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By J. Brent Hiskey

INTRODUCTION Metal electrodeposition processes are of fundamental technological importance to a number of fields. Electrorefining, electrowinning, electroplating, and electrogalvanizing have all been the subject of intense study for over a century. More recently, electrochem- ical deposition has played a critical role in advances in microelectronics and lately has been an enabling technology for the production of certain nanostructured materials. Electrometallurgists have most frequently been concerned with the structure and morphology of massive deposits. For example, in metal recovery steps such as electrorefining and electrowinning, deposits demonstrating adherent coarse-grained characteristics are most desirable. In the case of electroplating, a bright fine-grained, tenacious and strongly adherent deposit is required. The fabrication of microelectronic devices and the production of nanoscale structures such as nanoparticles, nanowires, and nanorods requires a keen understanding of early stage deposition effects. The initial stages of metal deposition, usually referred to as electroclystallization, are fundamentally linked to nucleation and growth phenomena. Early stage deposits are typically very ordered. Whereas, bulk metal deposition structures are much more ran- dom. In both cases, the discharge of a metal ion at an electrified interface is represented by simple cathodic reduction as follows: [ ] Me(H2O)xn[ ] is a hydrated metal ion residing in the bulk solution and Me is the metal atom occupying a crystallographic lattice position. A similar reduction reaction can be

Jan 1, 2005

By Qiang Ji, Richard L. Sanford

A laboratory-scale microcomputer-based autonomous excavation system has been developed that moves a pile of fragmented rock to a designated location using a shovel attachment on a robot arm. Navigation and excavation sub- systems interactively direct a robot excavator to move the shovel to the rock pile, intelligently load its bucket using a video camera, and dump the rocks to a designated area. Although research was conducted on a laboratory scale model, the system can serve as the basis for further work on a full-scale, robust excavation system.

Jan 1, 1993

By Karl E. Elers

The term "potash" denotes a family of minerals and compounds of potassium, containing greatly varying percentages of that element. In commercial usage, most of the potash products are used in agriculture, where they are used to furnish potassium, one of the three basic elements for plant growth; the other two being nitrogen and phosphorus. Potassium's contribution to plant life is principally as a stalk strengthener, and if soils can no longer supply this basic element, then crop failure is inevitable without nutrition supplied from fertilization. While agriculture uses some 95 per cent of the potash produced, other industries require highly refined potash, for the manufacture of soaps, dyes, pharmaceuticals, synthetic rubber, insecticides, photographic film, and other products. Until the mid-nineteenth century, world agriculture had three options related to the potash content of soils: 1) crop rotation and pasturing to attempt to minimize the loss of potash in harvesting, 2) abandoning depleted and exhausted soils (part of the reason for the vast migration of populations in Europe and Asia), and 3) burning forests for the use of the ashes, and concentrating the nutritional value by boiling the ashes in large kettles, for "pot - ash". With the discovery in the mid 1800's and exploitation of potash from underground deposits in Germany, the beginning of the modern potash industry was established, but American potash requirements remained substantially dependent on German production until the 1920's, when oil drilling in the Permian Basin of New Mexico

Jan 1, 1972

By M. D. Chatham

Revolutionary electronic monitoring and control systems provide a gold mine of diagnostic and prognostic information. Lower cost per ton results from timely operator action, increased visibility of information to production and maintenance personnel, and better fleet management. When information is effectively integrated into fleet management systems lower costs result from higher availability, longer component life and reduced repair cost. This paper will present the objectives of the Caterpillar Vital Information Management System (VIMS) and provide actual examples of successful use.

Jan 1, 1995

By C. H. Bucknam

An interlaboratory testing program was undertaken in support of an ASTM standardization program for simultaneous combustion-infrared analysis for carbon and sulfur in ores and related materials. Statistical analysis results from the study are used to generate the within-laboratory and between-laboratory precision data needed for standardization of the methods. The interlaboratory precision statistics are also interpreted to estimate the uncertainty in calculation of net carbonate value classifications using a simplified quantitative risk analysis technique.

Jan 1, 1998

By C. R. Everly

"The purpose of this paper is to review the most effective methods of reducing chloride transfer and chloride removal in the solution extraction and electrowinning (SX/EW) process. Elevated chlorides in electrolyte have various negative effects including a reduction in current efficiency, increased handling costs at rod plants and smelters, increased anode corrosion, cobalt losses due to increased electrolyte bleed, degradation of HDPE piping, and increased corrosion in the SX/EW plants. Historical controls that Sierrita has used to control chloride transfer, in order of effectiveness, have been chloride gasification at the EW that is directly correlated to amperage and chloride concentration in electrolyte, wash stage bleed and efficiency, width and velocity of aqueous bands, and electrolyte bleeds. Maintaining high bleed rates and high amperage settings has been a challenge with decreasing pregnant leach solution (PLS) grades, so keeping chlorides out of the electrolyte has become imperative. The effectiveness of reducing aqueous entrainment, optimizing wash stage efficiencies, and improving organic quality to reduce the transfer of chlorides to the electrolyte are illustrated in this study. INTRODUCTION The transfer of impurities from PLS feed streams to electrolyte in the Copper Solution Extraction process is a very common problem and is the reason that the wash stage exists in most SX operations. The main impurities affecting the SX process are iron, chloride, nitrate, and manganese. Elevated chlorides in the electrolyte have various negative effects including reduced current efficiency, increased handling costs at rod plants and smelters, increased anode corrosion, increased cobalt losses due to increased electrolyte bleed, degradation of HDPE piping, and increased corrosion in the SX/EW plants. Freeport-McMoRan Sierrita Hydromet is unique in that a high-chloride byproduct stream from the molybdenum process is pumped into the SX raffinate solution pond. This byproduct steam accounts for the majority of chloride introduced to the circuit, and over the years has built up to a point where 4000ppm chloride is consistently in the PLS feed to the SX. Concentrations of chloride over 70 ppm in electrolyte will result in downgraded cathode, so it is important to limit chloride carryover from SX as much as possible. Historically, Sierrita has been able to manage chloride levels with reactive techniques including increasing electrolyte bleeds and rectifier amps. Decreasing copper in PLS has made high amps harder to maintain, and increasing bleed rates have a direct impact on production goals."

Jan 1, 2015

By Rimas Pakalnis, Lyndon Clark, Tom Brady

A major focus of ground control research presently being conducted by the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) is to incorporate data on weak rock masses into existing design relationships, with an emphasis on updating the span design curve for manned entries and the overbreak curve for longhole entries. Both curves were originally developed at the University of British Columbia, Vancouver, BC. The original database has been augmented by information from mines throughout the United States, Canada, Australia, and Europe. The common factor in all these mines is the presence of a weak back and/or walls. In most cases, the ore zone is the weakest rock unit and must be stabilized so that the mineral-bearing rock can be extracted safety. The current NIOSH research attempts to provide rock mechanics tools to assist a mine operator in making economic decisions that will also ensure a safe working environment. This paper documents the Nevada database with a special emphasis on Nevada underground gold mines.

Jan 1, 2005

Various computer packages are now available for balancing data obtained from complex concentration plants. It is well established that the filtered data generated by these programs are statistically better than the raw data. However the degree of improvement as well as the accuracy of the estimated variables depend strongly on the propagation of measurement errors through the estimation algorithm. Therefore, for the subsequent use of the filtered data, their confidence intervals are as important as the data themselves. Variance of filtered variables have been derived in a very general way for any arbitrary flowsheet and when data originate from various sources such as flowrates, chemical assays, particle size distributions and pulp percentages of solids. The theoretical formulae are incorporated in the BILMAT package for mass balance calculation and illustrated on various flowsheets involving grinding, classification and flotation. The validity of the proposed method is discussed by a comparison to a Monte Carlo approach, for a simple processing circuit.

Jan 1, 1986

By A. C. Burrow, R. P. King

A dynamic model that predicts the variation of carbon content with time in the argon-oxygen decarburization (AOD) process has been developed. The model recognizes three distinct zones in the AOD vessel: the tuyere region in which the blown oxygen reacts very rapidly with the metal components in the molten alloy; a region in which bubbles of inert gas and oxide drop lets rise through the molten alloy; and a zone in which the slag layer can interact with the molten alloy. The process is dynamically controlled by the rate at which dissolved oxygen, produced on the surface of rising oxide droplets, and dissolved carbon diffuse through the molten alloy to react at the surface of the rising bubbles. The rate at which carbon and oxygen react on the bubble surface is assumed to be intrinsically very fast. Predicted decarburization rates compare reasonably well with rates measured in the AOD vessel at Middleburg Steel and Alloys. The model has been developed primarily to allow development of a time-optimal blowing stategy for the AOD vessel.

Jan 1, 1990

By A. M. Gaudin

At the 1971 Annual Meeting we presented a paper on the results s obtained by wet magnetic separation on very fine, slightly magnetic material . Considerable interest was shown in a corollary subject, namely; on the type of magnetic con¬struction of the Magnetic Engineering Associates (MEA) high-intensity magnetic separator (HIMS). it is the purpose of this paper to describe the principles of this separator and to give answers to many of the questions directed at us both in session and privately since the March 1971 meeting of the AIME. It is well-known that passage of a direct electric current through a wire shaped in the form of a loop results in a magnetic field being created in the volume enclosed within the loop. The magnetic field is proportional to the amperes of electric current passing through the wire. If the wire is in the form of a solenoid consisting of 11 turns, the magnetic field is n times larger. Hence the expression ampere-turns commonly associated with magnetic separators. If a particle, free to rotate and of higher magnetic susceptibility than the medium, is placed in a magnetic field, it will orient itself within that field, and it will move within the field in such a way as to go into a more intense part of the field. The traction on the particle is proportional to its inherent magnetic property which depends on its magnetic susceptibility and its volume, to the mag¬nitude of the field at the spot where the particle is situated, and to the magnitude of the field gradient at that spot. Of the three factors that control traction on a particle in a magnetic field, the magnet designer can effectively control two, the magnetic field and the field gradient. In a wet magnetic separator such as the HIMS magnetic separator, there is another force exerting traction on the particle, and that is the force of the fluid (liquid) on the particle. It is, therefore, essential to examine the relationship of the fluid to the magnetic field. First, assume the water in which magnetic and non-magnetic particles are suspended to be stagnant. In the absence of magnetic field, the only forces acting on the particles are those due to gravitation on the particles and on the fluid displaced. This is the subject, so important in gravity concentration, discussed in elementary texts of mineral engineering'.

Jan 1, 1972

By Y. J. Wang

This paper describes a procedure for solving the generalized system of n network equations in n unknowns considering the following ventilation variables and parameters: (a) air quantities, (b) pressure losses or gains caused by the control devices (i.e., fans or regulators), (c) resistance factors, (d) natural ventilation pressure, and (e) fan pressures (as a function of air quantities). The air quantities and pressure losses for all branches in the network are grouped into dependent and independent variables. The branches with an independent quantity are contained in a chord set, and the branches with a dependent pressure loss are contained in a chord set. In addition to the problem formulation, the solution procedure, applying the Newton method, is discussed and illustrated with a numerical example.

Jan 1, 1989

By S. Behl, S. Mathur

The viability of physico-chemical purification methods such as selective, flocculation for the separation of two components having similar chemical compositions and the same crystal structure but different surface properties is demonstrated. A loss of selectivity was observed in a dolomite-dolomite mixture when polyethylene oxide (PEO) (five million molecular weight) was used us the flocculant. Heteroflocculation was minimized using a low molecular weight PEO (MW =105) as a site blocking agent (SBA). Near complete separation was achieved at pH 10.5 at the 100% recovery level

Jan 1, 1996

By Alain Broussaud, Guy Fourniguet, Jacques Franck, Pierre Conil

Steady-state simulation is now in current use to assist mineral processing plant design and optimization. However, the reliability of results generated by simulators has not until now been seriously investigated. A simulator supervision algorithm was designed and programmed to study both the influence of the reliability of experimental data on the accuracy of unit operation model calibration, and the influence of unit operation model accuracy on the results of direct plant simulations. An application to a grinding flotation plant is described and discussed. The approach may open the way to the quantitative analysis of the risks taken in mineral processing projects, which would be similar to the application of geostatistics to mining projects.

Jan 1, 1990

By O. A. Paulson, D. D. Runnells, D. P. Dupon, K. J. Bruxvoort

Background groundwater quality is often used to drive remediation programs at sites with waters that have been affected by mining activities. In the past, these levels were sometimes chosen without rigorous statistical and geochemical analysis. A probability-distribution approach was used at the Sweetwater Uranium Project to separate a large set of geochemical data into populations that represent contribu¬tions from different sources. Natural background populations were identified for major ions, metals and radionuclides, and these were submitted to the US Nuclear Regulatory Commis¬sion (NRC) to modify the extent of a corrective-action pro¬gram and to establish control limits for future monitoring.

Jan 1, 2000

By Eric K. Albert

The permit generation and review process represents both a time consuming and expensive task for industry and government alike. Changes in regulations and in review procedures cause additional delays. This leads to potentially higher costs of doing business and the extension of time for a project to lie started. This paper describes the motivation and methodology of applying an expert system to function in the role of a permit reviewer. The problems of representing the knowledge of the reviewer and regulatory criteria are illustrated. Futhermore, the selection method for the expert system shell is addressed. Finally, a sample review is demonstrated to show the results of applying this artificial intelligence method to the process of permit review.

Jan 1, 1989

By Alex Harrison, K. Payne

Computer generated magnetic field reference signa- tures of steel cord belt splices are used to evaluate lay-up and fabrication irregularities of splices in operating conveyors. Used as a quality inspection tool, magnetic signature analysis is useful in auditing data collected by general non-destructive testing (NDT) consultants. The evaluation can detect irregularities that weaken a splice, as well as detecting signature changes that can be indicative of adhesion loss. The evaluation can be applied to any NDT data available from a variety of commercial sources, which means that independent review of critical splice data is possible.

Jan 1, 1996

By Ernest K. Yanful, Paul H. Simms

The lysimeter is a useful tool for evaluating the performance of mine waste covers or liners. A major problem with its application is the possibility for preferential flow into or away from the lysimeter, if the lysimeter soil is finer or coarser than the barrier soil or sub-base soil. Analysis of a field lysimeter using a two-dimensional unsaturated-saturated liquid flow model suggested that preferential flow would occur and little or no water would be collected; however, in the field, the lysimeters collected significant amounts of water. A similar discrepancy was found between the observed and predicted water balance of a simple laboratory test simulating the lysimeter design. Vapour flow and partial flow, two phenomena not generally simulated in conventional flow models, are possible explanations for the difference between field and laboratory observations.

Jan 1, 2000

By Markku Virtanen, Pertti Koivistoinen

From the perspective of a large mining company the comminution circuit design is worth keeping within the boundaries of the organisation. The correct circuit design begins from the understanding of the role of grinding. Grinding is a link only in the long "comminution chain," starting from solid rock and ending at the concentrating stage. The final target in comminution is to take a part in the maximization of Net Smelter Return, which goal provides the simultaneous considering of capital costs, operating costs and the economic effect of process results. As a general rule there will be a single crushing stage only, ahead of the grinding process. Grinding does not use any metallic grinding media at all, and there will be fine crushing for critical material in the grinding circuit. Grinding has a minimum two stages, besides, at many concentrators middling products and quite often also tailings are reground.

Jan 1, 1997

By M. K. Patel, K. C. Wade, M. Cross

In the past decade a good deal of effort has gone into the computer simulation of the heat distribution of pellet induration systems. The major uncertainty in the analysis of such systems is the gas flow distribution and, in particular, the role of leakage. Evaluation of the leakage into or out of a zone has proved to be very difficult, as has the cross-flow from one zone to another when adjoining zones have gas flows which change direction from up draft to down draft for example. This paper describes an initial model to calculate the gas flow distribution in a variety of practical situations of interest to those involved in pellet induration. The model is based upon a multiphase CFD code called CASCADE which is used in conjunction with the pellet induration simulation INDSYS.

Jan 1, 1990

By Hitch M.

Many mining wastes, especially those from the metal mining industry, have traditionally been treated as a matter of little or no value and in practice a cost burden. Some wastes, due to their reactivity characteristics, have emergent values that go beyond purely economic and into the environmentally beneficial realm. This paper discusses the changing paradigm of mine waste management. Such fundamental parameters such as cut off grade, and strip ratio, are positively impacted by the revaluation of waste rock material. Mine rock waste can now be seen as a commodity of value, similar to the underlying ore being mined and influences the economic performance of suitable projects. This valuable material can be used for industrial purposes including acid neutralization as well as the capture and long-term disposal of anthropogenic carbon dioxide. The Turnagain Nickel project, located in northern British Columbia serves as an example of how waste rock material can become an important matrix for carbon capture and sequestration and can benefit economically from it. By producing material that has emergent economic value as well as carbon capture and sequestration capabilities, the sequestration matrix producer is a beneficiary of new carbon credits that have a market value and is looked upon favourably by regulatory authorities and affected stakeholders.

Jan 1, 2010