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By D. R. Nagaraj

Adsorption of sulfide collectors such as xanthate on pyrite has been studied extensively over several decades using a wide variety of techniques. In spite of this, there are unanswered questions as to the identity of adsorbed species on pyrite surfaces -dixanthogen vs. iron xanthate complexes. Far less is known in non-xanthate collector systems. We have used Secondary Ion Mass Spectroscopy (SIMS) successfully in the past to obtain direct evidence for the identity of the adsorbed collector species on copper sulfides, galena and Cu-activated quartz. The present study is an extension of the SIMS analysis to investigate the adsorption of xanthate, dithiovhosphate, dithiocarbamate, and modified thionocarbamates and thioureas on pyrite. Adsorption of these collectors on chalcocite was also studied for comparison. An attempt was also made to obtain SIMS spectra for pure dixanthogens at room temperature. Only in the case of dithiocarbamate (DTC) was there direct evidence for the presence of not only the collector dimer, but also iron-DTC complexes. On chalcocite, only the copper-DTC complexes were detected (no dimer). In the case of xanthate, the collector molecular ion and its S adduct -which are possible fragments from dixanthogen -were detected on pyrite, along with a fragment peak: suggesting Fe2X. For dithiophosphate, the collector molecular ion and Fe(DTP)(OH) complex were detected (no dimer). For modified thionocarbamate and thiourea, adsorption on pyrite was negligible.

Jan 1, 1997

By C. S. Caldwell, L. C. Thompson

Mine closure and reclamation issues have evolved over the past several years becoming further complicated by stricter standards and by the cmrent economic climate and price of gold. Many mine permits are calling for more stringent remediation of spent ore heaps and tailings. Leachate solution water quality must meet strict discharge criteria for multiple parameters besides cyanide at mine closure. Closure standards are more difficult to meet and most mines do not have an increased budget at the end of mine life to deal with the falling standards. These issues make additional gold recove1y at the end of mine life a critical problem in financing some closure operations. Another issue is the length of time that must be budgeted for heap rinsing operations. Innovative biological processes developed and applied by Pintail Systems, Inc. at numerous mine closures have indicated that bio-processes can significantly enhance gold recovery dur­ing heap cyanide bio-detox over the recoveries expected from rinse operations. If heap rinsing can be eliminated or reduced and if gold recovery can be improved at the end of mine life, many mine closures may be possible with processes that pay for themselves or generate profit. Additional advantages of the bio­detox technology is that it can be engineered to treat multiple contaminants besides Weak Acid Dissociable (WAD) cyanide. Other contaminants treated in heap process solutions include nitrates, ammonia, heavy metals, thiocyanate and total cyanide. At the Cripple Creek and Victor Mining Company Ironclad Mine near Victor, CO, 5 million tons ofrinsed, heap leached spent ore were biologically detoxified to reduce cyanide content, enhance gold recovery during bio-detox and to reduce dissolved metals in heap leachate solutions. During the bio-detox treatment period a substantial improvement in gold recovery allowed the detox oper­ation to operate as a profit center. Final gold recovery was at least twice what was expected from a normal rinse operation.

Jan 1, 1998

By Richard M. Crowell, John W. Shield, Todd J. Harvey

Facing lower gold prices, gold mine operators throughout the world are seeking ways to reduce costs for treating refractory sulfide ores. Many gold mines, currently producing oxide ores, have underlying refractory sulfide deposits and the operators could extend the mine life by processing these sulfides. Fortunately, oxidation technologies for refractory ores need not be complex nor costly. GeoBiotics, Inc. has developed heap biooxidation technologies (GEOCOAT™) for treatment of refractory gold ores and concentrates. GEOCOATTM uses simple low cost unit operations common to heap leaching of gold and copper ores. The cost effectiveness and flexibility of GEOCOAT™ heap biooxidation allows mining companies to expand operations to include refract01y ore. In addition, GEOCOAT™ can be utilized to supplement or replace existing oxidation processes such as roasting, autoclaving, or agitated tank biooxidation, and to treat a lower resource grade than is currently economic. The GEOCOAT™ technology involves coating sulfide concentrates onto sized support rocks and biooxidizing the sulfides in a heap configuration. After biooxidation the concentrate is stripped from the support rock, neutralized and leached in conventional cyanidation facilities. Ashanti Goldfields Company Ltd. (AGC) produces over 885,000 ounces of gold per year from oxide and refractory ores at its Obuasi operations in Ghana. Refractory flotation concentrates are treated in roasters and in the world's largest stirred tank biooxidation facility. In August 1998, AGC and GeoBiotics jointly constructed and operated a field demonstration heap of the GEOCOATTM process at the Obuasi operations. The heap contained I 082 tonnes of support rock and 125 tonnes of concentrate. The heap was approximately 19 meters square at the base and 3.8 meters high, and ran for 88 days after which the concentrate was reclaimed. Average gold recovery after biooxidation was 91.5% with a NaCN consumption of 8.6 kg/t. Baseline gold recovery by direct cyanidation of the concentrate was 53.8%.

Jan 1, 1999

By V. Price

Abstract: Action of certain strains of bacteria has been implicated as a significant factor in the oxidation of ore deposits. Other bacteria are thought to be significant in the formation of syngenetic sedimentary ores and in supergene enrichment processes. A normal soil/ground-water regime provides all of the necessary pH and Eh conditions for several groups of bacteria which influence the sulfur cycle in nature. Limiting concentrations of nutrients such as sulfate ions can determine whether a particular microbial species is active at a given place. In the present study, ground water was analyzed from a mineralized area and from a presumed barren area. Trace metal content of the ground water gave no well defined clue as to the presence of a sulfide ore deposit. Sulfide producing bacteria (presumably sulfate users) were found in water from about 50% of wells sampled in the mineralized area and in about 30% of samples from the barren area. These bacteria are readily detected and may provide a useful tool for regional geochemical recon-naissance. Bacterially produced sulfide ions can remove metals such as copper and zinc from solution thus complicating the interpretation of hydrogeochemical prospecting.

Jan 1, 1972

Dravo Corporation was founded in 1891 and has long been recognized as a major domestic engineering and construction firm headquartered in Pittsburgh. In 1977, Dravo had revenue of $852.2 million with international business activities contributing $248 million; quite a different picture than envisioned at the turn of the century. Engineering and construction activities still dominate Dravo's most recent history and will do so for the immediate future. However, fluctuations in capital spending by large industrial sectors of our economy during the late sixties were affecting Dravo's planning for continued growth along its traditional lines of business. Diversification was a possible solution to smooth out the upward trend in corporate earnings. One large result of these continuing efforts was the formation of Dravo Lime Company, a vertically integrated, proprietary chemical supplier for the air pollution control market. Briefly retracing the seventies, the passage of the Federal "Clean Air Act" in 1970 supplied the impetus for Dravo Lime Company. This law promulgated limits on the emissions of sulfur dioxide (SO2) from large stationary sources that would affect local air quality. The major industry that felt the brunt of this regulation was the electric utility industry, especially those generating electricity with coal-fired boilers. The law hastened the development of a new industry, flue gas desulfurization (FGD), and is composed of three major segments: (1) the electric utility, (2) the FGD equipment suppliers (the scrubbing modules), and (3) the scrubbing chemical suppliers. Dravo's experience suggested the equipment end of the business but market analysis indicated that our long range corporate goals could be better attained by investigating the chemical processes involved in the removal of the SO, gas. The result being Dravo Lime Company. This paper will briefly describe the Thiosorbic lime scrubbing process and review our innovative mine and calcining facility.

Jan 1, 1978

By Mark Kuchta

A new database application for long term production scheduling has been developed for LKAB's Kiruna mine. The scheduler uses a new block data structure whereby the monthly production data for three raw ore products are predetermined on a month-by-month basis for each production area that could be mined within the schedule time horizon. The production schedule is created by assigning the starting dates to the each production area subject to various mining operational constraints such that that the monthly deviations for the production targets are minimized. The system is well integrated into the mine's overall computerized mine planning system.

Jan 1, 2002

The 6th International Mine Ventilation Congress (IMVC) was held May 17-22,1997, in Pittsburgh, PA. This marked the second time that the IMVC was held in the United States. The first congress, organized in 1975 by the Mine Ventilation Society of South Africa, was held in Johannesburg. Since then, the meetings have been held every four or five years, with the 1979 meeting being held in Reno, NV. This was followed by Harrogot, England, in 1984; Brisbane, Australia, in 1988; and Johannesburg, South Africa, again in 1992. The IMVC provides an international forum in the field of mine ventilation for the purpose of sharing technology and experience. The meetings are attended by ventilation engineers, academics, consultants, government employees and vendors interested in mine ventilation. As was evident from this meeting, significant progress has been made in the field of mine ventilation. However, disasters continue to occur around the world and long-term health problems continue to affect workers. So there is a need for further improvements in ventilation technology. The highlight of the conference was the technical sessions in which more than 80 papers were presented by authors from more than 20 countries. In addition to the technical sessions, the conference featured field trips to a number of mine properties throughout the United States. Five short courses were offered on topics ranging from respirable-dust control to mine fires and explosions. The conference also featured a trade show. It exhibited the latest advances in ventilation equipment, computer application software, consulting and engineering services, and health and safety equipment.

Jan 1, 1997

By K. H. McDaniel

This paper describes the development of a Windows-based interactive mine ventilation simulation software program at the Waste Isolation Pilot Plant (WIPP). To enhance the operation of the underground ventilation system, Westinghouse Electric Corp. developed a program called WIPPVENT. While WIPPVENT includes most of the functions of the commercially available simulation program VNETPC from Mine Ventilation Services Inc. and uses the same subroutine to calculate airflow distributions, the user interface was completely rewritten as a Windows application with screen graphics. WIPPVENT is designed to interact with WIPP ventilation-monitoring systems through the sitewide central monitoring system. Data (e.g., air quantity and differential pressure) can be continuously collected from the underground ventilation remote-monitoring and control system and from the mine's weather stations (psychrometric data). Furthermore, WIPPVENT incorporates regulator characteristic curves specific to the site. The program utilizes this data to create and continuously update a real-time ventilation model. This paper discusses the design, the key features and the interactive capabilities of WIPPVENT.

Jan 1, 1997

Ceremonies for the induction of four mining industry pioneers into the National Mining Hall of Fame will be held Saturday, Sept. 11, 2010 at the Charles F. Barber Pavilion of the Museum Convention Center in Leadville, CO. The 23rd Annual National Mining Hall of Fame and Museum Banquet will begin with an open house and reception at 5:30 p.m., followed by the dinner and program at 7 p.m. The four inductees are: William Wheeler Coleman who served 46 years, from 1911 to 1957, as president and chairman of the company that is now Bucyrus International of South Milwaukee, WI, a world leader in the manufacture of surface and underground mining equipment. Dr. Allen Van Heyl, Jr., an economic geologist who served with the U.S. Geological Survey for nearly 50 years beginning in 1943. He studied more of the nation?s mineral deposits than most could begin to imagine. Arthur Lakes contributed enormously to the geological and mining sciences in the western United States as a geologist, teacher, writer and artist over a period of more than four decades beginning in 1869. The Arthur Lakes Library at the Colorado School of Mines, Golden, CO, is named for him. Samuel Calvin McLanahan, through his inventive genius, changed the direction of his family?s company from that of a foundry to a leading manufacturer of minerals processing equipment to become today?s McLanahan

Jul 1, 2010

By M. S. Celik

Salt-type minerals are usually floated with anionic and cationic collectors. Flotation of a number of systems has been reported to remarkably increase above the concentrations where surface precipitation of collector-metal salt is initiated. Some studies attribute this phenomenon to heterocoagulation of oppositely charged collector colloid and mineral particles. In this study, examples are given on boron minerals to demonstrate that the high flotation region occurs when particles, colloidal precipitates and bubbles acquire a similar charge which induces Van der Waals interactions resulting in hydrophobic bonding.

Jan 1, 1995

By D. R. Lanners

Samples of the same coal measure overburden spoil were obtained from three different mine sites. Site A used a 27-m3 tub-mounted dragline, Site S used a front-end loader and truck combination, and Site C used a 6-m3 crawler-mounted dragline. The spoils were analyzed in the laboratory for the strength parameters using drained triaxial tests conducted on 150-mm diameter specimens. Regression analysis was utilized to determine the appropriate failure criterion for the strength data from each site. Spoil obtained from Site S yielded higher shear strengths than Sites A and C.

Jan 1, 1993

By V. G. Hill

The term bauxite was first used by O.P.A.P. Dufrenoy in 1845 for an ore which was discovered by Pierre Berthier in 1821 near the village of Les Beaux de Provence near Arles in southern France. His data suggested that this mineral was an alumina hydrate with two molecules of water. However, it was subsequently shown by thermal analysis that the mineral was a fortuitous mixture of the mono-hydrate and the tri-hydrate. Diaspore had been previously discovered in 1801 and gibbsite in 1822. The term was however retained as a rock name. The name of the village was changed to Les Baux around 1885; Sainte Claire Deville suggested that the mineral name should reflect this, and it was changed to bauxite (Bracewell, 1962, Rkgnier, 1988). Mining of bauxite began around 1860 in the Auriol region in the Bouches du Rhine area in the south of France. This ore was transported toMarseilles by carts and was processed in the Salindres plant, which at that time was the only plant producing alumina using the Deville process and aluminum by the chemical process. During that period white bauxite (low iron content) was particularly sought after for the production of aluminum sulfate, refractory bricks, and quick setting cement. Export of bauxite from France began in 1880 and was initially delivered to Chemische Fabrik, Goldschmischen near Breslau, and to Guilini's Ludwigshafen plant in Germany in 1885. These companies produced alum and aluminum sulfate (RCg- nier, 1988). The next bauxite mining operation was in Antrim County in Northern Ireland in 1873. This was first used for the manufacture of alumina refractory bricks and quick setting cement (Bracewell, 1962). It is important to emphasize that initially almost all of the bauxite which was produced came from France and was mainly used for non-metallurgical purposes. At that time even the production of alumina was mainly for use as a mordant in textile dying. However, with the development of the Hall-Héroult process, the alumina which was available was increasingly used for smelting to aluminum. In spite of this the demand for non-metallurgical bauxite continued to increase and a set of applications were developed. These include refractories, abrasives (including the recently developed proppants), high alumina cements, aluminum chemicals, activated bauxite, and alumina. It became increasingly evident that the high alumina-low alkali raw materials have special advantages. The question however was one of cost benefit. Chin (1989) has pointed out that the non-metallurgical operations have been traditionally grafted on a bauxite/alumina/aluminum industry tree. In this context the non-metallurgical alumina produced was, with few exceptions, regarded as either coproduct or byproduct i.e.: Bauxite Trunk Sector Alumina Trunk Sector Aluminum Trunk Sector

Jan 1, 1994

By M. Robson

Water & Earth Technologies, Inc. (WET), Habitat Management, Inc. (HMI) and Chevron Mining, Inc. (CMI) together developed a solution for reclaiming steep southwest facing slopes in mining Area 12C that have historically been prone to excessive erosion, low vegetation establishment and continuing maintenance. Area 12C is located in the east wing of the Chevron McKinley Coal Mine, 27 miles northwest of Gallup, New Mexico, on Navajo Nation land administered by the Office of Surface Mining (OSM). Mining in this area was completed in May of 2007. Challenges encountered for this reclamation project included the need to reclaim graded material on a slope of 18-35% with southwest facing aspect, the presence of undisturbed rock outcropping that needed to be avoided during reclamation, the operational need to limit bulldozer pushes and the inability to import or export additional materials for construction. Two different reclamation alternatives were considered for Area 12C. The first alternative would use a traditional reclamation approach including three levels of draining terraces designed to convey water on a 3% slope to a single riprapped down drain. Terracing and down drains have been used to reclaim areas with similar terrain conditions elsewhere at the McKinely Mine and have failed to adequately control erosion (Williamson 2006). Terrace overtopping and down drain blowouts have been issues in maintenance and functionality for the mine. Maintenance routines consist of cleaning out terraces where they have filled in with sediment and repairing damaged or blown out terraces and down drains.

Jan 1, 2010

By H. Ban

Triboelectrostatic separation tests were performed on a bench-scale, analytical separator using coal, coal combustion fly ash and mineral samples. Fractions of separated samples were collected and analyzed to characterize the performance of the separation. Particle size distribution and morphological characteristics for these samples were analyzed by optical microscopy, and scanning electron microscopy (SEM). It was found that smaller size fractions of a fly ash sample had better separation than the full sized parent fly ash sample, indicating interference or particle-particle interactions during the separation process. It was also observed experimentally that small kaolin particles attach to the surface of large silica spheres, causing charge neutralization and subsequent low separation efficiency.

Jan 1, 1997

By A. D. Davis

This project took a watershed approach in the evaluation of water-quality impacts from past mining activities and current restoration projects in the Bear Butte Creek basin, a small and well defined drainage in a heavily mineralized area of the northern Black Hills. The basin contains numerous inactive and abandoned mines as well as a currently active heap-leach surface gold mine. Bear Butte Creek normally loses all of its discharge to sinkholes in the Madison Limestone aquifer and thus can affect the water quality of this regionally important water resource. Water-quality data were analyzed, stream surveys were conducted, and two abandoned mine restoration projects were monitored to evaluate the effectiveness of the watershed approach and to identify practical remediation techniques that could be applied to other watersheds. A geographic information system (GIS) was developed to organize information on stream quality, abandoned mine locations, and other geologic and hydrologic data. The watershed approach toward assessing and reclaiming abandoned mines appears to be effective when compared to a point-source approach that might improve water quality at specific sites but not result in significant overall improvement to the watershed because of adjacent sources.

Jan 1, 1997

By J. P. Wilson

The Tessenderlo-Kerley Leach process has been shown to be effective in the removal of residual copper from molybdenite concentrates. Concentrates of varying mineralogy, including those containing relatively large amounts of chalcopyrite, have been successfully leached on laboratory and pilot plant scales. The lixiviant system is ammonia and ammonium bisulfite with air / oxygen addition. An abrasive is added which greatly enhances the kinetics, and it is subsequently screened out and reused. The dissolved copper is easily recovered using existing technology. Extraction profiles, reagent consumptions, and mineralogical data are presented.

Jan 1, 1999

By T. V. Falkie

REMARKS OF DR. THOMAS V. FALKIE, DIRECTOR, BUREAU OF MINES, U.S. DEPARTMENT OF THE INTERIOR, BEFORE THE FALL MEETING OF THE SOCIETY OF MINING ENGINEERS, AIME, ACAPULCO, MEXICO, SEPTEMBER 23, 1974 This is a time of uncertainty on the world mineral scene. For some of the world's so-called "developed" countries, reserves and production of key minerals are running low. And, we have learned that the energy so essential in recovering and processing minerals can suddenly be in short supply. The prospects for a "no growth" situation in energy or mineral consumption are practically nil. Moreover, the world's economy is in flux, casting doubt on whether traditional mineral customers will continue to be able to buy, or for that matter, whether traditional suppliers of minerals will continue to sell. It is clear that the mineral situation is contributing to world inflationary pressures, which incidentally are most damaging to developing countries. So it is appropriate that SME members devote this session to the world mineral situation, and consider some of the opportunities and responsibilities that we will inevitably encounter as the future becomes the present. The opportunities, to me at least, are especially intriguing, I have the good fortune to be part of an organization that has an enormous capability and responsibility for dealing with mineral problems. The Interior Department's Bureaus, including the Bureau of Mines, have been around for a long time. They are. a prolific and reliable source of both mineral information and mineral technology.

Jan 1, 1974

By B. A. Slaker, T. Miller

"An underground limestone mine in eastern Ohio was experiencing significant floor heave and roof falls, attributed to high horizontal stresses. Areas of the mine showing floor heave were monitored with roof-to-floor extensometers and photogrammetry surveys, to determine the rate and magnitude of heave. Extensometer data were recorded hourly at four locations across adjacent entries while photogrammetry surveys of the floor were performed at the same locations every two to five weeks. A final survey was performed using an I-Site 8200 laser scanner. Following instrumentation, floor heave up to 10.1 cm (4 in) was measured by the extensometers, photogrammetric reconstructions, and laser scanner over a 6-month period. The extensometers were biased by the location where they were placed, failing to consistently capture the location and extent of floor heave and cracking. The photogrammetry surveys were not precise enough to capture small magnitude movements. Mining in the area was halted and within several months the floor movement and incidence of roof falls was significantly lessened. INTRODUCTION Limestone formations in the United States can be subject to relatively high horizontal stresses due to the presence of tectonic loading of the strata. Horizontal stresses have a documented history of causing stability issues in underground limestone mines. Kuhnhein and Ramer (2004) discussed the influence of horizontal stress on complex ground control interactions associated with limestone pillar design and mine layouts. Esterhuizen et al. (2008) documented roof damage observations associated with high horizontal stresses such has roof guttering, beam instability, oval-shaped falls, and failure propagations. There have also been a number of documented case histories of horizontal stress causing unexpected roof and pillar failures at shallow depths (Stacey and Yathavan, 2003). To the knowledge of the authors, there has only been one well-documented case of floor failure causing stability issues in an underground limestone mine. Murphy et al. (2015) documented the role that a weak, moisture-sensitive floor had in the development of a massive roof collapse. For this paper, the study site neighbored, and was in the same general geology of, the site in Murphy et al. (2015). However, the weak, moisture-sensitive floor was not present for the current study. The current study site has experienced significant floor instabilities caused by high horizontal stresses. The instability area was monitored using two different methods to determine if the floor failure would eventually propagate into roof or pillar failure. The objective of this paper is to analyze displacement monitoring measurements from string potentiometers and remote sensing techniques in an area experiencing active movement. Based on the measurement trends and observed damage from inside of the mine, the presumed failure process will be discussed."

Jan 1, 2017

By D. E. Munson, H. J. Sutherland

Empirical methods for describing the shape of the subsidence trough over coal mines in Europe are tested against field measurements of subsidence over longwall panels in the United States. The graphical methods developed by the National Coal Board in the United Kingdom do not correlate well with the U.S. measurements; however, the profile functions typically used on the Continent give quite acceptable fits to the data. In the case of two longwall panels mined at Old Ben No. 24 in Illinois, a trigonometric profile function appears the best choice; in the case of two longwall panels mined at York Canyon in New Mexico, an error integral function is somewhat superior. Analyses of subsidence development curves show that rate effects occur. A comparison of fitting parameters establish influence functions as an important methodology for future analysis. In conjunction with the evaluation of empirical methods, an analytic model based on material failure and bulking was developed. A key element of the model is the void-volume distribution function which establishes a mechanism for transfer of significant amounts of the mined volume to the surface. Preliminary calculations demonstrate the features of the model and illustrate close correlation to physical observations in the field. Moreover, centrifuge models simulating the subsidence process have been used successfully to demonstrate the dominant or key failure modes necessary to the analytic model. General features of the centrifuge simulations and model calculations correlate well.

Jan 1, 1982

By Jerrold J. Marcus

United states reserves of oil and gas have been steadily declining while consumption of petroleum products has continued to increase. The nut result has been an ever increasing shortfall between supply and demand. This imbalance has been made up by imports of both oil and gas causing a strain on the United States Balance of Payments. To complicate the situation further, exporting nations have recently formed a cartel and dramatically increased the selling price of petroleum products. To meet U.S. energy demand, increased attention has been drawn to the production of synthetic oil and gas from coal. To date, considerable research has been conducted and is continuing on various processes for liquefaction and gasification of coal. Some of these processes are now in the pilot plant stage and at least one demonstration plant has been proposed. The coal conversion complexes envisioned will be very large, requiring substantial capital investments and abundant reserves of coal. Coal production to feed these proposed complexes has been estimated on the order of 75,000 tons per day. With the viability of these projects becoming economically attractive, the Office of Coal Research initiated a contract with Fluor Utah to determine and define the problems of surface mining coal at very high mining rates, under varied physical, geographic, and climatic conditions. The flow of recent events in the Middle East has created a greater sense of urgency for this study.

Jan 1, 1975