be separated from the molten solder by skimming or filtering. Drossing upgraded the gold concentration by a factor of 10. Further upgrading was achieved by a combination of steps including an oxidation roast and either a combined cyanidation-amalgamation treatment or an aqua regia leach. The gold was then recovered in highly concentrated form from the aqua regia or cyanide solutions by cementation and from the amalgam by volatilization or dissolution of the mercury. The solder was purified by reaction with NaOH to remove dissolved aluminum or with SnCl2 to remove dissolved zinc.

Jan 1, 1976

By H. S. Caldwell

This report describes work by the Bureau of Mines on the vacuum distilla¬tion of some of the more volatile metals such as cadmium, zinc, and magnesium from lead and tin. Evacuation within a distillation apparatus allows rapid diffusion of vapor away from the evaporation surface and prevents reaction of the vapor with residual gases. A reduction of pressure to several tenths of a millimeter makes possible practicable distillation rates, at temperatures for which the partial pressure of the metal vapor exceeds 10-3 atmosphere. The rate and selectivity of distillation depend primarily on the volatility and molal ratios of the alloy metals, and their chemical activity to each other. For very rapid evaporation or low concentration of the more volatile constituent, the rate is determined by the rate of diffusion of the evaporating metal, to the surface of the melt. Cadmium, zinc, magnesium, and tellurium were found to volatilize readily from both lead and tin. Tellurium appears to volatilize as an intermetallic compound rather than the pure metal. Antimony could not be removed from lead at 1,000° C.; the condensate was nearly all lead. Antimony, bismuth, and lead were removed from tin.

Jan 1, 1960

By Charles W. Huggins

Knoop hardness indentations were studied and measured with the electron microscope on TiB2, HfC, and A1B12 crystals. A detailed description of replicating the indentations using collodion and Faxfilm is made. A John Hopkins grating having 28,800 lines per inch was used to accurately determine the magnification used on the electron microscope. The primary objectives were to prepare carbon replicas of hardness indentations, to measure the indenations accurately, and to compare the results with those obtained with the light microscope. The resulting data showed excellent agreement between the measurements made on the replicas with the electron microscope and those made with the optical microscope. The replicas made from collodion showed slightly better agreement with the light optical values than did the replicas made from Faxfilm.

Jan 1, 1963

By Charles P. Lazzara

Concentration profiles of low-pressure, slightly lean CH4-02-Ar flames have been measured in situ for the following unstable species: oxygen atom, hydrogen atom, hydroxyl radical, methyl radical, and formyl radical. The observed maximum mole fractions were 2.0X10-2 for H, 1.1X10-2 for OH, and 0.8X10-2 for 0; the maxima occurred in the recombination zone. Methyl and formyl radicals have maximum mole fractions in the reaction zone of 2.2x10-3 and 6x10-5, respectively.

Jan 1, 1973

By A. Wahab Khair, S. Jung

"This paper deals with the fracturing process of laterally confined blocks of coal subjected to impact indentation. During the test, blocks of coal with approximate dimensions of 10 in. x 10 in. x 6 in. were laterally confined to predetermined equivalent in-situ stresses and then subjected to an impact indentation by dropping coal cutting bits (various shapes) attached to a known weight from a known height. During the test a number of parameters, namely surface strains (using strain gages), penetration depth (using L.V.D.T.) and acoustic emission characteristics were measured. After the test, the fractured surfaces were photographed with the aid of a camera attached to a microscope. The fracture, its intensity and extended zone within the coal blocks were mapped using sonic techniques. By correlating measured parameters, fractured zones under a given set of test parameters were identified and characterized.INTRODUCTION To improve the understanding of basic failure mechanisms in coal cutting, a better knowledge of fracture and crack regions caused by the indentation in coal is needed. This study reports the detailed experimental procedure used in fracture analysis of indentation experiments on coal specimens using the Acoustic Emission (A.E. hereafter) and sonic techniques. The relationship between microcracking and the inelastic deformation of rock was confirmed by a series of experiments in which the A. E. generated by the cracking in the rock specimen were recorded and the number of events were compared to the strain measurement. (Scholz, 1967).According to fracture mechanism theory, crack initiation in brittle materials such as rocks begins from ""flaws"" either pre-existing or induced by the indentation process itself. Rocks are pervaded by natural cracks and pores, from which numerous possibilities for crack initiation arise (Lindquist, Lai and Alm, 1984)."

Jan 1, 1989

By Robert S. Sanford

This paper deals with truck haulage methods and costs at one of the many open-cut mines that are replacing rail haulage with heavy-duty trucks. At this mine, ore is trucked to a crushing plant, centrally located within one of the open-cuts. The requirements for efficient low-cost truck haulage are: Good trucks designed for heavy loads, adequate truck maintenance, smooth roads, and well-trained truck drivers The weighted average cost of hauling a long ton of ore to the crusher and the waste to the dump was reduced from $0.1993 in 1948 to $0.1114 during the last half of 1949, his corresponds to a cost per ton mile of $0.0864.

Jan 1, 1952

By R. L. Grant

At the Eighth International Conference of the Directors of Safety in Mines Research, Sartorius and Thouzea5/ presented and discussed data obtained in explosives tests made under varying conditions of humidity. These tests showed that there was less probability of explosives failure when the humidity of the testing gallery atmosphere was high. As it is to be expected that the relative humidity of mine atmospheres where permissible explosives are used will not be identical with that of the test-gallery atmospheres, the influence of atmospheric moisture upon the incendivity of permissible explosives is of the utmost importance if decreasing humidity reduces the relative safety of an explosive. Because of this and because the question has recurred frequently in discussions of gallery testing at Bruceton, Pa., it was decided to investigate the effect of humidity and ambient temperature on the ignition of firedamp by explosives, applying the small-scale gallery methods developed at the Bureau of Mines and used earlier to study the fundamental causes of such ignitions.6 7 8/

Jan 1, 1956

By W. E. Wallace, V. Robinson, M. F. Keane, V. Vallyathan

"An in vitro study of the biologic responses of surface-modified and native silica and kaolin was made to provide comparative information on the supression of cytotoxicity by pulmonary surfactant. The release of alveolar macrophage cytoplasmic enzyme, lactate dehydrogenase (IDH), and lysosomal enzymes B-N-acetylglocosaminidase (B-NAG) and B-ghucuronidase (B-GLUC) and sheep blood-cell hemolysis were moni¬tored as indicators of cell membrane damage and cytutoxicity. Surface modification of silica and kaolin with dipalmitoyl lecithin (UPI) resulted in complete abrogation of cytotoxicity of both minerals. These findings indicate that surface modification of minerals with different adsorption properties by pulmonary surfactant generally lessens their prompt adverse effects.INTRODUCTIONAcute and chronic silicosis are well-characterized clinical and pathologic entities resulting from the inhalation of crystalline silica (Morgan and Seaton, 1984). Kaolin, a layered aluminosilicate clay frequently mined and used in manufacturing, contains tetrahedral silica alternately layered with alumina octahedra. Kaolin is relatively .inert biologically, and distinctly greater pulmonary burdens are seen in patients with kaolinosis than are seen in patients with silicosis. Crystalline siliea (quartz) induces a significantly greater degree of fibrosis in exposed animals in vivo than does kaolin (Hamilton and Hardy, 1974; Parkes, 1982; Hunter, 1976; Sheers, 1964; Warraki and t-lerant, 1963; Lynch and Mciver, 1954; Lapenas et al., 1984).This difference in pulmonary disease associated with the two types of dust is not reflected by in vitro cytotoxicity as Jetermined by pulmonary macrophage bioassays or erythrocyte hemolysis. Cytotoxicity studies using crystalline silica and kaolin of similar size fractions show comparable bioassay response on a mass basis. These cellular bioassays, therefore, do not correlate with the relative in vivo pathogenicity of silicates."

Jun 1, 1988

By Vernon C. Allison

The explosibility of coal dust has long been recognized by competent investigators as constituting one of the dangers of mining coal and in the use of pulverized coal as a fuel in industrial plants. The Bureau of Mines has carried on extensive series of experiments dealing with this subject, and has not only developed methods for the practical prevention of this danger, but in the, course of these experiments has developed a standard method of determining the relative explosibility of coal dusts and other organic dusts.3 Oil shale contains compounds 'of carbon and hydrogen that are either of a petroleum nature and are strongly ,adsorbed upon the incombustible part of the shale, or else are present in the shale as a compound ("kerogen") which has the property of changing into petroleum-like products when acted upon by heat. The oil shales may contain varying amounts of the organic matter, ranging from a trace to more than 66 per cent, depending upon their richness; therefore, it is important to know whether the dusts formed in mining and handling these oil shales are explosive when mixed with air and if so, to indicate remedial measures. This paper gives the results of explosibility tests of several pulverized oil shale's, selected as being typical of those which in the future may be used in commercial shale-oil production test on a sample of typical Colorado oil shale has been., published in an earlier paper.4

Jan 1, 1926

By D. E. Stone

Solid and liquid impurities must be removed almost completely from synthesis gas for the production of synthetic liquid fuels because of their effect on the synthesis catalyst and turbocompressors. The maximum permissible concentration of dust has been set at 0.05 grain per 100 cubic feet.5/ This is one part per million by weight, or about the same concentration as in average city air. The cost of synthesis gas is estimated to constitute 60 to 70 percent of the total cost of the synthetic liquid fuel. For this reason this station is developing processes using coal instead of the more valuable coke as raw material, which promises reduction in cost of the synthesis gas. This, however, increases the difficulty of attaining the above dust value. As failure of the dust-removing equipment to produce high-purity gas may ruin valuable equipment within a few minutes, it is imperative that a reliable and continuous method be obtained for determining such extremely low concentrations .of dust in the purified gas. A suitable device must also instantly sound an alarm and, if necessary, automatically actuate the proper valves to prevent damage. The Ess Instrument Co. designed and built an instrument which they believed might fulfill these specifications. It' continually compared, by means of photoelectric cells, the intensity of a light beam passing through the gas and a similar beam passing through clean air. For maximum sensitivity, the photocells were connected back to back, i.e., anode to cathode and cathode to anode. The difference in voltage produced by the two cells was amplified and operated an indicator.

Jan 1, 1951

By C. Pritchard

John Marks said in his acceptance of the Hartman Award in 2008, "I guess that without the occasional complaint, your mine is probably over-ventilated" (Marks, 2008). Miners are seldom in this situation and spend much of the time trying to find enough air to keep an operation running. With examination, there are usually changes that can be made to increase the efficiency of ventilation systems. Mine ventilation air is a costly commodity, especially by the time it has been heated or cooled and moved to the bottom of the shaft and through the mine airways. Modifications that result in surplus mine ventilation air could bring financial and environmental benefits. Some issues mine operators have needed to address recently are increased airflow requirements to dilute diesel particulates in metal and nonmetal mines, to ventilate reserves that are deeper, hotter, and further away from fans and shafts, and to meet demands from increased production. This paper discusses successful methods to find additional usable air when there is no extra ventilation capacity. Most of the options presented in this paper are useful for metal/ nonmetal operations but some may be applicable to coal as well.

Jan 1, 2010