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By Fabio Terzi

In this investigation some preliminary results are reported about the electrochemical oxidation of CO using goldbased encapsulated nanoparticles grafted on conducting substrate. The investigation has been planned in four steps: 1. production of Au(111) substrate and modification with self assembled monolayers; 2. synthesis and embedding of nanoparticles; 3. grafting of encapsulated nanoparticles on electrode substrates; 4. investigation of CO electroxidation on the modified electrode. The systems were characterized by means of various techniques (spectroscopic, microscopic, and electrochemical methods), obtaining information about SAM's structure and morphology, size and composition of nanoparticles and electrochemical behavior of modified electrodes.

Oct 1, 2003

By A. E. Wraith, R. Harris, J. Qiu, R. Parra

Small pilot scale experiments have shown that it is possible to almost fully eliminate the minor elements (ME), namely As, Sb, Bi and Pb contained in smelter dusts by vacuum calcination of mixtures of the dust with sulphidizing agents such as dirty copper concentrate or elemental sulphur at 900 °C and 80 +/- 30 Pa for 90 minutes. The products of this calcination are a residue comprising a purified mixture of copper containing compounds along with the gangue constituents and a high sulphur condensate comprising a mixture of the minor element compounds. In particular, the Cu:ME ratios of the concentrate and dust were increased from 250 and 50, from 28 and 12 and from 36 and 8 to roughly 3000, 3000 and 100 for the calcine, for Bi, As and Sb, respectively. It has also been calculated that (i) the copper content of the vacuum calcine may be recovered by feeding it into a Peirce-Smith converter during its slag blow, and (ii) the resulting recycling could increase the minor element treatment capacity of a smelter by 100 % while also reducing the blister As content by a factor of three. The experimental results are briefly discussed and a treated dust recycling option is examined. Example operating conditions are presented and available commercial technology for the vacuum calcination of the mixtures is reviewed.

Jan 1, 2007

By G. Scamans, J. Lazaro-Nebreda, Z. Fan, J. B. Patel

"Melt quality is crucial for both continuous and shape casting of light alloys and in order to improve it, removal of excessive inclusions, accumulated impurities and unwanted gases becomes necessary. To address this problem, a new multi-purpose high shear liquid metal treatment technology, based on intensive melt shearing by a rotor/stator unit, has been developed. The device ensures achieving uniform temperature and chemical composition and an efficient dispersion of gas and solid phases in the melt with minimal disturbance of melt surface, and can be used, among other things, for de-gassing and de-ironing of Al-alloy melts. Efficient degassing is achieved by dispersing each argon bubble into many small ones, which significantly increases the overall surface area of the bubbles and the time they remain in the melt capturing hydrogen before reaching the surface. This allows using much lower inert gas flow and mixing times than conventional rotary degassing. When applied to Al-alloy scrap, with accumulated iron, the high shear melt treatment speeds up the nucleation and growth of primary Fe-rich intermetallic particles, allowing a faster removal rate. Therefore it reduces processing times, increasing recycling productivity, and facilitates full metal circulation of secondary Al-alloys.INTRODUCTION Aluminium and magnesium alloys are widely considered in various industrial sectors for the purpose of weight saving (Polmear, 1995). In particular, they are used in the automotive sector, where components are mostly manufactured by high pressure die casting (HPDC) because of its simplicity and relatively low cost, but efficiency and mechanical properties are quite low compared with other processes. To date, the main focus to overcome this problem has been for improving the HPDC machinery (Dahle, 2001) but little attention has been paid to the opportunities of controlling the nature and quality of the molten metal supplied to the die. In this way, liquid metal treatment, which involves a variety of physical and/or chemical processing methods to improve melt quality prior casting, is crucial for both continuous and shape casting products."

Jan 1, 2018

By Carrasco .. P. J. A., R. Parada, I. Saavedra, F. Parada, R. Parra, E. Balladares

In most of the smelters, the management of flue dust has a double objective: the control of minor elements in the anodes and the management of volatiles compounds that can cause contamination due to fugitive gas emissions. This is a special concern when high content of Va elements (As, Sb & Bi) are present in concentrates. We present the results of the experimental study to prove the principle of a novel process that recovers, via volatilization, the As, Sb and Bi in the flue dust as gaseous sulfides, due to a previous sulfidization. In the case of as control any further classical treatment for its stabilization is possible from the gas. The clean calcine can be returned to the smelter avoiding any concentration of these minor elements in the circuit. This process is now tested at pilot scale and shows better indices on carbon footprint than the classical hydrometallurgical process for flue dust.

Jan 1, 2011

By E O. Foster

When roasting started at Giant Yellowknife Mines in 1949, it became apparent that, to prevent air and water pollution in the surrounding district, it would be necessary to collect the arsenic that was contained in the exit gases of the roaster. The arsenic collection problem was finally solved by the installation of both electrostatic and baghouse collectors. It was realized that a considerable quantity of gold-bearing dust was leaving the roaster with the exit gases. When the collection problem was solved, it was possible to measure this loss. The loss proved to be considerable and it became evident that a substantial quantity of gold could be recovered. Research programs on dust treatment began in 1958, and by May, 1960, the treatment process which is currently being followed was started in the plant. At present, the two electrostatic preci11itators, Operated at temperatures above 600°F, collect the gold-bearing dust.

Jan 1, 1963

By D. Campbell

Mining activity is increasing in northern boreal and subarctic regions of Canada. This is the case in the far north of Ontario, especially in and near the Hudson Bay Lowland (HBL). De Beers Canada opened the Victor diamond mine in the centre of the HBL in 2008, and advanced exploration and impact assessments are occurring to the west in the ?Ring of Fire? for ferrochrome, nickel/copper, iron/ vanadium and platinum-group elements, making it one of the richest mineral finds in Canada in recent years. However, the HBL is also a near-pristine, sensitive environment. Its peatlands forms the third largest wetland in the world and are globally important stores of terrestrial carbon. Human populations in the region are sparse, consisting almost entirely of First Nations communities. Local First Nations also have a strong land ethic and greatly influence mining developments. Through formal agreements, they have insisted on a gold standard for environmental management, including a small mine footprint and the return to representative native ecosystems after mine closure. However, knowledge on the revegetation of subarctic and northern boreal ecosystems is limited. Here, we are conducting research at the Victor mine to develop gold standard protocols for the revegetation of disturbed peatlands and mine waste uplands and present a summary of results. We first tested existing protocols for peatland restoration from southeastern Canada. We collected peat-forming plants from nearby muskeg, spread them sparsely over disturbed peatlands and applied a light phosphate fertilizer, but unlike southern protocols, no mulch appeared to be required to produce a representative cover of peat-forming plants within three years. A bigger challenge is the reclamation of uplands made of mine waste back to representative ecosystems. We first characterized reference conditions for uplands in the HBL, which are scarce in the region. Nearby natural uplands were divided into two classes, interior uplands and uplands along river valleys. Multiple parameters were examined at these sites including soil development, bulk density, soil chemistry in the rooting horizons, plant cover by stratum, plant species composition and dead wood. The mean condition and, more importantly, the range of these parameters allow us to set broad targets for progressive reclamation, which will facilitate success. Finally, we characterized local upland plant species through their functional traits to determine their likely abilities to colonize, grow and contribute to ecosystem processes. A classification of species by these simple functional attributes will help restoration managers to select candidate species to meet different goals at different successional stages (i.e. good versus poor dispersers or establishers). Research into these protocols remain in the early stages, but show promise that gold standards can be achieved to ensure that mining wastes can be reclaimed to productive ecosystems.

Aug 1, 2013

By Jacob W. Young

A casual reading of the geological literature extant to-day would give one the impression that carbon is an element which by some chance or another always existed at or near the surface of the earth, and was never of a magmatic origin. The carbonaceous matter in shales is said to be of vegetal derivation; petroleum is stated to have been derived from vegetable matter or from marine animal bodies; if carbon or bituminous matter is found in igneous rocks or associated with metallic ores, the statement is made that deeply buried carbonaceous sedimentaries were undoubtedly the source from which such carbon or bituminous matter was derived. This, I do not consider a reasonable or common sense view of the matter. Carbon is one of the elements of which the earth is composed. In the table giving the periodicity of the elements it comes sixth in the order of increasing atomic weights. It is an element formed like all the rest were formed, and must be as common to the interior of the earth as the rest of the eighty-odd elements so far discovered. The spectroscopic analysis of light from the sun, and the stars, shows the presence of carbon in the sun and in the colder stars. Thus with carbon, an element, found throughout the universe as well as on the earth, it is entirely reasonable to consider it as present in the interior of the earth with the other elements. Such being the case, the magmatic origin for the various forms of carbon in rocks and ores is a rational and logical conclusion. If but a small fraction of thought and effort was made along these lines, which is made in fostering the idea of the organic origin of the carbon found in the earth's crust, untold advances in this phase of geological science would result.

Jan 1, 1925

By E. Chiyangwa, L. Schoeman

The commercially successful electrowinning and refining of metals typically requires the optimization of the electrolyte composition and operating parameters to produce high quality compact electroplated metal. The prediction of the effect of the electrolyte composition on the structure and morphology of the plated metal remains a challenge. Initial work on the use of polarization measurements to predict and control plating behaviour in electrowinning plants involved potentiodynamic polarization but proved unsatisfactory as accurate and repeatable predictions could not be achieved. The aim of the present work was to develop a reliable galvanodynamic technique specifically applicable to the plating of zinc from sulfate electrolytes with which plant operation may be controlled and optimized. Initial results indicated that plating and nucleation potentials could be measured accurately and repeatably and that the relationship between the two could be used as a predictive tool for the effect of electrolyte composition on the quality of zinc electrodeposits.

Jan 1, 2014

By T. G. Joseph, A. Chamanara

ABSTRACT: The chicken and egg scenario — where adverse truck motions cause ground deterioration and poor ground profiles cause adverse truck motions — is a downward deterioration spiral dominating our industry. If we remove one action, the reaction stops. A simple truck to excavator load data analysis and wireless communication system is outlined, which will provide visual assistance to the excavator operator in achieving improved load placement and balance in a truck body. This will reduce subsequent hauler duty cycle adverse motions and g levels that contribute to structural fatigue, higher tkph, reduced tire life, and ongoing maintenance of haul roads.

Jan 1, 2012

By K. Mayhew, K. Murray

The CESL Copper Process was developed as a hydrometallurgical alternative to smelting and refining for copper sulphide concentrates. As the majority of such concentrates contain appreciable gold and silver values, effective recovery of these metals is essential to the economics of this technology. Unfortunately, conventional cyanide processing cannot be used on the residue from the copper process, clue to its unusual characteristics when compared with naturally occurring gold and silver ores. An abundance of elemental sulphur, as well as the presence of cyanide soluble copper, leads to the formation of both thiocyanate and copper cyanide which is detrimental to process economics clue to excessive cyanide consumption. This, however, can be reduced to acceptable levels by process innovations such as pressure cyanidation and cyanide recovery. This paper outlines the successful application of the CESL Gold Process to various gold-bearing copper concentrates from bench to demonstration scale.

Jan 1, 2011

By M. B. Shongwe, R. K. K. Mbaya, C. K. Thubakgale, P. Mendonidis

"A low-grade nickel-bearing ore was pre-concentrated on a SB40 laboratory model Falcon Concentrator. Three size fractions, -212+125, -125+75 and -75 µm were tested with the intent to upgrade the nickel content by reducing their content of fine silica, which becomes amorphous during leaching. Separation of silica from nickel-bearing magnesium silicate minerals; hornblende, clinochlore and talc, was more efficient in the finer particle sizes, -125+75 and -75 µm, and at high G-forces. For these two size fractions, nickel was upgraded from 0.06 to 0.07%, with a reduction in silica content from 52.12 to 50.71%. Leaching of feed samples prior to pre-concentration resulted in the formation of amorphous silica, indicative of the presence of fine silica in the samples. Leaching of nickel from the -125+75 µm fraction increased with increasing G-force and feed pulp percent solids, while that of -75 µm was not influenced. The optimum nickel recovery was 15.68% to the Falcon underflow, using the feed size fraction of -75 µm, 30 G and a feed pulp solids content of 10% solids, after 120 minutes of treatment.INTRODUCTION A low-grade South African nickel-bearing ore with about 0.06% Ni was previously studied for atmospheric pressure acid leaching using sulphuric acid. The study was motivated by the continuing search for methods to treat of low-grade ores, which appear to be an increasingly important source of valuable metals as a result of a declining production from rich sulphide ores. Nickel is a base metal that is used as an alloy in steelmaking and chemical industries because of its resistance to corrosion (Haudet et al., 2015). Nickel laterite ores with grades lower than 1.50% Ni are considered to be complex ores, accounting for 70% of the global nickel reserves (MacCarthy et al., 2016). Their complex nature may be attributed to the indefinite mineralogy of these ores, in which nickel may occur in more than one mineral host. In some cases, nickel may be finely disseminated in the ore. The grade of such an ore and complex mineralogy do not justify the application of pyrometallurgical methods for extraction of nickel (Zhu et al., 2012). This suggests that there is a need for less expensive alternative methods of extraction. This study investigates the application of centrifugal gravity concentration, using the Falcon concentrator, followed by leaching to determine the effect of pre-concentration of the ore prior to extraction by atmospheric pressure leaching with sulphuric acid."

Jan 1, 2017

By E. R. Weltevreden, C. Klauber, C. Vernon

"In this paper a review of the current status in recycling technologies for cathode ray tubes is given for both the glass and phosphors. Particular emphasis is placed on the opportunities for the recovery of the rare earth elements (REE) from the phosphor coatings. This is placed in the market context of alternative virgin sources and some of the advantages and disadvantages for REE waste recovery. Future opportunities are explored and also some experimental detail on a low cost leach system is presented. INTRODUCTIONThe disposal of cathode ray tube (CRT) based colour televisions has accelerated world-wide with the development of high definition flat screen panels. The total number of colour CRT televisions that have been sold in the United States in the mid-20th century is estimated to have been over 2 billion (U.S. Environmental Protection Agency, 2007), with high current rates of disposal. It is estimated that of the 20 million televisions annually discarded, 78% are send to landfill (Nnorom, Osibanjo & Ogwuegbu, 2011). However, this easily accessible item of electronics cannot only be turned into a valuable resource using the right recovery procedures, it can also prevent the substantial environmental contamination arising from improper disposal. In this review we focus on previous and current work performed on the recycling of CRT based televisions. Due to the increasing demand for rare earth metals, the main focus will be on the possibilities and challenges of recycling the fluorescent phosphor powders on the CRT’s panel glass.CATHODE RAY TUBE’S GLASS RECYCLINGConventional cathode ray tubes consist of three main parts, the panel, the funnel and the neck (Figure 1). To produce the different colours on the screen, the inside of the panel is coated with a matrix of hundreds of thousands of small phosphor dots. Each dot is one of three types of coloured phosphors, emitting either red, green or blue light. These emit light when excited by a beam of electrons generated by electron guns located in the neck of the CRT. These beams pass through holes in the shadow mask and excite the phosphor coating on the inside of the panel, to give light of variable RGB composition, see Figure 1."

Jan 1, 2012

By A. Y. Senchenko, Y. V. Kulikov

"In recent decades HPGR technology has proven itself in comminution circuits of mining plants. High technical and economic performance, lower specific energy consumption and reliability of HPGR equipment makes it an efficient alternative to conventional circuits using stage crushing and rod/ball milling, as well as to AG/SAG circuits. However, despite all the advantages of this technology the correct selection of key and auxiliary equipment is very important since errors at testing and design stages may lead to discrediting of the whole concept of HPGR application. There is a great variety of possible circuit configurations using HPGR, e.g. with circulation of edge product, with crushing of the whole discharge and circulation of screen oversize, successive two-stage crushing, etc. Each type of minerals will require its own optimal crushing circuit. In this context the testing methodology for selection of an optimal configuration becomes of prime importance. It is common knowledge that the best simulation of material crushing and softening within a HPGR can be obtained only in the course of a large-scale pilot test. The main approaches applied to this kind of testworks are described in this article. Special aspects of HPGR technology design and industrial operation are revealed as well. Some operational issues of HPGR equipment and of circuit as a whole were detected. They are related to regions specifics, plants location, and other factors. Process solutions proposed to deal with these issues are also indicated in the article. INTRODUCTIONDesign and construction of the processing plants involving High Pressure Grinding Rolls (HPGR) technology becomes more and more common in mining as this technology has specific technical and economic advantages against the circuits with autogenous/semiautogenous mills (AG/SAG) and other circuits. The main advantage of the technology is low energy consumption and low operation costs respectively. The presence of microcracks and increased content of fine size fractions in the crushed product contribute to reduction of energy required for further ball grinding. Besides, HPGR technology applies a special wear resistant liner that enables significant reduction of operation costs of grinding media and liner comparing with AG/SAG circuits."

Jan 1, 2016

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

By P. E. Cavanagh

FOR THE PAST seven years Mr. W. Simpson, Chief Mechanical Inspector for the Nova Scotia Department of Mines, has carried out exhaustive field trials of non-destructive inspection equipment in the coal mines of that Province. This work has demonstrated the usefulness of a number of types of non-destructive inspection when used for periodic inspection of hoisting and haulage equipment in the coal mines of Nova Scotia. As a result, the Dominion Coal Company has instituted a programme of regular preventive maintenance inspection ?by a special staff of qualified and trained men. The purpose of this present paper is to describe how non-destructive testing techniques are used on ropes, axles, couplings, and other hoisting and haulage equipment, how these methods are being used in other industries, and the expected benefits from intelligent and properly organized use of these techniques in the coal mining industry.

Jan 1, 1956

"The successful commissioning and ramp up of the Albion Process™ at the GPM Gold Project relied on the successful scaling up of the process from batch and continuous pilot plant campaigns (Voigt et al., 2015). Critical information about reaction kinetics and residence time, grind size and pulp density were determined at the laboratory scale and successfully applied to the commercial scale. A limitation of small scale testwork, is that some parameters cannot be measured reliably and scaling up is a function of the physical size of the equipment which isn’t possible to test with laboratory scale equipment. Oxygen mass transfer rate is one such parameter since this is a complex interaction of many factors including slurry temperature, solution and slurry chemistry, slurry viscosity, agitator type, dimensions and power, oxygen bubble residence time, oxygen purity, tank geometry and oxygen injection technique. Oxygen generation represents an important operating cost for the Albion Process™. Pivotal to the Albion Process™ operating economically at atmospheric pressure is the capability to efficiently transfer oxygen while utilising as much oxygen injected to the process as possible. To respond to this Glencore Technology developed the HyperSpargeTM supersonic gas injector. This paper compares the HyperSparge™ against other sparging techniques to quantify the benefits of oxygen injection via a supersonic gas jet on scale up of the oxygen mass transfer system. The paper then examines plant survey data from the GPM Gold Project to demonstrate the very high oxygen utilisation that can be achieved with a correctly designed oxygen mass transfer system.INTRODUCTION One of the main challenges in chemical reactor design is the scale-up of processes from the laboratory to industrial scale. Processes which cannot be faithfully simulated with an experiment at the laboratory scale face challenges due to the physical dimensions and complexity of full scale operation. One example of this is the design of oxygen mass transfer systems in atmospheric oxidative leaching circuits such as the Albion Process™. A number of constraints associated with the use of laboratory scale equipment to design full scale circuits are involved in gas mass transfer processes in agitated slurries such as the Albion Process. Chiefly, typical laboratory and pilot size equipment lacks the required volume to provide useful design data without relying on empirical correlations: the specific agitator power input is artificially high, the bubble residence time in the vessel is artificially low, the oxygen partial pressure at the base of the vessel is artificially low and the oxygen delivery method may differ significantly to the industrial process. Further, the dynamic nature of the process introduces additional impacts on gas mass transfer, including the presence of solids, recycle streams and minor elements, plus the variances within the reality of a process plant such as disruptions or variance of feed quality."

Jan 1, 2017

By F. P. Hassani, Jacque Ouellet, M. Hossein

A laboratory investigation was undertaken to evaluate the effectiveness of different binding agents in a paste backfilling operation suitable to be used in a sulphide-rich environment. Different combinations of Portland cement and fly ash type C as well as ferrous slag were used as the binding agents. The unconfined compressive strength of the samples was measured for extended curing periods. The results indicate that the addition of 3% slag in the binding agent mix could produce strengths up to 0.5 MPa in the samples under investigation. For higher binding contents, the addition of Portland cement will lead to higher availability of calcium hydroxide and calcium aluminate, which are susceptible to deterioration from the phenomenon known as sulphate attack. Using slag, on the other hand, will reduce the permeability, availability of calcium hydroxide, and dilute the calcium aluminate ions reducing the susceptibility of the samples to sulphate attack. However, gypsum will form which could have the same detrimental effect on the strength of the treated matrix. Therefore, special attention must be given to the content and properties of agents used to activate the pozzolanic properties of the slag.

Jan 1, 2001

By V. A. Chanturiya, T. N. Matveeva, N. K. Gromova, T. A. Ivanova

"The research is aimed at solving the problem of increasing the extraction of gold from refractory ores, which are the main source of growth in gold production in the next decades. The purpose of the research is the development and scientific substantiation of the reagent modes for flotation extracting of gold from refractory ores using eco-friendly low-cost herbal modifiers (HM), providing increase in gold recovery and quality of gold concentrates. In the course of research laboratory techniques for the preparation of experimental samples of HM were developed, which included the sequence of operations of grinding Heraclium leaves and stems grinding, 2-stages extraction at a temperature of 50-60 °C, short-term ultrasonic treatment, filtration and subsequent unification of extracts. According to the developed method, the experimental samples of HM and conducted research were tested to analyze their sorption and flotation activity related to the extraction of gold from refractory gold ores.New data on adsorption and flotation properties of Heraclium stems and leaves extracts (HSE) in selective flotation of Au-sulfide minerals were obtained using UV-spectroscopy, scanning electronic and laser microscopy and atomic force microscopy. The dimensions and shapes of adsorbed hydrophilic films of herbal reagents were identified and mechanism of formation of stable insoluble compounds on the surface of minerals in flotation was explained.Research flotation tests carried out on samples of refractory gold ore of one of Russia deposits showed the possibility of effective use of herbal modifiers to improve qualitative and quantitative indicators of enrichment compared with the standard reagent regime. New reagent modes, using herbal modifiers in an amount of 5 to 10 ml of the extract (300 - 600 g / t, respectively) improves the quality of the concentrate: gold content attains 14.7 g / t, 1.34 times higher than in the baseline experiment and provides a gain of 3.13% extraction.The developed reagent regime with herbal modifiers is the author's original design, patented (patent of the Russian Federation) and have no analogues in the world of mineral processing. (Application number 2015116125 from 04.28.2015, ""The method of flotation separation of sulfide minerals using herbal modifier"", Russia). Actual application of new plant extracts as modifiers in flotation of sulfide minerals is the possibility of replacing of highly toxic chemical compounds by environmentally safe substances of plant origin. Implementation of the developed methods of extracting gold from refractory minerals with herbal modifiers will help to improve gold recovery at 3-5% and the quality concentrate of not less than 1.2 times, leading to higher productivity and a reduction of the negative man-made effects on the environment ."

Jan 1, 2016

By Abu Syed H. Kabir, Mehdi Sanjari, Steve Yue, Jing Su, In-ho Jung

AZ31 magnesium alloy sheets were produced by high speed rolling (HSR) at 1000 m/min at a low temperature of 100 ?. A high reduction of 72% can be achieved in single pass. At the reduction of 30%, the microstructure was covered by shear bands and twins. When the reduction was increased to 49%, dynamic recrystallization (DRX) was clearly observed in the vicinity of shear bands and twins and the full recrystallization was seen at a reduction of 72%. In order to study the static recrystallization (SRX) behavior on the heavily twinned structure, annealing was then carried out at 200 ? on the as-rolled specimens at the reduction of 30% for different times. Static recrystallized grains were also firstly observed on shear bands and twins after 45 s and the microstructure was mostly fully recrystallized after 1 h annealing with a few retained large elongated un-recrystallized grains. Texture weakening was found during annealing on the heavily twinned specimens by SRX, but not during high speed rolling by DRX. In the present study, effect of DRX and SRX on microstructure and texture evolutions during rolling and annealing were compared.

Jan 1, 2015

By R. Pandher, R. Schonewille

Advanced process modelling tools were developed for the Xstrata Nickel Sudbury Smelter flow sheet using a combination of FACTSAGETH METSIMTM and ARENATM software. These tools were employed to assist with plant optimisation, emission control, process design, troubleshooting and case studies as applied to the smelter. The development of process modelling tools in pyro-metallurgy commonly involves an in-depth study of the therm o-chemical properties (heat capacity, liquidus temperature, etc.) of all high temperature phases, usually matte and slag. The preferred tool for this purpose is FACTSAGETM, a well-known then-no-chemical modelling software package. The results from the therm o-chemical model have been subsequently incorporated into the development of a process model for the entire smelting facility using the METSIMTM platform. Such process model also includes a number of special features adopted to effectively simulate the complex industrial phases; matte and slag systems. To ensure the robustness and reliability of the process model, several process parameters and assumptions were verified with laboratory and plant data. Consequently, the model includes the ability to examine the impact of a number of plant parameters on potential plant performance. Primary variables are the percent sulphur elimination during concentrate roasting, furnace matte grade and degree of matte metallization. Key output parameters include operating temperature, furnace coke requirement, sulphuric acid production, CO2 emissions and overall energy requirements. Selected outputs from the process model (for example blowing time, slag production rate and matte converting rate) can then be utilised in the development of a discrete event model (DEM) for the smelter using ARENATM software. Incorporation of reliable and validated mass balance parameters enhances the robustness and reliability of the DEM model. The integration of then-no-chemical, process and DEM modeling tools has a distinct advantage in planning plant trials and examining process design initiatives at Xstrata Nickel's Sudbury Smelter. The present paper discusses the development of these three models and the synergies existing among them. Typical results from all three models are also presented.

Jan 1, 2011