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By Yanping Xiao

In submerged-arc furnace (SAF) for smelting chromite ores into ferrochrome, there exist large temperature gradients and wide distributions of mineralogy and compositions in the furnace, due to the complexity of feed structure and electrical-thermal-chemical interactions. This leads to various zones in the furnace and thus different reaction mechanisms. In the present paper, the behaviour of chromium in the submerged arc furnace is discussed in various reaction zones, including solid state chromite reduction in the packed bed zone, chromite dissolution and reactions in the smelting and coke bed zone, and recovering chromium from slag to metal. In the gas-solid reaction zone, the reaction mechanism is discussed based on the experimental observations and analysis. In the smelting zone, the behaviour of partially reduced chromite and slag formation are analyzed based on the information in literature. The slag in FeCr process contains mainly Al2O3, MgO, SiO2, CaO and CrOx, featured by chromium with both divalent and trivalent oxidation state, which plays an important role for chromium recovery into metal. The factors influencing the slag and metal interfacial reactions and the chromium recovery are addressed.

Jan 1, 2006

By John W. M. Lambert

This paper describes the execution and the results of a new method to seal off leaks in water retaining constructions. The new method, called BioSealing is based on activating the bacteries, present in soil and groundwater. The method was tested under field conditions in 2004 and applied at the HSL aqueduct of the 'Ringvaart Haarlemmermeer' in 2005.

Jan 1, 2006

By W. J. Schlitt

The development of forced aeration as an approach to enhancing copper sulfide leaching is traced from its earliest development up to present day operations using this technology. Both large-scale field tests and commercial operations are covered. The historical portion is preceded by an introductory discussion of the role of air (oxygen) in sulfide leaching. Sufficient aeration may be achieved via naturally induced convective airflow. However, cases are identified where this is insufficient, leading to retardation of the sulfide leach rate. For these situations, forced aeration may be beneficial. The historical portion of the paper focuses on the major field tests that have been conducted in Montana, Nevada and Utah, along with commercial operations in the United States, Australia, Chile and Peru. The paper concludes with some general comments about the applicability of forced aeration, which are based on the information developed to-date.

Jan 1, 2006

By Helen S. W. Chow

The use of piled raft foundations for tall buildings has been increasing in this decade as it is an economical alternative to conventional piled foundations. Piled rafts are composite structures comprised of the piles, raft and soil and so soil-structure interaction is important in computing the behaviour of the foundation. In this paper, the behaviour of piled rafts subjected to non-uniform loadings will be examined where the raft is supported by piles of different lengths. Finite layer techniques are used for the analysis of the horizontally layered soils and finite element techniques are used for the analysis of the raft and piles. This method accounts for the soil-structure interaction and the lateral resistance of the soil on the piles and raft. Results provided from the present method are compared with the results of a full 3D finite element analysis.

Jan 1, 2006

By T. Taniguchi

The existing Mitsubishi Process line at Naoshima Smelter and Refinery has been operating successfully since 1991, and its present production capacity is 270,000tpy of copper. Furnace relining works have been carried out every two years to coincide with the compulsory bi-yearly boiler inspection, but the next target is to extend the furnace refractory life to four years, while still undergoing the mandatory boiler inspection every two years. Although the damage of hearth bricks beneath lances in the Smelting furnace was a matter of concern, it was reduced by controlling gas velocity and evening solid distribution to each lance. The life of bath level bricks in the Converting furnace was also a concern, but four-years continuous use of the bricks was achieved in the course of the last two campaigns. Several other improvements were also carried out to the cooling systems during the shutdown in 2005 to ensure longer campaign life. This paper summarizes recent improvements implemented to enhance the advantages of the Mitsubishi Process.

Jan 1, 2006

By E de Villiers

Several methods exist by which the capacity of a dense media separation (DMS) plant can be improved: 1) Increase the feed rate in spite of efficiency 2) Replace with bigger equipment 3) Add whole new module 4) Replace total plant 5) Change over to four shift/ seven days per week roster 6) Replace with alternative process 7) Increase the availability and utilization Options 1 ? 6 have varying degrees of cost implications. The seventh option would seem to be the easiest. Normally it is also the function of the plant operating and maintenance team to maximize this. Usually higher operating and maintenance cost are associated with an increase in these parameters. A general principle that is applicable to plants and systems is that as the complexity increases, the total availability decreases. By simplifying the flow line it may be possible to reduce cost while at the same time increase the availability and utilization. The typical standard DMS flow line contains components that compensate for the variance in pump performance or for the inefficient recovery of ferrosilicon with additional equipment. Things have changed though: 1) Advanced electronic control and monitoring is possible 2) More efficient magnetic separators are available 3) New more user friendly densifiers are available ORIGINAL FLOW LINE In principle the process consists of four flow lines or streams 1) Ore flow ? the feed is divided into a waste and product stream by means of the separating vessel

Jan 1, 2006

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By P. Bacher, L. Dubourg, M. Jahazi, G. Dezaise

Effect of friction stir welding parameters and natural ageing on weld properties are reported. Using a Taguchi design of experiment, attempt is made to systematically examine the influences of the welding speed, tool rotation speed, forge force, tilt angle and pitch ratio on the weld size and ultimate tensile strength of FSWed joints. One millimetre thick plates of AA7075-T6 were welded in lap joint configuration. Samples were characterized by optical microscopy, hardness and tensile measurements. Trends suggested by the results and directions for further investigation are discussed.

Jan 1, 2006

By Ali Ameli

Design loads are limited for piles relying upon toe stresses in rock due to uncertainty about the rock quality over the whole pile diameter because of rock mass properties or construction effects. The paper discusses the use of video images to evaluate rock quality at the bottom of piles socketed into graniodorite bedrock in a steel pipe pile project. Skillful interpretation was required to assess the 3D properties of the rock from video images. It is necessary to observe the rock mass characteristics near the project site for better perception of the rock features from the images. Video image interpretation skills were established by the evaluation of the cores drilled under the socket base and the results of pile loading tests. Correlations were found between rock appearance in the images and the rock socket drilling records. Rock socket acceptance criteria were developed through monitoring the drilling operations for the specific site procedures. Video images then served as one of the quality-assurance tools together with probing and pile loading test. Lessons and methods learned from video inspection in this project could be used to evaluate rock quality in similar cases.

Jan 1, 2006

By H. Immink

Keywords: Kyoto Protocol, carbon credits, global warming, energy, auditing Climate change is nowadays being taken increasingly seriously, and the link between global warming and the carbon dioxide released in the generation of energy is coming under increasing scrutiny. The Kyoto Protocol was signed in 1997, after five years of negotiation. So far, about 84 countries have ratified this agreement, under which terms developed countries have strict targets linked to their 1990 level of emissions. However, ?greenhouse gas? (such as carbon dioxide) emissions continue to rise alarmingly. According to the World Resources Institute, greenhouse gas emissions in the USA increased 13% from 1990-2002, while Australia recorded a 22% increase. In contrast, the European Union, a Kyoto signatory, has seen a small decline in its emissions during the same period. This is led by the UK and Germany, who reduced their emissions by 15% and 19% respectively. The concept of ?carbon credits? provides a funding mechanism for companies in the developed world to compensate for some of their CO2 emissions by paying companies (trading credits) elsewhere in the world to undertake projects to bring about reductions in emissions. In the southern African mining industry, it will be possible to get refunded for undertaking voluntary emission-reduction projects. Concern about the environment is creating business opportunities. A preliminary calculation has shown that various projects in South Africa (those in the pipeline, with quite a high likelihood of coming off) could earn a combined total of about R2.5-billion, under the initial phase of the Kyoto Protocol's carbon-credit scheme, which allows developed-country companies to trade credits with developing countries. A number of local companies are planning projects that could comply with the Clean Development Mechanism (CDM), in which they will implement techniques to achieve certified emission reductions (CERs) of greenhouse gases. In order to prevent abuse of such a system involving vast sums of money, vigorous audits need to be carried out. A company has to prove it has made real changes and is not simply conducting business as usual under a cloak of claimed environmental improvements. PricewaterhouseCoopers has applied to become one of only a few international agencies that will be accredited to conduct validation and verification of the credits, by auditing what is called the ?designated operational entity?. An independent validator needs to confirm that the project meets the strict requirements of the Kyoto Protocol. The company has to demonstrate that it?s not business as usual. So, if you refurbished every five years, the next refurbishment is not a good CDM project, unless you can demonstrate that you will do something beyond the maintenance - that is what can be registered. So, Kyoto intends to get additional projects going, and the money for that is actually quite good - prices of 14 euros per ton of carbon dioxide not emitted have been seen. The price depends on who takes the risk for non-delivery if a project doesn?t deliver the emission reductions on time. The highly energy-intensive South African mining industry is heavily dependent on coal. There should be many opportunities for the pyrometallurgical industry to come up with creative ideas to reduce emissions, and there is now an additional financial incentive to encourage this. Companies can actually get money in return for doing these types of projects, in addition to the contribution to corporate social responsibility.

Jan 1, 2006

By Wenbing Guo

The stability of strip pillar is the key to successful strip pillar mining. In analyzing the stability of the strip pillar, the width of yield zone must be determined. The determination of the width of yield zone has been an important subject for researchers. In this paper, the numerical method was used to study the relationship between the width of yield zone in strip pillar and coal recovery ratio. The results showed that as the recovery ratio increases, the width of yield zone increases exponentially. Accordingly, the formula for determining the width of yield zone was updated and the effect of changing coal recovery ratio on strip pillar deformation is presented.

Jan 1, 2006

By Bekir Karasu

Boron raw materials are amongst the most important natural sources for many industrial branches and their values become increasingly raised with the discovery of boron usage in many new technological fields. All the countries in the world are unfortunately not as lucky as Turkiye and USA where major boron deposits are mainly located. It is widely known fact that on one side, boron is very precious component with its technological importance, on the other; only its limited sources are available. Therefore, even its wastes have to be evaluated and regained. In the present work wastes of Etibor Kirka Borax Company of Turkiye were used in the production of opaque frits which was suitable for floor tile glazes. Standard and newly produced frit based glazes were applied on the pre-engobed floor tile bodies and single firing was employed. Final products were examined according to the certain standard tests and their microstructures were also investigated. All the results confirmed the evaluation of boron wastes in opaque floor tile glazes.

Jan 1, 2006

By A. S. Macfarlane

Mineral resource management (MRM) practice has developed in South Africa over the course of the last ten years, with the purpose of integrating previously isolated technical functions into a value chain aligned, process organization, responsible for mine planning and optimization. The implementation of MRM within various companies has met with varying degrees of success, often resulting in incremental improvements in the planning process and, conversely, often becoming the scapegoat for poor delivery on plans and projects. The reason for this has been, amongst others, a lack of a suitable metric to define the success rate of MRM in the business at hand, in terms of its contribution to the bottom line. This paper is the result of extensive research by the author into this subject, which has resulted in the conclusion that economic value added is an appropriate measure that will lead to real optimization and value creation in mining companies, if applied within a new, holistic model

Jan 1, 2006

The world is getting flatter through internet, mobile phone technology, relatively low cost travel, massive outsourcing of manufacturing to China and the transfer of company backroom operations to India. In the iron and steel industry, however, things will remain relatively the same with slow gradual improvements in technology; only the geographic location of plants may change over time. Or will it? The blast furnace smelting process has remained largely unchanged since 1828 when James Neilson came up with the idea of preheated air being delivered to the tuyeres. Likewise, oxygen steelmaking that takes molten iron from such blast furnaces has remained conceptually unchanged since Sir Henry Bessemer invented an air-based system in 1856. These two processes are the core of integrated steel mills that we know today. Typically such mills consist of coke ovens, sinter plant, blast furnace, oxygen steelmaking, continuous caster, rolling mills and metal coating lines. In the intervening 150 years the only real disruptive technology to the integrated steel mill has been the minimill. Based on the use of the electric arc furnace (EAF), in conjunction with a continuous caster and rolling mill, the term minimill is used because steel products are produced at down to one-tenth the scale required for economic operation of an integrated mill, with the EAF producing molten steel using largely scrap steel as its feed, as against transforming coal to coke (coke ovens), iron ore, coke and limestone into molten iron (blast furnace) and molten iron to steel (oxygen steelmaking). There are, however, a number of technologies in development that may cause a paradigm shift in the way steel products are produced and perhaps push the evolution of the minimill as a disruptive technology. Two examples are direct iron smelting, where iron is produced in a matter of seconds by injection of ironmaking feed materials into a molten bath, and thin strip casting, where molten steel is cast into 2 mm strip or less, in similar time. Both have Australian connections. A leading iron smelting technology is the HIsmelt« process, which has its first commercial application at Kwinana, Western Australia, where a joint venture of international parties, consisting of Rio Tinto and the Nucor, Mitsubishi and Shougang corporations, are in the stage of ramping up commercial production. The leading strip casting technology is the Castrip« process that arose from development work done by then BHP Steel, with IHI of Japan, at Port Kembla, New South Wales in the 1990s. Nucor followed this work up, building the first commercial plant for the technology at its Crawfordsville site in Indiana in 2001 and has recently announced an intention to build a second plant in the USA. While both technologies are only into the early stages of commercialisation they are likely to change the face of iron and steelmaking as we know it over the next 20 years. This paper elaborates on the technology of the two processes, why they could change the face of the iron and steel industry forever, what might drive the rapid change and what the changes may look like.

Jan 1, 2006

By Pengfu Tan

A thermodynamic model of KIVCET lead smelting process has been developed. The model has the capability to predict the distribution behaviors of Pb, Zn, Fe, S, O, As, and heat balance in KIVCET direct lead smelting furnace. The compositions of lead bullion, matte, slag and gaseous phases, and heat balance are calculated. The effect of the ratio between oxygen and feed on the chemistry of the smelt and heat balance of the coke checker has been simulated and discussed. The thermodynamic model also helps to understand the tapping issue of the lead bullion. In this paper, some applications of this model in the industry have been presented.

Jan 1, 2006

By O Ignatenko, A van Schaik

Environmental legislation for the process and manufacturing industries is frequently formulated without considering the fundamental limits of physics, chemistry and thermodynamics within process technology. Recycling of end-of-life goods is used in this paper to show how the limits can be evaluated on the basis of the theory of minerals processing and metallurgical engineering. This theory has been applied on European Union level to re-examine the legislation for automobile recycling in a recent stakeholder discussion involving the automotive industry (http://www.assurre.org). This theory and our models are finding their way into the computer aided design (CAD) tools of the automotive industry, developments that form part of a project to design the super light car of the future (http://www.superlightcar.com). Only such fundamental approaches will in future be able to provide the basis to argue and define realistic and sensible environmental legislation.

Jan 1, 2006

By R. Jovanovic

The main technological indicators of copper flotation which determine the level of revenue per mass unit of processed copper are utilization and the content of copper in concentration. This study describes the economic-technological model of copper flotation which can help determine, for the given technological and market conditions, an optimal percentage of copper in concentration, whereby the maximum revenue is achieved per ton of the processed ore in the process of flotation.

Jan 1, 2006

By John R. Davie

This paper describes the design and construction of two 5.6 MN capacity drilled piers installed to support the main loading elements of a large cantilevered gantry crane. The critical crane columns were located within and at the edge of an existing sheet-pile cofferdam, which had been filled with loose coal slag when it was originally constructed Due to the presence of the slag and the age and questionable condition of the sheet-piles, the drilled piers were installed to provide vertical and lateral supports for these columns. The lateral capacity of the piers was supplemented by two smaller drilled piers and two large spread footings that were linked by a system of grade beams.

Jan 1, 2006

Forty years ago Dr Pierre M Gy, a metallurgist, introduced variography as applied to monitoring a process. Consequently, his followers used the variogram to elaborate meaningful process control charts, especially since 1993. The name æChronostatisticsÆ was suggested several times by Gy as a logical name for this new science. The intent was to draw a parallel between the variogram identifying the variability components affecting a process parameter as a function of time, and the variogram used in geostatistics identifying the variability components of a given mineral content as a function of space. Heterogeneity problems encountered have indeed strong similarities. However, there is a fundamental difference. The variogram used in geostatistics is often stationary within a given type of mineralisation. While investigating a dynamic process through Chronostatistics, there is no such thing as a stationary variogram. Still, the evolving variogram provides essential information about subtle, often overlooked process difficulties. Chronostatistics is especially useful for management to take advantage of existing data that are often a forgotten source of valuable information to pinpoint recurring structural problems. The superiority of Chronostatistics over conventional statistical process control approaches is that it links observations to the inherent heterogeneity of materials under investigation, therefore to the sampling theory. Chronostatistics is like opening a new world to the metallurgist, making the process variability speak in a more comprehensive and in-depth way. Several case studies are presented to demonstrate the potency of this new science. For each of them, observations lead to solutions for continuous process improvement, therefore attractive economic opportunities. The philosophy is this: if a control chart shows a process is out of control, it must also suggest logical and pragmatic directions for solutions. The intent of this presentation is to vastly expand on these valuable, almost forgotten ideas.

Jan 1, 2006

By Andrew Howard

As the mining industry moves further into developing countries in search of new resources, its role in international development is coming under increasing scrutiny. This is a trend that is likely to accelerate, along with the potential for headaches among managers in the industry. Public interest in development and environmental issues is rising as faith in “big business” falls. This has strengthened nongovernmental organizations (NGOs) campaigning for sustainable development. And it has put more pressure on banks, governments and development agencies to curb corporate misdemeanors. Developing world governments are also becoming emboldened to reject previously agreed terms they do not consider equitable. The mining industry has begun to formulate a response to these pressures but must go much further. Societal and environmental issues must move from public relations to core strategic thinking. Abiding by rules or codes is not a relevant response. Instead, genuine support for sustainable development is required. This will involve delegating the responsibility for engaging with local communities to on-the-ground staff and developing a dialogue with local stakeholders rather than conducting an initial assessment and disengaging.

Jan 1, 2006