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By Paul M. Tyler

Hafnium appears to be among the more abundant of the newly discovered elements . Though quite widely distributed in nature , its compounds chemically so resembled those of zirconium , its sister element , that it escaped detection until 1923 , when Coster and Hevesy announced the discovery of the element , to which they gave the name of " hafnium " , from Hafniae , the Latin name for Copenhagen , where their research work was performed . Hafnium has so far been found only as a minor constituent of zirconium minerals . Zirconium as an element was discovered more than 140 years ago , but only a few unimportant uses were found for the metal or its compounds until some 18 years ago ; it is still classed among the rarer commercial metals . It is not surprising , therefore , that hafnium has not yet found a definite place for itself in industry . Nevertheless it has commanded a considerable interest among scientists ; and in 1930 some 70 grams of perfectly pure oxide of hafnium were prepared in Europe . A commercial future for hafnium is already glimpsed in the radio industry , and its high melting point and electronic emissivity have already led to the taking out of patents for its use in radio tubes and incandescent electric lamp filaments and for the cathode surfaces of devices such as X- ray tubes and rectifiers .

Apr 1, 1931

By Ingvar Bergqvist

El objetivo de la voladura de bancos es crear de forma económico un espacio ahuecado, donde los explosivos sean cargados para que el resultado óptimo de la voladura sea obtenido. Por ello, es necesario que toda la información pueda ser utilizada -en tanto determine los trazos de perforación y las cantidades adaptadas de explosivos. En ese sentido, el presente texto señala los diferentes métodos de cálculo de carga para voladura de bancos como el de trazo de perforación y cargas, donde estos últimos son los más idóneos de acuerdo a las fórmulas del texto.

Nov 1, 1977

By R. S. Conti, M. R. Krump, C. P. Lazzara Ph. D., R. L. Derick, L. L. Chasko

A mine fire is one of the most challenging safety issues facing a mine operator and can occur at any location underground. The National Institute for Occupational Safety and Health (NIOSH) and the Twentymile Coal Mine, CO, conducted in-mine experiments to determine the capability of high-expansion foam for addressing underground fires. The tests were conducted in sloping entries with high-capacity diesel-powered foam generators. The following results were observed: a well-designed, maintained and properly operated high-expansion foam generator can propagate a foam plug hundreds of feet in steep upward-sloping (20%) multiple entries against a ventilation pressure; stoppings and partitions designed to contain the foam plug in upward-sloping entries must be substantially constructed; and the predicted quantity of foam concentrate can be significantly less than the actual amount used, due to foam losses, such as bubble breakage on dry surfaces. This paper describes the production of high-expansion firefighting foam and discusses the in-mine experimental tests and results.

Jan 1, 2010

By Federico Schwalb

Actualmente la minera Yanacocha opera cuatro mineras a tajo abierto que abastecen a tres operaciones de lixiviación de oro. Paralelamente a estas, la minera planea otro yacimiento a fin de asegurar su nivel de producción. En este sentido, el presente trabajo señala el nuevo yacimiento denominado Quinua, que está ubicado al suroeste de las operaciones actuales. Esta nueva área incluye la construcción de instalaciones de lixiviación, planta de aglomeración, sistemas de recolección, transferencia y manipulación de solución y el tratamiento de soluciones en una planta de procesamiento Merrill Crowe ubicada en el área de Yanacocha Norte.

Sep 13, 2001

By Norris E. Brooks

MAPCO Inc. is an integrated energy company involved in oil, gas, gas liquids, pipelines, and coal. The Coal Segment has installed a simple incentive program based on profit, tons produced, and hours worked at each operation. The plan has two segments-production bonus and profit sharing. Each segment is described and the results, which include high productivity, good safety, and high morale are discussed.

Jan 1, 1983

By B. Grinbaum, A. Mazuelos, F. Carranza, N. Iglesias, M. Avila, J. L. Lozano, G. Perez, R. Romero, M. \/aliente

Following a failure of a tailings pond darn at a mine in Andalusia, Spain, a huge effluent stream, that contained about 1 g/1 Zn and significant amounts of ferrous, ferric, calcium, copper, aluminium and manganese cations has to be treated, to prevent pollution of a nature reserve. EGMASA, as the regional government environmental agency, suggested to improve the current depuration process by recovery of the Zn from the effluent. A solvent extraction (SX) followed by electrowinning (EW) was proposed and developed to remove zinc.. A pre-treatment stage consisting in bio-oxidation of ferrous iron by using a bacterial process followed by an alkaline precipitation was employed because iron in the effluent is incompatible with both the SX and the EW processes. The SX process was developed successfully at the laboratory scale and verified in a pilot plant on-site, using two Bateman Pulsed Columns for extraction and stripping of zinc. The results were satisfactory obtaining a recovery of 90% of Zn. The process was suitable for industrial application.

Jan 1, 2008

By V. Gangrade, J. Addis, S. Vanderslice

Researchers at the National Institute for Occupational Safety and Health (NIOSH) are conducting research to improve the ventilation of large-opening underground stone mines. The mine ventilation in these mines are characterized by: (1) challenges related to keeping airflow velocities high enough to effectively remove or dilute airborne contaminants, (2) low pressure losses needed to move large air volumes of air, and (3) costly stoppings needed to direct ventilation airflows. Each of two field studies was dedicated to specific focus areas. The first focus area was the characterization of underground mine ventilation airflow. The primary means of airflow control in stone mines is through the use of freestanding booster fans. The primary goal of this study was to identify the effectiveness of various fan types and optimize their placement. Both traverse and grid-based airflow readings were taken at various distances from the fans, ranging from 70 ft to 425 ft away from the fan. The air readings were taken using a vane-anemometer and a handheld hotwire anemometer. The data was used to develop precise computational fluid dynamics models. The second focus area was to determine diesel particulate matter (DPM) concentrations in the mine. For large-opening underground stone mines, controlling DPM exposures dictates the design of the ventilation system. Therefore, researchers carried out the DPM sampling campaign to identify potential areas of concern within the mine. The samples collected during the campaign were analyzed using NIOSH Method 5040. The sampling was done using the Mine Safety and Health Administration’s (MSHA) compliance sampling methodology.

Feb 1, 2023

By C R. Crook

A brief outline of production methods and processes is given to show how maintenance fits into the picture at this plant. The work force, and the tools needed to carry out this function, are then described. Preventive maintenance practices, scheduled annual shutdowns and routine check-downs are explained, especially as related to planning and to the materials and labour involved for a mini-mum downtime. A brief explanation of the materials, sup-plies and spare parts program, as well as the part played by the Stores Department in conjunction with the Maintenance Department, is given. Cost control and equipment expenditure indicators are explained. Some specific examples of maintenance jobs are described in order to show the flexibility of the program. S HERRITT GORDON Mines Limited has been in continuous production, except for the planned downtimes needed for expansion tie-ins, or the annual shutdown check-over periods, since the first shipment of nickel on a commercial basis in July of 1954.

Jan 1, 1964

By Gabriel Esterhuizen, Tom Goodwin, Scott Schilling, Anthony T. Iannacchione

The Roof Fall Risk Index (RFRI) is a new method introduced by the National Institute for Occupational Safety and Health (NIOSH) to assist the underground stone mine operator in 1) assessing defects the mine strata and 2) rating the relative roof fall risk these defects pose. The RFRI utilizes observational techniques to identify defects in the roof strata caused by local geologic, stress, and mining conditions. Assessment values for ten defined defect categories provides the foundation for estimating a range of risk conditions between 0 and 100 that define the potential for a roof fall. This paper examines how the defect information is collected using two field verification sites and proposes methods to analyze the RFRI data. These examples provide information on how well the method replicates observed conditions and how it might be applied in practice.

By Timothy C. Siegel, Derrick Dasenbrock, Rich Lamb, Paul J. Axtell

"The axial resistance provided by deep foundations may be divided into two components: side resistance and tip resistance. The direction that the side resistance acts depends on the relative movement between the deep foundation and the adjacent soil. That is, when the foundation moves downward relative to the soil, then the side resistance is positive and acts upward. Conversely, when the soil moves downward relative to the foundation the side resistance is negative and acts downward. Research supports that both positive side resistance and negative skin friction develop in essentially all deep foundations. The side resistance distribution is a function of the soil strength and stiffness, the applied top loads, and whether the top load is sustained, transient, or a combination of sustained and transient loads. Consideration of drag load and downdrag has become more convoluted with implementation of geotechnical aspects into the AASHTO LRFD Bridge Design Specifications and its use of load and resistance factors. This paper examines the current AASHTO Specifications and presents an alternative design approach for drag load and downdrag using the LRFD framework. The alternative design approach is illustrated by two examples involving drag load and downdrag.IntroductionThe axial resistance provided by deep foundations may be divided into two components: side resistance and tip resistance. The direction that the side resistance acts depends on the relative movement between the deep foundation and the adjacent soil. That is, when the foundation moves downward relative to the soil, then the side resistance is positive and acts upward. Conversely, when the soil moves downward relative to the foundation the side resistance is negative and acts downward. Research supports that both positive side resistance and negative skin friction develop in essentially all deep foundations. The side resistance distribution is a function of the soil strength and stiffness, the applied top load, and whether the top load is sustained, transient, or a combination of sustained and transient.Consideration of drag load and downdrag has become more convoluted with implementation of geotechnical aspects into the LRFD Bridge Design Specifications and its use of load and resistance factors. This paper examines current LRFD design specifications and presents an alternative design approach for drag load and alternative design approach is applied to several examples where drag load and/or downdrag may control design."

Jan 1, 2015

By K. J. Gill, P. Chiotti, J. T. Mason

Thermal, metallographic, and vapor pressure data were obtained to establish the pkase boundaries and the standard free energy, enthalpy, and entropy of formation for the compounds in the Y-Zn system. Three coinpounds with stoichiometric formulas of YZn, YZn2, and Y2Zn17 melt congruently at 1105", 1080°, and 890°C, respectively. Four compounds with stoiclziometric formulas of YZn3, YZn4, YZn5, and YZn,, undergo perztectic reactions at 905", 895", 870º, and 685ºC, respectively. Three eutec-tics exisl in this system with the .following eutectic temperatures and zinc contents in wtpct: 875ºC, 23.2 Zn; 1015ºC, 51 Zn; 865ºC, 82 Zn. The YZn, pkase undergoes an allotropic transformation. In the two phase YZn2 -YZn alloys the trans.formation gives a weak thermal arrest at 750°C, whereas in the two phase YZn2-YZn3 alloys no thermal arrest is observed and the transformation occurs over a temperature range below 750°C. At 500°C the free mzergies of formation per lnole vavy from —18,090 for YZn to —53,430 fov YZr11 and corresponding enthalpies vary from -24,050 to -92,080. The free energies and enthalpies per g atom as a function of composition show a maximum for the YZn2 phase; the 500°C values are -9580 and -13,180, vespectively. 1 HE only information found in the literature on Y-Zn alloys was the observation reported by Carlson, Schmidt. and speddingl that Y-20 wt pct Zn forms a low melting alloy. The alloy was produced by the bomb-reduction of YF3 and ZnF2 with calcium in an investigation of methods for producing yttrium metal. The solubility of yttrium in zinc has been determined by P. F. woerner2 and reported by Chiotti, Woerner, and Parry.3 In the temperature range 495" to 685°C the solubility may be represented by the relation In these equations N represents atom fraction of yttrium and T is the temperature in degrees Kelvin. The purpose of the present investigation was to establish the phase diagram for the Y-Zn system and to determine the standard free energy, enthalpy, and entropy of formation for the compounds formed. MATERIALS AND EXPERIMENTAL PROCEDURES The metals used in the preparation of alloys were Bunker Hill slab zinc, 99.99 pct pure, and Ames Laboratory yttrium sponge. Arc-melted yttrium buttons contained the following impurities in parts per million: C-129, N-12, 0-307, Fe-209, Ni-126, Mg-13, Ca < 10, F-105, and Ti < 50. Some of the alloys containing 70 wt pct or more of Zn were prepared from yttrium containing 5000 ppm Ti as a major impurity. Tantalum containers were found to be suitable for all alloys studied and were used throughout the investigation. The pure metals, total weight about 30 g, were sealed in 1 in. diam tantalum crucibles by welding on preformed tantalum covers. A 1/8 in. diam tantalum tube was welded in the base of each crucible for use as a thermocouple well. Welding was done with a heli-arc in a glove box which was initially evacuated and filled with argon. The sealed crucibles were enclosed in stainless steel jackets and heated in an oscillating furnace at temperatures up to 1150°C. Homogeneous liquid alloys were obtained within a half hr at these temperatures except for alloys containing less than 20 pct zinc. The latter alloys were held at 1000º to 1100°C for 2 to 3 days in order to obtain equilibrium. After the initial equilibrations the tantalum crucibles containing the alloys were removed from the steel containers and used directly for differential thermal analyses. Further annealing heat treatments for alloys in which peritectic reactions were involved were carried out in the thermal analyses furnace. After thermal analyses the tantalum crucibles were opened and the alloys sectioned and polished for metallographic examination. In the following discussion alloys referred to as "quenched" were obtained by quenching the sealed stainless steel jacket containing the tantalum crucible and alloy in water. The differential thermal analyses apparatus used was a modified version of the one described in an earlier paper., The graphite crucible was replaced by an inconel crucible, the nickel standard and sampie container were separated by a 1/8 in. MgO plate, no getter was used, and provisions were made to

Jan 1, 1963

By V. A. Chanturiya

In Pt- and Au-keeping complex ores processing, about 10% ~ 15% of noble metals are lost with true tailings that are due to low floatability of Pt- and Au-keeping minerals by the conventional collectors. With the aim to achieve the effective recovery of noble metals at flotation of Pt-Cu-Ni and Au-keeping ores organic complex reagents keeping electron-donating atoms of nitrogen, oxygen, sulfur or phosphorus may be offered as selective collectors for the indicated minerals. These rea-gents tend to form complex compounds with PGM. Besides this, Cu-Ni-Pt and complex Pt and Au carbonated mica ores are characterized by finely disseminated (up to nanometer size) mineral forms of Pt in multivalent states. In this connection, the use of a combination of the strong ionic collectors with nonionic reactants that are capable to derivate complex compounds with multivalent PGM seems to be expedient for this type of ores. In the research new complex reactants were tested such as cyclic alkylene-trithiocarbonates, oxyalkyl butylxanthogen acid ethers, a combination of the collectors ? mercaptobenzothiazole (MBT) and dialkyldithiophosphates (DTP). Sorption and flotation tests were made with monomine-ralic samples of chalcopyrite, pentlandite, pyrrhotite, pyrite, and Pt-Cu-Ni sulfide ore samples. Sorption properties were examined by the extractive UV spectrophotometric method and potentiometric measurements. To indicate a structure of modified xanthate solutions the method of a thin-layer chromatography (TLC) was applied. The chromatographic behavior of the basic components of modified xanthate solution ? ButX, cyclic propylene-trithiocarbonate (PTTC), diethyl-dithiocarbamate (DEDC) and the product of its modification ? oxypropyl-S-ether of dithiocarbamatic acid was studied on plates ?Silufol UV ? 254?. The composition of organic solvents and its ratio in a mobile phase was deter-mined for simultaneous chromatography of the main components of a reaction mixture. It was found that operating selectivity of MBT, DTP and cyclic alkylene-trithiocarbonates incorporated in modified xanthate in relation to Pt-Cu-Ni and Au-containing sulfide minerals might be explained by an electoral sorption of this nonionic collector on a surface of the minerals studied. It was demonstrated that the application new reagent modes with the use of a combination of designed complex reactants helped to increase the extraction index of Pt- and Au-keeping minerals from complicated ores.

Jan 1, 2014

By RALPH BALTES, AMIR EHSAN KIANFAR, FABIAN UTH, ELISABETH CLAUSEN

As indoor positioning provides particular challenges due to the unavailability of GPS signals, various systems such as ultrawideband (UWB), radio frequency identification (RFID), ultrasound, and wireless local area network (WLAN) have been proposed in recent years. Some of these technologies are currently being marketed and some are still being developed. UWB technology allows for higher precision while also reducing power consumption. Hence, the underground automation and localization systems can use this technology for more accuracy and robustness. This article discusses new robust UWB modules used for underground positioning and collision avoidance with regard to human safety in underground mining operations.

Jul 31, 2020

By R Klepper

Separation of leach residue suspended solids from pregnant liquor solution is an important step in hydrometallurgy flowsheets. Alternative flowsheet options are counter-current decantation (CCD) thickeners or counter current washing (CCW) horizontal belt vacuum filters. Extensive sedimentation and vacuum filtration simulations have been completed by FLSmidth on leach discharge slurries to indentify equipment capacity and performance. These data were used to compare Capex and Opex for CCD versus CCW alternatives. In addition, Capex and Opex for large horizontal belt vacuum filters with filtration areas greater than 250m2 are compared to current state of the art sizes of 150m2. This paper presents this information and discusses various advantages and disadvantages.

Aug 8, 2011

By André Wulff Hirano

O Alto Forno 01 da ThyssenKrupp CSA entrou em operação em 12/07/2010 dando inicio a uma etapa em que o Brasil recebeu sua mais recente usina integrada, sendo um marco no modelo de planta compacta com o nível de capacidade instalada de 5 milhões ton/ano de placas. O modelo de controle de fluxo gasoso centralizado e com baixa marcha periférica havia se mostrado não adequado. Desse modo, foi implementado um monitoramento de indicadores para auxiliar na avaliação e controle de nível térmico e de distribuição de gás. Logrou-se obter uma estabilização da marcha do Alto Forno resultando em um melhor desempenho nas condições de escoamento, melhor rendimento de gás e, por consequência, redução do Fuel Rate, além de uma otimização no custo de carga metálica. Este trabalho mostra o desenvolvimento das práticas operacionais e de controle que permitiram essa evolução nos resultados.

Aug 1, 2018

By Hormando Leocadio, CWM van der Geld, Julio Cesar Passos

Impinging water jets promote high heat flux extraction rate. Steel industry widely employs the process for accurate temperature control to improve the microstructure and to ensure adequate mechanical properties. The range of surface temperatures, heat fluxes and cooling rates are very large, which makes it important to obtain an accurate value of the heat transfer coefficient. This paper presents an experimental and numerical study of the heat transfer behavior of a high temperature (450°C - 900°C) steel plate cooled by a water jet at 20°C to 70°C. High-speed imaging (up to 20,000 fps) within water jet impingement zone allowed the characterization of the boiling regimes in the early stages of cooling. The effects of initial temperature, water jet temperature and velocity on the heat transfer coefficient were analyzed by inverse heat conduction method that predicts the heat flux and temperature on the top surface from temperatures measured with thermocouples inserted in test plate. Heat transfer is strongly affected by the initial temperature of the hot steel, water jet temperature and, less intensely, by jet velocity. High cooling rates start when liquid water is in direct contact with surface temperatures above 700°C.The results will contribute to the enhancement of the temperature cooling control on the runout table and cooling model employed at Usiminas Hot Strip Mill.

Oct 1, 2019

By Y. B. He

The effect of the overflow to underflow (O/U) flowrate ratio of a dense medium cyclone on its performance is tested utilizing a 6" dense medium cyclone and density tracers. The results show that the O/U flowrate ratio is clearly correlated with the separation cut point D50, the separation efficiency Ep, the density differential 0, and short circuiting of the cyclone. Within certain limits, a higher O/U ratio results in a better separation efficiency, a higher D50 and an increased density differential. A lower O/U ratio, on the other hand, reduces the cut point shift and density differential. The phenomenon of short circuiting to the underflow, which is especially significant for fine particles, is directly connected with an excessively low O/U ratio.

Jan 1, 1992

By Rodrigo Martins Barbosa

A água é utilizada em processos industriais desde o começo da era industrial. Sua utilização é variada, desde como matéria prima, até como utilidades. Muito se discute a respeito da qualidade da água para descarte e seus possíveis danos ambientais, mas é importante mostrar que, além disso, existe um impacto financeiro ao trabalharmos com a má qualidade da água industrial. Este trabalho propõe demonstrar a influência da qualidade da água nos processos industriais, através da avaliação do resultado da instalação de um filtro de água na tubulação de entrada de um trocador de calor.

Aug 17, 2017

By Michael Hughes, Paul Bonapace, Harry Charalambu, Stephen Rigbey

Ontario Power Generation is building a 10.4-km water diversion tunnel in Niagara Falls, Canada. The tunnel is a two-pass, cast-in-place prestressed concrete-lined pres-sure tunnel with a nominal internal diameter of 12.7 m. It is mostly situated within the Queenston formation which swells in contact with fresh water and has very aggressive groundwater. Tunneling in this material presents challenges in both design and construction. The tunnel design includes for a membrane to eliminate the potential for rock swelling and to protect the concrete liner from the ground conditions. A unique three-stage Geotechnical Baseline Report (GBR) is being used and is expected to provide an equitable method of dealing with any variations in subsurface conditions.

Jan 1, 2007

By Lilong Zhu, Shaoda Zhang, Qian Wang, Shengping He

The effects of ZrO2, Y2O3 and Sc2O3, which are transition metal oxides, on the melting temperature, viscosity at 1300 °C, and break temperature of three mold fluxes (two weak-reactive type and one non-reactive type) designed for the high manganese and high aluminum steels, and one another conventional CaO-SiO2 based mold flux is studied. The results indicate that the melting temperature and viscosity increases slightly, and the break temperature increases dramatically with the addition of ZrO2, Y2O3 and Sc2O3 content in the conventional CaO-SiO2 based mold flux system. While, the addition of ZrO2, Y2O3 and Sc2O3 in the weak-reactive or non-reactive mold flux systems has a negligible in fluence on the melting temperature, viscosity and break temperature, suggesting that these transition metal oxides are possible to regulate radiation heat transfer without changing the basic properties of mold fluxes.

Mar 1, 2018