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By Manoj Khandelwal, Minghui Liu, Jian Zhou, Kun Du

The waste rock and tailings backfill into the mined-out areas are the most effective method for solving the environmental pollution and surface disasters for nonferrous metals mines. In practice, the success and availability of backfill operations are dependent on the slurry fluidity and the strength properties of cement backfill. The transport of the slurry through the pipeline to the designated backfilling area relies on its eximious flow properties, while the appropriate strength of the filling body ensures the safe operation of the stope. In this paper, the effects of cement and aggregate types on the slurry fluidity and strength characteristics of cemented backfill are studied in detail, which are often ignored in other pieces of literature. Diffusivity is used as an indicator to evaluate the slurry fluidity. Various slurries whose concentrations ranging from 70%, 73%, 75%, 78%, and 80% are made with different aggregate ratios and cement-sand ratios are tested. It has been shown that slurry fluidity is inversely related to its concentration, but 78% is the “stopping point” for the deterioration of fluidity. The addition of rod-milled sand improves or worsens the cemented backfill (CB) strength depending on the amount of rob-milled sand. The uniaxial compression experiment results on 216 CB specimens produced by different combinations of influencing variables showed that CB specimens made from cement with superior mechanical properties have a higher uniaxial compressive strength (σucs). It has been also found that the effect of aggregate ratio on the CB strength is not singular, but works in conjunction with the curing time and the cement-sand ratio. The longer the curing time and the higher the cement content, the higher the CB’s σucs. To avoid the time-consuming and costly problem of obtaining the strength of the CB from indoor experiments, an SVR model capable of predicting the uniaxial compression strength of CB specimens is proposed, which is optimized by genetic algorithm (GA) and particle swarm optimization (PSO) algorithm. The results of the three performance indexes (MAPE, MSE, and R2) show the superior performance of the GA-SVR and PSO-SVR models and the agreement of the predicted results with the experimental results, which indicate that these two models can accurately predict the σucs of CB.

Feb 3, 2022

By H. Colin

The basic industry, such as mining, ferrous and non-ferrous, cement and aggregates, stores and handles millions of tons of raw materials, re- quiring often different types of storage, blending and reclaiming systems.

Jan 1, 1980

By William A. Vogely, Robert T. Deacon, Walter J. Mead

Oil and gas together are the most important energy sources consumed in the United States. In 1983, 67% of total energy consumption was represented by these two resources (43% was oil and 25% natural gas), while coal accounted for only 23% of U.S. energy use. All other sources (hydroelectric, nuclear, geothermal, wood and other waste products) accounted for only 10% (U.S. Department of Energy, 1983, p. 1). In this chapter we address the issue of regulation in the oil and natural gas sectors of the U.S. energy industry. In addition, we analyze the cartel characteristics of the Organization of Petroleum Exporting Countries (OPEC). If OPEC is an effective cartel, then U.S. oil as well as substitute energy prices, production, and consumption will be affected by cartel action. Further, as the nation learned in the 1970s, major changes in oil prices produced major disturbances in other sectors of the U.S. and world economies. Consequently, it is important to determine whether the roughly ten-fold increase in nominal prices that occurred in the 1970s was the result of cartel action, the result of normal economic forces adjusting to the fact that the world was running out of cheap oil, or some combination of the two. Furthermore, the presence of OPEC- associated oil price increases is related to regulations that were imposed on the energy sector during the decade of the 70s. THE RATIONALE FOR GOVERNMENT INTERVENTION Economists have traditionally judged the state of an economy to be efficient if it is impossible to improve the welfare of any one member of society without harming someone else. Any economy that satisfies this condition is said to be Pareto efficient, after the Italian economist Vilfredo Pareto who first gave rigorous attention to such questions (see Chapter 4.10). It is easy to see why an economy that fails to satisfy this condition could not be efficient; by definition, it would be possible to alter the allocation of resources in a way that improves everyone's welfare.' Much of the appeal of this weak efficiency criterion is that it avoids comparisons of levels of well being among different individuals. The cost of such generality, however, is that in any given economic system a wide array of different Pareto efficient states will typically be attainable. In the simple Robinson Cursoe economy of the undergraduate textbook, for example, efficiency could just as easily be attained in the case where most of the island's resources are owned by Friday as in the case where they are under Crusoe's control. However, the distribution of welfare among the two inhabitants would obviously be quite different in the two situations. Such equity issues cannot be settled on objective or scientific grounds. To decide which distribution of welfare is socially "best" an explicit value judgment is needed. It is useful to keep in mind the preceding distinction between efficiency and equity issues when analyzing the role of government in a market economy. Decentralized market processes will not necessarily result in a distribution of welfare that society considers just. For this reason a potential role for government lies in the redistribution of income among individuals. In some circumstances, however, market pro-

Jan 1, 1985

By Neel Gupta, Brijes Mishra

Coal mining activity disturbs the natural equilibrium of in situ stress state such that the induced stresses deform the surrounding rock mass. Although the installation of roof supports typically prevents rock deformation, rock mass failure may still occur in bolted roof. The erratic failure of rock mass after few days to months and years of excavation is the result of time-dependent deformation of roof rock under constant surrounding stresses. In the current research, the triaxial laboratory creep experiments proved that Marcellus shale exhibits time-dependent deformation under constant stress that was smaller than the failure strength. However, unlike conventional experimental results, the time-dependent deformation did not depend on the level of constant stress. The often-neglected initial state of specimens and intrinsic heterogeneity highly influenced the time-dependent failure of Marcellus shale.

Jul 27, 2021

By Jr. Pitts

Elevation of surface charge density on colloidal particles in the presence of a high potential electrostatic field is demonstrated as a viable technique for preventing the accumulation of solids in solvent extraction circuits. The effect of the technique is manifest by relative turbidity measurements between pregnant leach solution and raffinate, by changes in the character of the sludge accumulations, by alteration of the zeta potential of particulates, and by a general reduction in the mass of solids.

Jan 1, 1992

By M. Karmis

The determination of the surface area which may be impacted by underground mining is an important consideration in subsidence engineering. A number of parameters have been utilized to identify this influence area, most notably the angles of draw and break. This paper discusses the implications of selecting an appropriate "damage angle" for defining a potential damage area due to mining, within which surface structures may be impacted Furthermore, the influence of both mining and geological factors, such as mining width and depth and overburden lithology, on this angle is examined, using the Surface Deformation Prediction System (S.D.P.S) software. Finally, recommendations are given for applying these concepts in subsidence control.

Jan 1, 1994

By George Vranesh

Synfuels development in the upper Colorado River basin and the population growth attendant with such development demand sizeable quantities of water. Unfortunately, the water supply in the basin is limited and such limitation may impose a significant constraint on the development of the West's abundant energy resources. Although the water for the synfuels development will be governed by the law of prior appropriation adopted in the upper basin states, the authors point out that an apparently senior water right .my not deliver a firm supply of water. The federal and Indian Reserved Water Rights Doctrine, the Colorado River Compacts the Doctrine of Equitable Apportionment, and the federal and state environmental laws can all severely diminish the value of any given water right and the synfuels industry should take care to evaluate these factors in acquiring its water.

Jan 1, 1981

By P. T. Bissert, L. Yan, J. R. Srednicki, J. A. Yonkey

"Refuge alternatives (RAs) are required in underground coal mines to support life post-disaster. RAs are mandated by MSHA to maintain an apparent temperature (AT) at or below 95°F (35°C) while providing a safe and livable shelter for a minimum of 96 hours. Because strata composition and mine temperatures will affect the final AT within an occupied RA, NIOSH researchers have collaborated with five underground coal mines across the US to characterize the effects of geographic location and seasonal temperature fluctuations on mine air temperature, relative humidity, and mine strata temperatures. The data collected indicates that some mines will experience greater temperature fluctuations than others, based on geographic location. The mine which demonstrated the greatest temperature differential over the course of the year resulted in a mine air temperature that ranged from 53.4°F (11.9°C) to 84.2°F (29.0°C) and a rib surface temperature that ranged from 55.4°F (13.0°C) to 82.8°F (28.2°C). This data suggests that the location and seasonal peak temperature can significantly affect the mine strata temperature, which could lead to a fully occupied RA exceeding the 95°F (35°C) AT limit over the course of 96 hours. The data reported in this paper could be used to examine the heat buildup inside an RA for actual mine conditions. Thermal simulations could be implemented to evaluate maximum occupancy ratings based on actual mine temperatures and strata compositions. INTRODUCTION In the event of a mine disaster, miners’ primary focus is to escape. Should their attempt be futile, they can enter a refuge alternative (RA) to await rescue. In 2008, the Mine Safety and Health Administration (MSHA) mandated that underground coal mines implement RAs within 1,000 ft (304.8 m) of the working face and spaced within one-hour travel distances in outby areas where persons work such that persons in outby areas are never more than than a 30-minute travel distance from an RA or safe exit. These RAs are required to provide a safe and habitable shelter for a minimum of 96 hours and to prevent the apparent temperature (AT) from exceeding 95°F (35°C) [1]. There is concern throughout the industry that in some cases the internal ambient of occupied RAs may exceed the 95°F (35°C) AT limit due to the potentially hot mine atmosphere as well as the metabolic heat generated by RA occupants and the carbon dioxide scrubbing system. The National Institute for Occupational Safety and Health (NIOSH) has conducted tests in its Safety Research Coal Mine (SRCM) and its Experimental Mine (EM) to investigate heat buildup in RAs. It was found that the number of occupants in an RA may need to be reduced based on the ambient mine temperature, which varies from mine to mine [2]. Further testing and analyses were completed to evaluate the mechanisms (conduction, convection, radiation) by which heat is transferred from an RA to the mine surroundings. Additionally, the effects of varying mine strata compositions on the heat buildup inside an RA were studied [3]. The mine strata temperatures will increase due to heat transfer from within an RA. Depending on the mine strata composition, some mines may be more thermally conductive than others. For example, sandstone is much more conductive than shale or coal (i.e. it disippates heat at a quicker rate). All things being equal, the air temperature inside of an RA after 96 hours will be higher for a mine with strata that has low thermal conductivity compared to a mine with high thermal conductivity."

Jan 1, 2017

By Luther W. Hyde

Ground water, one of Florida's most valuable resources, is also one of its most abundant. The State is fortunate to have several prolific ground- water reservoirs that yield tremendous quantities of water to wells and to some of the world's largest springs. These ground-water reservoirs, or aquifers are of two types artesian and nonarteaian. Ad artesian aquifer is one that contains water under sufficient pressure to rise above the top of the oontaining formation. A nonartesian aquifer is one that contains water which is not confined, and the upper water surface (water table) is free to rise and fall. The principal source of ground water in Florida is the artesian Floridan aquifer which supplies most of the water users in the State. Nonartesian sources include the Biscayne aquifer of southeastern Florida, the sand-and-gravel aquifer of extreme western Florida, and a shallow aquifer which lies at depths of less than 100 feet over much of the State. The accompanying map shows the approximate areas where these aquifers are the main source of supply; however, the boundaries do not represent the areal extents of the aquifers. For example, the Floridan aquifer extends beyond the southern boundary shown on the map, but it is not of great economic significance there because the water is highly mineralized. Aquifers other than the four described occur in the State, but they are, for the most part, of minor significance. One of these is an artesian aquifer which is formed by permeable zones that occur locally within the confining beds above the Floridan aquifer.

Jan 1, 1966

By GRANT COLLIGAN, BROCK O’KELLEY, Corby Anderson

With the world’s ever-expanding push to expand technological capabilities, the need for specialized materials including rare earth elements has exploded. One source found in the USA is bastnaesite, a rare earth bearing fluorocarbonate mineral, currently mined at the Mountain Pass Mine in California. To increase production, it is essential to optimize existing processes and create new ones to better utilize current resources. Therefore, a US Department of Energy Critical Materials Institute sponsored research program was carried out at the Kroll Institute for Extractive Metallurgy to expand the fundamental understanding of the industrial bastnaesite concentrate leaching system. With the help of prior knowledge, thermodynamic calculations and design of experimentation based lab testing, a novel single-stage hydrochloric leach system was created to optimize the rare earth extraction from bastnaesite. Historically, the existing industrial process has utilized a two-stage leach system involving a high-temperature hydrochloric acid leach with liquid solid separations followed by a caustic crack stage of the leach residues. A series of single-stage leach experiments were run by reacting locked cycle flotation concentrates with hydrochloric acid to test common leaching parameters. The results of these patent pending single-stage tests have shown rare earth recoveries significantly higher than reported recoveries of historic two-stage caustic crack processes, all while decreasing the equipment required and the type and amount of reagents needed.

Jan 31, 2022

By David X. Zhang

This paper describes the results of using shear flocculation and flotation known as aggregative flotation technique for the enrichment of coal-derived char produced from mild gasification process. Aggregative flotation is a separation process which involves the use of suitable aggregating liquid under the action of high shear forces to render hydrophobic surface of coal-derived char particles to aggregate in an aqueous slurry. The fine carbonaceous particles are aggregated into larger floes while the impurities remain hydrophilic. In subsequent flotation process, the char aggregates are then separated from mineral matters by aeration in the flotation cell. The floatability of char aggregates and removal of mineral matters from chars are studied in a lab scale flotation column cell. The effect of various operating parameters on the aggregative flotation responses is presented. Emulsification of aggregating liquid using high intensity agitation and ultrasonic energy provides excellent aggregating liquid dispersion and increases selectivity for char aggregation. In subsequent flotation process, it results in significantly increasing the flotation rate of char aggregates. The microscopic examinations of bubble attachment to coal-derived char particles under various aggregating liquid dispersion levels were conducted by induction time measurement. The distributions of hydrophobicity of char particles and char aggregates prepared under various aggregating liquid dispersion techniques were measured by film flotation. The char particles prepared under high intensity emulsification attach at significantly faster rates to air bubble and with lower mean critical wetting surface tension than that of char with direct aggregating liquid addition. An interrelationship of increasing in flotation rate/combustible recovery with decreasing in induction time, mean critical wetting surface tension and dispersion of hydrophobicity on the char particles and char aggregates were obtained.

Jan 1, 1992

By M. Abdelkhalek, M. Hepworth, D. Tao, B. K. Parekh

Pre-combustion coal cleaning and post-combustion flue gas desulfurization (FGD) using lime or limestone are the primary methods employed to reduce sulfur dioxide (SO2) emission from coal combustion. These processes generate voluminous pyrite and gypsum solid wastes that are usually landfilled, occupying thousands of acres of land and creating serious land and water pollution problems due to the release of acids and toxic substances. An integrated process has been developed for the combined utilization of gypsum and pyrite wastes by converting them into useful products including lime, sulfur, and direct reduced iron (DRI). The process includes four major steps. The first step is to concentrate pyrite from coal preparation tailings using flotation or gravity separation. The second is the thermal decomposition of pyrite into pyrrhotite and sulfur. This is followed by the reduction of pyrrhotite with carbon in the presence of lime to produce iron and calcium sulfide. The fourth step involves the reaction of calcium sulfide with gypsum to produce lime. The chemical reactions involved in the process were studied using thermogravimetric analysis (TGA) and X-ray diffraction (XRD)techniques. Process variables studied included reaction temperature, time, reactant composition, and purity of reactants.

Jan 1, 2000

By Kent von Maubeuge, Charles R. Landis

The global bentonite industry is a dynamic market balancing a range of end uses with an ever growing number of bentonite producers. In addition, markets in developed countries are elevating the level of detail and transparency for materials reporting in programs, such as the Registration, Evaluation, Authorization and restrictions of Chemicals (REACH) program in the European Union. Bentonite is impacted by programs of this nature. The majority of the bentonite products sold around the world are sodium bentonites. These sodium bentonites consist either of natural sodium bentonites, or naturally occurring bentonite dominated by divalent interlayer cations (Ca+2 andMg+2) subsequently exchanged with sodium cation. The latter variety is often called “sodium-activated“, or “soda-ash treated” bentonite. Once exchanged with sodium, these bentonites are often difficult to distinguish from natural sodium bentonites using common commercial testing protocols. Due to their similar colloidal and bulk chemical properties; the lack of test procedures designed specifically to identify this product feature; and the failure to completely or effectively explain their differences, sodium-activated bentonite is often considered to be identical to natural sodium bentonite in the industry. This article defines both general types of sodium bentonite and presents a technique that could serve the industry as a tool to confirm the variety of sodium bentonite in question. Specifically, geochemical properties such as carbon (C13/C12) and oxygen (O18/O16) isotopic ratios can distinguish activated, even slightly activated bentonites, from bentonites not introduced to additional sodium during manufacture.

Jan 1, 2004

By Barbara C. Williams

U.S. Bureau of Mines researchers conducted field studies at an abandoned copper-gold mine tailings impoundment. Pore water quality was analyzed in the vadose and saturated zones. Three statistical procedures were employed to summarize the variability within and between the two zones. The results indicated that linear combinations of those variables reflecting sulfide oxidation and aluminum-silicate weathering best summarized the variability in each zone, and that the zones were most different on the basis of sulfide oxidation variables. The geochemical computer code WATEQ4F was used to assess the solubility status (saturation index) of minerals. Saturation indices of sulfide oxidation and aluminum-silicate weathering minerals were different in the two zones. It was demonstrated that the statistical analyses produced similar and complementary results to the geochemical code.

Jan 1, 1992

By T. Klemetti

Moisture deterioration of clay-rich roof rocks causes high numbers of roof falls in coal mines in humid summer months. Rocks with high moisture content are generally weaker and can further deteriorate when subjected to wetting and drying cycles. As a result, it is important to evaluate the moisture-sensitivity of roof rock prior to mining. The National Institute for Occupational Safety and Health (NIOSH) has evaluated three moisture-sensitivity index tests on roof rocks from 23 U.S. coal mines. The three tests were the University of Kentucky Weatherability test (Weatherability test), the Consol Energy Water Sensitivity test (Water Sensitivity test), and the NIOSH Immersion test (Immersion test). Of these three tests, the Weatherability and Water Sensitivity tests are more reliable in classifying the moisture-sensitivity of roof rocks. Disclaimer: The findings and conclusions in this report have not been formally disseminated by the National Institute for Occupational Safety and Health and should not be construed to represent any agency determination or policy.

Jan 1, 2009

By R. J. Lee

Asbestos analysis is conceptually simple. The objective, in most environmental analyses, is to determine the number of asbestos fibers per unit area or volume in a sample. The sample may be a consumer product, an ambient air sample, or a water sample. This determination is complicated by several factors including sample collection and preparation, counting techniques, and the operational definition of asbestos in use. Three different definitions have been used in the study of environmental samples; these are summarized in Table 1. [ ]

Jan 1, 1979

By William C. Peters

The frustration encountered by exploration crews in connection with land acquisition could be graphed to show a correlation with the natural law that everything tends to become more so. Figure I shows a rather common, situation. The combinations of ingredients are almost limitless and the resulting brew is often poisonous to an exploration man. A single step, that of taking a series of deep soil samples is often delayed until some sense can be made from "floating" unpatented claims which are obscure in orientation as well as position, placer claims overlapping lode claims, location posts with empty Prince Albert cans, and claims with no apparent assessment work for ten years. Add to this some patented claims with¬out monuments, a state or federal withdrawal area which may or may not invalidate pre-existing claims, a loosely defined tunnel site, and some ranchers who understandably resent the separation of surface rights from mineral rights. The picture is familiar to exploration men. One approach to such problems is to ignore them until someone voices an objection -- but then an even more chaotic situation is likely to develop. Another practice is to stake new claims to cover all ground that is "open" at first glance and then find out if there are conflicts so that the new claims can be adjusted accordingly.

Jan 1, 1970

By C. Beul, R. Schipper, L. Santisteban

The Garfield Mine is a legacy vanadium mine in western Colorado with multiple mine openings, waste rock piles, and adit seepages that Cyprus Climax Metals Company (a Freeport-McMoRan Inc. subsidiary) voluntarily remediated through the Colorado Voluntary Cleanup Program (VCUP). The process to obtain a No Further Action determination from the VCUP is presented. Water treatment of the adit discharge, which is not part of the VCUP, is also presented. The remedial action objectives (RAOs) included preventing direct human or biotic exposure to the waste rock and radiation emitting from the waste rock; reducing metal concentrations and radionuclide activities in adit discharge and keeping the discharge from leaving the site; maintaining the existing undeveloped character of the surrounding landscape; and eliminating the need for a stormwater permit. The design included regrading, installation of an infiltration barrier and rock cover, a diversion channel, and a biologically based passive remediation water treatment system. An initial lab-scale evaluation provided design criteria for the full-scale system, which consists of a sulfate-reducing biochemical reactor and post-treatment aerobic polishing cells. The system has been operational since construction was completed in late 2016. Results indicate that the treatment objective of 90% bulk removal of constituents of potential concern (COPCs) is largely being met. The system also provides year-round operation and non-point discharge of effluent. After 20 plus years of site investigations, the remedial action was completed in 2016 with all RAOs met and a No Further Action determination granted in 2018. INTRODUCTION The Garfield Mine is a legacy vanadium mine located approximately 11 miles north-northeast of Rifle, in Garfield County, Colorado. It was leased and operated intermittently from 1929 to 1975 but was never operated by Cyprus Climax Metals Company (Cyprus) (a Freeport-McMoRan Inc. subsidiary). Prior to reclamation, site features included: • six mine openings—five adits and a vertical opening; • two adits discharging mining-influenced water (MIW)— Adit 1 at less than 4 liters per minute (L/min) and Adit 2 at 7 to 10 L/min; • main waste rock pile (13,500 m3) and small waste rock pile (minimal volume); • debris (small structure, mattress, bottles, shells, etc.) indicating site used for recreational purposes; and, • unimproved road, which has been used to access forest fires.

Jan 1, 2019

By K. T. Brashear

Since the MINER Act of 2006, the minimum static load of in-situ underground mine seals has been increased from 20-psi to either 50-psi if monitoring is conducted or 120-psi if left unmonitored. These minimum strength requirements in seals must be designed, built, and maintained throughout the lifetime of the seal. Due to this, it has become necessary to assess the effectiveness of non-destructive testing (NDT) technologies to determine seal integrity, which in this case, are explored using sonic waves and tracer gases. Through both small and large scale testing, two NDT methods will be evaluated for their abilities to determine integrity of the seal. A sonic wave technique to observe a change in wave velocity to identify faults within the seal material. As a NDT method, tracer gases may be used as a potential indicator of a connection between both sides of the seal material through a series of faults and cracks within the material itself. This paper reviews the history of underground mine seals and discusses the overall assessment of sonic waves and tracer gases to serve as NDT methods for estimating the integrity of these seals.

Feb 23, 2014

By D. Mohapatra

Extraction of Al(III) from aqueous sulfuric acid solutions into organic Cyanex 272®-carbon tetrachloride systems was investigated from a multi-component mixture containing aluminum, cobalt and nickel. Al(III) extraction efficiency was quantitative with 1.0 M Cyanex 272® in two stages at an aqueous: organic (A:O) phase ratio of 1:1 and an equilibrium pH of 3.2. The stripping of Al(III) from the loaded organic (LO) with different acids indicated sulfuric acid to be the best stripping agent. More than 99% stripping of Al(III) from the LO was achieved using 2 M H2SO4 at an A:O phase ratio of 1:1 in a single stage. The stoichiometry of the extracted species of Al(III) was determined by the slope analysis method. The extraction reaction proceeded via the cation exchange mechanism and the extracted species was assumed to be AlA3?3HA, where HA refers to the dimeric and A the anionic form of the extractant, Cyanex 272®. The extraction of Al(III) was studied in the presence of various ions to ascertain the tolerance limit of individual ions.

Jan 1, 2008