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By J. A. Pagliero, R. T. Quiroz, S. H. Castro

Selected voltammograms in tetraborate buffer solutions in the presence of ethyl xanthate or isopropyl xanthate at pH 9.3, for chalcocite, covellite, chalcopyrite, and enargite mineral electrodes, are presented. The concept of critical Eh of dixanthogen condensation (Ehc) is introduced, and the line of Ehc is thermodynamically defined in plots of log [X i] vs Eh, for methyl, ethyl, propyl, and butyl xanthates. A reaction scheme of xanthate oxidation in four steps, involving the dixanthogen condensation step, is proposed. A first attempt to interpret mineral flotation from a more general point of view is made. The electrochemical mechanism of dixanthogen formation and condensation is considered as a particular case of a more general and relevant phenomenon, which is the decomposition of the collector giving hydrophobic colloidal forms, whose associative behavior in bulk solution and at the mineral/solution interface is governed by colloid chemistry.

Jan 1, 1989

By E. J. Donovan, O&apos

The use of Dynamic Analysis techniques in the design of conveyor systems is extremely limited. The most frequent use of the technique is in large and expensive systems where the emphasis is on insurance against failure caused by catastrophic tension waves. This paper sets out to illustrate a much wider range of applications where dynamic analysis has been successfully employed. The examples chosen deal with identification and correction of dynamic low tension problems, the variability in take-up movement as other system parameters change, the requirement for proper tuning of starting controls and finally the absolute necessity for a complete understanding of the entire system when specifying brakes for critical applications. The intent of the paper is to get designers to view a conveyor as a system of interacting flexible components rather than as a single rigid body.

Jan 1, 1993

By D. G. Fredlund, J. A. Wilson

Conventional disposal of waste rock results in the construction of benches with fine and coarse layers dipping at the angle of repose. This interbedded structure influences flow pathways within the waste rock. A numerical modeling program was conducted to study a four-layer system consisting of alternating fine and coarse waste rock. The system was inclined from the vertical to forty-five degrees with heights varying from one to twenty meters. The results show the effects of gravity as preferential flow developed under unsaturated flow conditions.

Jan 1, 2000

By Kadri Dagdelen, M. Waqar Asad

Cement production involves the processing of raw materials that contain - Si02, A1203, Fe203, CaO, MgO, LOI (loss of ignition), S03, K20, Na2O, Ti02, P2055 and Cl- to produce the synthetic mineral mixture called "clinker". The use of other additives - sandstone, flyash, iron ore, and clay - is also mandatory in order to achieve the optimum blending requirements of cement. However, the use of these additives needs to be minimized due to their significantly higher costs ($/Ton). This paper presents a mixed integer programming (MIP)-based optimum quarry scheduling algorithm, which is used to generate quarry plans, satisfying geometric and production capacity constraints while providing minimum cost/optimum blend of raw materials mix to a cement plant. The benefits of this new methodology are demonstrated on a case study.

Jan 1, 2002

By L. S. Jen

The seven most important base and precious metals produced in Canada are copper, nickel, lead, zinc, molybdenum, gold and silver. Because much of Canada's mineral production is exported in the form of concentrates, it is of special interest to keep track of the production of these various concentrates and the capacity utilization of the concentrators producing them. Annual data surveys on individual concentrators, coupled with the interactive capabilities of the computerized mineral product ion system through a custom-tailored, fairly low-cost computer system configuration are used for ongoing monitoring. Rapid analysis of concentrator production can be carried out on a disaggregated basis that allows policymakers to see specific reasons for significant changes over the years.

Jan 1, 1986

By Ishwar G. Mulani

In conveyor design, the first step is capacity and the second step is belt width and speed. The third step is decision on 'ff," where distinction arises between DIN/ISO and CEMA for calculating resistances. Then again, both the methods are virtually similar. This topic helps in understanding Dm design style and its comparison to CEMA. This topic is from the book Engineering Science and Application Design for Belt Conveyor wherein the issue has been analysed in detail. It presents a workable calculation model to calculate the value off in design office, based on conveyor parameters. CEMA uses Kx, Ky and 0.01 5 instead off. Thus, f is a sum effect of Kx, Ky and 0.015. Hence, knowledge on f is also applicable to Kx and Ky. This helps to understand their relationship.

Jan 1, 2004

By William G. Davenport, Eric H. Partelpoeg

Direct smelting of copper in a single vessel has long been the extractive metallurgist's dream. Such a process offers the important advantages of (i) maximum use of the energy available from oxidizing the sulphur and iron of the concentrate; (ii) restriction of SO2 emissions to a single constant-strength source; (iii) minimum materials handling and (iv) elimination of at least one process step. Extensive developmental work was carried out in the 1960's and 1970's to implement such single-step processes. Some of the processes reached the prototype stage and it appeared that copper smelting technology was on the threshold of a new, efficient, minimum-pollution era. Since that time, however, the forward thrust has slowed and single-step smelting is still a process of the future. The paper describes in detail the potential advantages of single-step smelting; its history and current status; and the reasons why it has not been adopted industrially. It concludes that the potential benefits of single-step smelting are powerful and that many of the difficulties encountered in the 1970's will be overcome in the 1980's.

Jan 1, 1985

By Steven A. Tesdahl

Maintenance means keeping equipment running or restoring it to operating condition. However, the 21st century will usher in a broader need for equipment management, a cradle-to-grave strategy to preserve equipment functions, avoid the consequences of failure and ensure the productive capacity of equipment. Profitable future mining operations will have reduced the 35% of operating costs typically spent on maintenance and the unfavorable impact of downtime that often multiplied these costs by 300%. They will survive those operations that tried to carry outdated "maintenance" thinking beyond the year 2000. These surviving operations will have applied modern management techniques, technology and information to align the efforts of people with the needs of equipment. Future managers will use equipment management as an integral part of an overall production strategy. They will see it as a means of raising productivity, improving performance and minimizing downtime to maximize profitability. This global thinking will characterize all operations planning to survive in the competitive world of mining of the next century.

Jan 1, 1998

By Mark W. Springett

The sampling of precious metal deposits entails inherent problems due to the low mineral abundances, high mineral specific gravities, skewed grade distributions and wide ranges of mineral particle sizes. Sampling practices and precautions are discussed with particular attention to each of the tripartite stages of sampling - sample acquisition, sample preparation and sample assaying. Practical examples of approaches to the sampling problem are given and some examples of significant sources of error are provided from gold and silver deposits in North America.

Jan 1, 1992

By W. Pariseau, J. Goris, S. R. Dismuke

Ore at the Magmont mine in southeast Missouri is extracted by the room-and-pillar method on two and sometimes three horizons. In 1991, a plan was formulated to recover high-grade ore in pillars using cable halts to accommodate spans of more than 27 m (90 ft ). A test area was selected and a recovery plan developed. A cooperative rock mechanics study was established by Cominco Metals, the US Bureau of Mines and the University of Utah. When initially opened in 1968, the planned production rate was about 910 kt/a (1 million stpy). Due to declining reserves, the production rate was decreased in November 1992 to 570 kt/a (630.000 stpy). Pillar recovery now accounts for about 40% to 50% of the mined tonnage. This method plays a vital role in allowing Magmont to continue to operate.

Jan 1, 1996

By A. Zorychta, T. Cyrul, Z. Kleczek

INTRODUCTION Underground mining causes disturbances of the primary state of stresses. Resulting from those disturbances a loss of stability of rocks that surround excavation may occur interrupting the production and creating life danger for the personnel. One of the manifestations of such an instability is a rock burst phenomenon which mainly occurs at great depths. From the mechanical mint of view the rock burst is a loss of stability /Filcek et a1.,1984; Pietuchow and Linkow, 1976/ due to : - quasi-static stress changes in the surrounding rocks; we will call it s seam burst , - dynamic stress changes in the surrounding rocks caused by rock shocks ; we will call it roof burst. Possibility of the rock burst occurrence Is uniquely determined by the state of stresses existing in the rock mass. In the following sections of the paper we will consider different aspects of this question. Moreover distributions of displacements and failure criteria for a coal seam at longwall mining will be defined. STATEMENT OF THE PROBLEM Determination of the vertical stresses and displacements resulting from longwail mining will be based on the Budryk’s idea of a stress wave /Salustowicz, 1955/. The idea originates from the analysis of a roof plate /beam/ resting on the deformable foundation /Sean/ and subjected to the cylindrical bending. Equation of the bending lice uniquely defines vertical stresses and displacements which are induced in the seam. The equation will account only the shear force effect. Elimination of the bending moment has been shown and discussed by Zorychta and Bcrecki /Zorychta, 1985; Borecki and

Jan 1, 1986

Horizontal stress is an important factor that contributes to roof failure during a long wall entry development, especially when the immediate roof is weak. In this study, the effects of the three factors, the stress angle between the maximum horizontal stress and entry development, the stress ratio of the maximum to the minimum horizontal stresses, and the sequence of entry development, on the stress distributions in the weak immediate roof of a three-entry system are analyzed using the finite element method, when the horizontal stress is fixed. The results have confirmed that the stress angle has a significant influence on the stress distributions. Generally, the three-entry system is in the worst stress condition when the angle is about 60°_75°. The stress ratio has little effect on the roof stresses. In addition, the sequence of entry development has also little effect on the roof stress for the specific case analyzed.

Jan 1, 1999

By A. W. Swanson

Iron carbide, containing 93.3% Fe and 6.7% C, is a tailor made feed for the electric arc furnace (EAF) and has recently gained worldwide attention as a possible replacement for premium quality scrap. With 38% of the steel in the United States being produced in EAFs, iron ore producers have an interest in becoming direct suppliers to the EAF industry. This paper explains the advantages of using iron carbide in an EAF and describes test work on the product and development work being per formed on engineering designs for a commercial plant.

Jan 1, 1994

By Jan Walaszczyk

The paper concerns the calculation of stresses and displacements in working area of room-and-pillar mining system of cooper ore mines. A three-dimensional rock mass model based on the finite element method has been developed. The complete strain-stress characteristic for pillars has been applied, but for the purpose of modeling the curve has been approximated by three segments of lines: - the first represents a behavior of pillar before a failure, -the second corresponds to a progressive pillar failure phase, - the third represents the part of the curve, where the increase of strains do not cause the stress changes, and it is called the residual strength. The criterion of model stability has been derived, which can be useful for predicting rockmass stability. The programs have been built, which allow to calculate stresses in bar elements, displacements in plate nodes, and estimate the stability of the model, which consists of plate elements and one-dimensional elements with a segment strain-stress characteristic. The programs were used to consider two different problems, which are connected with mining design and the exploitation systems.

Jan 1, 1992

By P. E. Nielsen, T. L. Loga, B. B. Mauko

A numerical model is presented which simulates the dynamic fracturing process for a circular geometry fracture in a uniform stress medium. The dependence of crack aperture and net pressure in the crack upon various dominant parameters of the fracturing process is discussed. An analysis of a 75% nitrogen foam fracture in a coal seam at 5600 feet (1707 m) is also presented. The analysis is based upon the discussed parametric trends, the job records of treatment parameters, and a Nolte plot of net downhole pressure. It is interpreted that fracturing with water, in pre-foam fracture pump tests, resulted in significant fracture height growth. However, the subsequent foam fracture had reduced height growth due to the high effective viscosity of the foam and due to the higher magnitudes of elastic modulus and stress in the bounding rock strata with respect to the coal.

Jan 1, 1986

By Peter H. Grimley

It is important to realize that lending institutions have a very different risk-profile from that of an equity investor. For bank financing, a feasibility study must address the concerns of the lender and these can be summarized under the four 'PI Is: Project, Performance, Product and People. Generally, feasibility studies focus on the measurable project risks associated with a new venture, but frequently insufficient emphasis is placed on key risk areas such as ore grade and metallurgical recovery. Before accepting full or even partial non-recourse risk, financial institutions will demand evidence that the project was constructed according to specifications and within budget and that its Performance within agreed limits has been demonstrated. Product risk should be discussed in detail in any feasibility study. For industrial minerals, penetration of the market can be critical to success and for commodities with volatile prices, the sensitivity of the cash flow to a range of prices should be carried out. Methods of reducing price risk such as long term contracts or, in the case of gold, forward selling should be carefully evaluated. The People risk is rarely discussed in feasibility studies, but can be a key element. Few projects turn out to be faithful copies of the study and the ability of the operator to identify

Jan 1, 1988

By H. H. Richards, Ray L. Tobie, L. A. Thomas

GENERAL DESCRIPTION Since the beginning of operations, with the exception of a small tonnage mined by slushing, ore extraction has been by full gravity caving. Formerly, a checkerboard sequence of block undercutting was followed with the even-numbered blocks in one panel and the odd¬numbered blocks in the adjacent panel being mined. As these blocks were depleted, the intermediate or pillar blocks were mined (Fig. 1). Following this checker¬board, the mining sequence went through a number of changes, finally evolving into diagonal retreat panel cav¬ing by blocks (Fig. 2). The numbers in Fig. 2 indicate the sequence in which blocks were undercut. Gaps in the numbering sequence indicate undercutting on the level outside the illustrated area. Geology The ore body is a low-grade deposit of chalcopyrite mineralization disseminated throughout structurally weak, highly fractured, strongly altered granitic host rocks. It takes the shape of a gently dipping elliptical cylinder consisting of an ore shell of variable thickness surrounding an interior waste core. Major and minor axes of the mineralized cylinder are 1524 m (5000 ft) and 762 m (2500 ft), respectively, and length approximates 2438 m (8000 ft). Ore is sufficiently fractured to break readily into medium-coarse size. The igneous rock complex containing the ore body is covered by a wedge-shaped blanket of Tertiary con¬glomerate which was brought into place by faulting along the major regional structure of the San Manuel fault. Thickness of the conglomerate cap varies from only 9 m (30 ft) at the east end of the ore body to more than 610 m (2000 ft) at the west. Structurally, the con¬glomerate is much more competent than the igneous host rocks and, when caving, it breaks into massive chunks. Conglomerate boulders seen in drawpoints underground are very coarse. The total rock column over the initial mining area of the 1415 grizzly level was 354 m (1160 ft) of which 122 m (400 ft) was ore, 79 m (260 ft) was leached igneous capping, and 152 m (500 ft) was conglomerate above the San Manuel fault. Diamond Drilling: From 4572 to 7620 m (15,000 to 25,000 ft) are drilled annually from underground workings to delineate the ore body. MINE DEVELOPMENT Haulage Level In the south or main ore body (see Figs. 3-6), with the exception of the draw and transfer raises, all the extraction openings are concreted (Seaney and Tobie, 1965). The haulage panel drifts, which are 18 m (60 ft) below the grizzly drifts, are first driven with pre¬concrete ground support. The drift, which has an arched section, then is concreted using mobile collapsible steel tunnel forms. The haulage drifts leading from the pan¬els to the hoisting shafts are not concreted. After the panel drifts have been concreted, the raise stations from which transfer raises will be driven are constructed and the raise-station ore-drawing chute is installed. The chute is prefabricated of A-36 steel with undercut guillo¬tine gates made of abrasion-resistant 2.5-cm (1-in.) steel plate powered by 20-cm (8-in.) air cylinder installed on each side of the raise station. Transfer Raises The transfer raises are lined with 15 x 20-cm (6 x 8-in.) cribbing and are 1.22 m (4 ft) in the clear. Each cribbing is protected from wear by a high carbon steel angle which is nailed onto the cribbing. The transfer raises are driven from each side of the raise station on an angle of 1.1 rad (63°). Each raise con¬sists of a main and a backover branch. The transfer¬raise driving crew consists of two men working one shift only. Grizzly Drifts After the transfer raise reaches the grizzly level, the grizzly drift can be driven. The grizzly drifts are spaced at 10.6-m (35-ft) centers and are driven parallel to the long axis of the ore body (see Fig. 2). This drift is driven by a two-man crew working on one or more drifts at a time using feed-leg machines. The eight grizzlies in the 42.7-m (140-ft) long drift are spaced at 5.3-m

Jan 1, 1982

By Jorge Lanza

SUMMARY La Granja copper deposit, in terms of volume, is among the five largest deposits in the world and represents reserves of three thousand million tones. The field consists of a 40 m. thick layer of copper lying over the secondary ore and further down the primary copper. The flotation process has indicated a recovery rate of 88 to 90 percent and concentrates of 27 to 32 percent of copper. The acid leaching process of low grade ore produces financially acceptable results. To carry out the project, it is necessary to build long distance pipelines and a port. Both the Feasibility Study and the Environmental Impact Study on the project have been approved by the Peruvian government. INTRODUCTION La Granja is located in the district of Querecoto, province of Chota, in the department of Cajamarca, in the Northwest of the country (Figure 1). Geographically it is situated on the eastern slopes of the Andean mountains at an altitude of 2,000 to 2,700 m.a.s.1. (Figure 1). The site is an 8 hour car ride from the city of Chiclayo, capital of the department. The first 60 km. are over a paved road and the remaining distance is over a narrow hard dirt road. The copper porphyry of La Granja was discovered between 1969 to 1971 during some geochemical prospecting activities carried out by the State mining institution, Ingeomin (currently Ingemmet). From 1978 to 1982, Ingemmet continued with its geochemical and geophysical studies supported by a German technical assistance program. A total of 19 bore- holes were drilled (5,814 m.) and a 90 m. long tunnel made. This study calculated reserves of 175 million MT. In 1993, Minero Peru drew up a technical-financial study based on the above studies and proposed a 12 year extraction operating program: 20,000 MT daily using the leaching process, followed by 13 years of operation using the flotation process with the same daily volumes. In 1994, Cambior Inc. won an international auction in order to carry on further exploration work and to have a purchasing option. Since that date the company

Jan 1, 1998

By M. R. Yalamanchili, C. A. Young, J. J. Kellar, W. M. Cross, J. D. Miller

Introduction Researchers have long speculated regarding the adsorption state of collectors on mineral surfaces. Only recently have analytical techniques become available that allow direct in situ analysis of adsorbed layers. With reactive internal reflection elements (IREs), Fourier transform infrared spectroscopy coupled with internal reflection spectroscopy (FT-IR/IRS) allows for unobtrusive investigation of the adsorbed layer (Harrick, 1979). This technique has been used both for the in situ identification of adsorbed species and for the direct calculation of collector adsorption density in real time from infrared spectral data (Miller and Kellar. 1988). The reactive mineral IRE serves both to internally reflect the infrared light and to act as a substrate at which collector adsorption can be monitored. Shown in Fig. I is a schematic of light being internally reflected in an IRE. As the light is totally reflected at the interface, an evanescent wave propagates a short distance (typically a few microns) away from the IRE, and sampling of the interfacial region occurs. Because of multiple internal reflections, great sensitivity can be obtained. Flotation systems for which this method has been demonstrated include CaF2/oleate, Al2O3/dodecylsulfate, CaCO3/oleate, ZnS/xanthate and KCI/octylamine (Miller and Kellar, 1988; Kellar et al., 1989, 1990; Miller et al., 1990). Of particular interest to flotation chemists is the conformational behavior of the alkyl chain of adsorbed collector molecules. In the simplest sense, conformation can bethought of as the relative flexibility of the hydrocarbon chain caused by rotations about carbon-carbon single bonds. The flexibility is described by the amount of gauche/trans conformations in the alkyl chain. Figure 2 shows examples of gauche and trans conformations (rotational isomers or rotamers) in a hydrocarbon chain. These two conformations are observed when the terminal methylene groups in any four-carbon subchain are on the same side (gauche) or opposites sides (trans) of the plane of the middle carbon-carbon bond. A gauche conformer (rotamer) is thus a state of maximum potential energy, whereas a trans conformer is a state with minimum potential energy. The difference between these states has been found to be approximately 0.5 to 0.8 kcal/mole (Mead et al., 1986). The relative number of butane molecules present as gauche conformers with respect to trans conformers can be calculated from the Boltzmann equation (Mead et al., 1986). At 25° C approximately 66% of the butane molecules are trans rotamers. [ ] However at 100° C, only 33% of butane molecules are trans rotamers. Exposing the hydrocarbon chain to a polar, rather than an a polar, medium should also cause an increase in the number of gauche butylene groups in a hydrocarbon chain, although this effect has been difficult to observe experimentally (Mead et al., 1986). Forming a crystalline hydrocarbon is equivalent to decreasing the temperature, which greatly increases the amount of trans butylene groups present in the chain. From the preceding discussion, a picture of the solution species of concern can be developed. The collector monomer should exhibit the greatest number of gauche rotamers and most likely will look crumpled or balled-up to reduce the surface area in contact with water. The micellar form is expected to be aggregated, with the hydrocarbon chain existing in a less polar environment. These characteristic conformational features have been examined by FT-IR spectroscopy for various liquid phases of alkanoic acids (Umemura et al., 1981; Cameron et al., 1982a; Yang et al., 1986; Wong, 1987; Wong and Mantsch, 1983; Cross et al., 1992), phospholipid membranes (Fringe Ii, 1980; Casal and Mantsch, 1985: Wong et al.. 1988;

Jan 1, 1994

By M. J. Meulendyke, J. D. Purdue

Within the mineral processing industry, a range of grinding conditions exists which include semiautogenous grinding (SAG),rod milling, and conventional ball milling. Each of these mill environments presents a unique environment for grinding media, requiring the application of specific physical and chemical properties for optimum grinding media performance. The environments are characterized by varying degrees and combinations of abrasive, corrosive, and impact wear. An extensive test program has been conducted to determine the extent wear rates vary between these different applications. Test results are related to production results, ball size, and mill operating conditions.

Jan 1, 1990