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By K. Osseo-Asare

Metal recovery from solution, i.e., the formation of a solid product from a purified aqueous electrolyte solution, is increasingly becoming more than a simple matter of bulk precipitation. In many cases, operating conditions must be carefully manipulated to control the rate and yield of the precipitation/crystallization process, as well as the purity and physical characteristics of the solid product. A review is presented of the underlying physico-chemical processes, with emphasis on solution and interfacial chemistry. Opportunities for the integration of hydrometallurgical metal recovery and materials processing operations are discussed.

Jan 1, 1989

By Marie-Antoinette Dziurla, Barrie Johnson, Åsa Kolmert

Acidophilic bacteria are well known for their role in accelerating the oxidative dissolution of sulfide minds, such as pyrite. Other acidophiles, however, are able to catalyze dissimilatory reductive reactions. Bacteria that reduce ferric iron to ferrous, and sulfate to sulfide, were isolated from ARD-impacted environments and immobilised onto porous beads made of recycled glass. Column bioreactors containing colonized beads were constructed and peacolated with synthetic and actual ARD, and evaluated for their capacities to promote iron or sulfate reduction, and pH amelioration. Iron reduction did not require strictly anoxic conditions in bioreactors, and rates of up to 800 mg Fe3+ reduced/(l*day) were achieved, with a conversion efficiency of up to 98%. Using mixed populations of acidophilic fungi and iron-reducing bacteria, the bioreactors were capable of promoting iron reduction using paper pulp as sole carbon and energy source. Reduction of sulfate in pack bed bioreactors was observed with acidic wastewaters of pH 3 and above, though average rates of 300 mg sulfate reduced/(l*/day) were less than those recorded for circum-neutral pH systems. Bioremediation of ferric iron-rich ARD was assessed using coupled iron-reducing and sulfate reducing bioreactors.

Jan 1, 2000

By M. C. Roberts

In assessing the future markets for a mineral from a producing district, three key aspects must be considered: 1) the future growth in markets, 2) the competitiveness of the district in terms of production costs and reserve adequacy, and 3) the competition from alternative sources of supply. This paper will focus on the first issue by developing a method of predicting the demand for phosphate from the trends in the major markets for phosphate products, primarily the fertilizer and agricultural markets. The paper will show how broad changes in the final end use markets for phosphate products have evolved over time and how this has affected the needs for phosphate rock. These trends are then projected into the future to make an assessment of future phosphate requirements.

Jan 1, 1998

By G. J. Olson, K. S. Noah

A combined physical/biochemical process for the precombustion removal of 13 inorganic hazardous air pollutant (HAP) precursors, i.e., Sb, As, Be, Cd, Cr, Cl, Co, F, Pb, Hg, Mn, Ni and Se, from coal was tested. Biochemical processes for removal of HAP precursors from coal potentially offer advantages of deeper cleaning, more specificity and less coal loss. The slurry column is a second-generation process for the beneficiation o f fine (60-mesh x µm coal by a combination of physical separation of mineral matter and biooxidation of pyrite. Sixty-seven percent removal of pyrite from a 60-mesh Pittsburgh #8 coal was achieved at a 35% (w/w) slurry concentration and a five-day reactor residence time. Ninety percent of the heating value of the feed coal was recovered. Among the HAP precursors of most concern, over half of the Se, As and Hg were removed from the feed coal. From 40% to 70% of most HAP precursors were removed from the feed coal. Hg in the feed coal was reduced from 0.12 to 0.054 ,µg/g in the product coal, while waste coal contained 0.24 µg/g.

Jan 1, 2000

By R. L. Lewis

A simple method for estimating the steady-state water quality of a pit lake is presented. The steady-state concentration of a conservative chemical constituent in a pit lake is shown to be a simple function of the inflow rate, the evaporation rate and the inflow concentration. An analytical method is presented for estimating the equilibrium ground water-inflow rate for use in water-quality predictions. The time required to reach chemical steady state is estimated using an iterative mass-balance model. Mine operators should find the methodology useful for planning and screening regulatory applications where conservative estimates of pit lake water quality are desirable.

Jan 1, 2000

By Ed Ramsay

The Hill is a cyanidation plant with flotation and roasting. The grinding and treatment have at the present time a capacity of 1400 tons of ore per day and the precipitation has a capacity of 6000 tons per day. The ore is delivered by a 36" conveyor belt and tripper to 8 mill bins having a capacity of 6000 tons. The ore from these bins is discharged onto 20" gathering conveyor belts which are regulated with p.i.v. speed changers to control the belt weight. A weightometer determines the tonnage milled. The feed enters the 8' x 12' rod mill through a rubber lined chute and the product is discharged through a launder to a 7' rake classifier in closed circuit with 10' by 6' hardinge ball mill. Lime slurry is added at the rake classifier to give a strength of .30#/ton. The classifier sand is fed into the ball mill with a scoop feeder and the mill discharge flows in a launder back to the classifier. The classifier overflow is pumped to a 24' by 12' bowl classifier in closed circuit with a 8' by 15' regrind mill. The bowl classifier sands are fed to this mill and the mill discharge is pumped back to the bowl. The bowl overflow at 8% - 200 mesh is the final product from the grinding circuit.

Jan 1, 1975

By Pedro Marques Bernardo, Carlos Dinis da Gama

This paper presents a methodology for design and simulation of underground ventilation networks, based on the analysis of real situations, followed by the careful interpretation of the obtained results in order to implement their optimization. The method involves two basic steps: the construction of a complete ventilation data base for the mine, upon a series of care- fully previous surveying studies in order to determine the values of its ventilation parameters, and the simulation of relevant situations for the ventilation system optimisation. A simulation model, modified after the Hardy Cross method, allows the testing of various mechanical means located at different points of the network, aiming to determine the technical-economical feasibility of each solution. These simulations obey the directions of air flow in each point of the mine, as determined by the directions of the natural ventilation flow established in the data base that represents the network. The methodology was validated upon studies developed in ventilation network of the Panasqueira Mine (Portugal), in two situations: regular production (mechanical ventilation) and care- maintenance (natural ventilation).

Jan 1, 1997

By Jan Leja

Surfaces of metal sulfides react readily with selected constituents of environment. Two types of reaction products may form: (1) primary, chemisorbed and hydrophobic surface products or primary hydrophilic surface products, and (2) secondary reaction products -- produced during continued oxidation-reduction processes. For flotation, the chemisorbed surface product and the secondary reaction products, elemental sulfur or metal xanthates, must provide sufficient hydrophobicity of the surface to ensure particle-bubble attachment.

Jan 1, 1986

By G. T. Lineberry, B. R. Yama

Artificial intelligence research has produced several tools for commercial application. Some of the techniques that are widely used today include neural networks, fuzzy logic and expert systems. Artificial neural networks (ANNs) are excellent predictive, pattern recognition and data analysis tools. In the mining industry, ANN techniques are being used commercially for real-time process-control applications. Modeling of spatial data, ore-reserve estimation, tunnel design, long wall-stability prediction and geologic roof classification are additional applications in which neural networks have been applied successfully. In this study, a standard back propagation algorithm was used to train a series of neural networks for a real-world predictive task. After training and optimizing the neural network architecture, the performance of the network is measured on an independent validation set. Results indicate a mean error of less than 1 % between the actual and predicted values. A neural network model was developed for learning the spatial continuity of a mineral field and, consequently, for predicting sulfur values for given coordinates. The neural network not only performed satisfactorily, but in some cases performed even better than the kriging model.

Jan 1, 2000

By M. Karmis

Surface subsidence has been recognized as an inevitable consequence of underground coal mining for several centuries. The damage resulting from this phenomenon has been witnessed in rural as well as in urban areas and ranges from simple land settlement to severe structural damage to buildings. Subsidence prevention is not feasible, at least under the existing technological and economic constraints of underground coal mining. Using a rational method of subsidence prediction, it has been demonstrated in many coalfields that subsidence control can be successfully practiced in order to reduce and accommodate subsidence within environmentally acceptable levels. This paper presents the development and testing of a subsidence model, based on the zone area method. This technique is a refined development of the influence functions and it is capable of investigating a mining plan of any shape, thus facilitating both longwall and room-and-pillar mining systems. More specifically, this study can be divided into two major efforts: (a) The development of the zone area model. This formulation was designed to accommodate the analysis of an optimum number of zones, over the area of interest, both accurately and efficiently. (b) The testing of the computer techniques with appropriate field measurements. In order to accomplish this, published as well as unpublished information was collected and analyzed according to a regionalized scheme. This procedure minimized differences in subsidence characteristics between the various coalfields and allowed a regional validation of the predictive capabilities of the model.

Jan 1, 1982

By J. E. Gebhardt, S. Chander

Significant advances have occurred in the use of electrochemical techniques for sulfide mineral flotation research. The techniques have been used singly or jointly with other characterization methods. When used in combination with other methods, the electrochemical methods provide a means to control the state of oxidation of the surface. Various analytical methods are employed for characterization. The methods that have been used include wetting, x-ray photoelectron and fourier transform infrared spectroscopies. The electrochemical methods include voltammetry and transient electrochemical techniques of galvanostatic polarization and AC impedance spectroscopy. The challenge for the future lies in the utilization of this knowledge in plant operations so as to increase the overall efficiency of flotation separations.

Jan 1, 1989

By Y. C. Kim

One aspect of long-range mine planning in an open-pit mine is first to define the ultimate pit limit, i.e., the projected size and shape of the pit at the end of its life. This chapter is concerned with various techniques that are currently in use today in determining the ultimate pit limits using the computer. Prior to the early 1960's, open-pit limits analyses were entirely performed manually. This manual technique has been well explained by Soderberg and Rausch in Surface Mining (1968). Soderberg and Rausch also explain clearly the need for establishing the ultimate pit limits in long-range mine planning, i.e., location of surface facilities, dumps, etc. Consequently, the need for ultimate pit limit design will not be reiterated here. Nor will the definitions of the most commonly accepted terminologies such as break-even stripping ratio, economic cutoff grade, ultimate and working slope angles, preproduction stripping, etc. be repeated here. Briefly, the objective of the ultimate pit limit design (which is also frequently referred to as pit design in short) is to determine the projected final pit limits of an ore body and its associated projected grade and tonnage, which will maximize some prespecified economic criteria while satisfying practical operational requirements.

Jan 1, 1979

By Michael D. Zuber

This paper discusses the use of a coalbed methane simulator that has been modified to account for the removal of grid blocks as a function of time to estimate gas emission and production for a variety of mine-associated problems. The specialized features of the simulator are presented. Example applications illustrate the models' use in estimating methane emission rates during mine roadway development, and estimation of longwall panel degasification by horizontal boreholes.

Jan 1, 1997

By Allan D. Fernie

Many long conveyors, 2 - 20 km plus, have been installed over the past 10 years. Conveyor belt life, depending on the conveyor length and material handled, will generally range from 10 - 15 years. To replace long conveyors splicing one or two rolls into a conveyor run on an intermittent basis can be prolonged in an operating system involving considerable downtime and scheduling problems. This paper presents some of the methods used to- date and highlights forward planning for such an event. Special belt handling equipment required and the execution of a belt change operation are described in detail. Wright Engineers Limited have worked in collaboration with Canada Conveyor to design and implement the methods described herein.

Jan 1, 1993

By Michel Grenier, Gopal Kunchur, Stephen Hardcastle

This paper presents the findings of a dust study in a typical fluorspar processing plant. The primary purpose of this study was to identify employees and occupational groups exposed to high dust levels and determine compliance with personnel regulations for regular and extended work shifts. The range of airborne concentration of respirable silica and fluoride compounds in specific areas and on personnel was determined. State of the art dust monitoring equipment and tracer gas techniques were used to measure dust concentration, pinpoint dust sources and map major airflow trends in the mill. Results of the survey indicated silica dust concentrations in excess of permissible limits being produced mainly by crushers at the south end of the building. Tracer gas releases and gas chromatographic analysis further showed that prevailing south to north air currents tended to carry and spread dust produced by the crushing operations throughout the process plant. Airborne concentrations of fluoride compounds measured during the study were always well below the prescribed threshold limit value (TLV) for the contaminant. Recommendations, including a mechanical exhaust ventilation system on crushers and transfer points, scheduled preventive maintenance on existing bar sprays and wearing of personal protective equipment were made which significantly improved the work environment. Further testing conducted after Installation of the dust extraction system revealed significant improvements in most areas of the mill.

Jan 1, 1991

By P. R. Shivdasan, R. D. Hagni

Cathodoluminescence microscopy (CLM) is uniquely applicable to the study of carbonatite-related fluorspar ore deposits. The mineralogy of the carbonatites, sodic and potassic fenites, marbles, quartzites and fluorite ores are readily determined and characterized. Calcite, dolomite, apatite and fluorite were deposited dominantly under high-temperature conditions, and they exhibit strong cathodoluminescence (CL). At the Okorusu, Namibia, carbonatite complex and fluorspar mines, three types of carbonatites have been recognized by field mapping and laboratory CLM. The main carbonatite intrusion is fine grained and consists mainly of calcite. A later phase of pegmatitic carbonatite consists of calcite, magnetite, Fe-rich pyroxene, apatite and pyrochlore. Pyroxene carbonatites were recognized mainly through their study by CLM.

Jan 1, 2002

By Peter A. Burger

The Greenvale Orebody comprises a series of contiguous lateriteprofiles developed terrace-like during the Cainozoic over a serpentinized harzburgite intrusive emplaced within Proterozoic schists. Each terrace displays individual characteristics of metal distribution. Topographically higher (older) profiles have been partially eroded and metal concentrations reworked. Within the laterite profile, metals have been concentrated or depleted according to their relative solubilities. At tropical temperatures, acidic meteoric waters have progressively depleted the ultrabasic parent rock of Si and Mg, leaving A1 and Fe to form a surface duricrust. Ni, Co, Mn and Cr have accumulated in the lower and middle levels of the weathering mantle. Only Ni and Co have accumulated to exploitable grades. Lateritization has evidently proceeded over a considerable portion of the Cainozoic and may be still continuing.

Jan 1, 1979

By K. G. Sutterer, P. T. Wang, R. Sweigard

One possible alternative for the disposal of flue gas desulfurization (FGD) by-products is to use it as backfilling support material in highwall mine adits. The finite element method was used to analyze the variation in stresses and displacements within and around a highwall adit backfilled with FGD materials. The engineering properties of the rock material and the optimum mix of the FGD materials were obtained from laboratory tests. Finite element analyses show that, for the case in question, the roof displacement would decrease about 48% and the peak stress could be decreased by about 58%. The study indicates that fairly weak FGD materials can eventually lead to the stability of backfilled highwall adits.

Jan 1, 1998

By J. D. Miller, J. Hupka

Environmental applications of the air-sparged hydrocyclone (ASH) technology are presented. The original ASH design used porous sintered steel or porous polyethylene tubes as spargers. To diminish/prevent plugging and to reduce pressure head loss in the gas path a wire screen sparger and new hydrocyclone design have been developed, which allows for wide application of the technology to solve environmental problems and to be used as a chemical reactor. Field and laboratory trials have shown that the ASH technology might be preferred for the stripping of volatile organic compounds WOC) from contaminated water. The ASH has also been developed for absorption of SO2, toluene vapors, and for the recovery of cyanide.

Jan 1, 2005

By R. Simon

Strain-burst phenomena are generally characterised by sudden releases of energy in a volume of highly stressed rock. Strain bursts are encountered in situations such as crown pillar bursts during cut-and-fill mining, face bursts at development headings cord floor bursts in deep shaft sinking. This paper describes a simple two-dimensional linear elastic FE modeling approach that leads to the calculation of the energy-release rate (ERR) and the total energy storage rate (TESR) in the rock-mass around the openings. The merits of using such energy parameters in the analysis of strain-burst problems for identifying areas of high energy release/storage are discussed through a case stud v. However, much site-specific back analyses are needed to better understand how strain bursts and energy parameters are interrelated.

Jan 1, 1999