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By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By H. S. Rathor

NTPC (National Thermal Power Corporation), a multi-unit organization, is generating 26% of India’s total power. This power is produced from its 14 coal based stations and 7 gas based stations. NTPC is entering into the business of power-distribution, power-trading, setting up of coal mines and diversification in non-conventional energy sector as well. For achieving the goal of the country “Power for All” NTPC has taken a giant stride by entering into Hydro Power generation which is also the cheapest and the cleanest renewable source of energy. In its pursuit for excellence, 800 MW Koldam Hydro Power Project is NTPC’s first venture in hydro sector. In Koldam, hydropower potential will be harnessed by constructing a 163m high earth and rock fill dam in a narrow gorge at upstream end of Bhakra reservoir. The river diversion is envisaged through two parallel, 14m finished diameter ‘horseshoe’ tunnels of length 901m and 934m at village Kian on the right bank, where the river forms a 180° loop. The diversion tunnels are designed to accommodate a flood of 6500m3/sec, taking into account the maximum probable discharge of 200 years return period. The tunnels pass through dolomite and limestone rock formations. The excavation of tunnels was done with drill and blast method. The excavation was attempted from both inlet and outlet faces. During geological investigation a rock fault was located at the outlet area. The location of the fault was such that it was passing through the edge of the Tunnel-1portal and around 30m away from the face of the Tunnel-2 portal. The quality of the rock at Inlet was also poor. To save the portals from slips, excavation of the tunnels was planned to start after the completion of the open excavation and its support system both at inlet and outlet. The tunnel excavation at inlet was envisaged by approaching the tunnels’ portal by constructing a road through 540EL bench and meeting the inlet portals on the upstream end, which would have been ready by mid2003, only after completion of the open excavation and its support system. To save time and cost, it was felt necessary to modify the planning by starting the tunnel excavation simultaneously along with open works both at inlet and outlet. The excavation at the inlet face of the tunnels started in December 2002 after rerouting the approach road to inlet portals through haulage road on the downstream and similarly Tunnel-1 at the outlet was started in the low cover area before completion of open area works. Thus the tunnel—heading excavation was started nearly 06 months early with the change of methodology.

Jan 1, 2005

By Terry M. Tilley, Gregory P. Sherry

Purpose This is a unique project because the mining and tunneling industries have become highly mechanized and cannot normally accommodate a project where surface disturbance must be minimized or eliminated when there is less than 10 feet of ground cover. More traditional less mechanized methods must be employed and the skills and techniques for accomplishing the work have become all but non-existent. Therefore, this article highlights those areas of specialized skills and techniques. Methods The article will describe the design approach, the method(s) of ground support selected, the method(s) of excavation selected, the planning, scheduling and materials selection process. In addition, the article will describe the actual production characteristics and the results of the project. This approach will concentrate on productivities, adaptations to actual conditions and the quality of the end product. The design approach basically was to insure that the temporary support methods were adequate for the excavation and shoring stage of the project. The final concrete liner was designed using conventional structural design methods with the goal of constructing a tunnel that will last 100 years. The methods of support were spiling and variations of spiling in order to provide advance temporary ground support. In this project spiling is steel channel cantilevered and driven into the ground ahead of the working tunnel face which supports the ground allowing the face muck to be removed with overhead protection’. Conclusion This will be a discussion of the applicability of the methods. The actual performance of the excavation and shoring methods will also be evaluated. The final concrete liner completion results, the actual production rates and the conformance with budget and schedule will be addressed.

Jan 1, 2005

By Omid Lashkari

Keywords: SEED, SSM materials, Microstructural evolution, Rheology, Swirling Speed SEED (Swirled Enthalpy Equilibration Device) is established itself as a new technology amongst the many Semi-Solid Metal (SSM) processes, where swirling of the mush plays an important role in modifying the dendritic structure of as-cast parts. A range of semi solid metal structures, dendritic, rosette and/or globular morphology of primary phase, can be prepared using SEED. The current article reports on the application of rheological tests in characterizing microstructural evolution during SSM processing of 356 Al-Si foundry alloy. A simple parallel plate test machine, designed and constructed at our labs, was used to determine viscosity values for each structure and identify the optimum structure with superior die filling characteristics. Such findings have important technological and economical implications during high pressure die casting of semi- solid metals. The strain-time graphs for 356 Al-Si foundry alloy indicated lower viscosity values for globular microstructure, i.e. improved die filling.

Jan 1, 2005

An established method exists for the computation of rope lifetimes for shaft hoisting applications in the mining industry. In an earlier study, during the 1990s, an initial comparison of the calculated and actual rope life for various types of hoisting plants showed reasonably good correlation. In the meantime the calculation method has been developed further. The rotation behaviour of the rope during hoisting and the effects of multilayer spooling on drums are now considered in the assessment of expected rope lifetimes. The ability to determine an estimate of rope life in advance is particularly useful for mining companies. Such analysis allows them to predict the effects of rope choice in their particular application and thereby reduce the total cost of rope ownership. Such calculation techniques also allow designers of winding plants to identify aspects of the hoisting configuration that may negatively affect rope life. Often small (low-cost) changes, like increasing the diameter of head sheaves, can result in considerable improvements in rope performance. This paper describes the extended lifetime calculation method and gives further examples of the comparison between actual and calculated rope lives for operational double-drum mine hoists.

Jan 1, 2005

By A. Steinmüller

Introduction In the design and operation of gravity concentration circuits, the application of process models for spiral concentrators offers significant benefits. A substantial amount of work has been produced over the last 30 years in the field of modeling the metallurgical performance of spiral concentrators. It is not the aim of this contribution to add to the refinement of modeling technique but to share some of the experiences and potential improvements which can be achieved in a relatively simple way. The design of spiral circuits usually requires extensive testing. This is often conducted in batch operation only, either due to lack of suitable continuous testing facilities, the unavailability of sufficient quantities of sample, or other constraints. Typical problems arising during circuit development from batch testwork are the extrapolation of results to different feed conditions, and resolving of internal recycles. Model selection and development The classic approaches in spiral modeling technique range from fundamental fluid dynamics, based on the Navier-Stokes equations in combination with expressions for local slurry properties, to fully empirical and statistical models. With the initial objective of developing an in-house tool for gravity circuit optimization and development, mathematical model types from each category, available either commercially or in the published literature, were evaluated. Model selection For the desired purpose, an approach proposed by Holland-Batt (1990) was found suitable, which was adopted and modified. Holland-Batt reported that the shape of release curves in spiral applications could be described by a combination of a linear function in the initial recovery zone, and a power law function outside this zone. The proposed recovery function was formulated as

Jan 1, 2005

A methodology for the fatigue life estimation of load haul dumpers, employed in underground platinum mines, has been developed and applied. This method entails the quantification of operating conditions by means of stress measurements. The measurements are then translated into a fatigue loading factor for a finite element model. The results of this analysis are then used to compare all the critical connections in the structure to detail categories in relevant fatigue codes, and predict a life in operating hours for the vehicle structure. The method was applied on a specific model and the results of this analysis were compared to actual failure occurrences with reasonable accuracy. It is intended that the methodology be embedded into performance specifications and purchasing contracts and that technology transfer to OEMs be achieved. Based on the experience of this project and other similar exercises it is estimated that structural life expectancies may be increased across a typical fleet of trackless mining vehicles (LHDs, drill rigs, utility vehicles, dump trucks) by at least 20 per cent.

Jan 1, 2005

By G L. Simmons, K M. LeVier, R Kappes

The low potential hydrophobic state of pyrite in amyl xanthate (PAX) flotation with nitrogen is of particular interest with regard to the N2TEC flotation technology currently being used for the recovery of auriferous pyrite at NewmontÆs Lone Tree Plant in Nevada. Initially, the N2TEC system had been found to operate satisfactorily, but cyanide in the flotation mill water appeared to be responsible for a loss in pyrite recovery. This supposition was confirmed with laboratory experiments, and a program was initiated to study flotation chemistry variables by electrochemically controlled contact angle measurements. Experimental results show that activation of pyrite in such cyanide solutions can be achieved more effectively with lead than with copper. Subsequently, based on these fundamental studies, significant improvement at the Lone Tree Plant was achieved by lead activation, in which case the recovery increased to expected levels. The effect of activator is particularly significant not only with respect to pyrite depression by residual cyanide, but also with respect to collector (PAX) consumption and the initial state of the pyrite surface. Experimental results show the importance of the pyrite surface state and the rather interesting features of the activation process.

Jan 1, 2005

By S Bandopadhyay

The seasonal fluctuations of the dust content in Arctic mine environments and the environmental variables affecting the intensity of dust production are qualitatively well known, but quantitative models that allow simulation and prediction of dust generation and the effects of engineering control of thermal regime on the mine environment are still non-existent. In Arctic mines, the migration of moisture in the surrounding rock mass releases fine dust by freeing it from the ice matrix allowing it to escape into mine airway. The migration of moisture is the direct cause for the production of mine dust and heat is the primary driving force. This paper examins the heat and moisture exchange between the ventilation air and the surrounding rock mass in frozen ground, placer mines in the Arctic. Based on the simulated results of a coupled heat and mass transfer problem with phase change, methods of dust control have been identified for mines in the Arctic.

Jan 1, 2005

By I. Protkova

Versa Power Systems solid oxide fuel cell (SOFC) stacks operate at intermediate temperatures 700 ? 800 °C allowing the use of metallic interconnects. Thermal expansion good matching with other stack components and cost restriction led to selecting ferritic stainless steels as interconnect material. Analytical tools and techniques were developed to understand the ferritic stainless steel behavior at high temperature while exposed to dual environment. Analytical tools such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) have provided valuable information towards describing interconnect degradation in a variety of testing conditions. Several examples are presented to demonstrate interconnect oxidation and its relation with SOFC testing results.

Jan 1, 2005

By Baisheng Zhang

The definition of Ultra-close multiple seams as defined by the floor disturbance depth, h, due to mining in the upper seam is proposed: it refers to those coal seams that are spaced very closely, i.e. h,, the distance between seams, is small or equal to h, , and mining of any one of the seams will significantly affect the others. Those seams are called the ultra-close multiple seam group. Theoretical formula for defining it and practical examples are given in this paper. Underground measurements and numerical analysis show that in ultra-close multiple seam mining, the characteristics of ground pressure due to lower seam mining is different from that of single seam mining. The major differences is that the roof, as a result of damaged caused by the upper seam mining, is full of factures; the roof broke up in the belt entry and fell down easily; support loading at the face was small without clear periodic weighting phenomenon. Based on these results the roof structure model and roof control theory for ultra-close multiple-seam are established.

Jan 1, 2005

The market for titanium feedstocks (ilmenite, rutile,synthetic rutile and slag) is driven primarily by offtake from the titanium dioxide (TiO2) pigment industry. The pigment sector depends on the performance of the global economy. Titanium sponge is the first stage of titanium metal manufacture. It constitutes a minor component (3 percent) of overall demand for titanium feed-stocks. Production and consumption TiO2 pigment consumption in 2004 was estimated to be 4.63 Mt (5.1 million st), up 7.6 percent from 2003. It was driven by strong demand in most regions. In the United States, apparent TiO2 pigment consumption rebounded by 5.4 percent (highest growth rate since 1997) to an estimated 1.12 Mt (1.23 million st), following the decrease in demand during 2003. Chinese TiO2 pigment consumption continued its strong upward trend, increasing by 10 percent to 598 kt (659,000 st) in 2004.

Jan 1, 2005

By L Grigorov, G J. Jame, A V. Nguyen

The dewetting kinetics between a small air-liquid interface and a silica (negatively charged in water) planar surface in solutions of dodecylammonium chloride (cationic surfactant) has been investigated using the Scheludko cell and digital high-speed video microscopy. The gas-liquid interface was created at the bottom of a small silica capillary of the cell and then was moved towards the silica planar surface. After the rupture of the liquid films between the interfaces, the expansion of the gas-liquid-solid three-phase contact (TPC) line was observed and recorded using a digital high-speed video microscope system, operating at 1000 frames per second. The surface tension of the surfactant solution was measured using the pendant drop technique. The equilibrium contact angle was measured using the Scheludko-Minings method with a silica micro-sphere. The TPC radius was determined as a function of time and compared against the available hydrodynamic and molecular-kinetic models. The experimental data are described very well by the molecular-kinetic model for the TPC line motion. The hydrodynamic model is in agreement with the experimental data only for a short time after inception of the three-phase contact expansion.

Jan 1, 2005

By A. M. Clegg

In general, overall experience has shown that the approach to the appointment of a project manager is given much attention, but little specific attention is given first to the risk associated with the project conceptual design and its overall executability within either the new legislative framework or the sustainability of the outcome. The risk in project executability and sustainability within the ?new age? legislative framework of the Mining Charter, etc, is itself however, of far greater importance. The degree of importance being defined by the intended projects impact on the business going forward. This is particularly the case where the intention of the implementation is effectively to turn around or even enhance a loss-making strategic investment like a mine or process plant operation in an ?old-order rights? or Brownfield?s operation. This paper attempts to highlight the importance of a ?pre-project project? (PPP) to mitigate the risk in the ?new age?, with specific reference to operational due diligence (ODD) and project conceptual design.

Jan 1, 2005

By J. Gebhardt, D. McBride, C. R. Bennett, Croft. N., M. Cross

A comprehensive model of solution flow through heap leach systems requires a numerical solution with the ability to predict variably saturated-unsaturated flow through porous media domains that contain materials with spatially variable properties. The types of flow associated with stockpile leach processes lead to flow problems, such as infiltration into dry soil, drainage, perched water tables and flow through heterogeneous materials. Computational methods for modelling this class of flow behaviour are conventionally based on the classical Richards' equation. However, the governing equations are highly non-linear, difficult to solve, and require iterative numerical solution methods. The pressure-based form of the Richards' equation suffers from poor mass balance, while the mixed form can possess convergence difficulties. An adaptive transformed mixed algorithm is described, which reduces the non-linearity of the problem, optimizes the time step size, and provides a fast, numerically robust scheme that significantly reduces computation (or CPU) time. This method is shown to give fast, accurate solutions on a number of complex flow problems. The utility of this algorithm is illustrated through its implementation within the PHYSICA computational modelling software, which incidentally, provides a framework for a comprehensive heap leach model.

Jan 1, 2005

The lignite resource in the southern part of the South Island is New ZealandÆs largest source of indigenous primary energy. The ten deposits evaluated by the Liquid Fuels Trust Board (LFTB) have a total recoverable reserve of 6.2 billion tones equivalent to 74 000 PJ of energy or 20 times the original energy content of the Maui gas field. Updating the economics of the original LFTB studies indicates that lignite could be mined for between NZ$1.0 and 3.0/GJ. Its conversion to synthesis gas for production of petroleum products, chemical methanol, ammonia/urea fertiliser or electricity would be in the national benefit and likely to be commercially economic at todayÆs product prices.

Jan 1, 2005

By Helmut Hass, Michael S. Shultz

For many tunneling, deep shaft and deep excavation projects ground freezing is one of the best if not the only technique available to create a watertight and load bearing temporary support system in soft ground conditions. When appropriate attention is given to the details of the ground freezing system design, ground freezing is a very safe method and is economically viable with competing techniques and combinations of techniques. Recent innovative uses of the technique in Europe are highlighted in this paper and compared with current uses in North America.

Jan 1, 2005

By A Nixon

The Australian mining industry has changed dramatically over the past 20 years in terms of mining methods, mining equipment and human resource policies. The industryÆs approach to safety and health in terms of attitudes, style of legislation, and risk management techniques has also changed significantly. These changes have had and continue to have major impacts on the design of underground mine ventilation systems. In some areas, trends are clearly emerging. In other areas, mine ventilation planning remains very æreactiveÆ and is performing poorly in terms of providing a safe and healthy work environment at a reasonable cost. New concepts involving the role of ramps and shafts, the provision of refrigerated air, æventilation on demandÆ and newe gress and entrapment approaches are likely to be incorporated into mine planning and operating practices over the next ten years. This paper discusses these and other trends and identifies some likely future developments in the area of hardrock mine ventilation.

Jan 1, 2005

We all live in professional silos û comfort zones, where we talk to like-minded people with the same training, experience and view of the world. We note in passing the existence of other disciplines, but they are tolerated rather than embraced. To the geologist, the metallurgist is a mad scientist conjuring gold out of some foul solution about which the less said the better. To the metallurgist, the geologist is a bearded, self-appointed sage who guesses what is under our feet by sniffing the air, and drives a Land Rover badly. As to the view of mining engineers held by both geologists and metallurgists, this is best left to the imagination. And of course we are all confused by the term æmetallurgistÆ. I am called a metallurgist though my skills are in mineral processing not metal processing, but I canÆt be called a mineralogist because that definition is already taken. *Please note that this is available as an extended abstract only*

Jan 1, 2005

By A. R. Hekmat

Hypereutectic Al-Si alloys are used in applications that require high resistance to wear and corrosion, hardness and low coefficient of thermal expansion, To maximize the properties of these alloys, semi-solid processing can be utilized to modify the solidification structure of the primary silicon crystals as well as to reduce microsegregation and porosity, The transformation and spheroidization of primary Si crystals by shearing in the semi-solid state are not fully understood as they precipitate in the presence of other alloy phases, The objective of the present work is the determination the rheological characteristics of A390 (Al-17%Si-4,5%Cu-0.5%Mg) alloy using a Couette type (Haake RV12) viscometer and examining the microstructural evolution during continuous cooling and isothermal shear rate experiments, The effect of shear rate, solid fraction (temperature) and morphological evolution of the silicon crystals are investigated.

Jan 1, 2005