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By V. I. Peresypkin, A. Y. Lein, N. S. Bortnikov, Yu. A. Bogdanov

"Abstract - The lipid component in hydrothermal deposits of the Logachev vent field, at 14°45_N of the Mid-Atlantic Ridge (MAR) and Broken Spur vent field, at 29°N of the MAR, was studied. Biochemical, gas chromatographic (GS), and molecular mass methods (GC-MS) research established the mixed nature of the organic matter (OM) including phytoplanktonogenous, chemosynthesized lipids, and lipids of questionable origin. Specific local conditions around the sulfide ores of the black smokers (absence of free oxygen and presence of reduced copper, which prevents OM degradation) facilitate the preservation of biogenic material, including bacteria. The main differences between the lipid compositions of the hydrothermal deposits of these two vent fields relate to the variable nature of hydrothermal circulation systems.At the 14°45_N vent field, high-temperature hydrothermal fields are forming due to the reaction of sea water with upper mantle ultrabasic rocks during serpentinization (a deep hydrothermal circulation system). High pressure and temperature (>400°C), a reducing environment and the presence of various metal oxides are favorable for the abiogenic synthesis of CH4 and oil hydrocarbons (HC). At the Broken Spur vent field, hydrothermal deposits are forming above axial crust magma chambers due to the interaction of sea water and basalts (an axial hydrothermal circulation system). Abiogenic synthesis of HC also occurs in this situation, but to a considerably lesser extent."

Jan 1, 1999

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By R. E. Molnar, P. A. Riveros, V. M. McNamara

"This paper describes some recent research done at CANMET in the areas of ion exchange and A VR (Acidification- Volatilization Reneutralization), as applied to the recovery of gold and cyanide, respectively. It also discusses the ways in which these two technologies may be combined in order to minimize the environmental impact of gold milling operations and optimize reagent usage. IntroductionGold milling operations can essentially be divided into those that carry out a liquid/solid separation after leaching and those that recover gold directly from a leach pulp. The former produce a barren solution which may contain considerable amounts of cyanide, either free or cornplexed with metals. The latter produce a similar solution but this is now part of a slurry rather than a clear stream. Due to its toxicity, any excess cyanide must be destroyed before the effluent is discharged into the environment. Ideally, this should be (and sometimes is) accomplished by natural degradation. However, in many cases natural degradation alone cannot remove the last traces of rnetallocyanide compounds from the effluent and , as a result, most Canadian gold producers utilize a supplementary chemical oxidation system. This not only increases the operating costs, but concerns have also arisen in recent years about the formation of ammonia as a result of the chemical oxidation of cyanide (via CN--CNO--HCNO-NH3) ·"

Jan 1, 1993

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

By K. C. Lahiri, H. P. Das, G. G. Sarkar

"The petrographic components of any particular rank of coal often show some distinct physical and chemical characteristics. Therefore, their pro-portionate distribution in a coal greatly influences the technological behaviour of the coal.In any size or gravity separation of a coal, the petrographic constituents become segregated to different degrees in some preferred size or specific gravity range. Therefore, a knowledge of the petrographic nature of the washed and/or screened fractions is often considered essential in selecting the most efficient method for coal preparation and in exploring the proper evenues for its utilization.A graphical method is described in this paper to indicate the mineral-matter content and the petrographic components of the washed fractions of a coal at different ash levels of separation in the form of a new washability diagram. This diagram can be conveniently used to assess or predict the petrographic composition of clean coal or sinks corresponding to any desired ash level in the cleans. With the help of this diagram, it is also possible to locate the yield level of cleans at which maximum enrichment of vitrinites and exinites occurs with the least amount of mineral-matter content."

Jan 1, 1971

By E. Ghali, A. D. Bas

There is a lack of electrochemical studies of oxidized gold ores since the majority of previous studies were conducted with sulphidic gold ores. In this study, the influence of agitation and iron oxide minerals, i.e. magnetite, hematite, and maghemite on gold leaching was investigated by means of galvanic and passivation phenomena. Cyclic voltammetry studies of Roasted Gold Ore (RGO) in de-aerated electrolyte have shown one oxidation and one reduction reaction while three oxidation and one reduction peaks were observed with gold electrode. Galvanic coupling results by Zero Resistance Ammeter (ZRA) mode indicated that magnetite showed a negative effect on gold dissolution while maghemite and hematite showed a positive effect, relatively, as a result of higher galvanic corrosion rates. Generally, gold dissolution was found to increase in the initial 15 minutes. Increasing agitation speed from 100 to 400 rpm resulted in higher galvanic corrosion rates for RGO, magnetite, and maghemite electrodes, while 250 rpm was found to be optimum for hematite electrode. Passive products such as silver and iron-oxide were identified by XPS and SEM-EDS analysis, respectively.

Jan 1, 2015

By R. E. MacAfee

THERE have been great changes in the design, capacity, and pressure of steam generating units over the past fifty years. If we go back as far as 1890, the plants then existing were largely horizontal return tubular boilers, hand-fired, with the boilers supported on the brick sitting which was com-posed of red brick with, probably, a refractory lining one brick thick in the combustion chamber. About this time, the water tube boiler began to supplant the H.R.T. boiler and, where new plants were being constructed of any size, water tube boilers were largely installed. In those days, say from 1890 to 1905, a 250 h. p. water tube boiler was considered a large unit. These boilers were largely the straight tube type and were set with the first row of boiler tubes three to six feet above the grates. The brick setting was a combination of red brick and fire-brick. The fire-brick lining in the furnace proper was usually 9 in. thick and in the first pass 4 1/2 in., while the rest of the setting was entirely red brick. These units were largely hand-fired and were expected to produce about 100 per cent rating as a maximum. It may be well at this point to define rating, which is the evaporation of one boiler horse power per hour by each ten square feet of heating surface in the boiler. A boiler horse power is the evaporation of 34.5 pounds of steam from and at 212°F. Consequently, a boiler containing 2,000 square feet of heating surface is rated at 200 h. p. and the evaporation at 100 per cent rating is 200 X 34.5, which equals 6,900 pounds of steam per hour from and at 212°F.

Jan 1, 1939

By M. Normandin

The performance of various polymers and other macromolecules used to flocculate red mud particulate materials in the Bayer process can be evaluated on the basis of their efficiency to achieve adequate settling velocity and turbidity level, The Jar Test is widely used in the mineral industry to determine the efficiency of solid-liquid separation processes, particularly for gravity settler of the Bayer process. However, a high level of variability is found in the data obtained by this methodology, In this study, different parameters of the cylinder test procedure are evaluated to determine their role in the overall variability of the method, As demonstrated by laboratory testing, the overall variability can be considerably reduced by good laboratory practices.

Jan 1, 2005

By Ken J. Brouwer

Stillwater Mining Company commenced construction and development of the East Boulder underground mine in 1998. This new PGM mine is situated adjacent to the East Boulder River approximately 35 miles south of Big Timber, Montana. Project planning and development incorporated detailed collaboration between the regulatory agencies, concerned citizens and mine personnel. A unique ?good neighbour agreement? was established with a local environmental group who have become actively involved in the review of ongoing site development and the implementation of environmental and compliance monitoring. Environmental management systems allow for integrated management of tailings, waste rock and water in order to minimize surface disturbances and to prevent adverse impacts to the East Boulder River. Long-term site development plans contemplate implementation of comingled waste rock and paste tailings. Water management capabilities allow biological treatment of all excess mine water in order to reduce nitrogen loadings prior to land application disposal by means of spray evaporation, snow making and land application. The comprehensive waste and water management plans have also been integrated with staged mine development and interim reclamation requirements.

May 1, 2002

By L. K. Sinclair

In situ leaching of copper has the potential to deliver low-cost recovery for soluble copper deposits of sufficient permeability. In order to provide key inputs for modeling of the in situ leaching process, bench scale test work can be used in conjunction with geochemical software to identify key leaching and precipitation reactions. A case study is presented in which a series of flow-through acid leaching tests were conducted on drill core sections from a porphyry copper deposit without crushing or grinding. Concentrations of copper and other key elements were monitored in the recirculating leach solution over several months. A geochemical model of each leaching test was prepared using Geochemist's Workbench using a combination of diffusion-controlled and reaction-controlled rate mechanisms. Key reactions included leaching of chrysocolla, iron oxides, and plagioclase. The model was able to simultaneously satisfy the evolving chemistry of the recirculating leach solution, mineralogy of the head and leach residue, measured acid consumption, and leaching rates for key minerals reported from previous laboratory studies. Opportunities and limitations for scaling up the model to simulate the commercial wellfield are discussed.

Jan 1, 2015

By Richard W. Herzer

Introduction Thermal methods have been predominant in the metallurgy of the base-metals ever since the foundation of the industry thousands of years ago. Development in hydrometallurgy has been confined largely to the past six or seven decades. It was at first necessarily slow, then for a number of years rapid progress was made. At present, the uncertain state of the metal industry has curtailed research on the subject; however, in the next few years one may assuredly look forward to an ever increasing use of wet processes. Leaching methods have attained the dominant position in the case of certain metals, notably zinc. For others, they have made no headway at all. Copper presents a situation all its own. Due to the varied nature of its ores and to the large number of localities in which it is mined, a great number of processes have been developed, each suitable in its own particular field. In the case of this metal, therefore, it is more difficult to arrive at definite conclusions. It is the purpose of this paper, first, to review the outstanding developments of base-metal hydrometallurgy, and, secondly, to consider possible Canadian applications of some of the processes in use. The discussion will be confined to the three metals, zinc, lead, and copper, with particular reference to the last mentioned. Zinc General Note At present, zinc is produced by two principal processes, the older retort process and the electrolytic process. The latter is a development of the last twenty years and, judging by its present progress, bids fair eventually to supplant older methods in a large proportion of cases. It is certain, at least, that in the erection of a new plant, a hydrometallurgical process would be given the most serious consideration

Jan 1, 1934

By George Kellock

Introductory The Alberta Provincial Government has contemplated a revision of the Mines Act for some time past, and it is understood that a definite decision has now been made to do this at the next session of the Legislature. The Operators' and Miners' organizations of the Province have been asked, or at least have been given the opportunity, to submit their views and ideas relative to the proposed changes. The operators have already drafted out a number of changes which they feel would improve the Act from the standpoint of safety and practicability, and this paper has been prepared so that the general membership of the Rocky Mountain Branch of the Institute, which is composed largely of the operating and certificated officials of the mines, might have an opportunity to discuss, criticize, and improve upon the suggested changes which the operators are putting forward.

Jan 1, 1929

By V. V. Severov, Z. Lafhaj

The flotation separation of salt type calcium minerals is problematic, due to the similarities in their formation properties and the same active Ca2+ related site for interaction with anionic collectors and similar physicochemical characteristics such as solubility, point of zero charge, surface speciation, Ca-site density. The work was performed to achieve effective and selective separation of the calcium-minerals using pure minerals samples: four calcite, two fluorite, and two apatite samples. The effect of pure and mixing anionic collectors such as oleic and linoleic acid to different ratio (2:1; 1:1; 1:2) as well as the role of nonionic collectors on the selective separation of Ca minerals were studied. All flotation tests were performed in self-aspirated flotation cell. The results obtained with the blend of anionic collectors with the molar ratio of 2:1 show a separation between apatite and calcite at pH 5 and a ratio 1:2 at pH 9. The enhancing of separation contrast using the sodium silicate as a depressant for calcite and apatite is also examined as a function of oleate/linoleate ratio. Additionally, this paper discusses the enhancing of the selective separation of Ca minerals when anionic collectors were blended with nonionic reagents. The surface reactions in aqueous mineral suspensions and the adsorption of anionic collectors blended with nonionic reagents were studied by FTIR spectroscopy. An unexpected synergistic effect was observed for some ratios between anionic and nonionic reagents. The mixture of fatty acids and nonionic reagent showed very high flotation efficiency in comparison with fatty acid alone for the flotation of an igneous low-grade phosphate ore.

Jan 1, 2016

By W J. Dyck

Past attempts to establish an integrated steel industry on the West Coast of Canada have been unsuccessful for at least three reasons: (a) insufficient reserves of a suit-able iron ore supply; (b) a relatively small local market for iron and steel; and (c) the non-availability of an economical process to produce primary iron on a small scale. Today, the reserves of economically mineable ore deposits are ample to support a steel production of 100,000 to 200,-000 tons per annum. The local market has increased so as to be able to absorb most of this capacity. With-in the next few years, a small integrated steel plant, including the "H-Iron" direct iron ore reduction process for electric furnace charge stock production, will be able to show a profitable operation. Introduction

Jan 1, 1963

By M. J. Gagnon

The agglomeration of particulate materials is used in many mineral processes to enhance the settling of the fine particles, Depending upon many physical and chemical parameters, the aggregates demonstrate specific density-size distributions, In this study, a fractal model of the agglomeration process is introduced, Based on reliable experimental data and on physical calculation, the model presented helps to envisage the initial formation of the micro-flocs, and to interpret the subsequent interactions between the aggregates in terms of either coagulation or flocculation, Data from different sources, materials and different agglomeration processes are analysed and compared in the light of the proposed model.

Jan 1, 2005

By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By D. Yuan, M. Sitter, S. St. Jean, M. Collins

The Ambatovy Joint Venture comprises an operating lateritic nickel mine, ore slurry pipeline, pressure acid leach plant and nickel refinery in Madagascar. The hydrometallurgical process selected by Sherritt for treatment of the Ambatovy ore is a long-term, sustainable approach to producing nickel. Sulphur, used to prepare hydrogen sulphide, which is used to produce mixed sulphide intermediate, is recovered in the refinery as ammonium sulphate fertilizer. Additional sulphur is used to generate sulphuric acid for treatment of the ore in the high pressure acid leach (HPAL) step; fossil fuel consumption is minimized by using the heat generated from the exothermic reaction between sulphur and oxygen in the acid plant to produce power and steam. Steam consumption is minimized by design of efficient flashing and preheat systems for HPAL, while the high temperature of the HPAL step serves to minimize acid consumption. Fossil fuel consumption by the operation as a whole is further minimized by locating the leach plant and refinery near the port of Toamasina and utilizing a 220 km slurry pipeline to transport ore from the mine to the leach plant. In addition, Ambatovy has demonstrated a strong commitment to sustainability programs such as the biodiversity management program at the mine and local procurement in Madagascar. In this paper, the hydrometallurgical process for nickel and cobalt recovery from Ambatovy ore is described, along with highlights of Ambatovy’s approach to sustainability in Madagascar.

Jan 1, 2015

By J. A. Reid

THE views and observations expressed herein on this old but constantly recurring question are our own, no effort having been made to align them with standard texts. Therefore, while they may find general acceptance amongst fellow engineers, they must stand as personal opinions and as such are open to debate and discussion. In order properly to consider the subject, it should first be 'set in proper perspective. Why are Prospects Examined? Prospects are examined to determine whether they may contain economic concentrations of metals or minerals, the legitimate mining business being run, pretty largely, to make money. Next to food and clothing, modern civilization is based on metals, with which are included in this discussion minerals, oils, and fuels. A constant and increasing demand for the common metals requires the location of replacements for depleted orebodies, while the use and appreciation of new metals brings increasing demand for them. Aluminium is a good example of a metal which has, within recent years, made great progress. Today, we are becoming increasingly aware of magnesium, chromium, tungsten, thallium, and other lesser known, metals.

Jan 1, 1945

By R. K. Collings

The annual production of mineral and mineral-based wastes in Canada is conservatively estimated to be 400 million tons. Over 90 per cent of this amount is waste rock or mill tailings from the mining and mineral processing industry. The remainder are slags and ashes from the metallurgical industry, and sludges from the chemical industry. Because of impurity content, remote location, or both, most wastes have limited usefulness and, indeed, are a liability in that they must be transported to waste disposal sites and contained therein. Certain mineral wastes do, however, have potential value. Some contain small percentages of metals that may be economically recoverable with price increases; others consist of mineral material that may be used for such purposes as road base, construction aggregate, railroad ballast, and in the manufacture of bricks or blocks. Increased interest has been shown in mineral wastes in recent years. This paper reviews the types of mineral wastes available in Canada, briefly describes a number that have potential value, and notes possible uses and related research by CANMET and other organizations.

Jan 1, 1978

By E. O. T. Simpson

"IntroductionAS COMPARED with coal mines in the United States, and even with some of those in eastern Canada, the coal mines of western Canada, generally speaking, :have made little progress toward mechanization at the working faces. So far as Vancouver island is concerned, there are three main reasons for this : ( 1 ) in some areas, conditions• easy for hand-loading but unsuitable for mechanical loading make high outputs per man •possible by the former method; (2) faulting of the coal seams in ..some areas precludes long-term planning and the introduction and efficient use of expensive equipment; (3) thinness •and other characteristics of the seams in many areas favour hand-loading.No. 8 MINENo. 8 mine of Canadian Collieries (Dunsmuir), Limited, is located in the Cumberland sub-area of the Comox coalfield on Vancouver island about 90 miles west-northwest of Vancouver. The geological structure of this coalfield has been described by J. D. McKenzie. The seams occur in the Comox formation, a subdivision of the Upper Cretaceous Nanaimo Group. The formation is of near-shore origin and was laid down on an irregular surface of' older rocks. The irregular generally have a northeasterly dip, modified by gentile folds and by a •few large, and a number of smaller, faults.Four seams have been worked in the Cumberland area and all vary in thickness and in the amount and number of interstratified bone and rock •bands."

Jan 1, 1953