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By N. N. Manu

In the Central African Copper Belt, sulfidization flotation is the standard practice for dolomitic copper oxide ores. It is a delicate process, and its plant application requires close control of the reagent addition. This paper presents the results of a thorough laboratory investigation. It features the monitoring, during sulfidization, of the pulp pH, the residual sulfide ion concentration and redox potential. Variables examined during the process were: retention times, sulfidizer additions, pH, collector type, dispersant dosage and reducing agent addition. Implications of the findings for plant application and process control are also briefly examined.

Jan 1, 1994

By J. P. Allen, D. A. Rice, H. L. Abercrombie

Cobalt, nickel and manganese can be recovered quickly, cleanly and selectively from cobalt-rich manganese ocean crust by leaching in dilute acid solutions in the presence of hydrogen peroxide. Common selective precipitation methods can then be used to recover these metals from the leach liquor. The leaching reaction produces only oxygen as a byproduct, and the waste residue from leaching was tested and found to be nonhazardous under existing EPA specifications. The leaching process is effective in either fresh water or seawater. This research is a part of the Bureau of Mines program to identify the mineral resources of the Exclusive Economic Zone and devise methods, for recovering their valuable components.

Jan 1, 1992

By Roger Beckie, Leslie Smith, Craig Nichol

To study the hydrogeological processes that control the movement of water through unsaturated waste rock, an intermediate-scale (8m x 8m x 5m) waste rock pile has been constructed and instrumented. The constructed pile is monitored for moisture content, matric suction, temperature, matrix water chemistry, gas chemistry, gas pressure, rainfall, evaporation, discharge volume and discharge chemistry. The pile is built upon a grid of 16 contiguous lysimeters. The experiment is designed to investigate the mechanisms that create rapid water flow through a pile and its exchange with slower-moving matrix water.

Jan 1, 2000

By J. Twining, V. Nguyen, J. Perera

A computer code for ecological risk assessment (ERA), AQUARISK, has been developed and applied to evaluate the likelihood of biotic detriment due to exposure to acid rock drainage (ARD) from the Burkunga mine site in Australia Stream water quality monitoring data were used for the assessment and were compared with a) national water quality guidelines, b) literature derived ecotoxicology data and c) biological monitoring data. With bioavailability calculations, the code predicted that, for metals exceeding the guidelines, 44% of macroinvertebrate species above the mine and 100% below the mine would be adversely affected by the metals in the stream. This compares reasonably and conservatively with biological monitoring that showed observed reductions of 41% and 85% of species respectively at each site. Using literature data for macroinvertebrates to predict impact produced similar estimates to using data for all taxa. Use of speciation modeling also lessened the degree of reduction in the median water metal concentrations required to achieve acceptable impact (measured either by exceedence of criteria or by species likely to be affected) by a factor of 75%. This result implies significant economic and management benefits in relation to remedial engineering or water treatment options for sites.

Jan 1, 2000

By Davidtz. John C.

INTRODUCTION The effectiveness of collector type on sulfide mineral flotation is generally determined by the amount and type of functional groups of collector molecules that interact with surface and water at the mineral/collector/water/gas interface. The final interfacial state when bubble contact takes place is preceded by chemical and physical reactions that involve these gas/liquid/solid interactions. These interactions differ not only for different minerals, solution and gas composition, but also for different collector molecules. The purpose of this paper is primarily to summarize the developments and status of short (C2-C6) and long (C12) chain, aliphatic collectors that contain three sulfur atoms in their polar function. These are trithiocarbonates (TT'Cs). For purposes of comparison, similarities in molecules containing 0, N and S are compared. Mostly short chain ionic collectors molecules of dithiocarbonates (DTCs) and TT'Cs were compared. The studies, largely bench scale flotation and plant testing, were carried out on ores containing Cu, Ni, Au, and PGM's. Studies of long chain 'ITC collectors are reported on Ni, PGM and auriferous pyrite ores containing uranium. Under starvation dosage conditions, surface activity coefficients of short chain collector molecules and interacting water were calculated. Based on the UNIFAC group contribution method of activity coefficient calculations, the Gibbs Excess Free Energy

Jan 1, 2005

By B. Cavender

The operating lifetime, or production rate, selected for a mining project is among the most important factors influencing the project's design and ultimate economic success. Incorrectly-determined lifetimes can lead to the erroneous rejection of projects as uneconomic as well as the suboptimal exploitation of producing properties. This paper examines the optimal lifetime calculation using traditional discounted cash flow and recently-proposed option pricing techniques. Using each method, the production rate is determined as that rate at which the project's net present value is maximized.

Jan 1, 1993

By E. S. Erickson, R. L. Stone

Introduction Evidence from blast furnace operations has indicated that using pellets with a higher ISO low temperature reducibility, a lower SiO2 content, and better resistance to low temperature degradation results in considerable coke savings and improved furnace operation. Although these benefits could not be directly related to reducibility differences alone, we believed there was sufficient evidence of the advantages in improved pellet reducibility to warrant laboratory investigation of ways and means to effect such improvements. It is well known that pellet reducibility can be significantly altered by changes in the basicity and the amount of non-iron oxide constituents. Past work (Friel and Erickson, 1980, 1982; Saeki et al., 1977; Thanning, 1974) has shown that with increased MgO contents, and at optimum CaO/S1O2 ratios, significant improvement in low temperature reducibility can be attained. The improved properties of such fluxed pellets have reportedly led to increased blast furnace efficiency and productivity (Saeki et al., 1977; Ilmoni, 1975). Less well known, however, is exactly what factors control reducibility in acid pellets. Because of this gap in knowledge, studies were undertaken of the factors affecting reducibility in acid pellets and to estimate their relative significances in modifying reduction behavior. This paper describes that part of our work done to determine the effect of bentonite on reduction behavior. Our approach was to first examine the effect of bentonite's presence on as pure an iron oxide as possible (i.e., a magnetite "superconcentrate" containing about 0.2% SiO2) so as to eliminate any gangue-binder interaction. The next step was to look at bentonite effects on concentrates with only limited amounts of gangue (containing about 1% SiO2), but of two different types, simple and complex silicates. Last, we

Jan 1, 1988

By D. W. Fohlen, B. A. Filas

The International Finance Corporation (IFC), the private investment arm of the World Bank Group (WBG), requires all IFC-financed projects to comply with its environmental and social policies and guidelines. IFC's review process involves an environmental and social assessment and the implementation of an Environmental Action Plan (EAP) that will set forth the necessary actions to bring the operation into compliance. This paper provides an overview of the environmental and social policies and guidelines that apply to mining projects and examines how WBG/IFC policies and guidelines are applied to mining projects in developing countries. In addition, it includes a review of the increased emphasis IFC is giving to social issues over the past several years based on the existing WBG policies. IFC’s process for the environmental and social review of proposed investments is briefly discussed. The paper focuses on how IFC emphasis has shifted from the traditional environmental and impact mitigation analyses of a few years ago to the integrated social and environmental awareness, action (EAP), and implementation programs (social plans) required today. Today, IFC's focus is to promote sustainable development by investing in projects that directly benefit local communities and the environment. Examples of these changes will be highlighted by a review of recent investments located in West Africa. The goalposts have not moved, but the rules of the game have become tougher.

Jan 1, 2001

By Adrian Smith, Debra W. Struhsacker

There is now overwhelming evidence that, despite concerns to the contrary, natural degradation of cyanide and cyanide attenuation by hydrogeochemical processes are capable of minimizing or eliminating potential water qua1ity impacts from heap leach systems. A1 though there was some recognition of these data by the regulatory authorities, for example the initial USEPA modification of cyanide standards to an advisory level, many states have codified standards inappropriate to the clearly site specific nature of heap leach operations. As an overview to this problem, this paper will integrate the theoretical chemical data on cyanide with the observed geochemical behavior of cyanide in the decommissioned heap leach environment. The cyanide species that are likely to exist within an abandoned heap leach system will be identified, and the relative toxicity and potential environment effect of these cyanide species will be discussed. These data will then be used to evaluate cyanide detoxification regulations for decommissioned heap leach projects in 14 states.

Jan 1, 1987

By S. N. Groudev

A process for the combined chemico-biological removal of iron present as oxide minerals in different mineral raw materials (quartz sands, kaolins, clays, etc.) was developed. In the process, mineral raw materials are leached at about 90 °C with lixiviant containing microbially produced oxalic and hydrochloric acids. The leaching is carried out in mechanically stirred acid-resistant reactors for periods of from 1 to 6 hours, depending on the iron content and the forms of iron in the raw materials being leached. The iron contents of some sands treated by this method were lowered from levels that were in the range of 0.035% to 0.088% Fe2O3 to less than 0.012% Fe2O3, making them suitable for the preparation of high-quality glass. The iron contents of different kaolins were lowered from levels that were in the range of 0.65% to 1.49% Fe2O3 to levels in the range of 0.44% to 0.75% Fe2O3. As a result, the whiteness was increased from values of 55% to 87% to values of 86% to 92%. The iron content of clay was lowered from 6.25% Fe2O3 to 1.85% Fe2O3, and this increased the “fireproofness" of the clay from 1,670°C to 1,750°C. A similar process was used for the leaching of aluminum from aluminosilicates, mainly clays and kaolins. However, in this case, the microbial fermentation fluid containing citric acid was acidified by means of sulfuric or hydrochloric acid or by means of different mixtures of mineral acids. For enhancing aluminum solubilization, the aluminosilicates were heated before leaching at 600° to 650°C for 1 to 2 hours. Over 90% of the aluminum present in different clays and kaolins were leached within 3 to 6 hours. "Silicate " bacteria related to the species Bacillus circulans were used to leach silicon from low-grade bauxite ores containing aluminosilicates as impurities. The bacterial action was connected with the degradation of the mineral structures (by means of microbial metabolites such as organic acids and exopolysaccharides), as well as with the selective separation of the rich-in-aluminum fine fractions, which were retained by the mucilaginous capsules of the bacteria. The solid residues after treatment were characterized by higher values of alumina and silicon module (A1203: SiO2 ratio), and they were suitable for processing by means of the Bayer process for recovering aluminum. The bending strength and other ceramic properties of kaolins were improved by contact with well-developed cultures of "silicate" bacteria. The improvement was caused mainly by bacterial metabolites (exopolysaccharides) that acted as resins during drying.

Jan 1, 2000

By J. S. Lewis

Beneficiation and physical and chemical processing of non-terrestrial materials will borrow strongly from terrestrial experience but will also involve the necessity of handling literally unEarthly feedstocks, reagents and environmental conditions. The present state of scientific and engineering understanding of the processing of non-terrestrial minerals, gases and hydrocarbons is reviewed, with the production of rocket propellants, life-support fluids, structural metals and refractories as the goal.

Jan 1, 1994

By Shaoxian Song, Shouci Lu, Jingyon Gou, Pan Yiuwen

The calculated potential energies of interaction between hydrophobic particle of three minerals (rhodochrosite, quartz and talc) and air bubble show that the energy of hydrophobic interaction is the dominant factor for their attachment. An attachment rate equation, integrating particle -bubble collision and adhesion by introducing a "capture efficiency", has been put forward. It was found that the hydrophobic particle-bubble aggregates can not be disconnected in the bulk zone of flotation cell, whereas in the impeller zone the breakup may occur, particularly for the coarser particles captured by bubble. Finally, the flotation rate constant was estimated theoretically and verified by experiments.

Jan 1, 1995

By Henry G. Healy

Observation well (Hydrographs are shown for these selected wells) Contour represents the height, in feet referred to mean sea level, to which water would have risen in tightly cased wells that penetrate the major water- bearing formations in the Floridan aquifer, July 6-17, 1961. Contour interval 10 and 20 feet, changing at mean sea level. [ ] Extent and distribution of flow areas vary with fluctuations of the piezometric surface, particularly in areas of heavy Relatively small areas of artesian flow are not included immediately adjacent to and paralleling the coast and many of the major rivers and springs

Jan 1, 1966

By Gordon R. Wicker, John A. Cole

Although the evaluation of autoclave oxidation for Getchell ore was begun nearly 40 years ago, its ultimate implementation in 1989 represents the first substantial improvement in the economics of processing this refractory ore. Sulfide ores at Getchell were previously roasted prior to leaching (in the 30's and 60's), resulting in somewhat lower recoveries than are currently realized by autoclave oxidation. Recoveries on the order of 90% are expected from the high-arsenic sulfide ore over the expected 10-year mine life.

Jan 1, 1990

By S. A. Kupferman

Cement raw materials used in southern California and Arizona cement plants occur in a wide variety of geologic environments. Limestone, the primary material making up 75-80% of the raw materials mix used in cement manufacture, is mined solely from Paleozoic Era deposits. During this time, 570-245 million years ago, vastly more limestone was formed in California and Arizona than at any other time (continent was in southern latitudes). The general geology of each limestone deposit associated with the eight southern California and two Arizona cement plants will be reviewed. Many of these deposits are geologically complex, having been subjected to Mesozoic deformation, metamorphism and instrusive events, along with Cenozoic uplift and deformation. All of the cement plants in this region require the use of secondary additives in order to meet the chemical requirements for cement. The kinds of additives vary greatly, depending upon the chemistry of the limestone deposit, cement specifications, and the cement manufacturing process. In some cases, clay deposits with suitable chemistry on or near the limestone sources are utilized. Where alkali limitations or need for alumina-rich materials exist, then specialty clay deposits are used. Iron-rich sources in the region include iron ore deposits and slag or mill scale from local steel mills. The geologic setting and location of these additives, along with gypsum and silica-rich deposits presently in use, will be mentioned.

Jan 1, 1987

By R. J. Sweigard, R. V. Ramani

Productive and beneficial use of reclaimed surface-mined land is a concern of industry, government, and the general public. A process has been developed that will aid mine planners and public planners in the evaluation of postmining land use potential. This process involves the application of site planning principles to surface-mined land in a way that ensures productive end use of reclaimed land. The process consists of 10 basic components and is iterative in nature. Termination of the process depends on the amount of data collected and the evaluation requirements of each mining site. The analysis centers around the economic, environmental, and social impacts of the alternative land use plans.

Jan 1, 1987

In 1990, US mine production of barite increased 54.1 %. Barite consumption, sold or used by grinding plants, increased by 27.6%. Imports were about the same as 1989. World mine production in¬creased 12.3%, according to the US Bureau of Mines. The value of domestically produced barite, fob mine, decreased 12.7%, according to the Bureau. The declared value, cif US port, of all imported crude barite during the year 1990 increased from $40.27/t ($36.54 per st) in 1989 to $40.61/t ($36.84 per st). Nevada continued to be the leading producer of barite with 82% of the total, followed by Georgia and Missouri. It is estimated that 750/c, of the domestically mined barite was used as a weighting agent in drilling fluids. The remaining 25% was used in barium chemicals, glass or as a filler. Most of the production from Missouri, Georgia and Tennessee was used in the non-oilfield sector. Of the total barite used by grinding plants and chemical manufacturers, it is estimated that 90% was used in drilling fluids and 10% in the non-oilfield sector. This includes barium chemicals and fillers in paper, plastics, and glass. Tonnage consumed in the drilling fluids market increased due to the higher average rig count during 1990. The average number of rotary rigs operating, (1010), was 16.2% more than the 1989 average of 869 in the US.

Jan 1, 1991

By J. F. Cuderman

In situ experiments at the Department of Energy's Nevada Test Site (NTS) have extended the technology of propellant-based fracturing to include liquid- filled, uncased boreholes. Previous work had developed the technology for liquid-free, uncased wellbores. Test results show that fracturing behavior is considerably more complex in liquid- filled boreholes than in the liquid-free case. Compared to liquid-free boreholes, liquid-filled boreholes have faster pressure risetimes and lower peak pressures, large hydraulic-type fractures propagating several meters beyond the end of the test zone, numerous oscillations in the pressure history, and variable types of fracturing within a single test region. Multiple fracturing is initiated in the wellbore of a fluid-filled borehole when the proper propellant mixture is used but, unlike fluid-free wellbores where up to eight fractures propagate, only one to three hydraulic- and/or shear-type fractures propagate. Hydrodynamic effects involving liquid compression during borehole pressurization appear to be responsible for the differing phenomena observed in fluid- filled boreholes.

Jan 1, 1986

By John O. Marsden

The project development metallurgist is faced with an interesting dilemma: The use of overly conservative metallurgical projections and cost estimates can kill a project that has the potential to provide needed jobs and growth to a company's bottom line. On the other hand if the metallurgist uses a highly aggressive approach by trimming capital and operating cost estimates to the bone and by applying highly optimistic metallurgical projections, there is a risk of creating a project that can never live up to expectations. The metallurgist must walk a tightrope between "sandbagging" and "overoptimism," and this tightrope is fraught with political intrigue and difficulty. This paper takes a some- what lighthearted look at some of the political aspects associated with this issue, and other issues, and offers a few guidelines for walking the "political metallurgical" tightrope.

Jan 1, 2001

By A. J. Neale, B. C. Flintoff

A relatively inexpensive and reliable method of using liquid phase tracers to aid in the solution of material balance problems is introduced. The method is of value in situations where one is required to calculate a material balance around a process that has the operating appearance of a "blender" or "splitter" with respect to the available slurry sample data. The paper briefly reviews material balance development and tracer applications in mineral processing, introduces the problem to he addressed, and provides both theoretical and industrial evidence establishing the potential of the method.

Jan 1, 1987